CN106881970A - Sticky thermal dye sublimation transfer printing paper - Google Patents
Sticky thermal dye sublimation transfer printing paper Download PDFInfo
- Publication number
- CN106881970A CN106881970A CN201710084530.2A CN201710084530A CN106881970A CN 106881970 A CN106881970 A CN 106881970A CN 201710084530 A CN201710084530 A CN 201710084530A CN 106881970 A CN106881970 A CN 106881970A
- Authority
- CN
- China
- Prior art keywords
- parts
- transfer printing
- sublimation transfer
- thermal dye
- aqueous dispersions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/06—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
- B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B23/08—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention discloses a kind of sticky thermal dye sublimation transfer printing paper, including body paper, water accepting layer, fibrage, antistatic backing, viscous layer and priming coat, wherein, the fibrage is provided with some first through hole, the water accepting layer is provided with some second through holes, the antistatic backing includes antistatic agent, the viscous layer includes carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide, polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder, thiophene aqueous dispersions and water, preparation process is simple of the present invention, finishing coat is obtained has mobility higher, also there is good wearability simultaneously, inoxidizability, water resistance and adhesive ability.
Description
Technical field
The present invention relates to transfer paper technical field, specially a kind of sticky thermal dye sublimation transfer printing paper.
Background technology
Thermal dye sublimation transfer printing is a kind of water-free dyeing technique, with environmental protection effect higher, the high energy advocated current country
Consumption industry energy-saving emission reduction improvement project has important value, and study hotspot has been turned at present.The principle of thermal dye sublimation transfer printing is in height
Under temperature (usually more than 220 DEG C), the disperse dyes on thermal dye sublimation transfer printing medium are sublimed up on chemical fiber plus material and directly by fabric
Fiber is fixed, and the chemical fiber plus material printed and dyed can be with Non-water washing.It is believed that thermal dye sublimation transfer printing technique, especially digital heat sublimation
Transfer printing process, is a kind of high in environmental protection and practical reliable technique, is hopeful to substitute traditional dyeing and finishing technique.
Thermal dye sublimation transfer printing medium is the technological core place of whole technique, especially coating formula technology.First, the coating
Recipe requirements can well receive the pattern that ink forms exquisiteness, and disperse dyes can be discharged in heating, it is fully risen
China, forms the heat sublimation rate of transform higher.But due to the limitation of current technology, existing product needs after ink is received
Treat that one section of longer time makes ink fully form dry surface by absorption, then transfer again.This is in the larger degree upper limit
The processing efficiency of heat sublimation technique is made.If being heated by the thermal dye sublimation transfer printing medium of ink using external heat equipment interconnection
Dry, the heat sublimation rate of transform can be significantly influenceed, so as to cause the aberration of product.Particularly digital thermal dye sublimation transfer printing technique, mistake
Low processing efficiency has seriously constrained the popularization degree of technique.Therefore it is have again at a high speed with the rate of transform high to need a kind of
The heat sublimation medium of drying capacity promotes the further development of heat sublimation technique.
The content of the invention
It is an object of the invention to provide a kind of sticky thermal dye sublimation transfer printing paper, with asking for solving to propose in above-mentioned background technology
Topic.
To achieve the above object, the present invention provides following technical scheme:A kind of sticky thermal dye sublimation transfer printing paper, including body paper,
Water accepting layer, fibrage, antistatic backing, viscous layer and priming coat, wherein, the fibrage is provided with some first through hole, the suction
Water layer is provided with some second through holes, and the antistatic backing includes antistatic agent 1-20 parts, and the viscous layer includes carboxymethyl cellulose
It is plain 5-30 parts, polyvinyl alcohol 2-20 parts, starch 5-20 parts, chitosan material 2-15 parts, glycerine 2-15 parts, pentaerythrite 2-20 parts,
Defoamer 1-10 parts, bactericide 1-15 parts, polyanion cellulose 1-15 parts, potassium alkyl phosphate 1-10 parts, gas phase dioxy
SiClx 1-15 parts, aluminum oxide 1-15 parts, titanium dioxide 1-15 parts, calcium carbonate 1-15 parts, diatomite powder 5-10 parts, thiophene moisture
Dispersion liquid 1-20 parts and water.
Preferably, the priming coat includes porous pigment.
Preferably, the preferred composition proportion of viscous layer is:It is 16 parts of carboxymethylcellulose calcium, 3 parts of polyvinyl alcohol, 8 parts of starch, poly-
3 parts of sugared material, 2 parts of glycerine, 3 parts of pentaerythrite, 2 parts of defoamer, 2 parts of bactericide, 3 parts of polyanion cellulose, alkyl phosphoric acid
2 parts of ester sylvite, 2 parts of aerosil, 1 part of aluminum oxide, 1 part of titanium dioxide, 1 part of calcium carbonate, 5 parts of diatomite powder, thiophene
2 parts of aqueous dispersions.
The viscous layer of described sticky thermal dye sublimation transfer printing paper is realized, its preparation method is comprised the following steps:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide,
Polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder,
Thiophene aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring, mechanical agitation in mechanical stirring kettle after mixing
Kettle rotating speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) preparation process is simple of the present invention, prepared coating has good wearability, inoxidizability, water resistance and attachment
Ability;
(2) the thiophene aqueous dispersions of present invention addition, can adjust the PH of coating, while print procedure can also be prevented
In, coating stopped nozzles influence transferring effect.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only it is a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, ordinary skill
The every other embodiment that personnel are obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
The present invention provides a kind of technical scheme:A kind of sticky thermal dye sublimation transfer printing paper, including it is body paper, water accepting layer, fibrage, anti-
Electrostatic layer, viscous layer and priming coat, wherein, the fibrage is provided with some first through hole, and the water accepting layer is provided with some second
Through hole, the antistatic backing includes antistatic agent 1-20 parts, and the viscous layer includes carboxymethylcellulose calcium 5-30 parts, polyvinyl alcohol
2-20 parts, starch 5-20 parts, chitosan material 2-15 parts, glycerine 2-15 parts, pentaerythrite 2-20 parts, defoamer 1-10 parts, sterilization
Agent 1-15 parts, polyanion cellulose 1-15 parts, potassium alkyl phosphate 1-10 parts, aerosil 1-15 parts, aluminum oxide
1-15 parts, titanium dioxide 1-15 parts, calcium carbonate 1-15 parts, diatomite powder 5-10 parts, 1-20 parts of thiophene aqueous dispersions and water, its
In, the priming coat includes porous pigment.
Embodiment one:
The composition proportion that viscous layer is used for:16 parts of carboxymethylcellulose calcium, 3 parts of polyvinyl alcohol, 8 parts of starch, chitosan material 3
Part, 2 parts of glycerine, 3 parts of pentaerythrite, 2 parts of defoamer, 2 parts of bactericide, 3 parts of polyanion cellulose, potassium alkyl phosphate 2
Part, 2 parts of aerosil, 1 part of aluminum oxide, 1 part of titanium dioxide, 1 part of calcium carbonate, 5 parts of diatomite powder, thiophene aqueous dispersions
2 parts.
The preparation method of the present embodiment is comprised the following steps:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide,
Polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder,
Thiophene aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring, mechanical agitation in mechanical stirring kettle after mixing
Kettle rotating speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Embodiment two:
The composition proportion that viscous layer is used for:10 parts of carboxymethylcellulose calcium, 4 parts of polyvinyl alcohol, 10 parts of starch, chitosan material
3 parts, 2 parts of glycerine, 3 parts of pentaerythrite, 3 parts of defoamer, 4 parts of bactericide, 3 parts of polyanion cellulose, potassium alkyl phosphate 2
Part, 6 parts of aerosil, 1 part of aluminum oxide, 2 parts of titanium dioxide, 1 part of calcium carbonate, 5 parts of diatomite powder, thiophene aqueous dispersions
2 parts.
The preparation method of the present embodiment is comprised the following steps:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide,
Polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder,
Thiophene aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring, mechanical agitation in mechanical stirring kettle after mixing
Kettle rotating speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Embodiment three:
The composition proportion that viscous layer is used for:16 parts of carboxymethylcellulose calcium, 2 parts of polyvinyl alcohol, 10 parts of starch, chitosan material
2 parts, 4 parts of glycerine, 3 parts of pentaerythrite, 2 parts of defoamer, 2 parts of bactericide, 3 parts of polyanion cellulose, potassium alkyl phosphate 2
Part, 2 parts of aerosil, 1 part of aluminum oxide, 3 parts of titanium dioxide, 1 part of calcium carbonate, 5 parts of diatomite powder, thiophene aqueous dispersions
2 parts.
The preparation method of the present embodiment is comprised the following steps:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide,
Polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder,
Thiophene aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring, mechanical agitation in mechanical stirring kettle after mixing
Kettle rotating speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Example IV:
The composition proportion that viscous layer is used for:15 parts of carboxymethylcellulose calcium, 4 parts of polyvinyl alcohol, 10 parts of starch, chitosan material
4 parts, 3 parts of glycerine, 2 parts of pentaerythrite, 3 parts of defoamer, 2 parts of bactericide, 3 parts of polyanion cellulose, potassium alkyl phosphate 2
Part, 2 parts of aerosil, 1 part of aluminum oxide, 1 part of titanium dioxide, 2 parts of calcium carbonate, 4 parts of diatomite powder, thiophene aqueous dispersions
3 parts.
The preparation method of the present embodiment is comprised the following steps:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide,
Polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder,
Thiophene aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring, mechanical agitation in mechanical stirring kettle after mixing
Kettle rotating speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Embodiment five:
The composition proportion that viscous layer is used for:18 parts of carboxymethylcellulose calcium, 2 parts of polyvinyl alcohol, 10 parts of starch, chitosan material
6 parts, 2 parts of glycerine, 3 parts of pentaerythrite, 2 parts of defoamer, 2 parts of bactericide, 3 parts of polyanion cellulose, potassium alkyl phosphate 3
Part, 2 parts of aerosil, 1 part of aluminum oxide, 1 part of titanium dioxide, 1 part of calcium carbonate, 5 parts of diatomite powder, thiophene aqueous dispersions
2 parts.
The preparation method of the present embodiment is comprised the following steps:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide,
Polyanion cellulose, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder,
Thiophene aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring, mechanical agitation in mechanical stirring kettle after mixing
Kettle rotating speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Preparation process is simple of the present invention, prepared coating has good wearability, inoxidizability, water resistance and energy of attachment
Power;The thiophene aqueous dispersions of present invention addition, can adjust the PH of coating, while during print procedure can also be prevented, coating resistance
Plug nozzle, influences transferring effect.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (4)
1. a kind of sticky thermal dye sublimation transfer printing paper, it is characterised in that:Including body paper, water accepting layer, fibrage, antistatic backing, viscous layer
And priming coat, wherein, the fibrage is provided with some first through hole, and the water accepting layer is provided with some second through holes, described anti-quiet
Electric layer includes antistatic agent 1-20 parts, and the viscous layer includes carboxymethylcellulose calcium 5-30 parts, polyvinyl alcohol 2-20 parts, starch 5-
20 parts, chitosan material 2-15 parts, glycerine 2-15 parts, pentaerythrite 2-20 parts, defoamer 1-10 parts, bactericide 1-15 parts, poly- the moon
1-15 parts of ion fiber element, potassium alkyl phosphate 1-10 parts, aerosil 1-15 parts, aluminum oxide 1-15 parts, titanium dioxide
Titanium 1-15 parts, calcium carbonate 1-15 parts, diatomite powder 5-10 parts, 1-20 parts of thiophene aqueous dispersions and water.
2. sticky thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that:The priming coat includes porous face
Material.
3. sticky thermal dye sublimation transfer printing paper according to claim 1, it is characterised in that:The preferred composition proportion of viscous layer
For:16 parts of carboxymethylcellulose calcium, 3 parts of polyvinyl alcohol, 8 parts of starch, 3 parts of chitosan material, 2 parts of glycerine, 3 parts of pentaerythrite, froth breaking
2 parts of agent, 2 parts of bactericide, 3 parts of polyanion cellulose, 2 parts of potassium alkyl phosphate, 2 parts of aerosil, aluminum oxide 1
Part, 1 part of titanium dioxide, 1 part of calcium carbonate, 5 parts of diatomite powder, 2 parts of thiophene aqueous dispersions.
4. the viscous layer of the sticky thermal dye sublimation transfer printing paper described in claim 1 is realized, it is characterised in that:Its preparation method include with
Lower step:
A, by carboxymethylcellulose calcium, polyvinyl alcohol, starch, chitosan material, glycerine, pentaerythrite, defoamer, bactericide, poly- the moon
Ion fiber element, potassium alkyl phosphate, aerosil, aluminum oxide, titanium dioxide, calcium carbonate, diatomite powder, thiophene
Aqueous dispersions are stirred, and obtain mixture A;
B, addition thiophene aqueous dispersions and the water in mixture A, add stirring in mechanical stirring kettle after mixing, mechanical stirring kettle turns
Speed is 3000 revs/min, and mixing time is 15min, obtains mixture B;
C, mixture B is put into constant temperature 10min in baking oven, oven temperature is 40 DEG C, viscous layer is obtained after taking out cooling.
Priority Applications (1)
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CN201710084530.2A CN106881970A (en) | 2017-02-16 | 2017-02-16 | Sticky thermal dye sublimation transfer printing paper |
Applications Claiming Priority (1)
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CN201710084530.2A CN106881970A (en) | 2017-02-16 | 2017-02-16 | Sticky thermal dye sublimation transfer printing paper |
Publications (1)
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CN106881970A true CN106881970A (en) | 2017-06-23 |
Family
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Family Applications (1)
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CN201710084530.2A Pending CN106881970A (en) | 2017-02-16 | 2017-02-16 | Sticky thermal dye sublimation transfer printing paper |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108193557A (en) * | 2017-12-19 | 2018-06-22 | 浙江锦旺新材料科技有限公司 | A kind of high temperature heat-resistant transfer paper |
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CN101261438A (en) * | 2008-04-21 | 2008-09-10 | 李剑平 | Thermal sublimation photographic paper electrostatic resistance coatings |
CN101274558A (en) * | 2007-03-28 | 2008-10-01 | 富士胶片株式会社 | Heat-sensitive transfer image-receiving sheet |
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CN104789050A (en) * | 2015-04-10 | 2015-07-22 | 浙江卡乐福印花纸有限公司 | Coating for heat sublimation transfer printing and preparation method of coating |
CN205439622U (en) * | 2016-03-30 | 2016-08-10 | 江阴市全佳数码科技有限公司 | Prevent that ghost image viscidity thermal sublimation changes printing paper |
CN106042701A (en) * | 2015-04-03 | 2016-10-26 | 佳能精技股份有限公司 | Transfer material, recorded matter, method of manufacturing recorded matter, image-recording apparatus, and apparatus for manufacturing recorded matter |
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2017
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US20060165920A1 (en) * | 2003-02-05 | 2006-07-27 | Hideki Nakanishi | Image recording sheet and method of image recording |
CN101274558A (en) * | 2007-03-28 | 2008-10-01 | 富士胶片株式会社 | Heat-sensitive transfer image-receiving sheet |
CN101024354A (en) * | 2007-03-29 | 2007-08-29 | 李剑平 | Heat-sublimation printing medium |
CN101261438A (en) * | 2008-04-21 | 2008-09-10 | 李剑平 | Thermal sublimation photographic paper electrostatic resistance coatings |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108193557A (en) * | 2017-12-19 | 2018-06-22 | 浙江锦旺新材料科技有限公司 | A kind of high temperature heat-resistant transfer paper |
CN108193557B (en) * | 2017-12-19 | 2020-06-05 | 浙江锦旺新材料科技有限公司 | High-temperature-resistant thermal transfer paper |
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Application publication date: 20170623 |