CN106883685A - A kind of modified electrically conducting transparent ink of Graphene - Google Patents
A kind of modified electrically conducting transparent ink of Graphene Download PDFInfo
- Publication number
- CN106883685A CN106883685A CN201710243270.9A CN201710243270A CN106883685A CN 106883685 A CN106883685 A CN 106883685A CN 201710243270 A CN201710243270 A CN 201710243270A CN 106883685 A CN106883685 A CN 106883685A
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- CN
- China
- Prior art keywords
- graphene
- parts
- electrically conducting
- conducting transparent
- transparent ink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Abstract
The invention belongs to electrically conductive ink technical field, more particularly to a kind of modified electrically conducting transparent ink of Graphene.Include following component according to parts by weight：10 30 parts of conductive material；15 parts of Graphene composite Nano auxiliary agent；10 20 parts of acrylyl oxy-ethyl-trimethyl salmiac；30 80 parts of binding material；1 20 parts of solvent；15 parts of auxiliary agent.Low, the lower cost according to tenor in the modified electrically conducting transparent ink of Graphene obtained in present component, and conduct electricity very well, adhesive force it is good compared with strong, printing performance.
Description
Technical field
The invention belongs to electrically conductive ink technical field, more particularly to a kind of modified electrically conducting transparent ink of Graphene.
Background technology
Electrically conductive ink has a certain degree of conduction property, is to be dispersed in binder with conductive material (gold, silver, copper and carbon)
In the paste-like ink that is made, can be used as printing conductiving point or conducting wire.
Electrically conductive ink is printed on conductive stock, is allowed to have conduction electric current, is excluded the ability of accumulation electrostatic charge, typically
It is printed on the non-conductive stock such as plastics, glass, ceramics or cardboard.With electronic product with equipment to multi-functional, highly reliable
The directions such as property are developed, and for the requirement more and more higher of electrically conductive ink, existing electrically conductive ink can not fully meet use requirement,
Urgently improve.
The content of the invention
The present invention is directed to above-mentioned problem, there is provided the Graphene that a kind of performance is good, adhesive force is strong, printing performance is good is modified saturating
Bright electrically conductive ink.
In order to achieve the above object, the technical solution adopted by the present invention is that a kind of Graphene of present invention offer is modified transparent
Electrically conductive ink, it is characterised in that include following component according to parts by weight：
Preferably, the conductive material is by graphite fibre, copper nanoparticle, nano zinc powder by weight 2：1：1 mixing group
Into.
Preferably, the Graphene composite Nano auxiliary agent is Graphene composite Nano gold grain, Graphene composite Nano
One or more in Argent grain, Graphene composite Nano copper particle, Graphene composite Nano zinc particle.
Preferably, it is 3 that the binding material is aqueous UV resins and vinylite by weight：2 mixing compositions.
Preferably, the solvent is to go water ion, propane diols and isopropanol to be mixed according to arbitrary proportion.
Preferably, the auxiliary agent is mixed for defoamer, levelling agent, corrosion inhibiter and dispersant according to arbitrary proportion.
Compared with prior art, advantages and positive effects of the present invention are,
1st, tenor is low in the modified electrically conducting transparent ink of the obtained Graphene of the present invention, lower cost.
2nd, the modified electrically conducting transparent ink of the obtained Graphene of the present invention conduct electricity very well, adhesive force relatively strong, printing performance
It is good.
Specific embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to embodiment to this hair
It is bright to be described further.It should be noted that in the case where not conflicting, the feature in embodiments herein and embodiment can
To be mutually combined.
Many details are elaborated in the following description in order to fully understand the present invention, but, the present invention may be used also
To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below
The limitation of embodiment.
The present invention provides a kind of black alkene modified electrically conducting transparent ink, and following component is included according to parts by weight：Conductive material
10~30 parts；1~5 part of Graphene composite Nano auxiliary agent；10~20 parts of acrylyl oxy-ethyl-trimethyl salmiac；Binding material 30~
80 parts；Solvent 1~20；Auxiliary agent 1~5.Conductive material is by graphite fibre, copper nanoparticle, nano zinc powder by weight 2 among these：
1：1 mixing composition；Graphene composite Nano auxiliary agent is Graphene composite Nano gold grain, Graphene composite Nano Argent grain, stone
One or more in black alkene composite Nano copper particle, Graphene composite Nano zinc particle；Binding material is aqueous UV resins and second
Ene based resins are 3 by weight：2 mixing compositions；Solvent for go water ion, propane diols and isopropanol according to arbitrary proportion mix and
Into；Auxiliary agent is mixed for defoamer, levelling agent, corrosion inhibiter and dispersant according to arbitrary proportion.Inventor is by many experiments
Draw from how much material consumption has different effects, in the following examples, just different selection is explained in detail.
Embodiment 1
A kind of modified electrically conducting transparent ink of Graphene, following component is included according to parts by weight：
10 parts of graphite fibre, 5 parts of copper nanoparticle, 5 parts of nano zinc powder, 1 part of Graphene composite Nano Argent grain, acryloyl-oxy
10 parts of ethyl-trimethyl salmiac, 30 parts of aqueous UV resins, 20 parts of vinylite, 8 parts of deionized water, 5 parts of propane diols, isopropyl
4 parts of alcohol, 0.5 part of defoamer, 0.5 part of levelling agent, 0.5 part of corrosion inhibiter, 0.5 part of dispersant.
Embodiment 2
A kind of modified electrically conducting transparent ink of Graphene, following component is included according to parts by weight：8 parts of graphite fibre, nanometer
4 parts of copper powder, 4 parts of nano zinc powder, 1 part of Graphene composite Nano zinc particle, 15 parts of acrylyl oxy-ethyl-trimethyl salmiac is aqueous
27 parts of UV resins, 18 parts of vinylite, 10 parts of deionized water, 6 parts of propane diols, 3 parts of isopropanol, 1 part of defoamer, levelling agent 1
Part, 1 part of corrosion inhibiter, 1 part of dispersant.
Embodiment 3
A kind of modified electrically conducting transparent ink of Graphene, following component is included according to parts by weight：6 parts of graphite fibre, nanometer
3 parts of copper powder, 3 parts of nano zinc powder, 2 parts of Graphene composite Nano zinc particle, 11 parts of acrylyl oxy-ethyl-trimethyl salmiac is aqueous
33 parts of UV resins, 22 parts of vinylite, 7 parts of deionized water, 5 parts of propane diols, 5 parts of isopropanol, 0.5 part of defoamer, levelling agent
0.5 part, 1 part of corrosion inhibiter, 1 part of dispersant.
By the modified electrically conducting transparent ink brush of Graphene obtained above on the transparent substrate, using the half tone of 200 mesh, carry out
Silk-screen printing, the dry solidification 40min under conditions of 150 DEG C/min finally gives the compound of the solidification that thickness is 20 μm or so
Conductive oil ink film, tests it, as a result as follows：
The modified electrically conducting transparent oil of the Graphene as obtained in the present invention according to Different Weight number is can be seen that as upper table data
Ink is small compared to common conductive ink sheet resistance, and electric conductivity is more preferable；Hardness is high；Adhesive force is stronger.
The above, is only presently preferred embodiments of the present invention, is not the limitation for making other forms to the present invention, is appointed
What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc.
Effect embodiment is applied to other fields, but every without departing from technical solution of the present invention content, according to technical spirit of the invention
Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.
Claims (6)
1. the electrically conducting transparent ink that a kind of Graphene is modified, it is characterised in that include following component according to parts by weight：
2. the electrically conducting transparent ink that a kind of Graphene is modified according to claim 1, it is characterised in that：The conductive material by
Graphite fibre, copper nanoparticle, nano zinc powder are by weight 2：1：1 mixing composition.
3. the electrically conducting transparent ink that a kind of Graphene is modified according to claim 1, it is characterised in that：The Graphene is combined
Nano assistant is Graphene composite Nano gold grain, Graphene composite Nano Argent grain, Graphene composite Nano copper particle, graphite
One or more in alkene composite Nano zinc particle.
4. the electrically conducting transparent ink that a kind of Graphene is modified according to claim 1, it is characterised in that：The binding material is water
Property UV resins and vinylite by weight be 3：2 mixing compositions.
5. the electrically conducting transparent ink that a kind of Graphene is modified according to claim 1, it is characterised in that：The solvent is to remove water
Ion, propane diols and isopropanol are mixed according to arbitrary proportion.
6. the electrically conducting transparent ink that a kind of Graphene is modified according to claim 1, it is characterised in that：The auxiliary agent is froth breaking
Agent, levelling agent, corrosion inhibiter and dispersant are mixed according to arbitrary proportion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710243270.9A CN106883685A (en) | 2017-04-14 | 2017-04-14 | A kind of modified electrically conducting transparent ink of Graphene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710243270.9A CN106883685A (en) | 2017-04-14 | 2017-04-14 | A kind of modified electrically conducting transparent ink of Graphene |
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| Publication Number | Publication Date |
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| CN106883685A true CN106883685A (en) | 2017-06-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710243270.9A Pending CN106883685A (en) | 2017-04-14 | 2017-04-14 | A kind of modified electrically conducting transparent ink of Graphene |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753044A (en) * | 2018-06-05 | 2018-11-06 | 沈阳建筑大学 | A kind of plating copper nano-particle Graphene conductive ink and preparation method thereof |
| CN113205903A (en) * | 2021-04-23 | 2021-08-03 | 广东省科学院新材料研究所 | Transparent conductive film and preparation method thereof |
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| CN101974266A (en) * | 2010-09-30 | 2011-02-16 | 彩虹集团公司 | Low-temperature conductive carbon slurry and preparation method thereof |
| CN103436099A (en) * | 2013-09-11 | 2013-12-11 | 中国科学院宁波材料技术与工程研究所 | Composite conductive printing ink |
| WO2014085473A1 (en) * | 2012-11-30 | 2014-06-05 | Nthdegree Technologies Worldwide Inc. | Ultra violet-curable conductive ink and dielectric ink compositions |
| CN104263082A (en) * | 2014-08-29 | 2015-01-07 | 南京航空航天大学 | Graphene organic silver conductive printing ink and preparation method thereof |
| CN104310388A (en) * | 2014-10-15 | 2015-01-28 | 宁波墨西科技有限公司 | Graphene composite powder material and preparation method thereof |
| CN106189526A (en) * | 2016-09-05 | 2016-12-07 | 李锦明 | A kind of electrically conducting transparent ink |
-
2017
- 2017-04-14 CN CN201710243270.9A patent/CN106883685A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974266A (en) * | 2010-09-30 | 2011-02-16 | 彩虹集团公司 | Low-temperature conductive carbon slurry and preparation method thereof |
| WO2014085473A1 (en) * | 2012-11-30 | 2014-06-05 | Nthdegree Technologies Worldwide Inc. | Ultra violet-curable conductive ink and dielectric ink compositions |
| CN103436099A (en) * | 2013-09-11 | 2013-12-11 | 中国科学院宁波材料技术与工程研究所 | Composite conductive printing ink |
| CN104263082A (en) * | 2014-08-29 | 2015-01-07 | 南京航空航天大学 | Graphene organic silver conductive printing ink and preparation method thereof |
| CN104310388A (en) * | 2014-10-15 | 2015-01-28 | 宁波墨西科技有限公司 | Graphene composite powder material and preparation method thereof |
| CN106189526A (en) * | 2016-09-05 | 2016-12-07 | 李锦明 | A kind of electrically conducting transparent ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753044A (en) * | 2018-06-05 | 2018-11-06 | 沈阳建筑大学 | A kind of plating copper nano-particle Graphene conductive ink and preparation method thereof |
| CN113205903A (en) * | 2021-04-23 | 2021-08-03 | 广东省科学院新材料研究所 | Transparent conductive film and preparation method thereof |
| CN113205903B (en) * | 2021-04-23 | 2022-06-14 | 广东省科学院新材料研究所 | Transparent conductive film and preparation method thereof |
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Application publication date: 20170623 |
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