CN106858933B - The production method of PVC badges with healthcare function - Google Patents
The production method of PVC badges with healthcare function Download PDFInfo
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- CN106858933B CN106858933B CN201710133752.9A CN201710133752A CN106858933B CN 106858933 B CN106858933 B CN 106858933B CN 201710133752 A CN201710133752 A CN 201710133752A CN 106858933 B CN106858933 B CN 106858933B
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- pvc
- badges
- healthcare function
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- printing
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C3/00—Medals; Badges
- A44C3/001—Badges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/22—Metallic printing; Printing with powdered inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Printing Methods (AREA)
- Laminated Bodies (AREA)
Abstract
The production method of PVC badges with healthcare function, the invention belongs to print fields.Currently there are silk-screen printing badge it is simple mainly for figure, the less preparation process of color, not having the function of that other are attached.The present invention passes through silk-screen printing bottom material of the preparation with healthcare function；Pass through the color pigment in addition to gold required on screen process press or UV press printing badges according to layout；It cuts into and the matched size of gilding press；Carry out gold stamping processing；According to badge concrete shape and it is dimensioned to PVC badge criteria sizes；Preparing has Nano-meter SiO_22Surfacecti proteon clear dope, the PVC badges that step 5 is handled well carry out surface brushing；The PVC badges that step 6 is handled well paste back support device or fixing device.Clear patterns that the present invention prints, it is wear-resisting, there are certain health care functions.
Description
Technical field
The invention belongs to print fields；More particularly to a kind of production method of the PVC badges with healthcare function.
Background technology
Badge, in short, being exactly the mark taken with oneself for indicating identity, occupation of wearing.It has long history, emblem
The manufacture craft of chapter has very much, for example baking vanish, imitates enamel, punching press, some other badge technique：Sting version (erosion version), silk-screen printing,
Offset printing, 3D stereoscopic effects etc..Wherein printing badge is divided into be divided into silk-screen printing, offset printing.It is general to be also called drop glue emblem
Chapter, because the finishing operation of badge is to protect resin, the material used mainly stainless plus layer of transparent on the surface of badge
Steel, bronze 2 kinds of materials.Currently there are silk-screen printing badge it is simple mainly for figure, the less preparation work of color
Skill, and currently there are badge only indicate this function, not having the function of that other are attached.
Invention content
It is an object of the present invention to provide a kind of production methods of the coloury PVC badges with healthcare function.
The invention is realized by the following technical scheme：
There is a kind of production method of the PVC badges with healthcare function the preparation method of the PVC badges of healthcare function to be
It carries out in the steps below：
Step 1 prepares the silk-screen printing bottom material with healthcare function, by being screen-printed on PVC bottom plates, time of printing
Number is 1~5 time, and it is primary that hot pressing is carried out after printing；
Step 2, the PVC board for handling step 1 well pass through screen process press or UV press printings emblem according to layout
The color pigment in addition to gold needed on chapter；
Step 3, the PVC board for handling step 2 well are sent into cutting apparatus, cut into and the matched size of gilding press；
Step 4, the PVC board for handling step 3 well are sent into gilding press, and gold stamping processing is carried out；
Step 5, the PVC board for handling step 4 well are sent into engraving machine, according to badge concrete shape and are dimensioned to
PVC badge criteria sizes；
Step 6 is prepared with Nano-meter SiO_22Surfacecti proteon clear dope, the PVC badge carry out tables that step 5 is handled well
It brushes in face；
Step 7, the PVC badges for handling step 6 well paste back support device or fixing device.
The production method of PVC badges of the present invention with healthcare function, the silk screen with healthcare function in step 1
Printing bottom material, including 80~100 parts of Corvics, 5~10 parts of polyvinyl alcohol, 10~20 parts of nano-scaled electric stone are micro-
Powder, 10~20 parts of nano zine oxide, 5~10 parts of lauryl sodium sulfate, 5~10 parts of vinyltriethoxysilane.
The production method of PVC badges of the present invention with healthcare function, the nano-scaled electric stone micro mist
Grain size is 20~50nm, and the nano zine oxide is 5~20nm.
The production method of PVC badges of the present invention with healthcare function, hot pressing temperature 150~180 in step 1
DEG C, 6~8MPa of hot pressing pressure, 2~5min of hot pressing time.
The production method of PVC badges of the present invention with healthcare function, in step 2 silk-screen printing by pigment, adjust
Black agent presses 1 with pore-creating agent：3：1.25 mass ratio is uniformly mixed and is placed in screen process press, and it is 20~30 to keep indoor temperature
DEG C, humidity be 35~45% under the conditions of, carried out after the corresponding different colours of printing on substrates pattern, printing with screen process press
It is dry.
The production method of PVC badges of the present invention with healthcare function, PVC board after cutting in step 3
Size is 100 × 150mm.
The production method of PVC badges of the present invention with healthcare function, in step 4 according to position, pattern, face
After color carries out position correspondence, gold stamping processing, 130~150 DEG C of gold stamping temperature are carried out.
The production method of PVC badges of the present invention with healthcare function, nanometer in surfacecti proteon coating in step 6
SiO2Shared mass percent is that mass percent shared by 0.5~5%, UV gloss oil is 95~99.5%.
The production method of PVC badges of the present invention with healthcare function, the Nano-meter SiO_22Grain size be 20
~50nm.
The production method of PVC badges of the present invention with healthcare function, the back support device described in step 7
Including support plate or support frame, the fixing device includes clip or safety pin.
The production method of PVC badges of the present invention with healthcare function, nano-scaled electric stone and nanoscale
Zinc is mixed in the silk-screen printing bottom material with healthcare function that Corvic is matrix, and tourmaline can be with biological cell
Resonance effects is generated, far infrared heat energy can be transmitted to human body subcutaneously deeper part, following deep layer temperature rise, the temperature of generation
Heat distributes from inside to outside.This action intensity, makes telangiectasis, promotes blood circulation, and strengthens new old between each tissue
Metabolism, increases the power of regeneration of tissue, improves the immunocompetence of body, adjust the exaltation state of spirit, to play doctor
Treat the effect of health care.Nano zine oxide has good ultraviolet-shielding type and superior antibacterial, bacteriostasis property, in conjunction with tourmaline
Function so that electromagnetic radiation of the silk-screen printing bottom material with far infrared band with healthcare function, generate negative oxygen ion with
And the feature capability of antibacterial, deodorization.By hot-press method, the silk-screen printing bottom material with healthcare function and the bottoms PVC are enabled to
Hardened to be integrated, hot pressing can also ensure have the surface of the processed PVC bottom plates of the silk-screen printing bottom material of healthcare function thick
Rugosity reaches Ra0.05~0.2 μm.
The production method of PVC badges of the present invention with healthcare function, the clear patterns of printing, wear-resisting, color
It is evenly distributed, image surface is smooth, feels smooth after the touch of flawless, hand.The product of the present invention can be mass, production efficiency
It is high.Product of the present invention has the texture of stereo gilding, class high.
The production method of PVC badges of the present invention with healthcare function, nanometer in the surfacecti proteon coating
SiO2Can light transmission, granularity it is small, surfacecti proteon coating transparency, intensity, toughness, water resistance and anti-ultraviolet aging can be improved
Performance.
Specific implementation mode
Specific implementation mode one：
There is a kind of production method of the PVC badges with healthcare function the preparation method of the PVC badges of healthcare function to be
It carries out in the steps below：
Step 1 prepares the silk-screen printing bottom material with healthcare function, by being screen-printed on PVC bottom plates, time of printing
Number is 3 times, and it is primary that hot pressing is carried out after printing；
Step 2, the PVC board for handling step 1 well pass through screen process press or UV press printings emblem according to layout
The color pigment in addition to gold needed on chapter；
Step 3, the PVC board for handling step 2 well are sent into cutting apparatus, cut into and the matched size of gilding press；
Step 4, the PVC board for handling step 3 well are sent into gilding press, and gold stamping processing is carried out；
Step 5, the PVC board for handling step 4 well are sent into engraving machine, according to badge concrete shape and are dimensioned to
PVC badge criteria sizes；
Step 6 is prepared with Nano-meter SiO_22Surfacecti proteon clear dope, the PVC badge carry out tables that step 5 is handled well
It brushes in face；
Step 7, the PVC badges for handling step 6 well paste back support device or fixing device.
The production method of the PVC badges with healthcare function described in present embodiment, with healthcare function in step 1
Silk-screen printing bottom material, including 100 parts of Corvics, 10 parts of polyvinyl alcohol, 20 parts of nano-scaled electric stone micro mist, 20 parts
Nano zine oxide, 10 parts of lauryl sodium sulfate, 10 parts of vinyltriethoxysilane.
The production method of the PVC badges with healthcare function described in present embodiment, the nano-scaled electric stone are micro-
The grain size of powder is 20~50nm, and the nano zine oxide is 5~20nm.
The production method of the PVC badges with healthcare function described in present embodiment, 180 DEG C of hot pressing temperature in step 1,
Hot pressing pressure 8MPa, hot pressing time 5min.
The production method of the PVC badges with healthcare function described in present embodiment, silk-screen printing is by face in step 2
Material, inking agent and pore-creating agent press 1：3：1.25 mass ratio is uniformly mixed and is placed in screen process press, and holding indoor temperature is
25 DEG C, humidity be 45% under the conditions of, with screen process press in the corresponding different colours of printing on substrates pattern, done after printing
It is dry.
The production method of the PVC badges with healthcare function described in present embodiment, the PVC after cutting in step 3
The size of plate is 100 × 150mm.
The production method of the PVC badges with healthcare function described in present embodiment, in step 4 according to position, figure
After case, color carry out position correspondence, gold stamping processing, 130 DEG C of gold stamping temperature are carried out.
The production method of the PVC badges with healthcare function described in present embodiment, in step 6 in surfacecti proteon coating
Nano-meter SiO_22Shared mass percent is that mass percent shared by 5%, UV gloss oil is 95%.
The production method of the PVC badges with healthcare function described in present embodiment, the Nano-meter SiO_22Grain size
For 20~50nm.
The production method of the PVC badges with healthcare function described in present embodiment, the back support described in step 7
Device includes support plate or support frame, and the fixing device includes clip or safety pin.
Face coat performance comparison using the PVC badges of present embodiment preparation is as shown in table 1, with present embodiment pair
The face coat of ratio is production method of the inventor in a kind of diploma of patent, medal, board, number of patent application
Face coat performance in the specific implementation mode one of the PVC medals prepared in CN201510939368.9, can from table
Go out, the application compared in documents the diploma, medal, board production method have superior performance, tensile strength
For 37.3MPa, bending strength reaches 29.8MPa, and gloss rate reaches 98%, and pencil hardness reaches 4 grades, and resistance to UV aging is excellent
It is different, there is anti-microbial property and emitting far-infrared performance.
The coating performance for the face coat and contrast sample that table 1 is prepared using present embodiment compares
| Performance | Present embodiment sample | Contrast sample |
| Tensile strength MPa | 37.7 | 32.2 |
| Bending strength MPa | 29.8 | 22.1 |
| Impact strength kg × cm | 47.5 | 38.6 |
| Gloss % | 98 | 95 |
| Pencil hardness | 4 | 3 |
| Resistance to UV aging | 72h | 48h |
| Anti-microbial property | Have | Nothing |
| Emitting far-infrared performance | Have | Nothing |
Specific implementation mode two：
There is a kind of production method of the PVC badges with healthcare function the preparation method of the PVC badges of healthcare function to be
It carries out in the steps below：
Step 1 prepares the silk-screen printing bottom material with healthcare function, by being screen-printed on PVC bottom plates, time of printing
Number is 5 times, and it is primary that hot pressing is carried out after printing；
Step 2, the PVC board for handling step 1 well pass through screen process press or UV press printings emblem according to layout
The color pigment in addition to gold needed on chapter；
Step 3, the PVC board for handling step 2 well are sent into cutting apparatus, cut into and the matched size of gilding press；
Step 4, the PVC board for handling step 3 well are sent into gilding press, and gold stamping processing is carried out；
Step 5, the PVC board for handling step 4 well are sent into engraving machine, according to badge concrete shape and are dimensioned to
PVC badge criteria sizes；
Step 6 is prepared with Nano-meter SiO_22Surfacecti proteon clear dope, the PVC badge carry out tables that step 5 is handled well
It brushes in face；
Step 7, the PVC badges for handling step 6 well paste back support device or fixing device.
The production method of the PVC badges with healthcare function according to the present embodiment, with health care work(in step 1
The silk-screen printing bottom material of energy, including 80 parts of Corvics, 5 parts of polyvinyl alcohol, 10 parts of nano-scaled electric stone micro mist, 10
The nano zine oxide of part, 5 parts of lauryl sodium sulfate, 5 parts of vinyltriethoxysilane.
The production method of the PVC badges with healthcare function according to the present embodiment, the nano-scaled electric
The grain size of stone micro mist is 20~50nm, and the nano zine oxide is 5~20nm.
The production method of the PVC badges with healthcare function according to the present embodiment, hot pressing temperature in step 1
160 DEG C, hot pressing pressure 7MPa, hot pressing time 2min.
The production method of the PVC badges with healthcare function according to the present embodiment, silk-screen printing general in step 2
Pigment, inking agent and pore-creating agent press 1：3：1.25 mass ratio is uniformly mixed and is placed in screen process press, keeps indoor temperature
Under the conditions of being 35% for 20 DEG C, humidity, carried out after the corresponding different colours of printing on substrates pattern, printing with screen process press
It is dry.
The production method of the PVC badges with healthcare function according to the present embodiment, after cutting in step 3
The size of PVC board is 100 × 150mm.
The production method of the PVC badges with healthcare function according to the present embodiment, in step 4 according to position
It sets, after pattern, color progress position correspondence, carries out gold stamping processing, 130 DEG C of gold stamping temperature.
The production method of the PVC badges with healthcare function according to the present embodiment, surfacecti proteon painting in step 6
Nano-meter SiO_2 in material2Shared mass percent is that mass percent shared by 0.5%, UV gloss oil is 99.5%.
The production method of the PVC badges with healthcare function according to the present embodiment, the Nano-meter SiO_22's
Grain size is 20~50nm.
The production method of the PVC badges with healthcare function according to the present embodiment, the back side described in step 7
Support device includes support plate or support frame, and the fixing device includes clip or safety pin.
The production method of the PVC badges with healthcare function according to the present embodiment, because being received in protective coating
Rice SiO2Can light transmission, granularity it is small, it is old to improve surfacecti proteon coating transparency, intensity, toughness, water resistance and uvioresistant
Change performance.
Claims (10)
1. a kind of production method of the PVC badges with healthcare function, it is characterised in that：PVC badges with healthcare function
Preparation method carries out in the steps below：
Step 1 prepares the silk-screen printing bottom material with healthcare function, and by being screen-printed on PVC bottom plates, the number of printing is
1~5 time, it is primary that hot pressing is carried out after printing；
Step 2, the PVC board for handling step 1 well pass through according to layout on screen process press or UV press printing badges
The required color pigment in addition to gold；
Step 3, the PVC board for handling step 2 well are sent into cutting apparatus, cut into and the matched size of gilding press；
Step 4, the PVC board for handling step 3 well are sent into gilding press, and gold stamping processing is carried out；
Step 5, the PVC board for handling step 4 well are sent into engraving machine, according to badge concrete shape and are dimensioned to the emblems PVC
Chapter standard size；
Step 6 is prepared with Nano-meter SiO_22Surfacecti proteon clear dope, the PVC badges that step 5 is handled well carry out surface brush
It applies；
Step 7, the PVC badges for handling step 6 well paste back support device or fixing device.
2. the production method of the PVC badges according to claim 1 with healthcare function, it is characterised in that：Have in step 1
There are the silk-screen printing bottom material of healthcare function, including 80~100 parts of Corvics, 5~10 parts of polyvinyl alcohol, 10~20 parts
Nano-scaled electric stone micro mist, 10~20 parts of nano zine oxide, 5~10 parts of lauryl sodium sulfate, 5~10 parts of ethylene
Ethyl triethoxy silicane alkane.
3. the production method of the PVC badges according to claim 2 with healthcare function, it is characterised in that：Described receives
The grain size of meter level tourmaline micro mist is 20~50nm, and the grain size of the nano zine oxide is 5~20nm.
4. the production method of the PVC badges according to claim 1 or 2 with healthcare function, it is characterised in that：Step 1
150~180 DEG C, 6~8MPa of hot pressing pressure, 2~5min of hot pressing time of middle hot pressing temperature.
5. the production method of the PVC badges according to claim 1 with healthcare function, it is characterised in that：Silk in step 2
Pigment, inking agent and pore-creating agent are pressed 1 by wire mark brush：3：1.25 mass ratio is uniformly mixed and is placed in screen process press, keeps
It is corresponding not in printing on substrates pattern with screen process press under the conditions of indoor temperature is 20~30 DEG C, humidity is 35~45%
Same color is dried after printing.
6. the production method of the PVC badges according to claim 1 with healthcare function, it is characterised in that：In step 3
The size of PVC board after cutting is 100 × 150mm.
7. the production method of the PVC badges according to claim 1 with healthcare function, it is characterised in that：In step 4
After carrying out position one-to-one correspondence according to position, pattern, color, gold stamping processing, 130~150 DEG C of gold stamping temperature are carried out.
8. the production method of the PVC badges according to claim 1 with healthcare function, it is characterised in that：Table in step 6
Nano-meter SiO_2 in the protective coating of face2Shared mass percent be mass percent shared by 0.5~5%, UV gloss oil be 95~
99.5%.
9. the production method of the PVC badges according to claim 8 with healthcare function, it is characterised in that：Described receives
Rice SiO2Grain size be 20~50nm.
10. the production method of the PVC badges according to claim 1 with healthcare function, it is characterised in that：In step 7
The back support device includes support plate or support frame, and the fixing device includes clip or safety pin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710133752.9A CN106858933B (en) | 2017-03-08 | 2017-03-08 | The production method of PVC badges with healthcare function |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710133752.9A CN106858933B (en) | 2017-03-08 | 2017-03-08 | The production method of PVC badges with healthcare function |
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| CN106858933B true CN106858933B (en) | 2018-08-28 |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108402610A (en) * | 2018-03-14 | 2018-08-17 | 温州奇越工艺品有限公司 | A kind of Multifunction badge |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB521995A (en) * | 1939-01-19 | 1940-06-05 | Hans Felix Stoffel | Improvements in or relating to badges, emblems or other insignia |
| US4048736A (en) * | 1975-02-11 | 1977-09-20 | Package Products Company, Inc. | Laminated composite sheet packaging material |
| CN1131000C (en) * | 2001-08-22 | 2003-12-17 | 李国华 | Badge making process |
| CN101712825A (en) * | 2008-10-06 | 2010-05-26 | 王微 | Negative ion-releasing inkpad and stamp-pad ink and preparation method thereof |
| CN103009842B (en) * | 2012-12-28 | 2015-09-30 | 深圳市柏星龙创意包装股份有限公司 | The preparation method of microballon decoration |
| CN106009363A (en) * | 2016-05-13 | 2016-10-12 | 佛山市天进塑胶有限公司 | Negative ion powder, negative ion PVC decorative film and preparing method of negative ion PVC decorative film |
| CN106113883A (en) * | 2016-06-23 | 2016-11-16 | 成都市森远通讯网络有限公司 | The preparation method of nano-negative ion PVC board and automobile pendant and house decoraton product |
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