CN106857627A - A kind of Pesticidal combination containing Acetamiprid and Bassa and its application - Google Patents
A kind of Pesticidal combination containing Acetamiprid and Bassa and its application Download PDFInfo
- Publication number
- CN106857627A CN106857627A CN201710083985.2A CN201710083985A CN106857627A CN 106857627 A CN106857627 A CN 106857627A CN 201710083985 A CN201710083985 A CN 201710083985A CN 106857627 A CN106857627 A CN 106857627A
- Authority
- CN
- China
- Prior art keywords
- bassa
- acetamiprid
- pesticidal combination
- combination containing
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Pesticidal combination containing Acetamiprid and Bassa and its application, including active ingredient Acetamiprid and active ingredient Bassa.The weight of Acetamiprid and Bassa is than 31:1‑3.This composition can be applied to agricultural chemicals pharmacy, be configured to the various formulations for agriculturally allowing.Instant component compounding is chlorination nicotinoids New-type wide-spectrum insecticide and carbamate insecticides, aphid, plant hopper to diversified economy crops such as preventing and treating paddy rice, vegetables, corn, oranges and tangerines, leafhopper, thrips have relatively good effect, and can effectively delay the generation of the resistance of insect.Compared with unitary agent, control effect is good, and the lasting period is long, expands insecticidal spectrum, and synergistic effect is obvious.
Description
Technical field
The present invention relates to technical field of pesticide combination, more particularly to a kind of Pesticidal combination containing Acetamiprid and Bassa
And its application.
Background technology
The insects such as aphid, plant hopper, leafhopper, thrips, are the important pests on the crops such as paddy rice, cotton, fruit tree, vegetables.
The growing way of these insect serious harm plants, and breeding is fast, generation is more, and generation overlap is serious, therefore preventing and treating is difficult, and holds
It is also easy to produce resistance.Therefore, it is current problem demanding prompt solution to develop new, efficient, safe chemical pesticide.
Acetamiprid belongs to chlorination nicotine compound, is a kind of novel pesticide, acts on insect nerve system cynapse portion
The nAChR of position, the stimulation conduction of interference insect nervous system, causes nervous system path blockade, causes nerve
Transmitter acetylcholine synapses accumulation, it is final dead so as to cause insect paralysis.With tagging and stomach poison function, also
With osmosis and systemic activity, desinsection is quick-acting, and the lasting period is long.Be generally used for fruit tree, vegetables, melon, tobacco, potato,
The crops such as careless mould, tea tree, paddy rice, can effectively prevent and treat plant hopper, aphid, leafhopper, thrips, aleyrodid, coccid etc..
Bassa (Ba Sha, bufencarb) belongs to carbamate insecticides, and toxicological mechanism is to suppress insect acetylcholine
The activity of enzyme (Ache) and carboxy-lesterase, causes the accumulation of acetylcholine (Ach) and carboxylate, and the normal nerve of influence insect is passed
Lead and lethal.Bassa has strong action of contace poison, and has certain stomach toxicity, stifling and ovicidal action.To planthopper and black tail
Leafhopper and rice stinkbug tag and have immediate effect, but the lasting period is short.
Aphid is also referred to as aphid, aphid, is China vegetables, one of the primary pest through crop, while reproduction speed speed is fast,
Generation overlap is serious, the features such as resistance produces fast.It is therefore desirable to rationally the agriculture chemical compounding or mixture of science expand insecticidal spectrum, carry
Prevention effect high, reduces dosage, reduces residues of pesticides, extends the Pesticide use life-span, delays the generation of pest resistance, favorably
In sustainable development.The report of the Pesticidal combination compounded on Acetamiprid and Bassa is there is no at present.
The content of the invention
In view of this, it is necessary to for above-mentioned problem, there is provided a kind of Pesticidal combination containing Acetamiprid and Bassa
And its application, this composition is formed by Acetamiprid with fenobucarb composite, safe efficient, and quick-acting is good, and the lasting period is long, extends agriculture
Medicine service life, improves the bioactivity of crop, and confrontation property of medicine pest controling effect is good, helps to overcome and delay the anti-of insect
The property of medicine.
The present invention uses following technical scheme:
A kind of Pesticidal combination containing Acetamiprid and Bassa, it is characterised in that:Including Acetamiprid and Bassa;
The weight ratio of the Acetamiprid and Bassa is 3-1:1-3.
Further, the weight summation of described Acetamiprid and Bassa percentage by weight in the composition is
5%-60%.
Further, the weight summation of described Acetamiprid and Bassa percentage by weight in the composition is
10%-50%.
Further, the composition also includes auxiliary element, and described auxiliary element includes solvent, cosolvent, dispersion
One kind or several in agent, emulsifying agent, wetting agent, disintegrant, thickener, stabilizer, defoamer, preservative, antifreeze and carrier
Kind.
Further, the Pesticidal combination is applied to agricultural chemicals pharmaceutical field.
Further, the Pesticidal combination can be made into emulsifiable concentrate, granule, wettable powder, water dispersible granules, micro emulsion
The formulations such as agent, suspending agent or aqueous emulsion.
Further, the described Pesticidal combination containing Acetamiprid and Bassa is applied to prevent and treat insect pest of the plant.
Further, the composition is applied to preventing and treating for preventing and treating aphid, plant hopper, leafhopper, thrips of crop etc..
The beneficial effect that can be reached using the present invention program:
Acetamiprid has synergistic function with fenobucarb composite, is used alone to significantly improve than single dose and insect is prevented
Control effect.Two kinds of different insecticidal mechanisms, can mutually compensate its defect, and extend the lasting period, more preferably play drug effect.Acetamiprid with it is secondary
Fourth prestige is compounded, and expands its insecticidal spectrum, improves prevention effect, reduces dosage, reduces residues of pesticides, extends the Pesticide use longevity
Life, delays the generation of pest resistance.
Specific embodiment
In order to preferably illustrate the Pesticidal combination containing Acetamiprid and fenobucarb composite and its application of present invention offer,
It is described further in conjunction with following examples and various experiments.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Shield scope.Therefore, the protection domain of patent of the present invention should be defined by claims.
The present invention is a kind of containing Acetamiprid and the multiple Pesticidal combination of Bassa and its application, and the Insecticidal combinations are included
Effect composition Acetamiprid and active ingredient Bassa;Weight ratio is 3-1 in the composition for described Acetamiprid and Bassa:1-
3.Percentage by weight of the described Acetamiprid and Bassa weight summation in composition pesticide is 5%-60%, preferably 10-
50%.Hereinafter illustrated using indoor co-toxicity test and field control effectiveness test.
The indoor biological determination of activity of Acetamiprid and Bassa to Bemisia tabaci adults
Using blade infusion process:Fresh pumpkin blade is won, the disk of diameter about 3cm is cut into cutting ring, be positioned ready for
Liquid in soak and take out after 5s and dry at room temperature, be laid on and be previously charged into the 3cm culture dishes of 1% agar (3cm thickness), often
Ware puts 1.Experiment set 5 chemicals treatments of concentration (i.e. concentration be respectively 5,10,20,40,80mg/L), each 3 weight for the treatment of
It is multiple;Another clear water soaks blade and is laid in culture dish as control after drying.Using pest sucking device size is drawn from culture cage
Consistent Bemisia tabaci adults (Bemisia tabaci belongs to sucking pest) freeze 40-60s in refrigerator, by female adult after removal male worm
It is positioned in culture dish, female adult 50 is placed per ware, covers culture dish lid.Culture dish is placed in 25 ± 2 DEG C of illumination of 70%RH
Cultivated in incubator, 12/12 Dark-light cycle is set.After 72h, check that Bemisia tabaci adults death condition (is gently touched with fine, soft fur pen
Dynamic Bemisia tabaci adults, the motionless person of body is death).Then the death rate is calculated, such as control group death rate is higher than 20%, then experiment is made
It is useless to reform.Death rate Abbott formula corrections, further according to log concentration --- death rate probit value analyzes (Bliss) method, asks
Go out the value of virulence regression equation and lethal concentration of 50 LC50.The co-toxicity coefficient (CTC values) of mixture is calculated according to the abundant methods of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
The co-toxicity coefficient of built agent:CTC >=120 are judged as synergistic effect;CTC≤80 are judged as antagonism;80<CTC<
120 are judged as summation action.
Table 1 is the Toxicity Determination data of reagent agent Acetamiprid and Bassa single dose and compounding to Bemisia tabaci.
Table 1
Table 2 is the Toxicity Determination result of reagent agent Acetamiprid and Bassa single dose and compounding to Bemisia tabaci.
Table 2
Acetamiprid and fenobucarb composite are can be seen that from table 1,2, in 3-1:In the ratio range of 1-3, co-toxicity coefficient
(CTC) 120 are all higher than, synergistic function is shown to Bemisia tabaci.Wherein Acetamiprid and Bassa ratio are 1:When 2, CTC values
Maximum is synergistic effect the most obvious.It can be seen that Acetamiprid and fenobucarb composite have reasonability and feasibility.
Pesticidal combination of the invention can be prepared into the various formulations for being suitable for agricultural production, be below specific embodiment
Percentage in formula is mass ratio.
Embodiment 1:
20% Acetamiprid Bassa missible oil
Acetamiprid 5%, Bassa 15%, neopelex 8%, glycerine fatty acid ester APEO 6%, two
Methyl sulfoxide 10%, dimethylbenzene complements to 100%.Dimethylbenzene and dimethyl sulfoxide (DMSO) are mixed, then Acetamiprid and Bassa is complete
CL is eventually adding remaining emulsifying agent and dispersant and uniform stirring, you can preparation cost embodiment in mixed liquor
20% Acetamiprid Bassa missible oil.
Embodiment 2:
30% Acetamiprid Bassa missible oil
Acetamiprid 10%, Bassa 20%, neopelex 8%, glycerine fatty acid ester APEO
12%th, dimethyl sulfoxide (DMSO) 15%, dimethylbenzene complements to 100%.Dimethylbenzene and dimethyl sulfoxide (DMSO) are mixed, then by Acetamiprid and
Bassa is dissolved completely in mixed liquor, is eventually adding remaining emulsifying agent and dispersant and uniform stirring, you can preparation cost
30% Acetamiprid Bassa missible oil of embodiment.
Embodiment 3:
20% Acetamiprid Bassa microemulsion
Acetamiprid 10%, Bassa 10%, NPE 10%, Sodium Octylphosphate 8%, dodecyl
Sodium sulfonate 7%, DMF10%, dimethylbenzene 10%, dimethyl sulfoxide (DMSO) 5%, propane diols 1.5%, tributyl phosphate 1%,
PEG4003%, deionization supplies 100%.Active ingredient is completely dissolved with solvent, emulsifying agent, defoamer, stabilization is subsequently adding
Agent is well mixed, and remaining deionized water is added during being finally stirred continuously, you can 20% Acetamiprid Bassa is obtained micro-
Emulsion.
Embodiment 4:
30% Acetamiprid Bassa microemulsion
Acetamiprid 10%, Bassa 20%, NPE 10%, Sodium Octylphosphate 10%, dodecane
Base sodium sulfonate 8%, DMF5%, dimethylbenzene 10%, dimethyl sulfoxide (DMSO) 10%, propane diols 1.5%, tributyl phosphate 1%,
PEG4003%, deionized water supplies 100%.Active ingredient is completely dissolved with solvent, emulsifying agent, defoamer, steady is subsequently adding
Determine agent to be well mixed, remaining deionized water is added during being finally stirred continuously, you can 30% Acetamiprid Bassa is obtained
Microemulsion
Embodiment 5
20% Acetamiprid Bassa suspending agent
Acetamiprid 15%, Bassa 5%, auxiliary agent 6%, ethylene glycol 4%, xanthans 0.5%, organosilicon 0.5%, remaining be
Water supplies 100%.Above-mentioned Acetamiprid, Bassa, auxiliary agent, ethylene glycol and water are well mixed through high speed shear, then are being sanded
1.0-1.5h is sanded in machine, organosilicon and xanthans is added during stirring at low speed, you can be prepared into 20% Acetamiprid secondary
Fourth prestige suspending agent.
Embodiment 6
30% Acetamiprid Bassa suspending agent
Acetamiprid 10%, Bassa 20%, auxiliary agent 8%, ethylene glycol 4%, xanthans 0.5%, organosilicon 0.5%, remaining
For water supplies 100%.Above-mentioned Acetamiprid, Bassa, auxiliary agent, ethylene glycol and water are well mixed through high speed shear, then in sand
1.0-1.5h is sanded in grinding machine, organosilicon and xanthans is added during stirring at low speed, you can be prepared into 30% Acetamiprid
Bassa suspending agent.
Field test prevents and treats planthopper
Test in Nanchang Rice Production base, planthopper harm is serious.Experiment sets 5 treatment altogether, and (treatment region rice flies
Lice harm is substantially uniform, and ecological environment is identical), carried out using spray pattern, after chemicals treatment, take random sampling (3 plants)
Method, investigates 4 times for 7 days 1 day before dispenser, after dispenser, 3 days after dispenser, after dispenser altogether.
Table 3 is the investigation result of each treatment agent field planthopper:
Table 3
Table 4 is the result of the test of each treatment agent field control planthopper:
Table 4
Note:Embodiment 2,6 corresponds to 30% Acetamiprid Bassa missible oil and 30% Acetamiprid Bassa suspending agent respectively.
From table 3,4 as can be seen that the preparation after Acetamiprid and fenobucarb composite is used to prevent and treat planthopper, its effect is substantially excellent
In single dose.To experimental group data analysis, 3 days prevention effects are best after medicine.7 days preventive effect effects are decreased obviously after medicine.Embodiment 2
Prevention effect is substantially better than the prevention effect of embodiment 6, because the active ingredient in embodiment 6 is deposited with little particulate state
, and the active ingredient of embodiment 2 exists for molecular state.Analyzed in terms of environmental consciousness, the carrier in embodiment 6 is water, more
For safe and environment-friendly.Without poisoning phenomenon is produced in experimentation, the compounding nematicidal composition has synergistic function, can
Agriculturally to promote the use of.
The present invention provide a kind of Pesticidal combination containing Acetamiprid and Bassa and its application, can be applicable to paddy rice,
In aphid, plant hopper, the thrips preventing and treating of the diversified economy crop such as vegetables, corn, oranges and tangerines.With relatively good effect, and can be with
Effectively delay the generation of the resistance of insect.Compared with unitary agent, control effect is good, and the lasting period is long, expands desinsection, and spectrum increases
Effect effect is obvious.It is good to crop safety.
Embodiment described above only expresses several embodiments of the invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for a person skilled in the art,
Without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection model of the invention
Enclose.Therefore the protection domain of patent of the present invention should be defined by appended claims.
Claims (8)
1. a kind of Pesticidal combination containing Acetamiprid and Bassa, it is characterised in that:Including active ingredient Acetamiprid and effectively
Composition Bassa;
Described Acetamiprid and the weight ratio of Bassa are 3-1:1-3.
2. the Pesticidal combination containing Acetamiprid and Bassa according to claim 1, it is characterised in that described pyridine worm
The weight summation of amidine and Bassa percentage by weight in the composition is 5%-60%.
3. the Pesticidal combination containing Acetamiprid and Bassa according to claim 2, it is characterised in that described pyridine worm
The weight summation of amidine and Bassa percentage by weight in the composition is 10%-50%.
4. according to the Pesticidal combination containing Acetamiprid and Bassa described in claim 1, it is characterised in that also including aiding in into
Point, described auxiliary element includes solvent, cosolvent, dispersant, emulsifying agent, wetting agent, disintegrant, thickener, stabilizer, disappears
One or more in infusion, preservative, antifreeze and carrier.
5. according to the Pesticidal combination containing Acetamiprid and Bassa described in claim 1, it is characterised in that the Insecticidal combinations
Thing is applied to agricultural chemicals pharmaceutical field.
6. according to the Pesticidal combination containing Acetamiprid and Bassa described in claim 5, it is characterised in that the Insecticidal combinations
Thing can be made into emulsifiable concentrate, granule, wettable powder, water dispersible granules, microemulsion, suspending agent or aqueous emulsion agent.
7. the Pesticidal combination containing Acetamiprid and Bassa according to claim 1-6 any one, it is characterised in that
The composition is applied to prevent and treat insect pest of the plant.
8. the Pesticidal combination containing Acetamiprid and Bassa according to claim 1-6 any one, it is characterised in that
The composition is applied to prevent and treat aphid, plant hopper, leafhopper, the thrips of plant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710083985.2A CN106857627A (en) | 2017-02-16 | 2017-02-16 | A kind of Pesticidal combination containing Acetamiprid and Bassa and its application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710083985.2A CN106857627A (en) | 2017-02-16 | 2017-02-16 | A kind of Pesticidal combination containing Acetamiprid and Bassa and its application |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106857627A true CN106857627A (en) | 2017-06-20 |
Family
ID=59167087
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710083985.2A Pending CN106857627A (en) | 2017-02-16 | 2017-02-16 | A kind of Pesticidal combination containing Acetamiprid and Bassa and its application |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106857627A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04368303A (en) * | 1991-06-13 | 1992-12-21 | Nippon Soda Co Ltd | New insecticidal and fungicidal composition for agriculture and horticulture |
JP2000080005A (en) * | 1998-06-22 | 2000-03-21 | Sumitomo Chem Co Ltd | Timber insect pest-controlling composition |
-
2017
- 2017-02-16 CN CN201710083985.2A patent/CN106857627A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04368303A (en) * | 1991-06-13 | 1992-12-21 | Nippon Soda Co Ltd | New insecticidal and fungicidal composition for agriculture and horticulture |
JP2000080005A (en) * | 1998-06-22 | 2000-03-21 | Sumitomo Chem Co Ltd | Timber insect pest-controlling composition |
Non-Patent Citations (1)
Title |
---|
李树香 等: "22%啶虫脒·仲丁威乳油防治稻飞虱田间药效试验", 《热带农业科学》 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100563447C (en) | A kind of aqueous pesticide and preparation method thereof | |
CN113875758A (en) | Compound composition containing trifloxystrobin and acaricide and preparation method and application thereof | |
CN101836644A (en) | Pesticide preparation for controlling rice pests of planthoppers and the like | |
CN102640762A (en) | Hot fogging concentrate containing acetamiprid | |
CN107969443A (en) | A kind of preparation method for preventing Citrus Huanglongbing pathogen medicament | |
CN103783030B (en) | The method of the green ground beetle of a kind of predatory natural enemy insect and green muscardine fungus combination control insect | |
CN101984828B (en) | Compound pesticide | |
CN106719777A (en) | Insecticides containing double third ring worm esters and guadipyr | |
CN103688961A (en) | A pesticide composition containing fluoropyridine furanone | |
CN102232385A (en) | Insecticidal composition containing clothianidin and abamectin | |
CN103947647A (en) | Insecticidal composition | |
CN103651552A (en) | Ultra-low-volume liquor containing chlorfenapyr | |
CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
CN108812707A (en) | One kind killing thrips plant essential oil composition, preparation and its application | |
CN101796960B (en) | Clothianidin-containing disinfestations composition | |
CN103875714A (en) | Bacillus thuringiensis.spinosyns.trisiloxane polyoxyethylene ether composition and use of bacillus thuringiensis.spinosyns.trisiloxane polyoxyethylene ether composition for preventing and controlling rice boring insects | |
CN104522006B (en) | A kind of preventing and treating Lepidoptera and homoptera pest compositions | |
CN106857627A (en) | A kind of Pesticidal combination containing Acetamiprid and Bassa and its application | |
CN106490014A (en) | A kind of plant compound pesticide containing ricidine. and preparation method thereof | |
CN110024803A (en) | A kind of Pesticidal combination and its preparation of spirotetramat | |
CN105076169A (en) | Bactericidal composition containing albendazole and fludioxonil and application | |
CN105941423B (en) | A kind of Pesticidal combination containing capillary and cyromazine | |
CN110250186A (en) | Synergetic pesticide composition containing pyridine quinazoline | |
CN105532736B (en) | A kind of composition pesticide and its application | |
CN103734167B (en) | A kind of pesticidal preparations preventing and treating Bemisia tabaci containing fluorine pyridine worm amine nitrile |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170620 |
|
RJ01 | Rejection of invention patent application after publication |