CN106854336A - A kind of toy resin of good flame resistance - Google Patents
A kind of toy resin of good flame resistance Download PDFInfo
- Publication number
- CN106854336A CN106854336A CN201611197407.3A CN201611197407A CN106854336A CN 106854336 A CN106854336 A CN 106854336A CN 201611197407 A CN201611197407 A CN 201611197407A CN 106854336 A CN106854336 A CN 106854336A
- Authority
- CN
- China
- Prior art keywords
- corncob
- toy
- biotic material
- load anti
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Toys (AREA)
Abstract
The invention discloses a kind of toy resin of good flame resistance, it is obtained by the raw material of following weight parts：ABS50 60, corncob loads anti-biotic material 24,1.4 cyclohexanedimethanols 13, nano silicon 13, bentonite 13, silane coupler KH540 13, soybean oil 12, cashew nut shell oil 0.1 0.3, activated carbon 0.3 0.5, titanium dioxide 13, hypo-aluminum orthophosphate 0.3 0.5, sldium lauryl sulfate 13, absolute ethyl alcohol 35, epoxidized linseed oil 0.1 0.2, hydrotalcite powder 13.
Description
Technical field
The present invention relates to toy material technical field, more particularly to a kind of good flame resistance toy resin.
Background technology
Toy is that especially children play the product of happy game for people.In ancient Egypt's historical relic away from modern about more than 5000 years
The doll for having the materials such as clay, timber, beast bone and ivory to be made, there is small-sized kitchenware and life appliance in children grave.Away from the present about
Find there is the pull toy for dividing into circle wheel in the Persian historical relic of 3000.Sound-emitting top and animal that the useful cotton rope of ancient Greek is started
The toy of image.Be unearthed the movable ivory carving portrait of four limbs in ancient Roman's mausoleum.18 th Century German Nuremburges turn into European toy
The production center.Doll uses stamping process, vivo devices mechanical part, the action such as can perform crying, walk.Also been produced music
Toy and winding-up toy etc..19th century, scientific and technical New TownMovement was applied to toy designs and production, the development for promoting toy to produce,
The optical toys such as appearance activity picture, raree show, magic lantern.American scientist T.A. Edison in 1878 is made of gramophone and can said
Words, the doll sung.The nineties in 19th century, the U.S. produces electronic small fan and the electronic mini train of rail in succession.Chinese toy
Also there is long history.Find there is small-sized pottery pig away from modern about 5500 Shandong Ningyang Dawenkou ruins.Away from about 3800 the presents
Also there are ceramic toy and jingle bell in Qijia culture remains.Kite and ball game also have the history of more than 2000.Diabolo, wind
The folk toys as Chinese tradition such as car, rolling ring, seven-piece puzzle, Chinese puzzle ring, after 20th century, toy manufacturing industry turns into important
Industry.The German Toy production thirties and outlet occupy first place in the world.The forties, toy production in the U.S.'s was developed rapidly, is produced, is consumed
With the hat that import leaps to the world.The fifties, Japan's toy industry emerged, and export amount catches up with Germany.Chinese toy industry at the end of the fifties
Formed, with Beijing, Shanghai as major production areas.Toy kind is up to kind more than 7000.The sixties Hong Kong Toy industry rise, the eighties with
Taiwan toy industry has very big development afterwards.
Current China is toy big producer, and the toy of global 70-80% is by domestic product.With China market
Constantly improve and specification, add inclination of the country in policy to toy, animation, game etc. " creative industry " and help energetically
Hold, domestic toy industry will be into a unprecedented golden period, trend pickup, the lifting of industry benefit.
Children are the main consumer groups of toy, and underproof toy material can endanger the healthy and life peace of children
Entirely.The main component of plastics is synthetic resin.Resin accounts for the 40-100% of plastics gross weight.The key property of plastics is mainly determined
Also played an important role due to the person's character of resin, but additive.However, existing plastic toys performance is not good, it is impossible to meet day
The market demand that benefit increases.
The B of patent CN 103965576, a kind of antibiotic toy plastics, it is compounded using ABS and PVC, and a kind of antibacterial modeling is obtained
Expect that, for toy, PVC material long-term use is dangerous, have potential hazard to the health of children, and the antiseptic for using is pure
Chemical antiseptic, inadequate environmental protection, it is therefore desirable to a kind of toy resin of more environmental protection safety.The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of toy resin of good flame resistance.
The present invention is achieved by the following technical solutions：
A kind of toy resin of good flame resistance, it is obtained by the raw material of following weight parts：ABS50-60, corncob load are anti-
Bacterium material 2-4,1.4- cyclohexanedimethanol 1-3, nano silicon 1-3, bentonite 1-3, silane coupler KH540 1-3,
Soybean oil 1-2, cashew nut shell oil 0.1-0.3, activated carbon 0.3-0.5, titanium dioxide 1-3, hypo-aluminum orthophosphate 0.3-0.5, laruyl alcohol sulphur
Sour sodium 1-3, absolute ethyl alcohol 3-5, epoxidized linseed oil 0.1-0.2, hydrotalcite powder 1-3；
Described corncob load anti-biotic material is obtained by the raw material of following weight parts：Linseed oil 0.1-0.2, APG
0.1-0.3, lecithin 0.1-0.2, citric acid 0.01-0.04, shitosan 1-2, polyglycol ether 0.3-0.4, irgasfos 168
0.1-0.2, corncob 2-4, silver nitrate 0.2-0.5.
A kind of toy resin of described good flame resistance, preparation method is comprised the following steps：
（1）Prepare corncob load anti-biotic material；
The preparation method of described corncob load anti-biotic material is：
Added water in corncob equivalent to the water of 0.8-1.5 times of above-mentioned raw materials, after mixing, anaerobic fermentation is cleaned after 1-2 days, is air-dried,
Dry, then steam blasting is carried out to it, explosion water vapour pressure is 0.05-0.3Mpa, and blasting time is 1-3s, produce thing through de-
Dried after water process, obtain xeraphium standby；Citric acid adds suitable quantity of water, after being configured to the citric acid solution that concentration is 2-5%, adds
Xeraphium, after stirring 0.5-1h at 40-60 DEG C, adds remaining needed for silver nitrate and corncob load anti-biotic material preparation
Raw material, after stirring, filtering, with distillation water washing filter residue, to filtrate in neutrality, it is the carbonic acid of 1-2% that filter residue is added into concentration
In hydrogen sodium solution, 1-2h is stirred at 30-50 DEG C, filtered, with distillation water washing filter residue, to filtrate in neutrality, filter residue is in 60-80
After being dried at DEG C, corncob load anti-biotic material is obtained final product standby；
（2）After absolute ethyl alcohol, silane coupler KH-540 stir, nano silicon, bentonite, hydrotalcite powder are added,
After ultrasonic vibration 1-2h, drying obtains modified powder standby；
（3）Soybean oil, cashew nut shell oil, activated carbon, titanium dioxide are put into reactor, with rotating speed, 400-500 revs/min is carried out
Stirring mixing 3-6 minutes, adds modified powder, corncob load anti-biotic material and remaining raw material, and 700-900 revs/min is mixed
Close uniform rear feeding screw extruder melting mixing；
(4) screw speed is 300-400rpm, after extruding pelletization, is obtained final product.
It is an advantage of the invention that：（1）Rationally, materials safety has no toxic side effect inventive formulation, with the addition of corncob, becomes useless
It is treasured, environmental protection and energy saving green non-pollution；Hydrotalcite powder is with the addition of, it is modified with fire-retardant left and right well；Hydrotalcite is being heated
When, its constitution water laminated sheet hydroxyl and interlayer ion are deviate from the form of water and CO2, play reduction burning gases concentration, intercept
The fire retardation of O2.
（2）Present invention adds corncob load antibacterial powder, bio-carrier can load antiseptic, slow release, antibacterial
Effect is strong, and lasting effect is good, tool broad spectrum activity and good advantage compatible with fabricated product, all has to various bacteriums, mould fine
Killing inhibitory action, to environment without any pollution.Make use of corncob as bio-carrier, turn waste into wealth.The present invention is used
Steam explosion technology, the acute expansion of gas in hole, produces " explosion " effect, is fiber fines by raw material tear, by increasing capacitance it is possible to increase raw
The load capacity of thing carrier.
（3）Attapulgite is modified using coupling agent, the strong of raw material is increased while the compatibility for increasing raw material
Degree and impact resistance, can effectively improve the service life using the toy of the resin manufacture..
Specific embodiment
A kind of toy resin of good flame resistance, it is obtained by the raw material of following weight parts：ABS50, corncob load
Anti-biotic material 2,1.4 cyclohexanedimethanols 1, nano silicon 1, bentonite 1, silane coupler KH540 1, soybean oil 1, waist
Shell oil 0.1, activated carbon 0.3, titanium dioxide 1, hypo-aluminum orthophosphate 0.3, sldium lauryl sulfate 1, absolute ethyl alcohol 3, epoxidized linseed oil
0.1st, hydrotalcite powder 1；
Described corncob load anti-biotic material is obtained by the raw material of following weight parts：Linseed oil 0.1, APG 0.1, ovum
Phosphatidase 0 .1, citric acid 0.01, shitosan 1, polyglycol ether 0.3, irgasfos 168 0.1, corncob 2, silver nitrate 0.2.
A kind of toy resin of described good flame resistance, preparation method is comprised the following steps：
（1）Prepare corncob load anti-biotic material；
The preparation method of described corncob load anti-biotic material is：
Added water in corncob equivalent to the water of 0.8 times of above-mentioned raw materials, after mixing, anaerobic fermentation is cleaned after 1 day, is air-dried, and is dried,
Steam blasting is carried out to it again, explosion water vapour pressure is 0.05Mpa, and blasting time is 1s, produce thing and done after dewater treatment
It is dry, obtain xeraphium standby；Citric acid adds suitable quantity of water, after being configured to the citric acid solution that concentration is 2%, xeraphium is added, at 40 DEG C
After lower stirring 0.5h, add silver nitrate and corncob load anti-biotic material prepares required remaining raw material, after stirring, mistake
Filter, with distillation water washing filter residue, to filtrate in neutrality, in being 1% sodium bicarbonate solution by filter residue addition concentration, at 30 DEG C
Stirring 1h, filtering, with distillation water washing filter residue, to filtrate in neutrality, filter residue obtains final product corncob load anti-after being dried at 60 DEG C
Bacterium materials for later use；
（2）After absolute ethyl alcohol, silane coupler KH stir, nano silicon, bentonite, hydrotalcite powder, ultrasound are added
After concussion 1h, drying obtains modified powder standby；
（3）Soybean oil, cashew nut shell oil, activated carbon, titanium dioxide are put into reactor, with rotating speed, 400 revs/min are stirred
Mixing 3 minutes, adds modified powder, corncob load anti-biotic material and remaining raw material, 700 revs/min it is well mixed after give
Enter screw extruder melting mixing；
(4) screw speed is 300rpm, after extruding pelletization, is obtained final product.
(1) antibacterial test：
Using conventional method by obtained resin forming, it is prepared into 50mm × 50mm × 4mm's respectively
Sample, carries out antibacterial test, antibacterial test standard：
QB/T2591-2003 antibiotic plastic Anti-microbial Performance Tests methods and antibacterial effect.
Escherichia coli sterilizing rate：99.8%；Staphylococcus aureus sterilizing rate:98.7%；
(2) toxotest：The antibiotic toy plastics of implementation, show through acute toxicity test, to the LD50 ＞ of small white mouse
10000mg/kg, true border innocuous substance.
Claims (2)
1. the toy resin of a kind of good flame resistance, it is characterised in that：It is obtained by the raw material of following weight parts：ABS50-
60th, corncob load anti-biotic material 2-4,1.4- cyclohexanedimethanol 1-3, nano silicon 1-3, bentonite 1-3, silane idol
Connection agent KH540 1-3, soybean oil 1-2, cashew nut shell oil 0.1-0.3, activated carbon 0.3-0.5, titanium dioxide 1-3, hypo-aluminum orthophosphate
0.3-0.5, sldium lauryl sulfate 1-3, absolute ethyl alcohol 3-5, epoxidized linseed oil 0.1-0.2, hydrotalcite powder 1-3；
Described corncob load anti-biotic material is obtained by the raw material of following weight parts：Linseed oil 0.1-0.2, APG
0.1-0.3, lecithin 0.1-0.2, citric acid 0.01-0.04, shitosan 1-2, polyglycol ether 0.3-0.4, irgasfos 168
0.1-0.2, corncob 2-4, silver nitrate 0.2-0.5.
2. the toy resin of a kind of good flame resistance according to claim 1, it is characterised in that：Preparation method includes following
Step：
（1）Prepare corncob load anti-biotic material；
The preparation method of described corncob load anti-biotic material is：
Added water in corncob equivalent to the water of 0.8-1.5 times of above-mentioned raw materials, after mixing, anaerobic fermentation is cleaned after 1-2 days, is air-dried,
Dry, then steam blasting is carried out to it, explosion water vapour pressure is 0.05-0.3Mpa, and blasting time is 1-3s, produce thing through de-
Dried after water process, obtain xeraphium standby；Citric acid adds suitable quantity of water, after being configured to the citric acid solution that concentration is 2-5%, adds
Xeraphium, after stirring 0.5-1h at 40-60 DEG C, adds remaining needed for silver nitrate and corncob load anti-biotic material preparation
Raw material, after stirring, filtering, with distillation water washing filter residue, to filtrate in neutrality, it is the carbonic acid of 1-2% that filter residue is added into concentration
In hydrogen sodium solution, 1-2h is stirred at 30-50 DEG C, filtered, with distillation water washing filter residue, to filtrate in neutrality, filter residue is in 60-80
After being dried at DEG C, corncob load anti-biotic material is obtained final product standby；
（2）After absolute ethyl alcohol, silane coupler KH-540 stir, nano silicon, bentonite, hydrotalcite powder are added,
After ultrasonic vibration 1-2h, drying obtains modified powder standby；
（3）Soybean oil, cashew nut shell oil, activated carbon, titanium dioxide are put into reactor, with rotating speed, 400-500 revs/min is carried out
Stirring mixing 3-6 minutes, adds modified powder, corncob load anti-biotic material and remaining raw material, and 700-900 revs/min is mixed
Close uniform rear feeding screw extruder melting mixing；
(4) screw speed is 300-400rpm, after extruding pelletization, is obtained final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611197407.3A CN106854336A (en) | 2016-12-22 | 2016-12-22 | A kind of toy resin of good flame resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611197407.3A CN106854336A (en) | 2016-12-22 | 2016-12-22 | A kind of toy resin of good flame resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106854336A true CN106854336A (en) | 2017-06-16 |
Family
ID=59126943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611197407.3A Pending CN106854336A (en) | 2016-12-22 | 2016-12-22 | A kind of toy resin of good flame resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106854336A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112011188A (en) * | 2020-08-04 | 2020-12-01 | 华南农业大学 | Inorganic modified toughened light-cured plant oil-based polymer and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530629A (en) * | 2014-11-13 | 2015-04-22 | 苏州威尔德工贸有限公司 | An antibacterial ABS composite material used for plastic toys and a preparing method thereof |
-
2016
- 2016-12-22 CN CN201611197407.3A patent/CN106854336A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530629A (en) * | 2014-11-13 | 2015-04-22 | 苏州威尔德工贸有限公司 | An antibacterial ABS composite material used for plastic toys and a preparing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112011188A (en) * | 2020-08-04 | 2020-12-01 | 华南农业大学 | Inorganic modified toughened light-cured plant oil-based polymer and preparation method and application thereof |
| CN112011188B (en) * | 2020-08-04 | 2021-07-09 | 华南农业大学 | Inorganic modified toughened light-cured plant oil-based polymer and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105802425B (en) | A kind of environment-friendly antibacterial interior wall coating containing oyster shell whiting | |
| CN103936402A (en) | Ceramic tile capable of releasing negative oxygen ions and preparation method thereof | |
| CN103469987A (en) | Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper | |
| CN100558950C (en) | Biological activity marine alga cellulose viscose and manufacture method thereof | |
| CN105433720A (en) | Environment-friendly tea dust incense stick and production technology thereof | |
| CN106854336A (en) | A kind of toy resin of good flame resistance | |
| CN104294614A (en) | Production method of novel negative ion rosemary cloth | |
| CN109852167A (en) | It is a kind of that liquid occurring applied to the anion sprayed on object or material | |
| CN109295799A (en) | A kind of cork paper containing additive | |
| CN106674867A (en) | Loofah sponge fiber-containing environment-friendly resin for toys | |
| CN105713329B (en) | A kind of preparation method of cinnamon essential oil spacetabs type functional ornamentation material | |
| CN106633600A (en) | Toy resin capable of being processed easily | |
| CN106854337A (en) | A kind of heat-resisting toy resin | |
| CN106700395A (en) | High-strength plastic resin for toys | |
| CN107311508A (en) | A kind of structure material that can be mould proof and preparation method | |
| CN106633602A (en) | High-toughness resin applied to toys | |
| CN106633599A (en) | Easy-to-scrub resin containing nanometer powder for toy | |
| CN108300055A (en) | Coating formula application based on the efficient anion material of Low emissivity and its preparation process | |
| CN104294713A (en) | Method for making novel environmentally-friendly wallpaper | |
| CN106633601A (en) | Difficult-to-crack resin containing soyabean protein for toy | |
| CN106674868A (en) | Konjak-containing safe resin for toys | |
| CN106589780A (en) | Corrosion resistant resin used for toys | |
| CN104014199B (en) | For removing the filter medium of phenol in drinking water, filter core and preparation method | |
| CN114015262A (en) | Negative oxygen ion coating containing cedar wood | |
| CN105754274B (en) | A kind of preparation method of Lavender spacetabs type functional ornamentation material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170616 |
|
| WD01 | Invention patent application deemed withdrawn after publication |