CN106861616A - Improver of water quality used for aquiculture and preparation method thereof - Google Patents
Improver of water quality used for aquiculture and preparation method thereof Download PDFInfo
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- CN106861616A CN106861616A CN201611268105.0A CN201611268105A CN106861616A CN 106861616 A CN106861616 A CN 106861616A CN 201611268105 A CN201611268105 A CN 201611268105A CN 106861616 A CN106861616 A CN 106861616A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
- B01J20/28019—Spherical, ellipsoidal or cylindrical
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4875—Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
- B01J2220/4881—Residues from shells, e.g. eggshells, mollusk shells
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The present invention provides a kind of improver of water quality used for aquiculture, is made up of following composition and its components by weight percent:8 15 parts of oyster shell powder, 25 parts of activated carbon, 25 parts of diatomite, 5 10 parts of bentonite, 5 10 parts of kaolin, 13 parts of zeolite, 0.01 0.1 parts of dodecyldimethylammonium hydroxide inner salt, 0.01 0.1 parts of myristic acid, 37 parts of activated alumina.The present invention is the compound improver of water quality based on Adsorption of Heavy Metals, to water body in several major pollutants there is good adsorption capacity, can be used for cultivation water improvement.Improver of water quality is in spherical, rough surface, and with more pore structure, specific surface area increase is conducive to the absorption to various polluters.The improver of water quality is with low cost, and preparation method is simple, works well, and will not produce secondary pollution when in use, with stronger exploitability.
Description
Technical field
The present invention relates to a kind of modifying agent and preparation method thereof, more particularly, to a kind of improver of water quality used for aquiculture and
Its preparation method.
Background technology
In recent years, the development of culture fishery is very rapid, however, largely rich in heavy metal, nitrogen, the industrial wastewater of phosphorus,
Agricultural effluent and sanitary sewage are entered in river, river, lake water, cause water area ecological environment severe exacerbation, also make cultivation water environment dirty
Dye problem becomes increasingly conspicuous.National Survey of Fishery Ecological Environment net shows the monitoring that most of inland fishery waters is carried out, Chinese
The state of ecological environment of fisheries water totally keeps stabilization, and local pollution is more serious, major pollutants be nitrogen, phosphorus, petroleum-type and
Copper.The deterioration of breeding ecological environment, easily causes the generation of various aquatic products diseases, is caused to culture fishery different degrees of
Economic loss, it has also become one of key factor that restriction China culture fishery develops in a healthy way.
As the continuous popularization of aquatic products intensive culture technology, pond culture density are increasing, specific yield is significantly increased, cultivation
Economic benefit is significantly improved.A large amount of is to improve the most important means of aquaculture organism yield using feed, but feed is residual
The accumulation of bits and aquaculture organism excreta generates serious pollution to breeding water body.The deterioration of breeding water body not only has influence on foster
The healthy growth of biology is grown, its death is resulted even in, huge economic loss is caused.Science carries out changing for breeding water body water quality
It is good, it is to improve breed variety growth quality, reduce disease and occur, the key of the excellent product of high yield is realized, and improver of water quality is undoubtedly
The important dependence of breeding water body regulating and controlling water quality.
The principle of the water quality of improver of water quality improvement both at home and abroad is broadly divided into 3 kinds at present:Physical absorption, refers to using with absorption
The raw material of property is adsorbed to the pollutant in water body, with to secondary pollution of water it is small the characteristics of;Chemical method, refers to utilizationization
Learn medicine to improve water quality, feature is rapid effect, and effect substantially, but can cause some to damage environment;Biological method, refers to
The nitrifying bacteria community in water is set to form population advantage using biological agent.Conventional improver of water quality mainly has following a few classes at present:
Quick lime and calper calcium peroxide, natural minerals modifying agent, biological modification agent, flocculant.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of with good adsorption effect, and absorption is quick, will not
Produce the improver of water quality used for aquiculture and preparation method simple to operate, cheap of secondary pollution.
The present invention solve the technical scheme that is used of above-mentioned technical problem for:A kind of aquatic products with good adsorption effect is supported
Grow and use improver of water quality, modifying agent is made up of following composition and its components by weight percent:Oyster shell powder 8-15 parts, activated carbon 2-5 parts, silicon
Diatomaceous earth 2-5 parts, bentonite 5-10 parts, kaolin 5-10 parts, zeolite 1-3 parts, dodecyldimethylammonium hydroxide inner salt 0.01-0.1 parts,
Myristic acid 0.01-0.1 parts, activated alumina 3-7 parts.The preparation method of improver of water quality used for aquiculture, including following step
Suddenly:Coastal Pacific oyster shell or discarded oyster shell will be taken from, surface is cleaned with low-concentration hcl;After cleaning, go
Except impurity subsidiary in oyster husk as raw material;100 mesh sieves are crossed after the size-reduced machine of oyster shell is crushed, sealing preserve is dried standby;Press
Above-mentioned components by weight percent weighs activated carbon, diatomite, dodecyldimethylammonium hydroxide inner salt, myristic acid, bentonite, kaolin, boiling
Stone, activated alumina sealing preserve are standby;Powder obtained above is mixed by a certain percentage with auxiliary material, suitable quantity of water is added and is glued
Mixture, water is ultra-pure water, is sufficiently stirred for, and after mediating uniformly, obtains sticky powdered improver of water quality used for aquiculture;Will be above-mentioned
The sticky powdered improver of water quality used for aquiculture for obtaining prepares spherical sample particle in being put into pellet processing machine, is placed in Muffle furnace
Middle calcining at constant temperature, Muffle furnace calcining heat is 550 DEG C, and calcination time is 2 h, and sealing preserve after cooling obtains form of spherical particles
Improver of water quality used for aquiculture.
The invention has the advantages that:The present invention is the compound improver of water quality based on Adsorption of Heavy Metals, in water body
Several major pollutants there is good adsorption capacity, can be used for cultivation water improvement.Improver of water quality is in spherical, and surface is thick
Rough, with more pore structure, specific surface area increase is conducive to the absorption to various polluters.The improver of water quality into
This is cheap, and preparation method is simple, works well, and will not produce secondary pollution when in use, with stronger exploitability.
Specific embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1:
A kind of improver of water quality used for aquiculture with good adsorption effect, modifying agent is by following composition and its components by weight percent group
Into:Oyster shell powder 8-15 parts, activated carbon 2-5 parts, diatomite 2-5 parts, bentonite 5-10 parts, kaolin 5-10 parts, zeolite 1-3
Part, dodecyldimethylammonium hydroxide inner salt 0.01-0.1 parts, myristic acid 0.01-0.1 parts, activated alumina 3-7 parts, dodecyl
Dimethyl betaine and myristic acid play a part of to promote absorption by activated carbon, while improver of water quality is in spherical, surface
Coarse, with more pore structure, specific surface area increase is more beneficial for the absorption to various polluters, therefore this implementation
Example is notable for water improvement.The preparation method of improver of water quality used for aquiculture, comprises the following steps:Coastal peace will be taken from
Foreign oyster shell or discarded oyster shell, are cleaned surface with low-concentration hcl;It is subsidiary in removal oyster husk as raw material after cleaning
Impurity;100 mesh sieves are crossed after the size-reduced machine of oyster shell is crushed, sealing preserve is dried standby;Work is weighed by above-mentioned components by weight percent
Property charcoal, diatomite, dodecyldimethylammonium hydroxide inner salt, myristic acid, bentonite, kaolin, zeolite, active oxidation alumiseal protect
Deposit standby;Powder obtained above is mixed by a certain percentage with auxiliary material, suitable quantity of water and adhesive is added, water is ultra-pure water, is filled
Divide stirring, after mediating uniformly, obtain sticky powdered improver of water quality used for aquiculture;By sticky powdered water obtained above
Produce during breeding water quality improving agent is put into pellet processing machine and prepare spherical sample particle, be placed in calcining at constant temperature in Muffle furnace, Muffle furnace
Calcining heat is 550 DEG C, and calcination time is 2 h, and sealing preserve after cooling obtains form of spherical particles water quality improvement used for aquiculture
Agent.
Embodiment 2:
Improver of water quality used for aquiculture is planted, in parts by weight, including following components:
10 parts of oyster shell powder, 3 parts of activated carbon, 3 parts of diatomite, 8 parts of bentonite, 7 parts of kaolin, 2 parts of zeolite, activated alumina 4
Part.
Its preparation method is comprised the following steps:
(1)Coastal Pacific oyster shell or discarded oyster shell will be taken from, surface is cleaned with low-concentration hcl;
(2)After cleaning, subsidiary impurity in removal oyster husk as raw material;
(3)100 mesh sieves are crossed after the size-reduced machine of oyster shell is crushed, sealing preserve is dried standby;
(4)The active charcoal of auxiliary material, diatomite, bentonite, kaolin, zeolite, activated alumina, can be obtained from commercially available, and sealing is protected
Deposit standby;
(5)By step(3)The powder for obtaining take 10 parts with auxiliary material take respectively 3 parts, 3 parts, 8 parts, 7 parts, 2 parts, 4 parts by a certain percentage
Mixing, adds suitable quantity of water and adhesive, is sufficiently stirred for, and after mediating uniformly, obtains sticky powdered water quality improvement used for aquiculture
Agent;
(6)By step(5)The sticky powdered improver of water quality used for aquiculture for obtaining prepares spherical sample in being put into pellet processing machine
Product particle, is placed in calcining at constant temperature in Muffle furnace, sealing preserve after cooling, obtains form of spherical particles water quality improvement used for aquiculture
Agent.
Embodiment 3
A kind of improver of water quality used for aquiculture, in parts by weight, including following components:
12 parts of oyster shell powder, 4 parts of activated carbon, 4 parts of diatomite, 8 parts of bentonite, 6 parts of kaolin, 1 part of zeolite, activated alumina 5
Part.
Its preparation method is comprised the following steps:
(1)Coastal Pacific oyster shell or discarded oyster shell will be taken from, surface is cleaned with low-concentration hcl;
(2)After cleaning, subsidiary impurity in removal oyster husk as raw material;
(3)100 mesh sieves are crossed after the size-reduced machine of oyster shell is crushed, sealing preserve is dried standby;
(4)The active charcoal of auxiliary material, diatomite, bentonite, kaolin, zeolite, activated alumina, can be obtained from commercially available, and sealing is protected
Deposit standby;
(5)By step(3)The powder for obtaining take 10 parts with auxiliary material take respectively 4 parts, 4 parts, 8 parts, 6 parts, 1 part, 5 parts by a certain percentage
Mixing, adds suitable quantity of water and adhesive, is sufficiently stirred for, and after mediating uniformly, obtains sticky powdered water quality improvement used for aquiculture
Agent;
(6)By step(5)The sticky powdered improver of water quality used for aquiculture for obtaining prepares spherical sample in being put into pellet processing machine
Product particle, is placed in calcining at constant temperature in Muffle furnace, sealing preserve after cooling, obtains form of spherical particles water quality improvement used for aquiculture
Agent.
Embodiment 4:
A kind of improver of water quality used for aquiculture, in parts by weight, including following components:
15 parts of oyster shell powder, 5 parts of activated carbon, 5 parts of diatomite, 10 parts of bentonite, 10 parts of kaolin, 3 parts of zeolite, activated alumina
7 parts.
Its preparation method is comprised the following steps:
(1)Coastal Pacific oyster shell or discarded oyster shell will be taken from, surface is cleaned with low-concentration hcl;
(2)After cleaning, subsidiary impurity in removal oyster husk as raw material;
(3)100 mesh sieves are crossed after the size-reduced machine of oyster shell is crushed, sealing preserve is dried standby;
(4)The active charcoal of auxiliary material, diatomite, bentonite, kaolin, zeolite, activated alumina, can be obtained from commercially available, and sealing is protected
Deposit standby;
(5)By step(3)The powder for obtaining takes 15 parts and auxiliary material takes 5 parts, 5 parts, 10 parts, 10 parts, 3 parts, 7 parts and compares by certain respectively
Example mixing, adds suitable quantity of water and adhesive, is sufficiently stirred for, and after mediating uniformly, obtains sticky powdered water quality used for aquiculture and changes
Good dose;
(6)By step(5)The sticky powdered improver of water quality used for aquiculture for obtaining prepares spherical sample in being put into pellet processing machine
Product particle, is placed in calcining at constant temperature in Muffle furnace, sealing preserve after cooling, obtains form of spherical particles water quality improvement used for aquiculture
Agent.
Although the present invention is disclosed as above with embodiment, it is not limited to protection scope of the present invention, any ripe
Those skilled in the art is known, in the change and retouching done without departing from the spirit and scope of the invention, this hair all should be belonged to
The protection domain of bright appended claims.
Claims (5)
1. improver of water quality used for aquiculture, it is characterised in that the modifying agent is made up of following composition and its components by weight percent:It is male
Oyster shells 8-15 parts, activated carbon 2-5 parts, diatomite 2-5 parts, bentonite 5-10 parts, kaolin 5-10 parts, zeolite 1-3 parts, 12
Alkyl dimethyl betaine 0.01-0.1 parts, myristic acid 0.01-0.1 parts, activated alumina 3-7 parts.
2. the preparation method of improver of water quality used for aquiculture, it is characterised in that comprise the following steps:
1)Coastal Pacific oyster shell or discarded oyster shell will be taken from, surface is cleaned with low-concentration hcl;
2)After cleaning, subsidiary impurity in removal oyster husk as raw material;
3)100 mesh sieves are crossed after the size-reduced machine of oyster shell is crushed, sealing preserve is dried standby;
4)Activated carbon, diatomite, dodecyldimethylammonium hydroxide inner salt, myristic acid, bentonite, height are weighed by above-mentioned components by weight percent
Ridge soil, zeolite, activated alumina sealing preserve are standby;
5)By step 3)The powder for obtaining mixes by a certain percentage with auxiliary material, adds suitable quantity of water and adhesive, is sufficiently stirred for, and mediates
After uniform, sticky powdered improver of water quality used for aquiculture is obtained;
6)By step 5)The sticky powdered improver of water quality used for aquiculture for obtaining prepares spherical sample in being put into pellet processing machine
Particle, is placed in calcining at constant temperature in Muffle furnace, sealing preserve after cooling, obtains form of spherical particles improver of water quality used for aquiculture.
3. a kind of preparation method of improver of water quality used for aquiculture according to claim 5, it is characterised in that step 5)
Described in water be ultra-pure water.
4. a kind of preparation method of improver of water quality used for aquiculture according to claim 5, it is characterised in that step 6)
Described in Muffle furnace calcining heat be 550 DEG C.
5. a kind of preparation method of improver of water quality used for aquiculture according to claim 5, it is characterised in that step 6)
Described in calcination time be 2 h.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107226533A (en) * | 2017-07-04 | 2017-10-03 | 合肥仙之峰农业科技有限公司 | It is a kind of to be used to support improver of water quality of shrimp and preparation method thereof |
CN108033527A (en) * | 2017-12-12 | 2018-05-15 | 长沙拜特生物科技研究所有限公司 | Improver of water quality and preparation method thereof |
CN114195563A (en) * | 2021-12-03 | 2022-03-18 | 泉州南京大学环保产业研究院 | Organic fertilizer and method for preparing anaerobic fermentation modifier based on oyster shells |
CN114467840A (en) * | 2022-03-16 | 2022-05-13 | 国家海洋环境监测中心 | Preparation method and device of reinforced particles for in-situ treatment of seawater pond culture tail water |
CN115536118A (en) * | 2022-10-09 | 2022-12-30 | 陕西水研环境科技研究院有限公司 | Sewage treatment flocculant and preparation method and application thereof |
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CN101715742A (en) * | 2009-11-16 | 2010-06-02 | 大连金砣水产食品有限公司 | Holothurian cultivation pond water quality modifier and preparation method thereof |
CN104229957A (en) * | 2013-06-24 | 2014-12-24 | 张家领 | Compound flocculant taking natural minerals as main components |
CN104944537A (en) * | 2015-06-17 | 2015-09-30 | 何素梅 | Bactericide for aquaculture |
CN105478074A (en) * | 2015-12-23 | 2016-04-13 | 中国科学院烟台海岸带研究所 | Preparation method and application of heavy metal ion remover |
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2016
- 2016-12-31 CN CN201611268105.0A patent/CN106861616A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101715742A (en) * | 2009-11-16 | 2010-06-02 | 大连金砣水产食品有限公司 | Holothurian cultivation pond water quality modifier and preparation method thereof |
CN104229957A (en) * | 2013-06-24 | 2014-12-24 | 张家领 | Compound flocculant taking natural minerals as main components |
CN104944537A (en) * | 2015-06-17 | 2015-09-30 | 何素梅 | Bactericide for aquaculture |
CN105478074A (en) * | 2015-12-23 | 2016-04-13 | 中国科学院烟台海岸带研究所 | Preparation method and application of heavy metal ion remover |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107226533A (en) * | 2017-07-04 | 2017-10-03 | 合肥仙之峰农业科技有限公司 | It is a kind of to be used to support improver of water quality of shrimp and preparation method thereof |
CN108033527A (en) * | 2017-12-12 | 2018-05-15 | 长沙拜特生物科技研究所有限公司 | Improver of water quality and preparation method thereof |
CN114195563A (en) * | 2021-12-03 | 2022-03-18 | 泉州南京大学环保产业研究院 | Organic fertilizer and method for preparing anaerobic fermentation modifier based on oyster shells |
CN114195563B (en) * | 2021-12-03 | 2023-09-26 | 泉州南京大学环保产业研究院 | Organic fertilizer and method for preparing anaerobic fermentation modifier based on oyster shells |
CN114467840A (en) * | 2022-03-16 | 2022-05-13 | 国家海洋环境监测中心 | Preparation method and device of reinforced particles for in-situ treatment of seawater pond culture tail water |
CN115536118A (en) * | 2022-10-09 | 2022-12-30 | 陕西水研环境科技研究院有限公司 | Sewage treatment flocculant and preparation method and application thereof |
CN115536118B (en) * | 2022-10-09 | 2024-04-12 | 陕西水研环境科技研究院有限公司 | Sewage treatment flocculant and preparation method and application thereof |
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