CN106752385A - A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof - Google Patents
A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof Download PDFInfo
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- CN106752385A CN106752385A CN201710019297.XA CN201710019297A CN106752385A CN 106752385 A CN106752385 A CN 106752385A CN 201710019297 A CN201710019297 A CN 201710019297A CN 106752385 A CN106752385 A CN 106752385A
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- electrically conductive
- conductive ink
- graphene
- modified water
- graphene modified
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention belongs to technical field of ink,More particularly to a kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof,Include 10 40 parts of water-base resin according to parts by weight,0 30 parts of water,5 25 parts of cosolvent,10 parts of auxiliary agent,30 80 parts of conductive black,0.1 20 parts of Graphene,The present invention takes full advantage of graphene conductive,The good performance of heat conductivility,The Graphene modified water-soluble electrically conductive ink mechanical performance of preparation is excellent,Pliability well can be resistant to bending,It is strong with base material adhesive force,Antistripping,It is not oxidizable after the printing product solidification that electrically conductive ink is made,Stable performance,It is acidproof,Alkali and chemical solvent corrode,Using the good conductive characteristic of Graphene,The sheet resistance of electrically conductive ink,Its sheet resistance is less than 10 Ω,The alternative oil product of electrically conductive ink that the present invention is provided,Organic solvent is used and discharge greatly reduces,Physical impairment to workmen is substantially reduced,Reach the purpose for reducing VOC emission,Green,Environmental protection,With good market value.
Description
Technical field
The invention belongs to technical field of ink, more particularly to a kind of Graphene modified water-soluble electrically conductive ink and its preparation side
Method.
Background technology
With flexible electronic industrial expansion, the combination of electronic technology and printing technology is more next closely, to electrically conductive ink
Demand is also increasing.Traditional solvent-borne type electrically conductive ink with the addition of substantial amounts of organic solvent, exist to human body and environment different
The harm of degree.Contain substantial amounts of VOC in ink, it can outwards volatilize substantial amounts of toxic chemical substance in use,
Wherein, benzene, formaldehyde, dimethylbenzene are all poisonous and hazardous chemical gas;These organic solvents evaporateing into air are while also make
Wasted into very serious petroleum resources;Oil paint belongs to combustible and explosive articles, exists during production and use very big
Potential safety hazard;The workman of Long Term Contact solvent-borne type electrically conductive ink, its life security is on the hazard.
In recent years, with national environmental protection and the reinforcement of workman's labour protection, with the waterborne conductive oil of water substitution organic solvent
Black technique has become the important directions of electrically conductive ink development.At present, water-soluble conducting ink be subject to that electric conductivity is weak, adhesive force compared with
A series of influences such as difference, stability, aspect of performance cannot be compared with ripe solvent-borne type to electrically conductive ink.
The content of the invention
The present invention is in order to solve the deficiencies in the prior art, there is provided a kind of low VOC emission, excellent performance, printable green are low
Graphene modified water-soluble electrically conductive ink of cost and preparation method thereof.
In order to achieve the above object, the technical solution adopted by the present invention is that the present invention provides a kind of Graphene modified water-soluble
Electrically conductive ink, it is characterised in that the Graphene modified water-soluble electrically conductive ink includes following component according to parts by weight:
Preferably, the water-base resin is water-soluble resin or artificial synthesized water-soluble resin.
Preferably, the cosolvent is in ethanol, triethylamine, butyl glycol ether, isopropanol, ethylene glycol, glycerine
One or more.
Preferably, the auxiliary agent is one or more in dispersant, wetting agent, defoamer, levelling agent and rheological agent,
Wherein, the addition of each material is, 0.1~2 part of dispersant, 0.1~2 part of wetting agent, 0.1~2 part of defoamer, levelling agent 0.1
~2 parts, 0.1~2 part of rheological agent.
Preferably, the dispersant is any in polycarboxylate sodium, polyacrylic acid sylvite, polyacrylic acid sodium salt
A kind of material;The wetting agent be fatty acid ester sulfate, APES, polyoxyethylene modifier in one kind or
It is various;The defoamer is the polysiloxane-based defoamer of hydrophobic type, mineral oil, organic silica modifying agent, silicone froth breaking
Any one material in agent;The levelling agent is organically-modified dimethyl silicone polymer;The rheological agent is association type propylene
Any one material in acid esters, polyurethane rheological agent.
Preferably, the conductive black is acetylene carbon black.
Preferably, the Graphene is single-layer graphene, bilayer graphene, multi-layer graphene or nano-graphene piece
In one or more.
9. inventor additionally provides a kind of preparation method of Graphene modified water-soluble electrically conductive ink, it is characterised in that including
Following steps:
(1) raw material and dispersion are weighed:According to Graphene modified water-soluble electrically conductive ink constituent content described in claim 1 according to
Certain proportion is put into stirring in Scattered Kettle, mixes pre-dispersed uniform;
(2) grind:The pre-dispersed material that step (1) is obtained is transferred to grinding in grinder, until fineness of materials reaches
Less than 10 microns;
(3) by ground material filtering, you can obtain Graphene modified water-soluble electrically conductive ink.
Preferably, the grinder is the one kind in sand mill, ball mill or three-roll grinder.
Compared with prior art, advantages and positive effects of the present invention are,
1st, Graphene is used for electrically conductive ink by the present invention, takes full advantage of the good performance of graphene conductive, heat conductivility,
Graphene modified water-soluble electrically conductive ink mechanical performance prepared by the present invention is excellent, and pliability well can be resistant to bending, with base material adhesive force
By force, antistripping, not oxidizable, stable performance after the printing product solidification that electrically conductive ink is made, acid and alkali resistance and chemical solvent corrode.
2nd, using the good conductive characteristic of Graphene, the sheet resistance of electrically conductive ink, its sheet resistance is less than 10 Ω to the present invention.
3rd, the alternative oil product of electrically conductive ink that the present invention is provided, organic solvent is used and discharge greatly reduces, to applying
The physical impairment of workman person is substantially reduced, and reaches the purpose for reducing VOC emission, green, environmental protection, with good market value.
Specific embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to embodiment to this hair
It is bright to be described further.It should be noted that in the case where not conflicting, the feature in embodiments herein and embodiment can
To be mutually combined.
Many details are elaborated in the following description in order to fully understand the present invention, but, the present invention may be used also
To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below
The limitation of embodiment.
The present invention provides a kind of Graphene modified water-soluble electrically conductive ink, and Graphene modified water-soluble electrically conductive ink is according to weight portion
Number includes 10-40 parts of following component water-base resin, water 0-30 parts, cosolvent 5-25 parts, -10 parts of auxiliary agent, conductive black 30-80
Part, Graphene 0.1-20 parts, wherein water-base resin is water-soluble resin or artificial synthesized water-soluble resin, such as aqueous third
Olefin(e) acid resin, waterborne polyurethane resin, phenolic resin, cellulose derivative, amino resins, modified polybutadiene resin, polyester
Resin etc..Cosolvent is one or more in ethanol, triethylamine, butyl glycol ether, isopropanol, ethylene glycol, glycerine.Auxiliary agent
It is one or more in dispersant, wetting agent, defoamer, levelling agent and rheological agent, wherein, the addition of each material is to divide
0.1~2 part of powder, 0.1~2 part of wetting agent, 0.1~2 part of defoamer, 0.1~2 part of levelling agent, 0.1~2 part of rheological agent, dispersion
Agent is any one material in polycarboxylate sodium, polyacrylic acid sylvite, polyacrylic acid sodium salt;Wetting agent is fatty acid ester sulfuric acid
One or more in salt, APES, polyoxyethylene modifier;Defoamer is the polysiloxane-based froth breaking of hydrophobic type
Any one material in agent, mineral oil, organic silica modifying agent, silicone defoamer;Levelling agent is organically-modified poly-
Dimethyl siloxane;Rheological agent is any one material in association type acrylate, polyurethane rheological agent.Conductive black is selected
Acetylene carbon black, the resistivity of acetylene carbon black is extremely low, with excellent electric conductivity, thermal conductivity and antistatic effect.Graphene is single
One or more in layer graphene, bilayer graphene, multi-layer graphene or nano-graphene piece of combination.Inventor passes through
Many experiments draw the Graphene modified water-soluble electrically conductive ink that different-effect is obtained from different material and different proportion, below
In embodiment, different choice is explained in detail
Embodiment 1
Weigh 10 parts of water-and acrylate, 10 parts of water, 5 parts of ethanol, 5 parts of triethylamine, 1 part of polycarboxylate sodium, fatty acid ester
1 part of sulfate, 1 part of the polysiloxane-based defoamer of hydrophobic type, 1 part of organically-modified dimethyl silicone polymer, association type acrylate 1
Part, 30 parts of conductive acetylene carbon black, 0.1 part of multi-layer graphene is put into stirring in Scattered Kettle, is well mixed, and obtains pre-dispersed material;Will
The pre-dispersed material for obtaining is transferred in sand mill until fineness of materials reaches less than 10 microns;By ground material filtering, i.e.,
Can obtain Graphene modified water-soluble electrically conductive ink.
Embodiment 2
Weigh 20 parts of aqueous polyurethane, 20 parts of water, 15 parts of ethanol, 15 parts of butyl glycol ether, 1.5 parts of polyacrylic acid sylvite,
1.5 parts of APES, 0.4 part of silicone defoamer, 1.5 parts of organically-modified dimethyl silicone polymer, association type third
1.5 parts of olefin(e) acid ester, 60 parts of acetylene carbon black, 10 parts of multi-layer graphene is put into stirring in Scattered Kettle, is well mixed, and obtains pre-dispersed
Material;The pre-dispersed material that will be obtained is transferred in ball mill until fineness of materials reaches less than 10 microns;By ground material mistake
Filter, you can obtain Graphene modified water-soluble electrically conductive ink.
Embodiment 3
Weigh 40 parts of resol resins, 30 parts of water, 25 parts of isopropanol, 2 parts of polyacrylic acid sodium salt, fatty acid ester sulfate
2 parts, 2 parts of the polysiloxane-based defoamer of hydrophobic type, 2 parts of machine modified dimethyl polysiloxane, 2 parts of polyurethane rheological agent is put into point
Dissipate stirring in kettle, be well mixed, obtain pre-dispersed material;The pre-dispersed material that will be obtained is transferred in three-roll grinder until material is thin
Degree reaches less than 10 microns;By ground material filtering, you can obtain Graphene modified water-soluble electrically conductive ink.
According to above-described embodiment 1, embodiment 2 and the print that is made of Graphene modified water-soluble electrically conductive ink obtained in embodiment 3
After product solidification, not oxidizable and stable performance, acid and alkali-resistance and chemical solvent corrode, with good electric conductivity, conductive oil
The sheet resistance of ink is less than 10 Ω.
The above, is only presently preferred embodiments of the present invention, is not the limitation for making other forms to the present invention, is appointed
What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc.
Effect embodiment is applied to other fields, but every without departing from technical solution of the present invention content, according to technical spirit of the invention
Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.
Claims (9)
1. a kind of Graphene modified water-soluble electrically conductive ink, it is characterised in that the Graphene modified water-soluble electrically conductive ink is according to weight
Amount number includes following component:
2. a kind of Graphene modified water-soluble electrically conductive ink according to claim 1, it is characterised in that:The water-base resin is day
Right water-soluble resin or artificial synthesized water-soluble resin.
3. a kind of Graphene modified water-soluble electrically conductive ink according to claim 1, it is characterised in that:The cosolvent is second
One or more in alcohol, triethylamine, butyl glycol ether, isopropanol, ethylene glycol, glycerine.
4. a kind of Graphene modified water-soluble electrically conductive ink according to claim 1, it is characterised in that:The auxiliary agent is dispersion
One or more in agent, wetting agent, defoamer, levelling agent and rheological agent, wherein, the addition of each material is, dispersant 0.1
~2 parts, 0.1~2 part of wetting agent, 0.1~2 part of defoamer, 0.1~2 part of levelling agent, 0.1~2 part of rheological agent.
5. a kind of Graphene modified water-soluble electrically conductive ink according to claim 4, it is characterised in that:The dispersant is
Any one material in polycarboxylate sodium, polyacrylic acid sylvite, polyacrylic acid sodium salt;The wetting agent is fatty acid ester sulfuric acid
One or more in salt, APES, polyoxyethylene modifier;The defoamer is that hydrophobic type is polysiloxane-based
Any one material in defoamer, mineral oil, organic silica modifying agent, silicone defoamer;The levelling agent is have
Machine modified dimethyl polysiloxane;The rheological agent is any one material in association type acrylate, polyurethane rheological agent.
6. a kind of Graphene modified water-soluble electrically conductive ink according to claim 4, it is characterised in that:The conductive black is second
Alkynes carbon black.
7. a kind of Graphene modified water-soluble electrically conductive ink according to claim 4, it is characterised in that:The Graphene is individual layer
One or more in Graphene, bilayer graphene, multi-layer graphene or nano-graphene piece.
8. a kind of preparation method of Graphene modified water-soluble electrically conductive ink, it is characterised in that comprise the following steps:
(1) raw material and dispersion are weighed:According to Graphene modified water-soluble electrically conductive ink constituent content described in claim 1 according to certain
Ratio is put into stirring in Scattered Kettle, mixes pre-dispersed uniform;
(2) grind:The pre-dispersed material that step (1) is obtained is transferred to grinding in grinder, until fineness of materials to reach 10 micro-
Rice is following;
(3) by ground material filtering, you can obtain Graphene modified water-soluble electrically conductive ink.
9. a kind of preparation method of Graphene modified water-soluble electrically conductive ink according to claim 8, it is characterised in that:It is described to grind
Grinding machine is the one kind in sand mill, ball mill or three-roll grinder.
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107057409A (en) * | 2017-06-09 | 2017-08-18 | 宁波工程学院 | A kind of preparation method of graphene-based electrically conductive ink filler |
CN108570265A (en) * | 2018-06-12 | 2018-09-25 | 苏州中亚油墨有限公司 | A kind of aqueous composite conducting ink and preparation method thereof |
WO2018228407A1 (en) * | 2017-06-14 | 2018-12-20 | 厦门信达光电物联科技研究院有限公司 | Graphene/metal nanobelt composite conductive ink, preparation method therefor and application thereof |
CN109181153A (en) * | 2018-08-08 | 2019-01-11 | 广东冠盛新材料有限公司 | A kind of high durable outdoor decoration film and preparation method thereof |
CN110283497A (en) * | 2019-06-28 | 2019-09-27 | 深圳烯材科技有限公司 | A method of printing the silk-screened conductive ink of accurate self limiting temperature flexible electrothermal membrane |
CN110408267A (en) * | 2019-08-19 | 2019-11-05 | 泰能环保科技(浙江)有限公司 | A kind of Graphene conductive ink and preparation method thereof |
CN110769528A (en) * | 2019-10-11 | 2020-02-07 | 深圳天元羲王材料科技有限公司 | Graphene aqueous heating film conductive paste |
CN112029342A (en) * | 2020-09-25 | 2020-12-04 | 欧菲微电子技术有限公司 | Conductive ink, ultrasonic fingerprint module and electronic equipment |
CN112940561A (en) * | 2021-04-13 | 2021-06-11 | 浙江伟航新材料科技有限公司 | High-adhesion water-based ink and preparation method thereof |
CN113881287A (en) * | 2021-10-21 | 2022-01-04 | 北京旭碳新材料科技有限公司 | Water-based graphene conductive ink composition, water-based graphene conductive ink, and preparation method and application thereof |
CN115340823A (en) * | 2022-08-18 | 2022-11-15 | 东莞市樱之蓝新材料科技有限公司 | Odorless environment-friendly low-resistance water-based conductive paint and preparation method thereof |
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CN107057409B (en) * | 2017-06-09 | 2019-03-05 | 宁波工程学院 | A kind of preparation method of graphene-based electrically conductive ink filler |
CN107057409A (en) * | 2017-06-09 | 2017-08-18 | 宁波工程学院 | A kind of preparation method of graphene-based electrically conductive ink filler |
WO2018228407A1 (en) * | 2017-06-14 | 2018-12-20 | 厦门信达光电物联科技研究院有限公司 | Graphene/metal nanobelt composite conductive ink, preparation method therefor and application thereof |
CN108570265A (en) * | 2018-06-12 | 2018-09-25 | 苏州中亚油墨有限公司 | A kind of aqueous composite conducting ink and preparation method thereof |
CN109181153A (en) * | 2018-08-08 | 2019-01-11 | 广东冠盛新材料有限公司 | A kind of high durable outdoor decoration film and preparation method thereof |
CN110283497B (en) * | 2019-06-28 | 2022-07-12 | 深圳烯材科技有限公司 | Method for printing screen printing conductive ink of precise self-temperature-limiting flexible electrothermal film |
CN110283497A (en) * | 2019-06-28 | 2019-09-27 | 深圳烯材科技有限公司 | A method of printing the silk-screened conductive ink of accurate self limiting temperature flexible electrothermal membrane |
CN110408267A (en) * | 2019-08-19 | 2019-11-05 | 泰能环保科技(浙江)有限公司 | A kind of Graphene conductive ink and preparation method thereof |
CN110769528A (en) * | 2019-10-11 | 2020-02-07 | 深圳天元羲王材料科技有限公司 | Graphene aqueous heating film conductive paste |
CN112029342A (en) * | 2020-09-25 | 2020-12-04 | 欧菲微电子技术有限公司 | Conductive ink, ultrasonic fingerprint module and electronic equipment |
CN112940561A (en) * | 2021-04-13 | 2021-06-11 | 浙江伟航新材料科技有限公司 | High-adhesion water-based ink and preparation method thereof |
CN113881287A (en) * | 2021-10-21 | 2022-01-04 | 北京旭碳新材料科技有限公司 | Water-based graphene conductive ink composition, water-based graphene conductive ink, and preparation method and application thereof |
CN115340823A (en) * | 2022-08-18 | 2022-11-15 | 东莞市樱之蓝新材料科技有限公司 | Odorless environment-friendly low-resistance water-based conductive paint and preparation method thereof |
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