CN106883947A - A kind of transparent liquid detergent composition containing fragrant sulfobetaines - Google Patents
A kind of transparent liquid detergent composition containing fragrant sulfobetaines Download PDFInfo
- Publication number
- CN106883947A CN106883947A CN201510945481.8A CN201510945481A CN106883947A CN 106883947 A CN106883947 A CN 106883947A CN 201510945481 A CN201510945481 A CN 201510945481A CN 106883947 A CN106883947 A CN 106883947A
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- CN
- China
- Prior art keywords
- sodium
- liquid detergent
- alkylbenzenesulfonate
- sulfobetaines
- transparent liquid
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
A kind of transparent liquid detergent composition containing fragrant sulfobetaines, is related to a kind of hard water resistance liquid detergent composition, belongs to daily-use chemical industry washing product technical field.Multifunctional assistant of the said composition with long chain alkyl dimethyl benzyl sulfobetaines as anticalcium magnesium ion, sodium n-alkylbenzenesulfonate is the transparent liquid detergent composition of primary surfactant, and each main component and its weight percentage are：Sodium n-alkylbenzenesulfonate, 10-30%；Alkyldimethylbenzylammonium glycine betaine, 0.2-5%；AEO, 1-5%；Paratoluenesulfonic acid sodium salt, 0-4%；EBSA sodium, 0-4%；Cumene sodium sulfonate, 0-4%；Sodium carboxymethylcellulose, 0-1.5%；Hydroxyethyl cellulose, 0-1.2%；Sodium silicate, 0-15%；Soda ash, 0-15%；Glauber salt, 0-10%；Water, surplus.Washing clean effect of the liquid detergent in hard water is good, also has preferably washing dirt-removing power in the seawater.
Description
Technical field
The present invention relates to a kind of Liquid laundry composition, and in particular to a kind of hard water resistance Liquid laundry composition, belong to daily-use chemical industry washing product skill
Art field.
Background technology
Compared with detergent powder, liquid detergent can bring more facilities to the daily life of consumer, be such as easy to dissolve, measure
Accurately, no dust pollution etc.；Liquid detergent is also more more environmentally-friendly than detergent powder, in need not evaporating raw material in production process
Moisture and save heat energy, the amount that diffussion of dust goes out and reduces air neutral and alkali particulate matter is not had under liquid, it is not necessary to addition with washing
The unrelated additive of decontamination and reduce using for chemicals.The best surfactant of current liquid detergent cost performance surely belongs to straight chain alkane
Base benzene sulfonic acid sodium salt.But the integration capability of washing decontamination of the sodium n-alkylbenzenesulfonate in hard water is poor, and it is straight chained alkyl to trace it to its cause
Calcium ions and magnesium ions effect in benzene sulfonic acid sodium salt and hard water generates the calcium and magnesium salt of water insoluble LABS, the calcium and magnesium mineralization of generation
In clothing surface or in being suspended in washings and influence detergent detergency ability.It is solution that anticalcium magnesium ion auxiliary agent is added in detergent compositions
Certainly detergent containing sodium n-alkylbenzenesulfonate does not tolerate the main method of the problem of hard water, the anticalcium magnesium ion added in current detergent
Composition mainly has sodium tripolyphosphate, sodium pyrophosphate, disodium EDTA, nitrilotriacetic acid sodium salt, AEO
Sulfuric ester sodium salt, 4A zeolites and phyllosilicate etc..Sodium tripolyphosphate, sodium pyrophosphate are developed by Dow Chemical company, are a kind of
The very capable and raising sodium n-alkylbenzenesulfonate of anticalcium magnesium ion is washed and removes unable auxiliary agent, but is contained because being excessively used these
Phosphate builder can aggravate the eutrophication of water body and progressively exit in detergent compositions field；Disodium EDTA, nitrilotriacetic acid
Sodium salt chelates the very capable of calcium ions and magnesium ions, but they can also chelate other high volence metal ions while calcium ions and magnesium ions are chelated,
These chelating agents are excessively used while the loss of other metal ions in environment can be caused, in addition nitrilotriacetic acid sodium salt or a kind of environment
Toxin；The yield of AES is big, resistance to hard water is strong, and being widely used in dish washing detergent strengthens straight chain
Washing dirt-removing power of the sodium alkyl benzene sulfonate in hard water, but due to the foam of addition AES formula
Excessively enrich, be not suitable for being added in use in washing machine liquid detergent formula；4A zeolites and phyllosilicate in water do not dissolve and cannot
In being formulated for transparent liquid detergent.
Therefore resistance to hard water is good, compound property is good with environment-friendly New-type adjuvant into the important of current liquid detergent industry for exploitation
Task.
The content of the invention
[problem for intending to solve]
It is an object of the invention to provide the anticalcium in a kind of transparent liquid detergent with sodium n-alkylbenzenesulfonate as primary surfactant
The auxiliary agent of magnesium ion；
It is a further object to provide a kind of comprehensive liquid improved containing sodium n-alkylbenzenesulfonate for principal surfactant
The multifunctional assistant of detergent；
It is a further object to provide a kind of liquid detergent formula for being applicable in seawater wash decontamination.
[technical scheme]
To achieve these goals, the invention provides it is a kind of with long chain alkyl dimethyl benzyl sulfobetaines be many of anticalcium magnesium ion
Function additive, sodium n-alkylbenzenesulfonate is the transparent liquid detergent composition of primary surfactant.The technical scheme of use is as follows：
By appropriate sodium n-alkylbenzenesulfonate, straight chained alkyl dimethylbenzyl sulfobetaines, AEO, paratoluenesulfonic acid sodium salt,
Cumene sodium sulfonate, sodium carboxymethylcellulose, hydroxyethyl cellulose, sodium silicate, soda ash and glauber salt etc. are added in appropriate hot water
Stir, cooled and filtered removes possible mechanical admixture.
The basic structure of long chain alkyl dimethyl benzyl sulfobetaines of the invention is：
Wherein R group is octyl, decyl, dodecyl, myristyl, cetyl, octadecyl or more each alkyl
Mixture of chain or more states alkyl chain for principal component.
Each composition and compositing range of hard water resistance transparent liquid detergent composition of the invention be：
| Sodium n-alkylbenzenesulfonate | 10-30% |
| Alkyldimethylbenzylammonium glycine betaine | 0.2-5% |
| AEO | 1-5% |
| Paratoluenesulfonic acid sodium salt | 0-4% |
| EBSA sodium | 0-4% |
| Cumene sodium sulfonate | 0-4% |
| Sodium carboxymethylcellulose | 0-1.5% |
| Hydroxyethyl cellulose | 0-1.2% |
| Sodium silicate | 0-15% |
| Soda ash | 0-15% |
| Glauber salt | 0-10% |
| Water | Surplus |
[beneficial effect]
Compared with existing transparent liquid detergent, beneficial effects of the present invention are as follows：
Primary surfactant in the liquid detergent composition that 1 present invention is provided is still sodium n-alkylbenzenesulfonate, therefore the combination
The wide material sources of the primary raw material of thing, cost performance are good；
The transparent liquid detergent composition that 2 present invention are provided has preferable hard water resistance performance, can make in salinity area higher
With；
The transparent liquid detergent composition that 3 present invention are provided still old preferable washing detergency ability, Ke Yi in simulated seawater
During the ocean of cargo ship or naval vessels, or the transparent liquid detergent used in coastal waters fishing zone.
The anticalcium magnesium ion auxiliary agent that 4 present invention are provided will not aggravate the eutrophication of water body, will not cause the stream of metal ion in soil
The foam for losing, not resulting in formula excessively enriches, and is a kind of liquid detergent builder of good combination property.
Specific embodiment
With reference to specific embodiment, the invention will be further described, but the present invention is any limitation as never in any form, based on this
Any conversion or replacement that invention training centre is made, belong to protection scope of the present invention.
Embodiment 1
By 12.0g sodium n-alkylbenzenesulfonates (93.5%), 1.0g dodecyl dimethyl benzyl sulfobetaines and 2.0g fatty alcohols
APEO -9 is well mixed, and it is added in the deionized water of 60 DEG C of 77g, is stirred；Again in the surfactant
0.5g paratoluenesulfonic acid sodium salts, 0.5g sodium carboxymethylcelluloses, 2.0g sodium silicates, 2.0g soda ash and 3.0g glauber salt are added in solution,
Transparent liquid detergent is cooled down to obtain after stirring.The formula viscosity is 1500cp, the decontamination in 250ppm manual simulation's hard water
Power is 1.31 with the ratio of standard flour detergency.
Embodiment 2
By 15.5g sodium n-alkylbenzenesulfonates (93.5%), 2.0g dodecyl dimethyl benzyl sulfobetaines and 1.0g fatty alcohols
APEO -9 is well mixed, and it is added in the deionized water of 60 DEG C of 77g, is stirred；Again in the surfactant
Add 1.0g paratoluenesulfonic acid sodium salts, 0.6g strong in solution and cellulose, 4.0g sodium silicates, cooling obtains transparent liquid after stirring
Body detergent.The formula viscosity is 1100cp, the ratio of detergency and standard flour detergency in 250ppm manual simulation's hard water
It is 1.38, the detergency in the artificial hard water of 400ppm is 1.24 with the ratio of standard flour detergency under 250ppm, illustrates that this is matched somebody with somebody
Side goes for the detergent in water hardness area higher.
Embodiment 3
By 25.0g sodium n-alkylbenzenesulfonates (93.5%), 4.0g dodecyl dimethyl benzyl sulfobetaines and 3.0g fatty alcohols
APEO -7 is well mixed, and it is added in the deionized water of 60 DEG C of 60g, is stirred；Again in the surfactant
Add 0.5g to EBSA sodium, 2.5g to cumene sodium sulfonate, 3.0g soda ash and 2.0 grams of glauber salt in solution, after stirring
Transparent liquid detergent is obtained by degassing and cooling.The formula viscosity is 1600cp, going in 250ppm manual simulation's hard water
Dirty power is 1.43 with the ratio of standard flour detergency, standard flour decontamination under the detergency and 250ppm in the artificial hard water of 400ppm
The ratio of power is 1.31, illustrates that the formula goes for the detergent in water hardness area higher.
Embodiment 4
By 18.0g LABSs and NaOH neutralized reaction product (content of sodium n-alkylbenzenesulfonate is 55%), 1.0g ten
Dialkyl dimethyl benzyl sulfobetaines and 5.0g AEOs -9 are added separately in the deionized water of 60 DEG C of 70g,
Stir；0.8g sodium carboxymethylcelluloses and 3.0g soda ash are added in the surfactant solution again, is cooled down after stirring
To transparent liquid detergent.The formula viscosity is 1600cp, and foam height is 130mm, and the foam height after 5min is 95mm,
Illustrate that the foaming characteristic and foam stability of the formula are good；The ratio of detergency and standard flour detergency in 250ppm manual simulation's hard water
It is 1.30, illustrates that washing dirt-removing power of the formula in hard water is good.
Embodiment 4
By 35.0g LABSs and NaOH neutralized reaction product, (content of sodium n-alkylbenzenesulfonate is about 55%, sulfuric acid
The content of sodium be about 0.8%), 3.0g decyl dimethylbenzyl sulfobetaines and 5.0g AEOs -7 be separately added into
To in the deionized water of 60 DEG C of 53g, stir；3.0g soda ash and 2.5g glauber salt are added in the surfactant solution again,
Cooling obtains transparent liquid detergent after stirring.The formula viscosity is 1500cp；Decontamination energy is washed with carbon black grease soiled cotton evaluation
Power, detergency and the ratio of standard flour detergency in 250ppm manual simulation's hard water are 1.47, illustrate the formula in hard water
Washing dirt-removing power is good, in simulated seawater (128.0g sodium chloride, 15.4g magnesium chlorides, 0.3g magnesium sulfate and 36.0g calcium chloride
Be dissolved in 930g deionized waters to configure and form) in washing detergency and 250ppm hard water in the decontamination ratio of standard flour that determines
It is 1.07, illustrates that the formula has preferably washing dirt-removing power in simulated seawater, it is adaptable to which cargo ship, naval vessels or fishing boat are in ocean
Seawer washing, it is also possible to suitable for washing fishing gear in the seawater.
Claims (6)
1. a kind of transparent liquid detergent composition containing fragrant sulfobetaines, it is characterized by with long chain alkyl dimethyl benzyl sulfobetaines
Alkali is the multifunctional assistant of anticalcium magnesium ion, and sodium n-alkylbenzenesulfonate is combined for the transparent liquid detergent of primary surfactant
Thing, each main component and its weight percentage are：Sodium n-alkylbenzenesulfonate, 10-30%；Alkyldimethylbenzylammonium glycine betaine,
0.2-5%；AEO, 1-5%；Paratoluenesulfonic acid sodium salt, 0-4%；EBSA sodium, 0-4%；Cumene sodium sulfonate,
0-4%；Sodium carboxymethylcellulose, 0-1.5%；Hydroxyethyl cellulose, 0-1.2%；Sodium silicate, 0-15%；Soda ash, 0-15%；Unit
Bright powder, 0-10%；Water, surplus.
2. the architectural feature of the long chain alkyl dimethyl benzyl sulfobetaines described in claim 1 is：
Wherein R group is octyl, decyl, dodecyl, myristyl, cetyl, octadecyl or more each alkyl chain
Mixture or more states alkyl chain for principal component.
3. the feature of the sodium n-alkylbenzenesulfonate described in claim 1 is that sodium n-alkylbenzenesulfonate can be industrial powdered product, can
With the liquid product that to be LABS neutralize with NaOH, it is also possible in process of production by sodium n-alkylbenzenesulfonate scene
Neutralize.
4. the feature of the AEO described in claim 1 is that the fatty alcohol in structure is lauryl alcohol or tetradecyl alchohol or ten
The mixture of tetracosanol or the mixed fatty alcohol based on lauryl alcohol or tetradecyl alchohol；The average link number of APEO is in 5-11.
5. according to claim 1, at least add paratoluenesulfonic acid sodium salt, to EBSA sodium and to cumene sodium sulfonate in one or
Wherein several mixtures.
6. according to claim 1, sodium carboxymethylcellulose, hydroxyethyl cellulose, sodium silicate, soda ash and glauber salt are according to formula
The requirement such as viscosity and anti-deposit adds or is not added with.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510945481.8A CN106883947A (en) | 2015-12-16 | 2015-12-16 | A kind of transparent liquid detergent composition containing fragrant sulfobetaines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510945481.8A CN106883947A (en) | 2015-12-16 | 2015-12-16 | A kind of transparent liquid detergent composition containing fragrant sulfobetaines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106883947A true CN106883947A (en) | 2017-06-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510945481.8A Pending CN106883947A (en) | 2015-12-16 | 2015-12-16 | A kind of transparent liquid detergent composition containing fragrant sulfobetaines |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106883947A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112827660A (en) * | 2020-12-31 | 2021-05-25 | 湖北富邦新材料有限公司 | Method for improving activity of fatty acid salt ore flotation collector in hard water |
| CN114806742A (en) * | 2022-05-25 | 2022-07-29 | 晋江市佐净日用品有限责任公司 | Oxygen-increasing phosphorus-free cleaning paste and preparation method thereof |
-
2015
- 2015-12-16 CN CN201510945481.8A patent/CN106883947A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 董燕超等: "十二烷基苄磺基甜菜碱作为代磷助剂的性能研究", 《日用化学工业》 * |
| 闻迪: "N-十二烷基-N，N-二甲基苄磺基甜菜碱的合成与性能", 《江南大学》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112827660A (en) * | 2020-12-31 | 2021-05-25 | 湖北富邦新材料有限公司 | Method for improving activity of fatty acid salt ore flotation collector in hard water |
| CN114806742A (en) * | 2022-05-25 | 2022-07-29 | 晋江市佐净日用品有限责任公司 | Oxygen-increasing phosphorus-free cleaning paste and preparation method thereof |
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Application publication date: 20170623 |
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