CN114806742A - Oxygen-increasing phosphorus-free cleaning paste and preparation method thereof - Google Patents
Oxygen-increasing phosphorus-free cleaning paste and preparation method thereof Download PDFInfo
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- CN114806742A CN114806742A CN202210576336.7A CN202210576336A CN114806742A CN 114806742 A CN114806742 A CN 114806742A CN 202210576336 A CN202210576336 A CN 202210576336A CN 114806742 A CN114806742 A CN 114806742A
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- 238000004140 cleaning Methods 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 174
- 239000011265 semifinished product Substances 0.000 claims abstract description 84
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 56
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 36
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 28
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 28
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 28
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 28
- 239000008213 purified water Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 23
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 23
- 238000002156 mixing Methods 0.000 claims abstract description 22
- 230000002087 whitening effect Effects 0.000 claims abstract description 22
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 21
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 21
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 21
- 229960001922 sodium perborate Drugs 0.000 claims abstract description 20
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims abstract description 20
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 19
- 229940045872 sodium percarbonate Drugs 0.000 claims abstract description 19
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 18
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000007798 antifreeze agent Substances 0.000 claims abstract description 16
- 239000000084 colloidal system Substances 0.000 claims abstract description 14
- 238000005303 weighing Methods 0.000 claims abstract description 13
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 12
- 239000000047 product Substances 0.000 claims abstract description 8
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 8
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 8
- 230000009471 action Effects 0.000 claims abstract description 7
- 229940093956 potassium carbonate Drugs 0.000 claims abstract description 7
- 229960001407 sodium bicarbonate Drugs 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims description 35
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 18
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 230000003044 adaptive effect Effects 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000007710 freezing Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- -1 polyoxyethylene Polymers 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 3
- 238000006213 oxygenation reaction Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 description 5
- 230000003028 elevating effect Effects 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000006694 eating habits Nutrition 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3953—Inorganic bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to an oxygenation phosphorus-free cleaning paste and a preparation method thereof, wherein the cleaning paste is stirred by a self-adaptive stirring system, and the oxygenation phosphorus-free cleaning paste comprises the following steps: weighing purified water; mixing sodium carboxymethylcellulose and sodium carbonate; adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product; slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate into the first semi-finished product, and stirring under the action of a self-adaptive stirring system to form a viscous colloid; the self-adaptive stirring system is stopped, dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence are sequentially added into the formed viscous colloid, and the product is uniform and fine.
Description
Technical Field
The invention relates to the technical field of cleaning paste production, in particular to an oxygen-increasing phosphorus-free cleaning paste and a preparation method thereof.
Background
With the development of the times, people put higher demands on various aspects of clothes and eating habits in life. The washing product is a cleaning product which is most used in daily life, and mainly utilizes the wetting, penetrating, emulsifying and dispersing abilities of a surfactant to weaken and separate the adhesive force of stains on attachments of the stains into washing liquor, so that the purposes of removing oil stains and cleaning the surface are achieved.
The existing cleaning paste needs to be stirred, mixed and ground for a long time in the production process, on one hand, the formula of the cleaning paste is not good in dispersing and emulsifying capacity, and on the other hand, the formula of the cleaning paste is limited by the grinding capacity of stirring and grinding equipment.
Disclosure of Invention
In order to overcome the technical defects in the prior art, the invention provides the oxygen-increasing phosphorus-free cleaning paste and the preparation method thereof, and the oxygen-increasing phosphorus-free cleaning paste is uniform and fine, has short stirring time, and is energy-saving and environment-friendly.
The technical solution adopted by the invention is as follows:
the oxygen-increasing phosphorus-free cleaning paste comprises the following raw materials in parts by weight: 4-6 parts of sodium percarbonate, 3-5 parts of sodium perborate, 5-7 parts of potassium carbonate, 28-30 parts of sodium bicarbonate, 6-8 parts of sodium carbonate, 1-1.5 parts of sodium carboxymethylcellulose, 18.2-24.3 parts of active matter, 0.1-0.2 part of essence, 5-7 parts of whitening anti-freezing agent and the balance of purified water.
Preferably, the active matter comprises 2-3 parts of dodecyl betaine, 0.2-0.3 part of alkylphenol polyoxyethylene, 6-8 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 8-10 parts of linear alkyl benzene sulfonate and 2-3 parts of alkylolamide.
Preferably, the whitening antifreeze agent is a saturated edible sodium chloride solution.
The preparation method of the oxygen-increasing phosphorus-free cleaning paste is stirred by a self-adaptive stirring system and comprises the following steps:
and SA: respectively weighing 4-6 parts of quasi sodium percarbonate, 3-5 parts of sodium perborate, 5-7 parts of potassium carbonate, 28-30 parts of sodium bicarbonate, 6-8 parts of sodium carbonate and 1-1.5 parts of sodium carboxymethylcellulose;
SB: weighing purified water;
SC: mixing sodium carboxymethylcellulose and sodium carbonate;
SD: adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product;
and SE: slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate in the SC into the first semi-finished product in the SD, and stirring under the action of a self-adaptive stirring system to form a viscous colloid;
SF: stopping the self-adaptive stirring system, and sequentially adding dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence into a viscous colloid formed by SE.
Preferably, the SF comprises the following steps:
SF 1: adding dodecyl betaine, lifting and positively rotating a self-adaptive stirring system at the rotating speed of 12-15 revolutions per minute, and uniformly stirring to form a second semi-finished product;
SF 2: adding alkylphenol ethoxylates into the second semi-finished product, lifting and positively rotating the self-adaptive stirring system at a rotating speed of 12-15 revolutions per minute, and uniformly stirring to form a third semi-finished product;
SF 3: adding alkylolamide into the third semi-finished product, lifting and positively rotating the self-adaptive stirring system at the rotating speed of 12-15 revolutions per minute, and uniformly stirring to form a fourth semi-finished product;
SF 4: lifting the self-adaptive stirring system, starting reverse rotation for grinding, and grinding the fourth semi-finished product for 6-10 minutes to form a fifth semi-finished product;
SF 5: adding essence into the fifth semi-finished product, lifting the self-adaptive stirring system, and starting to rotate positively for 2-4 minutes to stir to form a sixth semi-finished product;
SF 6: adding fatty alcohol-polyoxyethylene ether sodium sulfate into the sixth semi-finished product, lifting the self-adaptive stirring system and starting forward rotation at the rotating speed of 12-15 revolutions per minute, and starting reverse rotation grinding for 9-11 minutes after the fatty alcohol-polyoxyethylene ether sodium sulfate is uniformly mixed to form a seventh semi-finished product;
SF 7: adding linear alkyl benzene sodium sulfonate into the seventh semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at the rotating speed of 12-15 revolutions per minute, uniformly mixing the linear alkyl benzene sodium sulfonate, and then starting reverse rotation grinding for 12-18 minutes to form an eighth semi-finished product;
SF 8: adding a whitening antifreeze agent into the eighth semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at the rotating speed of 12-15 r/min, uniformly mixing the linear alkyl benzene sulfonic acid sodium, and then starting reverse rotation grinding for 20-30 min to form a finished product.
Preferably, self-adaptation mixing system includes frame, elevating gear, self-adaptation agitating unit and agitator, self-adaptation agitating unit includes agitator motor, agitator frame, slip doctor-bar and distance plate subassembly, agitator motor installs on elevating gear, elevating gear is along frame elevating movement, the agitator frame is installed at the agitator motor output, the agitator frame bottom is equipped with the discharge opening, the agitator frame stretches into in the agitator frame, the agitator frame is equipped with the parallel horizontal guide rail roof beam of a plurality of groups, the slip doctor-bar is along corresponding horizontal guide rail roof beam horizontal slip, the distance plate subassembly rotates the in-process at the agitator frame and extrudees the slip doctor-bar to the agitator lateral wall, the be close to agitator one side of slip doctor-bar is equipped with the rubber sword.
Preferably, the lifting device comprises a lifting motor, a lifting frame, a lifting screw rod and a plurality of lifting guide rails, the lifting guide rails are parallel to each other and fixedly arranged on the rack, the lifting motor is arranged on the rack, the lifting screw rod is arranged at the output end of the lifting motor, the lifting screw rod is connected with the lifting frame through a thread pair, and the lifting frame slides along the lifting guide rails.
Preferably, the thrust plate subassembly includes push pedal and torsional spring, the rotatable installation of push pedal is on corresponding the slip scraper, the axis of rotation plummet of push pedal, the both ends of torsional spring are adorned admittedly respectively on push pedal and slip scraper, the axis that makes the directional agitator of push pedal when being in free state of torsional spring.
The invention has the beneficial effects that:
the cleaning paste is stirred by a self-adaptive stirring system, and the beneficial effects in each stirring step are as follows:
and SA: respectively weighing 4-6 parts of quasi sodium percarbonate, 3-5 parts of sodium perborate, 5-7 parts of potassium carbonate, 28-30 parts of sodium bicarbonate, 6-8 parts of sodium carbonate and 1-1.5 parts of sodium carboxymethylcellulose, wherein the sodium percarbonate is used for oxidizing stains and sterilizing, the sodium perborate is used for mild decontamination, the sodium perborate has a bleaching function, the sodium carbonate has a function of removing stubborn stains, and the sodium bicarbonate is used for improving the decontamination capability; sodium carbonate is used to saponify fatty stains, sodium carboxymethyl cellulose is used to repel stains and make the solution colloidal;
SB: weighing purified water;
SC: mixing sodium carboxymethylcellulose and sodium carbonate, mixing the sodium carboxymethylcellulose into the sodium carbonate, and preventing the sodium carboxymethylcellulose from caking during dissolution;
SD: adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product;
and SE: slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate in the SC into the first semi-finished product in the SD, and stirring to form a viscous colloid under the action of a self-adaptive stirring system, wherein the self-adaptive stirring system can automatically adjust the grinding force under different stirring strengths to ensure sufficient grinding capacity;
SF: the self-adaptive stirring system is stopped, dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence are sequentially added into a viscous colloid formed by SE, wherein the dodecyl betaine has an emulsifying and thickening effect, the alkylphenol ethoxylates has an effect of enhancing the dirt-removing power, the alkylolamide has an effect of stabilizing foam, the fatty alcohol-polyoxyethylene ether sodium sulfate has an effect of stabilizing the paste, and the linear alkyl benzene sulfonate has an effect of removing dirt and increasing foam.
Drawings
Fig. 1 is a schematic structural diagram of the self-adaptive stirring system after a stirring barrel is detached.
Fig. 2 is an enlarged schematic view of a point a in fig. 1.
Fig. 3 is a schematic structural diagram of the adaptive stirring system.
Description of reference numerals:
1. a frame;
2. a lifting device; 21. a lifting motor; 22. a lifting frame; 23. lifting a screw rod; 24. a lifting guide rail;
3. a self-adaptive stirring device; 31. a stirring motor; 32. a stirring frame; 321. a horizontal guide rail beam; 33. sliding the wiper blade; 34. a thrust plate assembly; 341. pushing the plate;
4. and (4) a stirring barrel.
Detailed Description
The invention will be further described with reference to the accompanying drawings in which:
example 1
As shown in fig. 1-3, the present embodiment provides an oxygen-increasing phosphorus-free cleaning paste, which comprises the following raw materials in parts by weight: 4 parts of sodium percarbonate, 3 parts of sodium perborate, 5 parts of potassium carbonate, 28 parts of sodium bicarbonate, 6 parts of sodium carbonate, 1 part of sodium carboxymethylcellulose, 18.2 parts of active substances, 0.1 part of essence, 5 parts of whitening antifreeze agent and the balance of purified water.
The active matter comprises 2 parts of dodecyl betaine, 0.2 part of alkylphenol polyoxyethylene, 6 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 8 parts of linear alkyl benzene sulfonate and 2 parts of alkylolamide.
The whitening antifreeze agent is saturated edible sodium chloride solution.
Stirring by an adaptive stirring system, comprising the following steps:
and SA: respectively weighing 4 parts of sodium percarbonate, 3 parts of sodium perborate, 5 parts of potassium carbonate, 28 parts of sodium bicarbonate, 6 parts of sodium carbonate and 1 part of sodium carboxymethylcellulose;
SB: weighing purified water;
SC: mixing sodium carboxymethylcellulose and sodium carbonate;
SD: adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product;
and SE: slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate in the SC into the first semi-finished product in the SD, and stirring to form a viscous colloid under the action of a self-adaptive stirring system, wherein the self-adaptive stirring system can automatically adjust the grinding force under different stirring strengths to ensure sufficient grinding capacity;
SF: stopping the self-adaptive stirring system, and sequentially adding dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence into a viscous colloid formed by SE.
The SF comprises the following steps:
SF 1: adding dodecyl betaine, lifting and positively rotating a self-adaptive stirring system at a rotating speed of 12 revolutions per minute, and uniformly stirring to form a second semi-finished product;
SF 2: adding alkylphenol ethoxylates into the second semi-finished product, lifting and rotating the self-adaptive stirring system forwards at a rotating speed of 12 revolutions per minute, and uniformly stirring to form a third semi-finished product;
SF 3: adding alkylolamide into the third semi-finished product, lifting and positively rotating the self-adaptive stirring system at the rotating speed of 12 revolutions per minute, and uniformly stirring to form a fourth semi-finished product;
SF 4: lifting the self-adaptive stirring system, starting the self-adaptive stirring system to reversely rotate for grinding, and grinding the fourth semi-finished product for 6 minutes to form a fifth semi-finished product;
SF 5: adding essence into the fifth semi-finished product, lifting the self-adaptive stirring system, and starting to rotate positively for 2 minutes to stir to form a sixth semi-finished product;
SF 6: adding fatty alcohol-polyoxyethylene ether sodium sulfate into the sixth semi-finished product, lifting the self-adaptive stirring system and starting forward rotation at the rotating speed of 12 revolutions per minute, uniformly mixing the fatty alcohol-polyoxyethylene ether sodium sulfate, and then starting reverse rotation grinding for 9 minutes to form a seventh semi-finished product;
SF 7: adding linear alkyl benzene sodium sulfonate into the seventh semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at a rotating speed of 12 revolutions per minute, uniformly mixing the linear alkyl benzene sodium sulfonate, and then starting reverse rotation grinding for 12 minutes to form an eighth semi-finished product;
SF 8: adding a whitening anti-freezing agent into the eighth semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at the rotating speed of 12 revolutions per minute, uniformly mixing the linear alkyl benzene sulfonic acid sodium, and then starting reverse rotation grinding for 20 minutes to form a finished product.
The self-adaptive stirring system comprises a frame 1, a lifting device 2, a self-adaptive stirring device 3 and a stirring barrel 4, wherein the self-adaptive stirring device 3 comprises a stirring motor 31, a stirring frame 32, a sliding scraper 33 and a thrust plate assembly 34, the stirring motor 31 is arranged on the lifting device 2, the lifting device 2 moves up and down along the frame 1, the stirring frame 32 is arranged at the output end of the stirring motor 31, the bottom of the stirring barrel 4 is provided with a discharge opening used for discharging the stirred cleaning paste, the stirring frame 32 extends into the stirring barrel 4, the stirring frame 32 is provided with a plurality of groups of parallel horizontal guide rail beams 321, the sliding scraper 33 horizontally slides along the corresponding horizontal guide rail beams 321, so that the sliding scraper 33 is adaptive to the barrel wall of the stirring barrel 4, the thrust plate assembly 34 extrudes the sliding scraper 33 to the side wall of the stirring barrel 4 in the rotation process of the stirring frame 32, one side of the sliding scraper 33, which is close to the stirring barrel 4, is provided with a rubber cutter, the rubber knife is used for extruding the slurry in the stirring barrel 4 onto the barrel wall of the stirring barrel 4 for grinding, the materials of the stirring barrel 4, the stirring frame 32 and the thrust plate component 34 are all 316# stainless steel, and the rubber knife is inclined with the barrel wall so as to realize forward rotation stirring and reverse rotation grinding.
The lifting device 2 comprises a lifting motor 21, a lifting frame 22, a lifting screw 23 and a plurality of lifting guide rails 24, the lifting guide rails 24 are parallel to each other and fixedly arranged on the rack 1, the lifting motor 21 is arranged on the rack 1, the lifting screw 23 is arranged at the output end of the lifting motor 21, the lifting screw 23 is connected with the lifting frame 22 through a thread pair, the lifting frame 22 slides along the lifting guide rails 24, and the lifting motor 21 drives the lifting screw 23 to rotate so as to drive the lifting frame 22 to lift.
The thrust plate assembly 34 includes a push plate 341 and a torsion spring, the push plate 341 is rotatably mounted on the corresponding sliding scraper 33, the rotation axis plumb of the push plate 341, two ends of the torsion spring are respectively and fixedly mounted on the push plate 341 and the sliding scraper 33, and the torsion spring is in a free state so that the push plate 341 points to the axis of the stirring barrel 4, which is worth noting: when the stirring goes on, the material in the agitator 4 can drive push pedal 341 and rotate, and then make push pedal 341 drive the torsional spring and twist reverse, the torsional spring gives push pedal 341 elastic support, herein simultaneously, push pedal 341 promotes sliding scraper 33 along horizontal guide rail roof beam 321 horizontal slip, and then make sliding scraper 33 extrude 4 barrel walls of agitator, stirring speed is fast more, the turned angle of push pedal 341 is big more, the torsional force that the torsional spring receives is also big more, and then the dynamics that push pedal 341 extrudes 4 barrel walls of agitator is also big more, the grinding dynamics improves along with stirring rotational speed, can adapt to the grinding demand under the different stirring rotational speeds, the churning time is short, energy-concerving and environment-protective.
Example 2
This example differs from example 1 in that: the embodiment provides an oxygenation phosphorus-free cleaning paste which comprises the following raw materials in parts by weight: 5 parts of sodium percarbonate, 4 parts of sodium perborate, 6 parts of potassium carbonate, 29 parts of sodium bicarbonate, 7 parts of sodium carbonate, 1.3 parts of sodium carboxymethylcellulose, 20 parts of active substances, 0.15 part of essence, 6 parts of whitening antifreeze agent and the balance of purified water.
The active matter comprises 2.5 parts of dodecyl betaine, 2.5 parts of alkylphenol polyoxyethylene, 7 parts of fatty alcohol polyoxyethylene ether sodium sulfate, 9 parts of linear alkyl benzene sulfonate and 2.5 parts of alkylolamide.
The whitening antifreeze agent is saturated edible sodium chloride solution.
Stirring by an adaptive stirring system, comprising the following steps:
and SA: respectively weighing 5 parts of quasi sodium percarbonate, 4 parts of sodium perborate, 6 parts of potassium carbonate, 29 parts of sodium bicarbonate, 7 parts of sodium carbonate and 1.3 parts of sodium carboxymethylcellulose;
SB: weighing purified water;
SC: mixing sodium carboxymethylcellulose and sodium carbonate;
SD: adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product;
and SE: slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate in the SC into the first semi-finished product in the SD, and stirring under the action of a self-adaptive stirring system to form a viscous colloid;
SF: stopping the self-adaptive stirring system, and sequentially adding dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence into a viscous colloid formed by SE.
The SF comprises the following steps:
SF 1: adding dodecyl betaine, lifting and positively rotating a self-adaptive stirring system at a rotating speed of 13 revolutions per minute, and uniformly stirring to form a second semi-finished product;
SF 2: adding alkylphenol ethoxylates into the second semi-finished product, lifting and rotating the self-adaptive stirring system forwards at a rotating speed of 13 revolutions per minute, and uniformly stirring to form a third semi-finished product;
SF 3: adding alkylolamide into the third semi-finished product, lifting and positively rotating the self-adaptive stirring system at a rotating speed of 13 revolutions per minute, and uniformly stirring to form a fourth semi-finished product;
SF 4: lifting the self-adaptive stirring system, starting the self-adaptive stirring system to reversely rotate for grinding, and grinding the fourth semi-finished product for 8 minutes to form a fifth semi-finished product;
SF 5: adding essence into the fifth semi-finished product, lifting the self-adaptive stirring system, and starting to rotate positively for 3 minutes to stir to form a sixth semi-finished product;
SF 6: adding fatty alcohol-polyoxyethylene ether sodium sulfate into the sixth semi-finished product, lifting the self-adaptive stirring system and starting forward rotation at a rotating speed of 13 revolutions per minute, uniformly mixing the fatty alcohol-polyoxyethylene ether sodium sulfate, and then starting reverse rotation grinding for 10 minutes to form a seventh semi-finished product;
SF 7: adding linear alkyl benzene sodium sulfonate into the seventh semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at a rotating speed of 13 revolutions per minute, uniformly mixing the linear alkyl benzene sodium sulfonate, and then starting reverse rotation grinding for 15 minutes to form an eighth semi-finished product;
SF 8: and adding a whitening anti-freezing agent into the eighth semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at a rotating speed of 13 revolutions per minute, uniformly mixing the linear alkyl benzene sulfonic acid sodium, and then starting reverse rotation for grinding for 25 minutes to form a finished product.
Example 3
This example differs from example 1 in that: the embodiment provides an oxygenation phosphorus-free cleaning paste which comprises the following raw materials in parts by weight: 6 parts of sodium percarbonate, 5 parts of sodium perborate, 7 parts of potassium carbonate, 30 parts of sodium bicarbonate, 8 parts of sodium carbonate, 1.5 parts of sodium carboxymethylcellulose, 24.3 parts of active matter, 0.2 part of essence, 7 parts of whitening antifreeze agent and the balance of purified water.
The active matter comprises dodecyl betaine, alkylphenol polyoxyethylene 0.3, fatty alcohol polyoxyethylene ether sodium sulfate 8, linear alkyl benzene sodium sulfonate 10 and alkylolamide 3.
The whitening antifreeze agent is saturated edible sodium chloride solution.
Stirring by an adaptive stirring system, comprising the following steps:
and SA: respectively weighing 6 parts of quasi sodium percarbonate, 5 parts of sodium perborate, 7 parts of potassium carbonate, 30 parts of sodium bicarbonate, 8 parts of sodium carbonate and 1.5 parts of sodium carboxymethylcellulose;
SB: weighing purified water;
and (3) SC: mixing sodium carboxymethylcellulose and sodium carbonate;
SD: adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product;
and SE: slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate in the SC into the first semi-finished product in the SD, and stirring under the action of a self-adaptive stirring system to form a viscous colloid;
SF: stopping the self-adaptive stirring system, and sequentially adding dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence into a viscous colloid formed by SE.
The SF comprises the following steps:
SF 1: adding dodecyl betaine, lifting and positively rotating a self-adaptive stirring system at the rotating speed of 15 revolutions per minute, and uniformly stirring to form a second semi-finished product;
SF 2: adding alkylphenol ethoxylates into the second semi-finished product, lifting and rotating the self-adaptive stirring system forwards at a rotating speed of 15 revolutions per minute, and uniformly stirring to form a third semi-finished product;
SF 3: adding alkylolamide into the third semi-finished product, lifting and positively rotating the self-adaptive stirring system at the rotating speed of 15 revolutions per minute, and uniformly stirring to form a fourth semi-finished product;
SF 4: lifting the self-adaptive stirring system, starting the self-adaptive stirring system to reversely rotate for grinding, and grinding the fourth semi-finished product for 10 minutes to form a fifth semi-finished product;
SF 5: adding essence into the fifth semi-finished product, lifting the self-adaptive stirring system, and starting to rotate forward for 4 minutes to stir to form a sixth semi-finished product;
SF 6: adding the sodium fatty alcohol-polyoxyethylene ether sulfate into the sixth semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at a rotation speed of 15 revolutions per minute, uniformly mixing the sodium fatty alcohol-polyoxyethylene ether sulfate, and then starting reverse rotation grinding for 11 minutes to form a seventh semi-finished product;
SF 7: adding linear alkyl benzene sodium sulfonate into the seventh semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at a rotation speed of 15 revolutions per minute, uniformly mixing the linear alkyl benzene sodium sulfonate, and then starting reverse rotation grinding for 18 minutes to form an eighth semi-finished product;
SF 8: and adding a whitening anti-freezing agent into the eighth semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at a rotation speed of 15 revolutions per minute, uniformly mixing the linear alkyl benzene sulfonic acid sodium, and then starting reverse rotation grinding for 30 minutes to form a finished product.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be understood by those skilled in the art that the invention is not limited by the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents.
Claims (8)
1. The oxygen-increasing phosphorus-free cleaning paste is characterized by comprising the following raw materials in parts by weight: 4-6 parts of sodium percarbonate, 3-5 parts of sodium perborate, 5-7 parts of potassium carbonate, 28-30 parts of sodium bicarbonate, 6-8 parts of sodium carbonate, 1-1.5 parts of sodium carboxymethylcellulose, 18.2-24.3 parts of active matter, 0.1-0.2 part of essence, 5-7 parts of whitening anti-freezing agent and the balance of purified water.
2. The oxygen-increasing phosphorus-free cleaning paste as claimed in claim 1, wherein the active substances comprise 2-3 parts of dodecyl betaine, 0.2-0.3 part of alkylphenol polyoxyethylene, 6-8 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 8-10 parts of linear alkyl benzene sulfonate and 2-3 parts of alkylolamide.
3. The oxygen-increasing phosphorus-free cleaning paste according to claim 1, wherein the whitening antifreeze agent is a saturated edible sodium chloride solution.
4. The preparation method of the oxygen-increasing phosphorus-free cleaning paste as claimed in claim 2, wherein the cleaning paste is stirred by a self-adaptive stirring system, comprising the following steps:
and SA: respectively weighing 4-6 parts of quasi sodium percarbonate, 3-5 parts of sodium perborate, 5-7 parts of potassium carbonate, 28-30 parts of sodium bicarbonate, 6-8 parts of sodium carbonate and 1-1.5 parts of sodium carboxymethylcellulose;
SB: weighing purified water;
SC: mixing sodium carboxymethylcellulose and sodium carbonate;
SD: adding weighed purified water into a self-adaptive stirring system, wherein the self-adaptive stirring system has the functions of lifting and forward and reverse rotation, the forward rotation and the reverse rotation of the self-adaptive stirring system are respectively and correspondingly scraped and ground, and the weighed sodium percarbonate, sodium perborate, potassium carbonate and sodium bicarbonate are added into the purified water one by one to be dissolved to form a first semi-finished product;
and SE: slowly adding the mixed sodium carboxymethylcellulose and sodium carbonate in the SC into the first semi-finished product in the SD, and stirring under the action of a self-adaptive stirring system to form a viscous colloid;
SF: stopping the self-adaptive stirring system, and sequentially adding dodecyl betaine, alkylphenol ethoxylates, alkylolamide, fatty alcohol-polyoxyethylene ether sodium sulfate, linear alkyl benzene sulfonate, a whitening antifreeze agent and essence into a viscous colloid formed by SE.
5. The method for preparing the oxygen-increasing phosphorus-free cleaning paste according to claim 4, wherein the SF comprises the following steps:
SF 1: adding dodecyl betaine, lifting and positively rotating a self-adaptive stirring system at the rotating speed of 12-15 revolutions per minute, and uniformly stirring to form a second semi-finished product;
SF 2: adding alkylphenol ethoxylates into the second semi-finished product, lifting and positively rotating a self-adaptive stirring system at the rotating speed of 12-15 revolutions per minute, and uniformly stirring to form a third semi-finished product;
SF 3: adding alkylolamide into the third semi-finished product, lifting and positively rotating the self-adaptive stirring system at the rotating speed of 12-15 revolutions per minute, and uniformly stirring to form a fourth semi-finished product;
SF 4: lifting the self-adaptive stirring system, starting the self-adaptive stirring system to reversely rotate for grinding, and grinding the fourth semi-finished product for 6-10 minutes to form a fifth semi-finished product;
SF 5: adding essence into the fifth semi-finished product, lifting the self-adaptive stirring system, and starting to rotate positively for 2-4 minutes to stir to form a sixth semi-finished product;
SF 6: adding fatty alcohol-polyoxyethylene ether sodium sulfate into the sixth semi-finished product, lifting the self-adaptive stirring system and starting forward rotation at the rotating speed of 12-15 revolutions per minute, and starting reverse rotation grinding for 9-11 minutes after the fatty alcohol-polyoxyethylene ether sodium sulfate is uniformly mixed to form a seventh semi-finished product;
SF 7: adding linear alkyl benzene sodium sulfonate into the seventh semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at the rotating speed of 12-15 revolutions per minute, uniformly mixing the linear alkyl benzene sodium sulfonate, and then starting reverse rotation grinding for 12-18 minutes to form an eighth semi-finished product;
SF 8: adding a whitening anti-freezing agent into the eighth semi-finished product, lifting the self-adaptive stirring system, starting forward rotation at the rotating speed of 12-15 revolutions per minute, uniformly mixing the linear alkyl benzene sulfonic acid sodium, and then starting reverse rotation grinding for 20-30 minutes to form a finished product.
6. The method for preparing the oxygen-increasing phosphorus-free cleaning paste as claimed in claim 4, wherein the adaptive stirring system comprises a frame, a lifting device, an adaptive stirring device and a stirring barrel, the adaptive stirring device comprises a stirring motor, a stirring frame, a sliding scraper and a thrust plate assembly, the stirring motor is mounted on the lifting device, the lifting device moves up and down along the frame, the stirring frame is mounted at the output end of the stirring motor, a discharge opening is formed in the bottom of the stirring barrel, the stirring frame extends into the stirring barrel, the stirring frame is provided with a plurality of groups of parallel horizontal guide rail beams, the sliding scraper horizontally slides along the corresponding horizontal guide rail beams, the thrust plate assembly extrudes the sliding scraper towards the side wall of the stirring barrel during rotation of the stirring frame, and a rubber knife is arranged on one side of the sliding scraper, which is close to the stirring barrel.
7. The method for preparing the oxygen-increasing phosphorus-free cleaning paste as claimed in claim 6, wherein the lifting device comprises a lifting motor, a lifting frame, a lifting screw and a plurality of lifting guide rails, the lifting guide rails are parallel to each other and fixedly arranged on the frame, the lifting motor is arranged on the frame, the lifting screw is arranged at the output end of the lifting motor, the lifting screw is connected with the lifting frame through a thread pair, and the lifting frame slides along the lifting guide rails.
8. The method for preparing the oxygen-increasing phosphorus-free cleaning paste as claimed in claim 6, wherein the thrust plate assembly comprises a push plate and a torsion spring, the push plate is rotatably mounted on the corresponding sliding scraper, the rotation axis of the push plate is plumbed, two ends of the torsion spring are respectively and fixedly mounted on the push plate and the sliding scraper, and the torsion spring enables the push plate to point to the axis of the stirring barrel when in a free state.
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