CN106884345A - A kind of printing and dyeing assistant containing sodium carboxymethylcellulose - Google Patents
A kind of printing and dyeing assistant containing sodium carboxymethylcellulose Download PDFInfo
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- CN106884345A CN106884345A CN201710145437.8A CN201710145437A CN106884345A CN 106884345 A CN106884345 A CN 106884345A CN 201710145437 A CN201710145437 A CN 201710145437A CN 106884345 A CN106884345 A CN 106884345A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65131—Compounds containing ether or acetal groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The present invention provides a kind of printing and dyeing assistant containing sodium carboxymethylcellulose, is made up of the raw material of following weight portion:The weight portion of guar gum 68, the weight portion of polyethylene glycol laurate 13 15, the weight portion of polyalkyl acrylate 8 10, the weight portion of sodium carboxymethylcellulose 12 13, the weight portion of dodecyl sodium sulfate 8 10, the weight portion of polyalkyl acrylate 78, the weight portion of octadecyl dimethyl benzyl ammonium chloride 9 10, the weight portion of fatty alcohol 67, the weight portion of oxirane 57, the weight portion of acetic acid 23, the weight portion of barium chloride 9 24;Compared with prior art, the present invention has following beneficial effect:Color fastness, color protection, fade-proof effect are improved with good, while the usage amount of dyestuff can be reduced, environmental protection is nontoxic, reduces cost, with extensive industrial prospect and market value.
Description
Technical field
The present invention is a kind of printing and dyeing assistant containing sodium carboxymethylcellulose, belongs to technical field of textile printing.
Background technology
Dyeing assistant is increasingly wider in industrial application, and occupies special and consequence.Currently on the market
Cloth can all be processed in preparation process by printing and dyeing, and the fabric of dyefastness difference encounters water, sweat stain, Exposure to Sunlight, saliva or thing
During reason friction, dyestuff easily comes off and fades, and influences attractive in appearance, and the dye molecule that comes off or heavy metal ion may be by skins
It is absorbed by the body and endangers health.The effect of dyeing is thus usually improved in printing and dyeing treatment using printing and dyeing assistant, increases color jail
Degree etc..
With the improvement of people ' s living standards, people see further important for own health, in order to meet people increasingly
Enhanced health care demand, environmental protection develops green dyeing as nontoxic as possible to human body and to ecological environmental nonpollution
Auxiliary agent is significant.Although existing various dyeing assistants in the prior art, its is hyperchromic, color protection performance is still not ideal enough.
But existing auxiliary agent is most of to be caused to stimulate to skin, and effect is relatively simple, when multi-effect is needed, it is necessary to add
Various auxiliary agents, cause cost increase, and the effect reduction that can print and dye.
The content of the invention
In view of the shortcomings of the prior art, helped it is an object of the present invention to provide a kind of printing and dyeing containing sodium carboxymethylcellulose
Agent, to solve the problems, such as to be proposed in above-mentioned background technology.
To achieve these goals, the present invention is to realize by the following technical solutions:One kind contains carboxymethylcellulose calcium
The printing and dyeing assistant of sodium, is made up of the raw material of following weight portion:Guar gum 6-8 weight portions, polyethylene glycol laurate 13-15 weight
Part, polyalkyl acrylate 8-10 weight portions, sodium carboxymethylcellulose 12-13 weight portions, dodecyl sodium sulfate 8-10 weight
Part, polyalkyl acrylate 7-8 weight portions, octadecyl dimethyl benzyl ammonium chloride 9-10 weight portions, fatty alcohol 6-7 weight
Part, oxirane 5-7 weight portions, acetic acid 2-3 weight portions, barium chloride 9-24 weight portions.
Further, it is raw material with natural guars, remaining endosperm fraction after removal epidermis and plumule, then xeraphium
Precipitated with 20% ethanol solution after broken and pressurized hydrolysis, centrifugation is reacted after drying with dehydration contracting glycerin ether trimethyl ammonia chloride ammonia,
The guar gum in raw material is obtained.
Further, using acidic catalyst, esterification is carried out with polyethylene glycol and laurate, it is poly- in prepared raw material
Ethylene glycol laurate.
Further, the carboxymethylcellulose calcium that will be obtained after native cellulose and caustic alkali and monochloroacetic acid reaction in raw material
Sodium.
Further, ethene and chlorine are passed through in water, generate ethylene chlorhydrin, it is then anti-with ethylene chlorhydrin with milk of lime
Should, the oxirane in generation raw material.
Further, the weight portion of guar gum 8 is contained in the raw material of every 100 weight portion, is contained in the raw material of every 100 weight portion
The weight portion of polyethylene glycol laurate 15, contains the weight portion of polyalkyl acrylate 10, every 100 in the raw material of every 100 weight portion
Contain the weight portion of sodium carboxymethylcellulose 12 in the raw material of weight portion, dodecyl sodium sulfonate is contained in the raw material of every 100 weight portion
The weight portion of sodium 10, contains the weight portion of polyalkyl acrylate 7 in the raw material of every 100 weight portion, contain in the raw material of every 100 weight portion
There is the weight portion of octadecyl dimethyl benzyl ammonium chloride 10, the weight portion of fatty alcohol 6, every 100 are contained in the raw material of every 100 weight portion
Contain the weight portion of oxirane 7 in the raw material of weight portion, the weight portion of acetic acid 2, every 100 weight are contained in the raw material of every 100 weight portion
Contain the weight portion of barium chloride 13 in the raw material of amount part.
Beneficial effects of the present invention:A kind of printing and dyeing assistant containing sodium carboxymethylcellulose of the invention, carries with good
High color fastness, color protection, fade-proof effect, while the usage amount of dyestuff can be reduced, environmental protection is nontoxic, reduces cost, tool
There are extensive industrial prospect and market value.
Specific embodiment
For technological means, creation characteristic, reached purpose and effect for making present invention realization are easy to understand, with reference to
Specific embodiment, is expanded on further the present invention.
The present invention provides a kind of technical scheme:A kind of printing and dyeing assistant containing sodium carboxymethylcellulose, by following weight portion
Raw material is constituted:Guar gum 6-8 weight portions, polyethylene glycol laurate 13-15 weight portions, polyalkyl acrylate 8-10 weight
Part, sodium carboxymethylcellulose 12-13 weight portions, dodecyl sodium sulfate 8-10 weight portions, polyalkyl acrylate 7-8 weight
Part, octadecyl dimethyl benzyl ammonium chloride 9-10 weight portions, fatty alcohol 6-7 weight portions, oxirane 5-7 weight portions, acetic acid
2-3 weight portions, barium chloride 9-24 weight portions.
It is raw material with natural guars, then remaining endosperm fraction after removal epidermis and plumule drying and crushing and pressurizes
Precipitated with 20% ethanol solution after hydrolysis, centrifugation is reacted after drying with dehydration contracting glycerin ether trimethyl ammonia chloride ammonia, and raw material is obtained
In guar gum.
Using acidic catalyst, esterification is carried out with polyethylene glycol and laurate, the polyethylene glycol month in raw material is obtained
Cinnamic acid ester.
The sodium carboxymethylcellulose that will be obtained after native cellulose and caustic alkali and monochloroacetic acid reaction in raw material.
Ethene and chlorine are passed through in water, ethylene chlorhydrin is generated, are then reacted with ethylene chlorhydrin with milk of lime, generate raw material
In oxirane.
As one embodiment of the present of invention:Contain the weight portion of guar gum 8, every 100 weight in the raw material of every 100 weight portion
Contain the weight portion of polyethylene glycol laurate 15 in the raw material of part, polyalkyl acrylate is contained in the raw material of every 100 weight portion
10 weight portions, contain the weight portion of sodium carboxymethylcellulose 12 in the raw material of every 100 weight portion, contain in the raw material of every 100 weight portion
There is the weight portion of dodecyl sodium sulfate 10, the weight portion of polyalkyl acrylate 7, every 100 weight are contained in the raw material of every 100 weight portion
Contain the weight portion of octadecyl dimethyl benzyl ammonium chloride 10 in the raw material of amount part, fat is contained in the raw material of every 100 weight portion
The weight portion of alcohol 6, contains the weight portion of oxirane 7 in the raw material of every 100 weight portion, acetic acid 2 is contained in the raw material of every 100 weight portion
Weight portion, contains the weight portion of barium chloride 13 in the raw material of every 100 weight portion.
As one embodiment of the present of invention:A kind of printing and dyeing assistant containing sodium carboxymethylcellulose of the invention, with good
Good improves color fastness, color protection, fade-proof effect, while the usage amount of dyestuff can be reduced, environmental protection is nontoxic, reduces into
This, with extensive industrial prospect and market value.
General principle of the invention and principal character and advantages of the present invention has been shown and described above, for this area skill
For art personnel, it is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing substantially from it is of the invention spirit or
In the case of essential characteristic, the present invention can be in other specific forms realized.Therefore, no matter from the point of view of which point, all should be by
Embodiment regards exemplary as, and is nonrestrictive, and the scope of the present invention is by appended claims rather than above stating
Bright restriction, it is intended that all changes fallen in the implication and scope of the equivalency of claim are included in the present invention
It is interior.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (6)
1. a kind of printing and dyeing assistant containing sodium carboxymethylcellulose, it is characterised in that:It is made up of the raw material of following weight portion:Guar gum
6-8 weight portions, polyethylene glycol laurate 13-15 weight portions, polyalkyl acrylate 8-10 weight portions, sodium carboxymethylcellulose
12-13 weight portions, dodecyl sodium sulfate 8-10 weight portions, polyalkyl acrylate 7-8 weight portions, octadecyldimethyl benzyl
Base ammonium chloride 9-10 weight portions, fatty alcohol 6-7 weight portions, oxirane 5-7 weight portions, acetic acid 2-3 weight portions, barium chloride 9-24
Weight portion.
2. a kind of printing and dyeing assistant containing sodium carboxymethylcellulose according to claim 1, it is characterised in that:Use natural Guar
Glue is raw material, remaining endosperm fraction after removal epidermis and plumule, then uses 20% ethanol solution after drying and crushing and pressurized hydrolysis
Precipitation, centrifugation is reacted after drying with dehydration contracting glycerin ether trimethyl ammonia chloride ammonia, and the guar gum in raw material is obtained.
3. a kind of printing and dyeing assistant containing sodium carboxymethylcellulose according to claim 1, it is characterised in that:Urged using acidity
Agent, esterification is carried out with polyethylene glycol and laurate, and the polyethylene glycol laurate in raw material is obtained.
4. a kind of printing and dyeing assistant containing sodium carboxymethylcellulose according to claim 1, it is characterised in that:By natural fiber
Element is obtained the sodium carboxymethylcellulose in raw material after being reacted with caustic alkali and monochloroacetic acid.
5. a kind of printing and dyeing assistant containing sodium carboxymethylcellulose according to claim 1, it is characterised in that:By ethene and chlorine
Gas is passed through in water, generates ethylene chlorhydrin, is then reacted with ethylene chlorhydrin with milk of lime, the oxirane in generation raw material.
6. a kind of printing and dyeing assistant containing sodium carboxymethylcellulose according to claim 1, it is characterised in that:Every 100 weight
Contain the weight portion of guar gum 8 in the raw material of part, the weight portion of polyethylene glycol laurate 15 contained in the raw material of every 100 weight portion,
Contain the weight portion of polyalkyl acrylate 10 in the raw material of every 100 weight portion, it is fine containing carboxymethyl in the raw material of every 100 weight portion
The plain weight portion of sodium 12 of dimension, contains the weight portion of dodecyl sodium sulfate 10, the original of every 100 weight portion in the raw material of every 100 weight portion
Contain the weight portion of polyalkyl acrylate 7 in material, octadecyl dimethyl benzyl ammonium chloride is contained in the raw material of every 100 weight portion
10 weight portions, contain the weight portion of fatty alcohol 6 in the raw material of every 100 weight portion, oxirane is contained in the raw material of every 100 weight portion
7 weight portions, contain the weight portion of acetic acid 2 in the raw material of every 100 weight portion, the weight of barium chloride 13 is contained in the raw material of every 100 weight portion
Amount part.
Priority Applications (1)
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CN201710145437.8A CN106884345A (en) | 2017-03-13 | 2017-03-13 | A kind of printing and dyeing assistant containing sodium carboxymethylcellulose |
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CN201710145437.8A CN106884345A (en) | 2017-03-13 | 2017-03-13 | A kind of printing and dyeing assistant containing sodium carboxymethylcellulose |
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Cited By (4)
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---|---|---|---|---|
CN107326703A (en) * | 2017-08-28 | 2017-11-07 | 江苏四新界面剂科技有限公司 | A kind of multifunctional textile printing and dyeing assistant |
CN107476090A (en) * | 2017-09-04 | 2017-12-15 | 句容躬行创客管理咨询有限公司 | A kind of environmental type printing and dyeing assistant and preparation method thereof |
WO2019033456A1 (en) * | 2017-08-17 | 2019-02-21 | 南通中润纺织印染有限公司 | Printing and dyeing auxiliary for fabric |
CN112921679A (en) * | 2021-02-24 | 2021-06-08 | 江苏四新界面剂科技有限公司 | Printing and dyeing auxiliary agent for dyeing natural pigment |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019033456A1 (en) * | 2017-08-17 | 2019-02-21 | 南通中润纺织印染有限公司 | Printing and dyeing auxiliary for fabric |
CN107326703A (en) * | 2017-08-28 | 2017-11-07 | 江苏四新界面剂科技有限公司 | A kind of multifunctional textile printing and dyeing assistant |
CN107476090A (en) * | 2017-09-04 | 2017-12-15 | 句容躬行创客管理咨询有限公司 | A kind of environmental type printing and dyeing assistant and preparation method thereof |
CN112921679A (en) * | 2021-02-24 | 2021-06-08 | 江苏四新界面剂科技有限公司 | Printing and dyeing auxiliary agent for dyeing natural pigment |
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Application publication date: 20170623 |