CN106872676A - No. 903 standard oils of rubber oil-resistant detection of a kind of replacement IRM and preparation method thereof - Google Patents
No. 903 standard oils of rubber oil-resistant detection of a kind of replacement IRM and preparation method thereof Download PDFInfo
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- CN106872676A CN106872676A CN201710259959.0A CN201710259959A CN106872676A CN 106872676 A CN106872676 A CN 106872676A CN 201710259959 A CN201710259959 A CN 201710259959A CN 106872676 A CN106872676 A CN 106872676A
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- Prior art keywords
- oil
- rubber
- naphthenic
- standard
- oils
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- 239000003921 oil Substances 0.000 title claims abstract description 139
- 229920001971 elastomer Polymers 0.000 title claims abstract description 98
- 239000005060 rubber Substances 0.000 title claims abstract description 98
- 238000001514 detection method Methods 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 18
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 Diisoamyl naphthalene Chemical compound 0.000 claims abstract description 7
- KEVMYFLMMDUPJE-UHFFFAOYSA-N diisoamyl Natural products CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002367 Polyisobutene Polymers 0.000 claims description 11
- QAPZDZDRMADDOM-UHFFFAOYSA-N 1,2-bis(3-methylbutyl)naphthalene Chemical compound C1=CC=CC2=C(CCC(C)C)C(CCC(C)C)=CC=C21 QAPZDZDRMADDOM-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000010687 lubricating oil Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 230000008676 import Effects 0.000 abstract description 3
- 238000011160 research Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 4
- 239000012467 final product Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather
- G01N33/445—Rubber
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of standard oil of replacement IRM903 rubber oil-resistant detections and preparation method thereof, the standard oil is made up of the component of following weight proportion：Diisoamyl naphthalene 13.5 14.5%, KN4010 naphthenic rubbers oil 25 45%, the KN4006 naphthenic rubbers oil 45 65%, rubber oils 5 10% of KG 12, the rubber oils 5 15% of KG 06, antioxidant T501 0.1 0.5%.Independent research formula of the present invention, can be used to substitute IRM No. 903 standard oils of imported from America, and the raw material for using can the country buy, it is to avoid import, effectively reduce cost.
Description
Technical field
The invention belongs to rubber detection field, and in particular to a kind of standard working solution for rubber oil-resistant detection.
Background technology
Rubber oil-resistant performance is the important performance indexes of oil resistant rubber.Ke Biao inspection centers provide according to GB, HB, ISO,
The standards such as ASTM, EN provide rubber oil-resistant test, and provide report.In existing detection, more using the ASTM standard pair in the U.S.
Rubber carries out oil resistant test.
Because current U.S. ASTM new standards are adjusted to the quality of its oil product, and in new standard by former 1,2,
3rd, No. 5 experiment standard oils are upgraded to IRM 901, IRM902, IRM903, IRM905.They are mainly used in rubber seal product
Oil resistant test, such as oil sealing（NBR nitrile rubber oil sealings, ACM acrylate oil sealings etc.）, O-ring and sebific duct class product test.
Different elastomeric materials, can be tested according to the different qualities of U.S.'s ASTM D471 standards and each money test oil.
But, it is necessary to use each money test standard oil IRM for arriving when being tested using U.S.'s ASTM D471 standards
901st, IRM902, IRM903, IRM905, the country are required to from imported from America without corresponding product and formula, expensive, are increased
Cost is added.Therefore it is badly in need of a experiment standard oil for meeting U.S.'s ASTM D471 standards of research and development, instead of the standard of import
Oil.
The content of the invention
The invention aims to solve defect present in prior art, there is provided one kind can effectively substitute IRM
903 rubber oil-resistant detection experiment oil.
In order to achieve the above object, the invention provides a kind of rubber oil-resistant detection standard oil, by following weight proportion
Component composition：Diisoamyl naphthalene 13.5-14.5%, KN4010 naphthenic rubber oil 25-45%, KN4006 naphthenic rubber oil
45-65%, KG-12 rubber oil 5-10%, KG-06 rubber oil 5-15%, antioxidant T501 0.1-0.5%.
The preferred ingredient weight proportion of standard oil of the present invention is：Diisoamyl naphthalene 13.5-14.5%, KN4010 cycloalkyl rubber
It is glue oil 25-40%, KN4006 naphthenic rubber oil 45-60%, KG-12 rubber oil 5-10%, KG-06 rubber oil 5-10%, anti-
Oxygen agent T501 0.1-0.5%, polyisobutene 0-2%.Best composition weight proportion is：Diisoamyl naphthalene 13.8%, KN4010 rings
Alkyl rubber oil 26.1%, KN4006 naphthenic rubbers oil 46%, KG-12 rubber oils 7%, KG-06 rubber oils 6.2%, antioxygen
Agent T501 0.3%, polyisobutene 0.6%.
Wherein, KN4010 and KN4006 naphthenic rubbers oil is respectively selected from the production of Kelamayi lubricating oil plant of CNPC
KN4010 and KN4006 high-quality naphthenic rubber oil；KG-12 and KG-06 rubber oils are respectively selected from the prosperous profit limited public affairs of petrochemical industry in Xiamen
KG12 the and KG06 rubber oils of department；Antioxidant T501 is selected from the antioxidant T501 of Nanjing Datang chemical industry Co., Ltd.
Present invention also offers the preparation method of above-mentioned standard oil, step is as follows：By diisoamyl naphthalene, KN4010 cycloalkyl
After rubber oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils, KG-06 rubber oils, antioxidant T501 are mixed in proportion,
Its viscosity is detected, polyisobutene is subsequently adding, viscosity of the standard oil at 38 DEG C is reached 32-34 mm2/s。
The present invention has advantages below compared to existing technology：
1st, the present invention by the diisoamyl naphthalene of specific proportioning, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers it is oily,
KG-12 rubber oils, KG-06 rubber oils adjust the aniline point of oil product of the present invention；While utilization KN4010 naphthenic rubbers oil,
The naphthene content of KN4006 naphthenic rubbers oil regulation oil product；Pass through KG-12 rubber oils, the proportioning of KG-06 rubber oils respectively
The content of regulation cycloalkane and alkane；Strengthen the antioxygenic property of oil product by antioxidant T501；Made by adding polyisobutene
It is thickener, improves the viscosity of product.
2nd, by the research to formula composition and each group distribution ratio, the final product formula for determining can fully meet the present invention
Requirement of U.S.'s ASTM D471 standards to experiment oil IRM903, it is adaptable to test rubber oil-resistant.
3rd, independent research formula of the present invention, can be used to substitute No. 903 standard oils of IRM of imported from America, and the raw material for using
Can the country buy, it is to avoid import, effectively reduce cost.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
Naphthenic rubber oil KN4010 and KN4006 is purchased from Kelamayi lubricating oil plant of CNPC；Rubber oil KG-12 and
KG-06 is purchased from Xiamen Heng Run petrochemical industry Co., Ltd；Antioxidant T501 is purchased from Nanjing Datang chemical industry Co., Ltd.
Embodiment 1
The composition weight proportioning of rubber liquid influence experiment standard oil of the present invention is as follows：
Diisoamyl naphthalene 13.6kg, KN4010 naphthenic rubber oil 25.5kg, KN4006 naphthenic rubber oil 45.6kg, KG-
12 rubber oil 6kg, KG-06 rubber oil 9kg, antioxidant T501 0.3kg.
By above-mentioned diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils,
KG-06 rubber oils, antioxidant T501 are well mixed.
Embodiment 2
The composition weight proportioning of rubber liquid influence experiment standard oil of the present invention is as follows：
Diisoamyl naphthalene 13.8kg, KN4010 naphthenic rubber oil 26.1kg, KN4006 naphthenic rubber oil 46kg, KG-12 rubber
Glue oil 7kg, KG-06 rubber oil 6.2kg, antioxidant T501 0.3kg, polyisobutene 0.6kg.
By above-mentioned diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils,
KG-06 rubber oils, antioxidant T501, polyisobutene are well mixed.
Embodiment 3
Rubber liquid influence experiment of the present invention is as follows with standard oil configuration process：
Take diisoamyl naphthalene 14kg, KN4010 naphthenic rubber oil 28kg, KN4006 naphthenic rubber oil 45.7kg, KG-12
Rubber oil 5.6kg, KG-06 rubber oil 5.8kg, antioxidant T501 0.3kg are well mixed, and its viscosity is 31 after testing, is added
Polyisobutene 0.6kg, it is well mixed to obtain final product.
Embodiment 4
Rubber liquid influence experiment of the present invention is as follows with standard oil configuration process：
Take diisoamyl naphthalene 14.2kg, KN4010 naphthenic rubber oil 26kg, KN4006 naphthenic rubber oil 46.6kg, KG-
12 rubber oil 6.5kg, KG-06 rubber oil 5.4kg, antioxidant T501 0.3kg are well mixed, and its viscosity is 30.5 after testing,
Polyisobutene 1kg is added, it is well mixed to obtain final product.
The particular product performance parameters that the present invention is prepared are as shown in table 1 below with the performance comparison of IRM903 standard oils：
The performance comparison of the standard oil of the present invention of table 1 and IRM903 standard oils
As can be seen from Table 1, the standard oil performance indications that the present invention is prepared reach requirement, are entirely capable of substituting IRM903 marks
Quasi- oil carries out rubber oil-resistant test.
The standard oil prepared to various embodiments of the present invention carries out performance test, as a result as shown in table 2 below：
Standard oil performance comparison prepared by the various embodiments of the present invention of table 2
As can be seen from Table 2, the standard oil performance indications that the present invention is prepared reach requirement, are entirely capable of substituting IRM903 marks
Quasi- oil carries out rubber oil-resistant test.And standard oil performance that embodiment 2 is prepared is optimal.
Claims (5)
1. a kind of standard oil of replacement IRM903 rubber oil-resistant detections, it is characterised in that the standard oil includes following heavy
Measure the component of proportioning：Diisoamyl naphthalene 13.5-14.5%, KN4010 naphthenic rubber oil 25-45%, KN4006 naphthenic rubber
Oily 45-65%, KG-12 rubber oil 5-10%, KG-06 rubber oil 5-15%, antioxidant T501 0.1-0.5%.
2. the standard oil according to claim 1, it is characterised in that the standard oil by following weight proportion component
Composition：Diisoamyl naphthalene 13.5-14.5%, KN4010 naphthenic rubber oil 25-40%, KN4006 naphthenic rubber oil 45-
60%th, KG-12 rubber oils 5-10%, KG-06 rubber oils 5-10%, antioxidant T501 0.1-0.5%, polyisobutene 0-2%.
3. standard oil according to claim 1 and 2, it is characterised in that KN4010 the and KN4006 naphthenic rubbers oil
It is respectively selected from KN4010 the and KN4006 high-quality naphthenic rubber oil of Kelamayi lubricating oil plant of CNPC production；Described
KG-12 and KG-06 rubber oils are respectively selected from KG12 the and KG06 rubber oils of Xiamen Heng Run petrochemical industry Co., Ltd；Described antioxidant
T501 is selected from the antioxidant T501 of Nanjing Datang chemical industry Co., Ltd.
4. standard oil according to claim 3, it is characterised in that the standard oil by following weight proportion component group
Into：Diisoamyl naphthalene 13.8%, KN4010 naphthenic rubbers oil 26.1%, KN4006 naphthenic rubbers oil 46%, KG-12 rubber
Oil 7%, KG-06 rubber oils 6.2%, antioxidant T501 0.3%, polyisobutene 0.6%.
5. the preparation method of standard oil described in Claims 2 or 3, it is characterised in that the standard oil is prepared by the following method：
By diisoamyl naphthalene, KN4010 naphthenic rubbers oil, KN4006 naphthenic rubbers oil, KG-12 rubber oils, KG-06 rubber oils, anti-
After oxygen agent T501 is mixed in proportion, its viscosity is detected, be subsequently adding polyisobutene, make the standard oil viscous at 38 DEG C
Degree reaches 32-34mm2/s。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710259959.0A CN106872676B (en) | 2017-04-20 | 2017-04-20 | A kind of standard oil of replacement IRM903 rubber oil-resistant detections and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710259959.0A CN106872676B (en) | 2017-04-20 | 2017-04-20 | A kind of standard oil of replacement IRM903 rubber oil-resistant detections and preparation method thereof |
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| CN106872676A true CN106872676A (en) | 2017-06-20 |
| CN106872676B CN106872676B (en) | 2018-02-16 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212488A (en) * | 2013-06-05 | 2014-12-17 | 中国石油天然气股份有限公司 | Environment-friendly rubber oil and preparation method thereof |
| EP2990218A1 (en) * | 2014-08-26 | 2016-03-02 | The Goodyear Tire & Rubber Company | Rubber composition and tire with silica-rich rubber tread |
| CN106280037A (en) * | 2016-08-09 | 2017-01-04 | 深圳市前海龙达新能源有限公司 | A kind of modified rubber oil additive, preparation method and modified rubber oil thereof |
| CN106398126A (en) * | 2015-07-31 | 2017-02-15 | 魏忠 | Environment-friendly rubber oil |
-
2017
- 2017-04-20 CN CN201710259959.0A patent/CN106872676B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212488A (en) * | 2013-06-05 | 2014-12-17 | 中国石油天然气股份有限公司 | Environment-friendly rubber oil and preparation method thereof |
| EP2990218A1 (en) * | 2014-08-26 | 2016-03-02 | The Goodyear Tire & Rubber Company | Rubber composition and tire with silica-rich rubber tread |
| CN106398126A (en) * | 2015-07-31 | 2017-02-15 | 魏忠 | Environment-friendly rubber oil |
| CN106280037A (en) * | 2016-08-09 | 2017-01-04 | 深圳市前海龙达新能源有限公司 | A kind of modified rubber oil additive, preparation method and modified rubber oil thereof |
Non-Patent Citations (3)
| Title |
|---|
| 吴庆云: "橡胶试验用国产1、2、3号标准油简介", 《化工标准化》 * |
| 姚亚平 等: "粘度指数改进剂的增稠能力与剪切稳定性", 《润滑油》 * |
| 杨士钊 等: "高性能烷基萘基础油", 《合成润滑材料》 * |
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| CN106872676B (en) | 2018-02-16 |
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