CN106861647A - A kind of preparation method of the base of marine alga containing grease water-purifying material - Google Patents
A kind of preparation method of the base of marine alga containing grease water-purifying material Download PDFInfo
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- CN106861647A CN106861647A CN201710227942.7A CN201710227942A CN106861647A CN 106861647 A CN106861647 A CN 106861647A CN 201710227942 A CN201710227942 A CN 201710227942A CN 106861647 A CN106861647 A CN 106861647A
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- marine alga
- containing grease
- water
- purifying material
- base
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
- B01J2220/4843—Algae, aquatic plants or sea vegetals, e.g. seeweeds, eelgrass
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cultivation Of Seaweed (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Water Treatment By Sorption (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
The present invention relates to environmental technology field, specifically a kind of preparation method of the base of marine alga containing grease water-purifying material.By Lipid-producing marine alga according to 0.1 0.2g L‑1Inoculum concentration be added in sea water medium, in 10 20 DEG C, Light To Dark Ratio be 12h:Under the condition of culture of 12h, culture to Lipid-producing marine alga enters exponential phase latter stage, adds the poor Nutrient Stress sea water medium isometric with cultivating system, and then then at 10 20 DEG C, Light To Dark Ratio is 12h:Under conditions of 12h, carrying out poor Nutrient Stress culture stimulates energy algae oil-producing, to algae fat content>10%, addition aluminium polychloride and nano ferriferrous oxide mixture stir coagulation, and the marine alga containing grease that will be collected puts into steam blasting device, carries out steam blasting broken wall treatment；Then add into shitosan cetomacrogol 1000 dilute acid solution, stir and evenly mix, collect modified algal biomass, dry, the base water-purifying material of marine alga containing grease is obtained.Material of the present invention can remove the base water-purifying material of marine alga containing grease of various organic or inorganic pollutants.
Description
Technical field
The present invention relates to environmental technology field, specifically a kind of preparation method of the base of marine alga containing grease water-purifying material.
Background technology
China's seaweed biomass resource very abundant, marine alga yield ranks first in the world.Seaweed biomass is compared to land
Biomass are advantageous.Seaweed growth in the sea, is being not take up land resource, fast growth, a large amount of titanium dioxides of growth course capture
Carbon, and absorb a large amount of nitrogen phosphorus of removal.Therefore, if China coastal seas seaweed biomass is made full use of, show with important
Sincere justice.
The main Land use systems of current seaweed biomass are including exploitation biomass energy and refine algal product etc..Marine alga institute
Not only as important nutrient and healthcare products, and the important oil plant source of biodiesel can be alternatively arranged as containing grease.Due to grease all
It is wrapped in alginic cell, the extraction of current marine alga grease is always the difficult point of seaweed biomass using energy source.According to estimation algae
In class production biodiesel process, harvesting, drying and the grease extraction of algal biomass account for production of biodiesel cost
50%, and grease yield high depends on the algae culture condition of harshness, and these seriously limit algae Lipid use industry
Development.Therefore, algae Lipid use new technology is created, this kind of grease-contained seaweed biomass is directly used, reduced
Algae grease develops cost, cuts down algae culture cost, has important practical significance.
Found by the retrieval to prior art literature, in terms of algae Lipid use, concentrate on and how effectively to extract
Marine alga grease aspect.Up to the present, there is not yet not for the purpose of extracting algae grease, directly application marine alga containing grease prepares and contains
The report of grease water-purifying material.
The content of the invention
The purpose of the present invention is to solve the shortcomings of the prior art, there is provided one kind application seaweed biomass is prepared containing grease sea
The method of algae base water-purifying material.
To achieve the above object, the present invention use technical scheme for：
A kind of preparation method of the base of marine alga containing grease water-purifying material,
1) by Lipid-producing marine alga according to 0.1-0.2g L-1Inoculum concentration be added in sea water medium, in 10-20 DEG C, light
Dark ratio is 12h:Under the condition of culture of 12h, culture to Lipid-producing marine alga enters exponential phase latter stage, stand-by；
2) added and the isometric poor Nutrient Stress sea water medium of cultivating system to above-mentioned Lipid-producing algae culture system,
Then then at 10-20 DEG C, Light To Dark Ratio is 12h:Under conditions of 12h, carrying out poor Nutrient Stress culture stimulates energy algae oil-producing, to algae
Quasi-grease content>10%, it is stand-by；
3) to the fat content of above-mentioned acquisition>15mg L are pressed in 10% algae-1Addition add aluminium polychloride and
Nano ferriferrous oxide mixture (mass ratio 4:1), stirring coagulating sedimentation collects seaweed biomass, the marine alga containing grease that will be collected
Input steam blasting device, carries out steam blasting broken wall treatment；
4) collect the marine alga containing grease after above-mentioned broken wall to add into shitosan-cetomacrogol 1000 dilute acid solution, stir
Mixing is mixed, solid is then collected, dried, the base water-purifying material of marine alga containing grease is obtained；Wherein, the marine alga containing grease after broken wall with it is dilute
The mass ratio between shitosan in aqueous acid is 1:30-60.
The Lipid-producing marine alga refers to the marine alga that can produce grease of growth and breeding in seawater；As green alga, diatom, chrysophyceae,
Chlorella and grid algae etc..
The sea water medium is that nitrogen content is more than 40mg L-1, phosphorus content is more than 3mg L-1Seawater.Such as sea-farming
Waste water, artificial seawater of rich Nitrogen-and Phosphorus-containing prepared etc.；
The poor Nutrient Stress sea water medium is that nitrogen content is less than 20mg L-1, phosphorus content is less than 1mg L-1Seawater.
The outer last person's water of sea-farming such as, coastal seawater.
The steam blasting broken wall treatment is that the marine alga containing grease that will be collected puts into steam blasting device, and is passed through saturation steaming
Vapour, 5-15min is maintained in 105-150 DEG C, and rapidly discharge pressure carries out broken wall to marine alga.
The step 4) in shitosan-cetomacrogol 1000 dilute acid solution chitosan concentration be 1-10wt%, shell gathers
Sugar is 4 with the mass ratio of cetomacrogol 1000:1；Wherein, diluted acid is that concentration is the hydrochloric acid or acetic acid of 1-2%；The de- second of shitosan
Acyl degree>50%.
A kind of application of the base water-purifying material of marine alga containing grease for preparing, the adsorbing material of marine alga containing grease is going
The application being used in purification of water quality in removal organic polluter and heavy metal multiple pollutant.
Principle：The present invention harvests grease-contained marine alga and gives birth to by using the cultivation in sea water Lipid-producing energy alga of rich Nitrogen-and Phosphorus-containing
After material, by follow-up steam blasting carry out cell wall damage process be beneficial to lipophilic contaminants to algae oil fat granule inhale it is molten
Enrichment, while preventing grease grain from overflowing in algal biomass surface parcel chitosan film, finally prepares the base of marine alga containing grease
Water-purifying material, uses it for purification of water quality, removes the multiple pollutants such as removal organic polluter and heavy metal.
Advantage for present invention：
1) method of the present invention is to have abolished conventional algae Lipid use to extract the available limitation in rear, effectively
The multiple technologies problem for overcoming marine alga grease higher value application to be faced, initial investment capital cost is cheap, being capable of rapid build
Reactor so that seaweed biomass being capable of higher value application.
2) it is stable in properties using the inventive method gained base water-purifying material of marine alga containing grease, remove various organic-inorganics in water removal
Pollutant excellent performance, belongs to multiduty environment friendly material.
3) it can be directly reaction mass using the fresh sample of marine alga that prepared by the present invention, eliminate conventional seaweed biomass reaction treatment
The step of preceding needs advance drying and dewatering, while steam blasting broken wall temperature of reaction system is less than 150 DEG C, belong to Low Temperature Steam quick-fried
Broken reaction, the reaction time is less than 15 minutes, so as to greatly reduce energy consumption, while ensure that the preparation base water purification material of marine alga containing grease
The operability and security of material.
Specific embodiment
Below by embodiment, the present invention is further described, but the invention is not limited in following examples.
The present invention is inoculated with 0.1-0.2g L in the seawater of rich Nitrogen-and Phosphorus-containing-1Lipid-producing marine alga, cultivate 6-10 days, treat oil-producing
Fat marine alga enters exponential phase latter stage, carries out poor nutrition culture induction oil-producing 2-3 days, marine alga fat content>10%, Ran Houshou
Grease-contained seaweed biomass is obtained, carrying out the destruction of alginic cell wall by follow-up steam blasting is processed, and is collected at by broken wall
The marine alga containing grease of reason, is added in shitosan-cetomacrogol 1000 aqueous solution, and shitosan is controlled with seaweed biomass mass ratio
In 30-60:1, stirring mixing collects solid after 5-30 minutes, parcel water penetration chitosan film in seaweed biomass surface after drying
To prevent grease grain from overflowing, so as to the base water-purifying material of marine alga containing grease that can remove various organic or inorganic pollutants is obtained.
Embodiment 1
The Lipid-producing chrysophyceae that will be bought is according to 0.1g L-1Inoculum concentration is added to marine culture wastewater (TN=40mg L-1, TP
=3mg L-1) in, set Light To Dark Ratio as 12h:12h, Primary culture at a temperature of 10 DEG C after reacting 10 days, adds isometric sea
Water cultivation discharge tail water (TN=14mg L-1, TP=0.4mg L-1), cultivate 3 days, marine alga fat content is reached 10%, then
According to 15mg L-1Aluminium polychloride and nano ferriferrous oxide mixture (aluminium polychloride and nanometer four that addition is added
Fe 3 O mass ratio 4:1), stirring coagulating sedimentation collects seaweed biomass.The seaweed biomass of collection is put into steam blasting
In reaction unit, 15min is incubated at 105 DEG C, rapidly discharging pressure carries out steam blasting broken wall treatment.At steam blasting broken wall
After reason, seaweed biomass is collected, be added to diluted acid (1% vinegar containing shitosan (1%) and cetomacrogol 1000 (0.25%)
Acid) aqueous solution (wherein, diluted acid for concentration be 1% acetic acid, shitosan and 0.25wt% containing 1wt% in dilute acid solution
Ethylene glycol 1000) in, the shitosan in dilute acid solution is with above-mentioned broken wall algae clay mass ratio 30:1, after stirring mixing 5min
Modified algal biomass is collected, is dried, the base water-purifying material of marine alga containing grease is obtained.
Prepared composite is added into the waste water containing phenols endocrine disruptors according to the ratio of 3% (mass ratio)
In (the μ g/L of nonyl phenol 200, the μ g/L of octyl phenol 50, bisphenol-A 100 μ g/L, zinc 3mg/L), the clearance of pollutant is more than 90%.
Embodiment 2
Shrimp ponds breeding wastewater (TN=80mg L are gathered in certain sea-farming base-1, TP=15mg L-1), by this laboratory
Screening obtains Lipid-producing green alga LZ-1 according to 0.2g L-1Inoculum concentration is added in shrimp ponds breeding wastewater, sets Light To Dark Ratio as 12h:
12h, Primary culture at a temperature of 15 DEG C adds isometric sea-farming to discharge tail water (TN=18mg L after culture 8d-1, TP=
0.8mg L-1), seaweed biomass containing grease is generated after continuing to cultivate 3 days, marine alga fat content is 30%, according to 15mg L-1Add
Aluminium polychloride and nano ferriferrous oxide mixture (mass ratio 4 that dosage is added:1), stirring coagulating sedimentation collects marine alga life
Material.Collect seaweed biomass and be directly placed into steam blasting reaction unit, 10min is kept at 120 DEG C, rapidly discharging pressure is carried out
Steam blasting broken wall treatment.After steam blasting broken wall treatment, collect seaweed biomass, be added to containing shitosan (4%) with it is poly-
In diluted acid (1% hydrochloric acid) aqueous solution of ethylene glycol 1000 (1%), shitosan and above-mentioned broken wall marine alga shale in dilute acid solution
Amount ratio is 40:1, modified algal biomass is collected after stirring mixing 15min, dry, the base water purification material of marine alga containing grease is obtained
Material.By prepared composite according to 2% (mass ratio) ratio add containing stink substance waste water (ground depth 300ng/L,
2- methyl isoborneol 100ng/L) in, the clearance of stink substance is more than 98%.
Embodiment 3
The Lipid-producing diatom for obtaining will be bought according to 0.2g L-1Inoculum concentration is added to the rich nitrogen phosphorus artificial seawater culture of preparation
Base (takes from addition nitrogen 60mg L in the seawater of immediate offshore area-1With phosphorus element 8mg L-1) in, set Light To Dark Ratio as 12h:12h, 20
Primary culture at a temperature of DEG C, adds the coastal seawater of isometric not extra addition nitrogen phosphorus, sea after continuing to cultivate 3 days after culture 6d
Algae fat content is 50%, according to 15mg L-1Aluminium polychloride and nano ferriferrous oxide mixture (quality that addition is added
Than 4:1), stirring coagulating sedimentation collects seaweed biomass.The mixture is directly placed into steam blasting reaction unit, temperature exists
150 DEG C of holding 5min, rapidly discharging pressure carries out steam blasting broken wall treatment.After steam blasting broken wall treatment, marine alga life is collected
Material, is added in diluted acid (2% acetic acid) aqueous solution containing shitosan (10%) and cetomacrogol 1000 (2.5%), diluted acid
Shitosan in the aqueous solution is with above-mentioned broken wall algae clay mass ratio 60:1, collect modified algae after stirring mixing 30min
Biomass, dry, and the base water-purifying material of marine alga containing grease is obtained.Prepared composite is added according to the ratio of 1% (mass ratio)
Enter in the waste water (copper 4mg/L, cadmium 0.3mg/L, lead 1mg/L, zinc 2mg/L) containing heavy metal, the clearance of heavy metal exceedes
95%.
Claims (6)
1. a kind of preparation method of the base of marine alga containing grease water-purifying material, it is characterised in that：
1) by Lipid-producing marine alga according to 0.1-0.2g L-1Inoculum concentration be added in sea water medium, in 10-20 DEG C, Light To Dark Ratio
It is 12h:Under the condition of culture of 12h, culture to Lipid-producing marine alga enters exponential phase latter stage, stand-by；
2) added and the isometric poor Nutrient Stress sea water medium of cultivating system to above-mentioned Lipid-producing algae culture system, then
Then at 10-20 DEG C, Light To Dark Ratio is 12h:Under conditions of 12h, carrying out poor Nutrient Stress culture stimulates energy algae oil-producing, to algae oil
Fat content>10%, it is stand-by；
3) to the fat content of above-mentioned acquisition>15mg L are pressed in 10% algae-1Addition add aluminium polychloride and nanometer
Ferroso-ferric oxide mixture, stirring coagulating sedimentation collects seaweed biomass, the input steam blasting dress of marine alga containing grease that will be collected
Put, carry out steam blasting broken wall treatment；
4) collect the marine alga containing grease after above-mentioned broken wall to add into shitosan-cetomacrogol 1000 dilute acid solution, stirring is mixed
It is even, solid is then collected, dry, the base water-purifying material of marine alga containing grease is obtained；Wherein, the marine alga containing grease after broken wall and diluted acid water
The mass ratio between shitosan in solution is 1:30-60.
2. the preparation method of the base water-purifying material of marine alga containing grease as described in claim 1, it is characterised in that：The Lipid-producing sea
Algae refers to the marine alga that can produce grease of growth and breeding in seawater.
3. the preparation method of the base water-purifying material of marine alga containing grease as described in claim 1, it is characterised in that：The cultivation in sea water
Base is that nitrogen content is more than 40mg L-1, phosphorus content is more than 3mg L-1Seawater；The poor Nutrient Stress sea water medium contains for nitrogen
Amount is less than 20mg L-1, phosphorus content is less than 1mg L-1Seawater.
4. the preparation method of the base water-purifying material of marine alga containing grease as described in claim 1, it is characterised in that：The steam blasting
Broken wall treatment is that the marine alga containing grease that will be collected puts into steam blasting device, and is passed through saturated vapor, and 5- is maintained in 105-150 DEG C
15min, rapidly discharge carries out broken wall to marine alga.
5. the preparation method of the base water-purifying material of marine alga containing grease as described in claim 1, it is characterised in that：The step 4) in
Chitosan concentration is the matter of 1-10wt%, shitosan and cetomacrogol 1000 in shitosan-cetomacrogol 1000 dilute acid solution
Amount is than being 4:1；Wherein, diluted acid is that concentration is the hydrochloric acid or acetic acid of 1-2%；The deacetylation of shitosan>50%.
6. the application of the marine alga containing grease for the preparing base water-purifying material described in a kind of claim 1, it is characterised in that：It is described
Application of the adsorbing material of marine alga containing grease in purification of water quality is used in removing removal organic polluter and heavy metal multiple pollutant.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0523883A1 (en) * | 1991-07-01 | 1993-01-20 | Water Research Commission | A process for the treatment of saline effluents |
| WO2009082696A1 (en) * | 2007-12-21 | 2009-07-02 | Aurora Biofuels, Inc. | Methods for concentrating microalgae |
| CN102718325A (en) * | 2012-07-13 | 2012-10-10 | 广西湘桂糖业集团有限公司 | Method for culturing high-density oil microalgae to treat yeast industrial wastewater |
| CN104513799A (en) * | 2013-09-29 | 2015-04-15 | 重庆工商大学 | New idea of utilizing sewage to culture oil-rich algae and also purify water |
-
2017
- 2017-04-10 CN CN201710227942.7A patent/CN106861647B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0523883A1 (en) * | 1991-07-01 | 1993-01-20 | Water Research Commission | A process for the treatment of saline effluents |
| WO2009082696A1 (en) * | 2007-12-21 | 2009-07-02 | Aurora Biofuels, Inc. | Methods for concentrating microalgae |
| CN102718325A (en) * | 2012-07-13 | 2012-10-10 | 广西湘桂糖业集团有限公司 | Method for culturing high-density oil microalgae to treat yeast industrial wastewater |
| CN104513799A (en) * | 2013-09-29 | 2015-04-15 | 重庆工商大学 | New idea of utilizing sewage to culture oil-rich algae and also purify water |
Non-Patent Citations (2)
| Title |
|---|
| V. C. RENGE ET AL.: "REMOVAL OF HEAVY METALS FROM WASTEWATER USING LOW COST ADSORBENTS : A REVIEW", 《SCI. REVS. CHEM. COMMUN.》 * |
| 王金扣等: "藻类生物吸附剂应用于处理水中重金属离子研究进展", 《江西化工》 * |
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