CN106752385A - A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof - Google Patents

A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof Download PDF

Info

Publication number
CN106752385A
CN106752385A CN201710019297.XA CN201710019297A CN106752385A CN 106752385 A CN106752385 A CN 106752385A CN 201710019297 A CN201710019297 A CN 201710019297A CN 106752385 A CN106752385 A CN 106752385A
Authority
CN
China
Prior art keywords
electrically conductive
conductive ink
graphene
modified water
graphene modified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710019297.XA
Other languages
Chinese (zh)
Inventor
车云霞
侯士峰
吕艳红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Special Novel Material Science And Technology Ltd Of Qingdao Rayleigh
Original Assignee
Special Novel Material Science And Technology Ltd Of Qingdao Rayleigh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Special Novel Material Science And Technology Ltd Of Qingdao Rayleigh filed Critical Special Novel Material Science And Technology Ltd Of Qingdao Rayleigh
Priority to CN201710019297.XA priority Critical patent/CN106752385A/en
Publication of CN106752385A publication Critical patent/CN106752385A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/52Electrically conductive inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

Abstract

The invention belongs to technical field of ink,More particularly to a kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof,Include 10 40 parts of water-base resin according to parts by weight,0 30 parts of water,5 25 parts of cosolvent,10 parts of auxiliary agent,30 80 parts of conductive black,0.1 20 parts of Graphene,The present invention takes full advantage of graphene conductive,The good performance of heat conductivility,The Graphene modified water-soluble electrically conductive ink mechanical performance of preparation is excellent,Pliability well can be resistant to bending,It is strong with base material adhesive force,Antistripping,It is not oxidizable after the printing product solidification that electrically conductive ink is made,Stable performance,It is acidproof,Alkali and chemical solvent corrode,Using the good conductive characteristic of Graphene,The sheet resistance of electrically conductive ink,Its sheet resistance is less than 10 Ω,The alternative oil product of electrically conductive ink that the present invention is provided,Organic solvent is used and discharge greatly reduces,Physical impairment to workmen is substantially reduced,Reach the purpose for reducing VOC emission,Green,Environmental protection,With good market value.

Description

A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof
Technical field
The invention belongs to technical field of ink, more particularly to a kind of Graphene modified water-soluble electrically conductive ink and its preparation side Method.
Background technology
With flexible electronic industrial expansion, the combination of electronic technology and printing technology is more next closely, to electrically conductive ink Demand is also increasing.Traditional solvent-borne type electrically conductive ink with the addition of substantial amounts of organic solvent, exist to human body and environment different The harm of degree.Contain substantial amounts of VOC in ink, it can outwards volatilize substantial amounts of toxic chemical substance in use, Wherein, benzene, formaldehyde, dimethylbenzene are all poisonous and hazardous chemical gas;These organic solvents evaporateing into air are while also make Wasted into very serious petroleum resources;Oil paint belongs to combustible and explosive articles, exists during production and use very big Potential safety hazard;The workman of Long Term Contact solvent-borne type electrically conductive ink, its life security is on the hazard.
In recent years, with national environmental protection and the reinforcement of workman's labour protection, with the waterborne conductive oil of water substitution organic solvent Black technique has become the important directions of electrically conductive ink development.At present, water-soluble conducting ink be subject to that electric conductivity is weak, adhesive force compared with A series of influences such as difference, stability, aspect of performance cannot be compared with ripe solvent-borne type to electrically conductive ink.
The content of the invention
The present invention is in order to solve the deficiencies in the prior art, there is provided a kind of low VOC emission, excellent performance, printable green are low Graphene modified water-soluble electrically conductive ink of cost and preparation method thereof.
In order to achieve the above object, the technical solution adopted by the present invention is that the present invention provides a kind of Graphene modified water-soluble Electrically conductive ink, it is characterised in that the Graphene modified water-soluble electrically conductive ink includes following component according to parts by weight:
Preferably, the water-base resin is water-soluble resin or artificial synthesized water-soluble resin.
Preferably, the cosolvent is in ethanol, triethylamine, butyl glycol ether, isopropanol, ethylene glycol, glycerine One or more.
Preferably, the auxiliary agent is one or more in dispersant, wetting agent, defoamer, levelling agent and rheological agent, Wherein, the addition of each material is, 0.1~2 part of dispersant, 0.1~2 part of wetting agent, 0.1~2 part of defoamer, levelling agent 0.1 ~2 parts, 0.1~2 part of rheological agent.
Preferably, the dispersant is any in polycarboxylate sodium, polyacrylic acid sylvite, polyacrylic acid sodium salt A kind of material;The wetting agent be fatty acid ester sulfate, APES, polyoxyethylene modifier in one kind or It is various;The defoamer is the polysiloxane-based defoamer of hydrophobic type, mineral oil, organic silica modifying agent, silicone froth breaking Any one material in agent;The levelling agent is organically-modified dimethyl silicone polymer;The rheological agent is association type propylene Any one material in acid esters, polyurethane rheological agent.
Preferably, the conductive black is acetylene carbon black.
Preferably, the Graphene is single-layer graphene, bilayer graphene, multi-layer graphene or nano-graphene piece In one or more.
9. inventor additionally provides a kind of preparation method of Graphene modified water-soluble electrically conductive ink, it is characterised in that including Following steps:
(1) raw material and dispersion are weighed:According to Graphene modified water-soluble electrically conductive ink constituent content described in claim 1 according to Certain proportion is put into stirring in Scattered Kettle, mixes pre-dispersed uniform;
(2) grind:The pre-dispersed material that step (1) is obtained is transferred to grinding in grinder, until fineness of materials reaches Less than 10 microns;
(3) by ground material filtering, you can obtain Graphene modified water-soluble electrically conductive ink.
Preferably, the grinder is the one kind in sand mill, ball mill or three-roll grinder.
Compared with prior art, advantages and positive effects of the present invention are,
1st, Graphene is used for electrically conductive ink by the present invention, takes full advantage of the good performance of graphene conductive, heat conductivility, Graphene modified water-soluble electrically conductive ink mechanical performance prepared by the present invention is excellent, and pliability well can be resistant to bending, with base material adhesive force By force, antistripping, not oxidizable, stable performance after the printing product solidification that electrically conductive ink is made, acid and alkali resistance and chemical solvent corrode.
2nd, using the good conductive characteristic of Graphene, the sheet resistance of electrically conductive ink, its sheet resistance is less than 10 Ω to the present invention.
3rd, the alternative oil product of electrically conductive ink that the present invention is provided, organic solvent is used and discharge greatly reduces, to applying The physical impairment of workman person is substantially reduced, and reaches the purpose for reducing VOC emission, green, environmental protection, with good market value.
Specific embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to embodiment to this hair It is bright to be described further.It should be noted that in the case where not conflicting, the feature in embodiments herein and embodiment can To be mutually combined.
Many details are elaborated in the following description in order to fully understand the present invention, but, the present invention may be used also To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below The limitation of embodiment.
The present invention provides a kind of Graphene modified water-soluble electrically conductive ink, and Graphene modified water-soluble electrically conductive ink is according to weight portion Number includes 10-40 parts of following component water-base resin, water 0-30 parts, cosolvent 5-25 parts, -10 parts of auxiliary agent, conductive black 30-80 Part, Graphene 0.1-20 parts, wherein water-base resin is water-soluble resin or artificial synthesized water-soluble resin, such as aqueous third Olefin(e) acid resin, waterborne polyurethane resin, phenolic resin, cellulose derivative, amino resins, modified polybutadiene resin, polyester Resin etc..Cosolvent is one or more in ethanol, triethylamine, butyl glycol ether, isopropanol, ethylene glycol, glycerine.Auxiliary agent It is one or more in dispersant, wetting agent, defoamer, levelling agent and rheological agent, wherein, the addition of each material is to divide 0.1~2 part of powder, 0.1~2 part of wetting agent, 0.1~2 part of defoamer, 0.1~2 part of levelling agent, 0.1~2 part of rheological agent, dispersion Agent is any one material in polycarboxylate sodium, polyacrylic acid sylvite, polyacrylic acid sodium salt;Wetting agent is fatty acid ester sulfuric acid One or more in salt, APES, polyoxyethylene modifier;Defoamer is the polysiloxane-based froth breaking of hydrophobic type Any one material in agent, mineral oil, organic silica modifying agent, silicone defoamer;Levelling agent is organically-modified poly- Dimethyl siloxane;Rheological agent is any one material in association type acrylate, polyurethane rheological agent.Conductive black is selected Acetylene carbon black, the resistivity of acetylene carbon black is extremely low, with excellent electric conductivity, thermal conductivity and antistatic effect.Graphene is single One or more in layer graphene, bilayer graphene, multi-layer graphene or nano-graphene piece of combination.Inventor passes through Many experiments draw the Graphene modified water-soluble electrically conductive ink that different-effect is obtained from different material and different proportion, below In embodiment, different choice is explained in detail
Embodiment 1
Weigh 10 parts of water-and acrylate, 10 parts of water, 5 parts of ethanol, 5 parts of triethylamine, 1 part of polycarboxylate sodium, fatty acid ester 1 part of sulfate, 1 part of the polysiloxane-based defoamer of hydrophobic type, 1 part of organically-modified dimethyl silicone polymer, association type acrylate 1 Part, 30 parts of conductive acetylene carbon black, 0.1 part of multi-layer graphene is put into stirring in Scattered Kettle, is well mixed, and obtains pre-dispersed material;Will The pre-dispersed material for obtaining is transferred in sand mill until fineness of materials reaches less than 10 microns;By ground material filtering, i.e., Can obtain Graphene modified water-soluble electrically conductive ink.
Embodiment 2
Weigh 20 parts of aqueous polyurethane, 20 parts of water, 15 parts of ethanol, 15 parts of butyl glycol ether, 1.5 parts of polyacrylic acid sylvite, 1.5 parts of APES, 0.4 part of silicone defoamer, 1.5 parts of organically-modified dimethyl silicone polymer, association type third 1.5 parts of olefin(e) acid ester, 60 parts of acetylene carbon black, 10 parts of multi-layer graphene is put into stirring in Scattered Kettle, is well mixed, and obtains pre-dispersed Material;The pre-dispersed material that will be obtained is transferred in ball mill until fineness of materials reaches less than 10 microns;By ground material mistake Filter, you can obtain Graphene modified water-soluble electrically conductive ink.
Embodiment 3
Weigh 40 parts of resol resins, 30 parts of water, 25 parts of isopropanol, 2 parts of polyacrylic acid sodium salt, fatty acid ester sulfate 2 parts, 2 parts of the polysiloxane-based defoamer of hydrophobic type, 2 parts of machine modified dimethyl polysiloxane, 2 parts of polyurethane rheological agent is put into point Dissipate stirring in kettle, be well mixed, obtain pre-dispersed material;The pre-dispersed material that will be obtained is transferred in three-roll grinder until material is thin Degree reaches less than 10 microns;By ground material filtering, you can obtain Graphene modified water-soluble electrically conductive ink.
According to above-described embodiment 1, embodiment 2 and the print that is made of Graphene modified water-soluble electrically conductive ink obtained in embodiment 3 After product solidification, not oxidizable and stable performance, acid and alkali-resistance and chemical solvent corrode, with good electric conductivity, conductive oil The sheet resistance of ink is less than 10 Ω.
The above, is only presently preferred embodiments of the present invention, is not the limitation for making other forms to the present invention, is appointed What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc. Effect embodiment is applied to other fields, but every without departing from technical solution of the present invention content, according to technical spirit of the invention Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.

Claims (9)

1. a kind of Graphene modified water-soluble electrically conductive ink, it is characterised in that the Graphene modified water-soluble electrically conductive ink is according to weight Amount number includes following component:
2. a kind of Graphene modified water-soluble electrically conductive ink according to claim 1, it is characterised in that:The water-base resin is day Right water-soluble resin or artificial synthesized water-soluble resin.
3. a kind of Graphene modified water-soluble electrically conductive ink according to claim 1, it is characterised in that:The cosolvent is second One or more in alcohol, triethylamine, butyl glycol ether, isopropanol, ethylene glycol, glycerine.
4. a kind of Graphene modified water-soluble electrically conductive ink according to claim 1, it is characterised in that:The auxiliary agent is dispersion One or more in agent, wetting agent, defoamer, levelling agent and rheological agent, wherein, the addition of each material is, dispersant 0.1 ~2 parts, 0.1~2 part of wetting agent, 0.1~2 part of defoamer, 0.1~2 part of levelling agent, 0.1~2 part of rheological agent.
5. a kind of Graphene modified water-soluble electrically conductive ink according to claim 4, it is characterised in that:The dispersant is Any one material in polycarboxylate sodium, polyacrylic acid sylvite, polyacrylic acid sodium salt;The wetting agent is fatty acid ester sulfuric acid One or more in salt, APES, polyoxyethylene modifier;The defoamer is that hydrophobic type is polysiloxane-based Any one material in defoamer, mineral oil, organic silica modifying agent, silicone defoamer;The levelling agent is have Machine modified dimethyl polysiloxane;The rheological agent is any one material in association type acrylate, polyurethane rheological agent.
6. a kind of Graphene modified water-soluble electrically conductive ink according to claim 4, it is characterised in that:The conductive black is second Alkynes carbon black.
7. a kind of Graphene modified water-soluble electrically conductive ink according to claim 4, it is characterised in that:The Graphene is individual layer One or more in Graphene, bilayer graphene, multi-layer graphene or nano-graphene piece.
8. a kind of preparation method of Graphene modified water-soluble electrically conductive ink, it is characterised in that comprise the following steps:
(1) raw material and dispersion are weighed:According to Graphene modified water-soluble electrically conductive ink constituent content described in claim 1 according to certain Ratio is put into stirring in Scattered Kettle, mixes pre-dispersed uniform;
(2) grind:The pre-dispersed material that step (1) is obtained is transferred to grinding in grinder, until fineness of materials to reach 10 micro- Rice is following;
(3) by ground material filtering, you can obtain Graphene modified water-soluble electrically conductive ink.
9. a kind of preparation method of Graphene modified water-soluble electrically conductive ink according to claim 8, it is characterised in that:It is described to grind Grinding machine is the one kind in sand mill, ball mill or three-roll grinder.
CN201710019297.XA 2017-01-11 2017-01-11 A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof Pending CN106752385A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710019297.XA CN106752385A (en) 2017-01-11 2017-01-11 A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710019297.XA CN106752385A (en) 2017-01-11 2017-01-11 A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106752385A true CN106752385A (en) 2017-05-31

Family

ID=58947622

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710019297.XA Pending CN106752385A (en) 2017-01-11 2017-01-11 A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106752385A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057409A (en) * 2017-06-09 2017-08-18 宁波工程学院 A kind of preparation method of graphene-based electrically conductive ink filler
CN108570265A (en) * 2018-06-12 2018-09-25 苏州中亚油墨有限公司 A kind of aqueous composite conducting ink and preparation method thereof
WO2018228407A1 (en) * 2017-06-14 2018-12-20 厦门信达光电物联科技研究院有限公司 Graphene/metal nanobelt composite conductive ink, preparation method therefor and application thereof
CN109181153A (en) * 2018-08-08 2019-01-11 广东冠盛新材料有限公司 A kind of high durable outdoor decoration film and preparation method thereof
CN110283497A (en) * 2019-06-28 2019-09-27 深圳烯材科技有限公司 A method of printing the silk-screened conductive ink of accurate self limiting temperature flexible electrothermal membrane
CN110408267A (en) * 2019-08-19 2019-11-05 泰能环保科技(浙江)有限公司 A kind of Graphene conductive ink and preparation method thereof
CN110769528A (en) * 2019-10-11 2020-02-07 深圳天元羲王材料科技有限公司 Graphene aqueous heating film conductive paste
CN112029342A (en) * 2020-09-25 2020-12-04 欧菲微电子技术有限公司 Conductive ink, ultrasonic fingerprint module and electronic equipment
CN112940561A (en) * 2021-04-13 2021-06-11 浙江伟航新材料科技有限公司 High-adhesion water-based ink and preparation method thereof
CN113881287A (en) * 2021-10-21 2022-01-04 北京旭碳新材料科技有限公司 Water-based graphene conductive ink composition, water-based graphene conductive ink, and preparation method and application thereof
CN115340823A (en) * 2022-08-18 2022-11-15 东莞市樱之蓝新材料科技有限公司 Odorless environment-friendly low-resistance water-based conductive paint and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073953A (en) * 2013-02-07 2013-05-01 苏州牛剑新材料有限公司 Waterborne conductive ink and preparation method thereof
CN103436074A (en) * 2013-08-05 2013-12-11 南昌大学 Preparation method of water-based conductive ink
CN103834235A (en) * 2014-02-20 2014-06-04 江苏格美高科技发展有限公司 Conductive graphene carbon slurry printing ink and preparation method thereof
CN105694594A (en) * 2014-11-28 2016-06-22 中国科学院金属研究所 An aqueous graphene conductive printing ink suitable for screen printing and a preparing method thereof
CN105936769A (en) * 2016-05-25 2016-09-14 青岛瑞利特新材料科技有限公司 Graphene modified nano-silver aqueous conductive ink and preparation method thereof
CN106118227A (en) * 2016-08-29 2016-11-16 佛山市高明区尚润盈科技有限公司 A kind of conduction water color ink and preparation method thereof
CN106243836A (en) * 2016-08-15 2016-12-21 青岛德通纳米技术有限公司 A kind of graphene conductive carbon slurry and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073953A (en) * 2013-02-07 2013-05-01 苏州牛剑新材料有限公司 Waterborne conductive ink and preparation method thereof
CN103436074A (en) * 2013-08-05 2013-12-11 南昌大学 Preparation method of water-based conductive ink
CN103834235A (en) * 2014-02-20 2014-06-04 江苏格美高科技发展有限公司 Conductive graphene carbon slurry printing ink and preparation method thereof
CN105694594A (en) * 2014-11-28 2016-06-22 中国科学院金属研究所 An aqueous graphene conductive printing ink suitable for screen printing and a preparing method thereof
CN105936769A (en) * 2016-05-25 2016-09-14 青岛瑞利特新材料科技有限公司 Graphene modified nano-silver aqueous conductive ink and preparation method thereof
CN106243836A (en) * 2016-08-15 2016-12-21 青岛德通纳米技术有限公司 A kind of graphene conductive carbon slurry and preparation method thereof
CN106118227A (en) * 2016-08-29 2016-11-16 佛山市高明区尚润盈科技有限公司 A kind of conduction water color ink and preparation method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057409B (en) * 2017-06-09 2019-03-05 宁波工程学院 A kind of preparation method of graphene-based electrically conductive ink filler
CN107057409A (en) * 2017-06-09 2017-08-18 宁波工程学院 A kind of preparation method of graphene-based electrically conductive ink filler
WO2018228407A1 (en) * 2017-06-14 2018-12-20 厦门信达光电物联科技研究院有限公司 Graphene/metal nanobelt composite conductive ink, preparation method therefor and application thereof
CN108570265A (en) * 2018-06-12 2018-09-25 苏州中亚油墨有限公司 A kind of aqueous composite conducting ink and preparation method thereof
CN109181153A (en) * 2018-08-08 2019-01-11 广东冠盛新材料有限公司 A kind of high durable outdoor decoration film and preparation method thereof
CN110283497B (en) * 2019-06-28 2022-07-12 深圳烯材科技有限公司 Method for printing screen printing conductive ink of precise self-temperature-limiting flexible electrothermal film
CN110283497A (en) * 2019-06-28 2019-09-27 深圳烯材科技有限公司 A method of printing the silk-screened conductive ink of accurate self limiting temperature flexible electrothermal membrane
CN110408267A (en) * 2019-08-19 2019-11-05 泰能环保科技(浙江)有限公司 A kind of Graphene conductive ink and preparation method thereof
CN110769528A (en) * 2019-10-11 2020-02-07 深圳天元羲王材料科技有限公司 Graphene aqueous heating film conductive paste
CN112029342A (en) * 2020-09-25 2020-12-04 欧菲微电子技术有限公司 Conductive ink, ultrasonic fingerprint module and electronic equipment
CN112940561A (en) * 2021-04-13 2021-06-11 浙江伟航新材料科技有限公司 High-adhesion water-based ink and preparation method thereof
CN113881287A (en) * 2021-10-21 2022-01-04 北京旭碳新材料科技有限公司 Water-based graphene conductive ink composition, water-based graphene conductive ink, and preparation method and application thereof
CN115340823A (en) * 2022-08-18 2022-11-15 东莞市樱之蓝新材料科技有限公司 Odorless environment-friendly low-resistance water-based conductive paint and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106752385A (en) A kind of Graphene modified water-soluble electrically conductive ink and preparation method thereof
CN103113786B (en) Graphene conductive ink and preparation method thereof
WO2018228407A1 (en) Graphene/metal nanobelt composite conductive ink, preparation method therefor and application thereof
CN101624490B (en) Electroconductive polymer printing ink and preparation method thereof
CN108250844A (en) A kind of preparation method of the highly conductive ink of watersoluble plumbago alkene
CN109468017A (en) A kind of watersoluble plumbago alkene anticorrosive paint
CN103436099A (en) Composite conductive printing ink
CN105694594B (en) A kind of watersoluble plumbago alkene electrically conductive ink and preparation method thereof suitable for screen painting
CN106158065A (en) A kind of anti-silver of handset touch panel special low temperature solidification migrates laser-induced thermal etching conductive silver paste and preparation method thereof
CN105802346B (en) A kind of composite conducting ink film and preparation method thereof
CN106554696A (en) A kind of Graphene antistatic aqueous epoxy floor paint
CN103666152A (en) Light gray dry-film conductive primer and preparation method thereof
CN104449022B (en) Carbon-serial conductive coating with ultralow content of carbon tubes and preparation method thereof
CN104419261A (en) Colorized conductive ink
CN108997841A (en) A kind of aqueous, environmental protective Graphene conductive ink
CN108359326A (en) A kind of use for electronic products antistatic coating and preparation method thereof
CN113881287A (en) Water-based graphene conductive ink composition, water-based graphene conductive ink, and preparation method and application thereof
GB2526591A (en) Conductive carbon ink
CN104449246A (en) Water-based epoxy antistatic floor primer and surface paint and preparation method thereof
CN101624491B (en) Water-based driography electrically conductive ink and preparation method thereof
CN105244077B (en) Conductive carbon paste and preparation method thereof
CN104387912A (en) Graphene-based nanometer zero-valent aluminum coating and preparation method thereof
CN104479494A (en) Graphene-based nanometre zero-valent zinc coating and preparation method thereof
CN104419249B (en) A kind of environment-friendly black scrapes the preparation method of ink off
CN106398396A (en) Graphene conductive printing ink

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531

RJ01 Rejection of invention patent application after publication