CN106894295B - A kind of Multifunctional clothing drop and preparation method thereof - Google Patents

A kind of Multifunctional clothing drop and preparation method thereof Download PDF

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Publication number
CN106894295B
CN106894295B CN201510951398.1A CN201510951398A CN106894295B CN 106894295 B CN106894295 B CN 106894295B CN 201510951398 A CN201510951398 A CN 201510951398A CN 106894295 B CN106894295 B CN 106894295B
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China
Prior art keywords
parts
drop
slurry
matrix
agent
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CN106894295A (en
Inventor
张斌
王本刚
赵颖辉
王文辉
邱建涛
康有国
朱敏杰
刘培省
习冉
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Shanghai Sml Co
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Shanghai Sml Co
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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/005Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02Material of vegetable origin
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/10Retention agents or drainage improvers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2519/00Labels, badges
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0282Forms or constructions for textiles, e.g. clothing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Theoretical Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Printing Methods (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of Multifunctional clothing drops and preparation method thereof, drop for clothing of the present invention itself has anti-fake, water is smeared on drop, drop can change colour, without additionally increasing false proof device, it is cost-effective, the ink font of drop for clothing, after meeting water, font color changes, and further increases anti-fake effect, have the function of to remove clothes peculiar smell, drying, dehumidifying, inhibition bacterium etc., it is used for a long time as products such as drier, eliminating smell agent, moisture-proof indicator after being bought with clothes, reduces the wasting of resources, meet the market demand.

Description

A kind of Multifunctional clothing drop and preparation method thereof
Technical field
The present invention relates to a kind of drop for clothing, and more specifically, it relates to a kind of Multifunctional clothing drop and its preparation sides Method.
Background technology
Drop for clothing includes information (such as price, bar code recognition, manufacturer's information in relation to retail item or other commodity Deng) information labels or Sticker be commonly referred to as drop, clothes manufacture when can all hang with various drops, such as the clothes quality certification Drop, clothes material, washing points for attention drop etc., some criminals are also in the personation drop for constantly copying high emulation It adulterates, reaps staggering profits, this undoubtedly brings prodigious challenge to the making of Anti-counterfeiting tag, how to allow Anti-counterfeiting tag can Antiforge function is really played, and clothes can be eliminated in process of production since there are special smells for dyestuff etc., promotes brand Image;Clothes are easy to grow bacterium in wet environment, and drop currently on the market, which has a single function, only has the function of information labels, It cannot be satisfied the market demand.
Invention content
In view of the deficiencies of the prior art, and provide a kind of drop for clothing itself has anti-fake, dry, function of odor removal to the present invention A kind of Multifunctional clothing drop and preparation method thereof.
A kind of Multifunctional clothing drop of the present invention, the drop for clothing are made of following quality proportioning component:
10-15 parts of activated carbon, 3-10 parts of anhydrous calcium chloride, 3-5 parts of polyacrylamide, 50-70 parts of wood-fibred, high score subtree 20-30 parts of fat, 0.7-2 parts of sansevieria trifasciata extracting solution, 1-5 parts of negative ion powder, 0.5-1 parts of perfume agent, 0.1-1 parts of color developing agent, desensitization 0.7-1.5 parts of agent, 1-10 parts of retention agent, 0.5-0.8 parts of colour former, 1-10 parts of bacteriostatic agent, 1-2 parts of foaming agent.
The activated carbon is that grain size is 400-500 mesh.
The retention agent is cationic polyacrylamide.
The grain size 100-200 mesh of the negative ion powder.
The color developing agent is selected from the mixing of phenolphthalein, methyl red, bromocresol green, methylene blue and wherein two or more Object.
A kind of preparation method of Multifunctional clothing drop, includes the following steps:
(1) by 10-15 parts of quality proportioning activated carbon, 3-10 parts of anhydrous calcium chloride, 3-5 parts of polyacrylamide, wood-fibred 50- 70 parts, 20-30 parts of macromolecule resin, 0.7-1.5 parts of desensitizer, 1-10 parts of retention agent, 0.5-0.8 parts of colour former, be mutually mixed Stirring is added in pulper and carries out slurrying, polishes to obtain using fiberizer and is formed uniformly slurry;
(2) 1-2 parts of foaming agents of foaming agent are added in slurry and stir 30-60s, slurry is put into the bulk machine of ultrasonic wave, Slurry, which gets angry to expand, forms uniformly tiny stomata, and it is for use that drop matrix A is made through online in slurry;
(3) step (1) slurry be added 0.7-2 parts of sansevieria trifasciata extracting solution, 1-5 parts of negative ion powder, 0.5-1 parts of perfume agent, It is for use that drop matrix B is made through online in 1-10 parts of bacteriostatic agent, 0.1-1 parts of color developing agent, slurry;
(4) drop matrix A and drop matrix B being put into heat-pressing compound machine, heat-pressing compound machine selects 100-140 DEG C of temperature, Method hot rolling is put into 250-280 DEG C of temperature drying in dryer and goes moisture, press polish molding that drop matrix is made;
(5) surfaces drop matrix A are covered with the ventilated membrane of 0.01-0.05mm thickness, be put into ventilated membrane in heat-pressing compound machine and Drop matrix compression moulding, drop is put into cutter, and installation dimension is sheared, punching;
(6) use printing machine on ventilated membrane surface printing, printing ink is as following formula:Gloss oil 16-18%, mute oil 4- 6%, anthocyanidin ink 16-19%, diluent 58-64%;The ink thickness of printing is 0.9-1.3 microns.
The beneficial effects of the invention are as follows:
(1) drop for clothing itself has anti-fake, water is smeared on drop, drop can change colour, without additionally increasing anti-camouflage It sets, it is cost-effective.
(2) the ink font of drop for clothing, after meeting water, font color changes, and further increases anti-fake effect.
(3) drop for clothing of the present invention has the function of to remove clothes peculiar smell, drying, dehumidifying, inhibition bacterium etc., can be purchased with clothes It is used for a long time as products such as drier, eliminating smell agent, moisture-proof indicator after buying, reduces the wasting of resources, meet the market demand.
Specific implementation mode
With reference to embodiment, present invention is further described in detail.
Embodiment 1
A kind of preparation method of Multifunctional clothing drop, includes the following steps:
(1) by 3 parts of 3 parts of 10 parts of activated carbon, anhydrous calcium chloride, polyacrylamide, the wood-fibred 50 of 500 mesh of quality proportioning Part, 20 parts of macromolecule resin, 0.7 part of desensitizer, 1 part of cationic polyacrylamide, 0.5 part of colour former are mutually mixed stirring and add Enter and carry out slurrying in pulper, polishes to obtain using fiberizer and be formed uniformly slurry;
(2) 2 parts of foaming agents of foaming agent are added in slurry and stir 30-60s, slurry is put into the bulk machine of ultrasonic wave, is expected Slurry, which gets angry to expand, forms uniformly tiny stomata, and it is for use that drop matrix A is made through online in slurry;
(3) slurry of step (1) be added 0.7 part of sansevieria trifasciata extracting solution, 200 mesh 0.5 part of 1 part of negative ion powder, perfume agent, It is for use that drop matrix B is made through online in 1 part of bacteriostatic agent, 0.1 part of phenolphthalein, slurry;
(4) drop matrix A and drop matrix B are put into heat-pressing compound machine, heat-pressing compound machine selects 100 DEG C of temperature, hot rolling It is compound, it is put into 250 DEG C of temperature dryings in dryer and goes moisture, press polish molding that drop matrix is made;
(5) surfaces drop matrix A are covered with the ventilated membrane of 0.01mm thickness, are put into ventilated membrane and drop base in heat-pressing compound machine Body compression moulding, drop is put into cutter, and installation dimension is sheared, punching;
(6) use printing machine on ventilated membrane surface printing, printing ink is as following formula:Gloss oil 18%, mute oily 6%, Anthocyanidin ink 18%, diluent 58%;The ink thickness of printing is 1.3 microns.
Embodiment 2
A kind of preparation method of Multifunctional clothing drop, includes the following steps:
(1) by 4 parts of 5 parts of 13 parts of activated carbon, anhydrous calcium chloride, polyacrylamide, the wood-fibred 60 of 400 mesh of quality proportioning Part, 25 parts of macromolecule resin, 1 part of desensitizer, 1 part of cationic polyacrylamide, 0.5 part of colour former are mutually mixed stirring and are added Slurrying is carried out in pulper, is polished to obtain using fiberizer and is formed uniformly slurry;
(2) 2 parts of foaming agents of foaming agent are added in slurry and stir 30-60s, slurry is put into the bulk machine of ultrasonic wave, is expected Slurry, which gets angry to expand, forms uniformly tiny stomata, and it is for use that drop matrix A is made through online in slurry;
(3) 1 part of 2 parts of negative ion powder, the perfume agent, antibacterial of 2 parts of sansevieria trifasciata extracting solution, 100 mesh is added in the slurry of step (1) It is for use that drop matrix B is made through online in 0.1 part of 1 part of agent, methyl red and methylene blue composition, slurry;
(4) drop matrix A and drop matrix B are put into heat-pressing compound machine, heat-pressing compound machine selects 140 DEG C of temperature, hot rolling It is compound, it is put into 280 DEG C of temperature dryings in dryer and goes moisture, press polish molding that drop matrix is made;
(5) surfaces drop matrix A are covered with the ventilated membrane of 0.01-0.05mm thickness, be put into ventilated membrane in heat-pressing compound machine and Drop matrix compression moulding, drop is put into cutter, and installation dimension is sheared, punching;
(6) use printing machine on ventilated membrane surface printing, printing ink is as following formula:Gloss oil 16%, mute oily 4%, Anthocyanidin ink 16%, diluent 64%;The ink thickness of printing is 0.9 micron.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (1)

1. a kind of preparation method of Multifunctional clothing drop, which is characterized in that include the following steps:
(1)By 10-15 parts of quality proportioning activated carbon, 3-10 parts of anhydrous calcium chloride, 3-5 parts of polyacrylamide, wood-fibred 50-70 Part, 20-30 parts of macromolecule resin, 0.7-1.5 parts of desensitizer, 1-10 parts of retention agent, 0.5-0.8 parts of colour former, are mutually mixed and stir It mixes to be added in pulper and carries out slurrying, polish to obtain using fiberizer and be formed uniformly slurry;
(2)1-2 parts of foaming agents are added in slurry and stir 30-60s, slurry are put into the bulk machine of ultrasonic wave, slurry is got angry swollen It is for use that drop matrix A is made through online at uniformly tiny stomata, slurry in bulging;
(3)Step(1)Slurry 0.7-2 parts of sansevieria trifasciata extracting solution, 1-5 parts of negative ion powder, 0.5-1 parts of perfume agent, antibacterial is added It is for use that drop matrix B is made through online in 1-10 parts of agent, 0.1-1 parts of color developing agent, slurry;
(4)Drop matrix A and drop matrix B are put into heat-pressing compound machine, heat-pressing compound machine selects 100-140 DEG C of temperature, hot rolling It is compound, it is put into 250-280 DEG C of temperature drying in dryer and goes moisture, press polish molding that drop matrix is made;
(5)The surfaces drop matrix A are covered with the ventilated membrane of 0.01-0.05mm thickness, are put into ventilated membrane and drop in heat-pressing compound machine Matrix compression moulding, drop is put into cutter, and installation dimension is sheared, punching;
(6)Using printing machine on ventilated membrane surface printing, printing ink is as following formula:Gloss oil 16-18%, mute oil 4-6%, Anthocyanidin ink 16-19%, diluent 58-64%;The ink thickness of printing is 0.9-1.3 microns.
CN201510951398.1A 2015-12-19 2015-12-19 A kind of Multifunctional clothing drop and preparation method thereof Active CN106894295B (en)

Priority Applications (1)

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CN106894295B true CN106894295B (en) 2018-08-31

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Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09274437A (en) * 1996-04-04 1997-10-21 Nippon Dam Kk Functional fabric label
CN201251891Y (en) * 2008-05-23 2009-06-03 本视力科技(香港)有限公司 Allochroic label
CN101581053B (en) * 2009-06-05 2011-07-27 山东凯丽特种纸股份有限公司 Method for producing anti-counterfeiting card paper with windowed security thread
CN202293713U (en) * 2011-09-22 2012-07-04 曹志雄 Multicolor thermosensitive paper
CN104401066B (en) * 2014-11-19 2016-06-29 东莞市枭森环保包装材料有限公司 A kind of environment friendly mildew resistant drop and preparation method thereof
CN204614350U (en) * 2015-04-08 2015-09-02 嘉兴市捷诚包装有限公司 A kind of drop for clothing

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