CN106854038A - A kind of mobile phone wear and shock-resistant cover-plate glass - Google Patents
A kind of mobile phone wear and shock-resistant cover-plate glass Download PDFInfo
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- CN106854038A CN106854038A CN201611068623.8A CN201611068623A CN106854038A CN 106854038 A CN106854038 A CN 106854038A CN 201611068623 A CN201611068623 A CN 201611068623A CN 106854038 A CN106854038 A CN 106854038A
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- parts
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- mobile phone
- resistant cover
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of mobile phone wear and shock-resistant cover-plate glass, belong to glass manufacturing area, be specifically made up of following material：Quartz sand, calcium carbonate, kaolin, antimony oxide, aluminium hydroxide, zirconium sulfate, cerium oxide, barium chloride, titanium carbide, additive.Shortcoming of the present invention for existing glass board material is optimized improvement, reasonably combined each raw material of substance composition, obtained cover-plate glass has good heatproof, corrosion resistant performance, there is good hardness, wearability and impact property again, reduce hand-set lid and occur the incidence that surface such as scratched, and wore and tore, rupturing at the phenomenon in routine use, outward appearance is penetrating, and glossiness is good, stay in grade, has good production and application to be worth.
Description
Technical field
The invention belongs to glass manufacturing area, and in particular to a kind of mobile phone wear and shock-resistant cover-plate glass.
Background technology
With the development of society, smart mobile phone is constantly popularized.The function and quality of mobile phone constantly strengthen.Initially
Smart mobile phone cover plate more be made of plastics, although low cost, but feel, texture etc. are weaker, gradually by ceramics, glass etc.
Material replaces.Wherein glass obtains the accreditation of most consumers with performances such as the feel of high-quality, outward appearances.But glass is there are still hard
The poor problem of low, impact resistance is spent, duration can surface scratches caused by the general idea for using, the phenomenon of even rupture of wearing and tearing occurs,
Reduce the experience sense of consumer.
The content of the invention
The present invention is intended to provide a kind of mobile phone wear and shock-resistant cover-plate glass.
The present invention is achieved through the following technical solutions：
A kind of mobile phone wear and shock-resistant cover-plate glass, is made up of the material of following weight portion：
300 ~ 320 parts of quartz sands, 55 ~ 60 parts of calcium carbonate, 32 ~ 36 parts of kaolin, 2 ~ 3 parts of antimony oxides, 1.5 ~ 2.5 parts of hydroxides
Aluminium, 0.2 ~ 0.3 part of zirconium sulfate, 0.1 ~ 0.3 part of cerium oxide, 0.4 ~ 0.6 part of barium chloride, 0.02 ~ 0.04 part of titanium carbide, 2 ~ 3 parts add
Plus agent；The additive is made up of the material of following weight portion：16 ~ 18 parts of shepardites, 10 ~ 12 parts of illites, 5 ~ 8 parts of leaf waxes
Stone, 2 ~ 3 parts of strontium carbonates, 1 ~ 3 part of ammonium fluozirconate, 1 ~ 2 part of sodium acetate, 2 ~ 3 parts of magnesium chloride hexahydrates, 0.3 ~ 0.5 part of diethanol amine,
0.2 ~ 0.4 portion of triphenyl phosphate.
Preferably, it is made up of the material of following weight portion：
310 parts of quartz sand, 58 parts of calcium carbonate, 35 parts of kaolin, 2.5 parts of antimony oxides, 2 parts of aluminium hydroxide, 0.25 part of zirconium sulfate,
0.2 part of cerium oxide, 0.5 part of barium chloride, 0.03 part of titanium carbide, 2.5 parts of additives；The additive by following weight portion material
It is made：17 parts of shepardites, 11 parts of illites, 6 parts of pyrophyllites, 2.5 parts of strontium carbonates, 2 parts of ammonium fluozirconates, 1.5 parts of sodium acetates, 2.5
Part magnesium chloride hexahydrate, 0.4 portion of diethanol amine, 0.3 portion of triphenyl phosphate.Shepardite, illite in additive and pyrophyllite into
Divide hardness, elastic modelling quantity and the impact resistance that can well improve glass, the addition of strontium carbonate, ammonium fluozirconate and magnesium chloride hexahydrate
Overall mechanical performance can further be optimized.
Further, the preparation method of the additive comprises the following steps：
（1）By shepardite, illite and pyrophyllite be placed in immersion treatment 15 in the sodium hydroxide solution that mass fraction is 3% ~
18min, is rinsed well with deionized water rear standby after taking-up；
（2）By step（1）Shepardite, illite and pyrophyllite after treatment are placed in temperature to be calcined under conditions of 420 ~ 440 DEG C
After 20 ~ 23min for the treatment of, then temperature is risen to 630 ~ 650 DEG C, take out standby after 6 ~ 8min of calcination processing；
（3）By step（2）Shepardite, illite and the same strontium carbonate of pyrophyllite after treatment, ammonium fluozirconate, sodium acetate, six water chlorine
Change magnesium, diethanol amine, triphenyl phosphate mixing, 200 mesh are crossed after continuous ball milling.
A kind of mobile phone preparation method of wear and shock-resistant cover-plate glass, comprises the following steps：
（1）By quartz sand, calcium carbonate, kaolin, antimony oxide, aluminium hydroxide, zirconium sulfate, cerium oxide, barium chloride, titanium carbide and add
Plus agent obtains compound standby by mixing after weight portion is weighed is corresponded to after 3 ~ 4h of ball-milling treatment；
（2）By step（1）The compound of gained obtains glass metal after 5 ~ 7h of melt process is incubated under conditions of being placed in 1430 ~ 1480 DEG C
It is standby；
（3）By step（2）It is standby that the glass metal of gained obtains plate glass after being pressed；
（4）To step（3）Obtained plate glass is annealed, is cut, being polished, deburring, inspection, packaging.
The present invention has the advantages that：
Shortcoming of the present invention for existing glass board material is optimized improvements, reasonably combined each raw material of substance composition, prepared
Cover-plate glass there is good heatproof, corrosion resistant performance, and with good hardness, wearability and impact property, reduce
Hand-set lid occurs the incidence that surface such as scratched, and wore and tore, rupturing at the phenomenon in routine use, and outward appearance is penetrating, and glossiness is good,
Stay in grade, has good production and application to be worth.
Specific embodiment
Embodiment 1
A kind of mobile phone wear and shock-resistant cover-plate glass, is made up of the material of following weight portion：
300 parts of quartz sands, 55 parts of calcium carbonate, 32 parts of kaolin, 2 parts of antimony oxides, 1.5 parts of aluminium hydroxides, 0.2 part of zirconium sulfate, 0.1
Part cerium oxide, 0.4 part of barium chloride, 0.02 part of titanium carbide, 2 parts of additives；The additive is made up of the material of following weight portion：
16 parts of shepardites, 10 parts of illites, 5 parts of pyrophyllites, 2 parts of strontium carbonates, 1 part of ammonium fluozirconate, 1 part of sodium acetate, 2 part of six water chlorination
Magnesium, 0.3 portion of diethanol amine, 0.2 portion of triphenyl phosphate.
Further, the preparation method of the additive comprises the following steps：
（1）Shepardite, illite and pyrophyllite are placed in immersion treatment 17min in the sodium hydroxide solution that mass fraction is 3%,
Rinsed well with deionized water after taking-up rear standby；
（2）By step（1）It is calcination processing under conditions of 430 DEG C that shepardite, illite and pyrophyllite after treatment are placed in temperature
After 22min, then temperature is risen to 640 DEG C, take out standby after calcination processing 7min；
（3）By step（2）Shepardite, illite and the same strontium carbonate of pyrophyllite after treatment, ammonium fluozirconate, sodium acetate, six water chlorine
Change magnesium, diethanol amine, triphenyl phosphate mixing, 200 mesh are crossed after continuous ball milling.
A kind of mobile phone preparation method of wear and shock-resistant cover-plate glass, comprises the following steps：
（1）By quartz sand, calcium carbonate, kaolin, antimony oxide, aluminium hydroxide, zirconium sulfate, cerium oxide, barium chloride, titanium carbide and add
Plus agent obtains compound standby by mixing after weight portion is weighed is corresponded to after ball-milling treatment 3.5h；
（2）By step（1）The compound of gained be incubated under conditions of being placed in 1460 DEG C after melt process 6h glass metal is standby；
（3）By step（2）It is standby that the glass metal of gained obtains plate glass after being pressed；
（4）To step（3）Obtained plate glass is annealed, is cut, being polished, deburring, inspection, packaging.
Embodiment 2
A kind of mobile phone wear and shock-resistant cover-plate glass, is made up of the material of following weight portion：
310 parts of quartz sand, 58 parts of calcium carbonate, 35 parts of kaolin, 2.5 parts of antimony oxides, 2 parts of aluminium hydroxide, 0.25 part of zirconium sulfate,
0.2 part of cerium oxide, 0.5 part of barium chloride, 0.03 part of titanium carbide, 2.5 parts of additives；The additive by following weight portion material
It is made：17 parts of shepardites, 11 parts of illites, 6 parts of pyrophyllites, 2.5 parts of strontium carbonates, 2 parts of ammonium fluozirconates, 1.5 parts of sodium acetates, 2.5
Part magnesium chloride hexahydrate, 0.4 portion of diethanol amine, 0.3 portion of triphenyl phosphate.
Embodiment 3
A kind of mobile phone wear and shock-resistant cover-plate glass, is made up of the material of following weight portion：
320 parts of quartz sands, 60 parts of calcium carbonate, 36 parts of kaolin, 3 parts of antimony oxides, 2.5 parts of aluminium hydroxides, 0.3 part of zirconium sulfate, 0.3
Part cerium oxide, 0.6 part of barium chloride, 0.04 part of titanium carbide, 3 parts of additives；The additive is made up of the material of following weight portion：
18 parts of shepardites, 12 parts of illites, 8 parts of pyrophyllites, 3 parts of strontium carbonates, 3 parts of ammonium fluozirconates, 2 parts of sodium acetates, 3 part of six water chlorination
Magnesium, 0.5 portion of diethanol amine, 0.4 portion of triphenyl phosphate.
Comparative example 1
This comparative example 1 compared with Example 1, does not contain additive in its composition, method and step all same in addition.
Control group
Existing commercially available hand-set lid glass.
In order to contrast effect of the present invention, hardness and shock resistance reality are carried out to the corresponding glass board material of above-mentioned five kinds of modes
Test, the experiment of hardness is specifically that glass board material is tested with micro Vickers, the pressure applied during test is p=
0.2kgf/cm2, the time of holding is 15s, measures hardness number；The shock resistance experiment is specifically with the steel that quality is 80g
Ball is straight on test plate with the movement of falling object, a height of 30mm × 25mm of the length and width × 1mm of wherein test plate, measures glass
The height h of steel ball, the shock resistance of glass is evaluated with this when glass model is just crashed to pieces.Specific correction data such as table 1 below
It is shown：
Table 1
| Vickers hardness（Hv） | Height h（cm） | |
| Embodiment 1 | 681 | 71 |
| Embodiment 2 | 690 | 73 |
| Embodiment 3 | 685 | 72 |
| Comparative example 1 | 638 | 66 |
| Control group | 572 | 57 |
There is good hardness and impact property, use value by can be seen that the obtained glass board material of the present invention in upper table 1
It is higher.
Claims (4)
1. a kind of mobile phone wear and shock-resistant cover-plate glass, it is characterised in that be made up of the material of following weight portion：
300 ~ 320 parts of quartz sands, 55 ~ 60 parts of calcium carbonate, 32 ~ 36 parts of kaolin, 2 ~ 3 parts of antimony oxides, 1.5 ~ 2.5 parts of hydroxides
Aluminium, 0.2 ~ 0.3 part of zirconium sulfate, 0.1 ~ 0.3 part of cerium oxide, 0.4 ~ 0.6 part of barium chloride, 0.02 ~ 0.04 part of titanium carbide, 2 ~ 3 parts add
Plus agent；The additive is made up of the material of following weight portion：16 ~ 18 parts of shepardites, 10 ~ 12 parts of illites, 5 ~ 8 parts of leaf waxes
Stone, 2 ~ 3 parts of strontium carbonates, 1 ~ 3 part of ammonium fluozirconate, 1 ~ 2 part of sodium acetate, 2 ~ 3 parts of magnesium chloride hexahydrates, 0.3 ~ 0.5 part of diethanol amine,
0.2 ~ 0.4 portion of triphenyl phosphate.
2. a kind of mobile phone wear and shock-resistant cover-plate glass according to claim 1, it is characterised in that by following weight portion
Material be made：
310 parts of quartz sand, 58 parts of calcium carbonate, 35 parts of kaolin, 2.5 parts of antimony oxides, 2 parts of aluminium hydroxide, 0.25 part of zirconium sulfate,
0.2 part of cerium oxide, 0.5 part of barium chloride, 0.03 part of titanium carbide, 2.5 parts of additives；The additive by following weight portion material
It is made：17 parts of shepardites, 11 parts of illites, 6 parts of pyrophyllites, 2.5 parts of strontium carbonates, 2 parts of ammonium fluozirconates, 1.5 parts of sodium acetates, 2.5
Part magnesium chloride hexahydrate, 0.4 portion of diethanol amine, 0.3 portion of triphenyl phosphate.
3. a kind of mobile phone wear and shock-resistant cover-plate glass according to claim 1 and 2, it is characterised in that the addition
The preparation method of agent comprises the following steps：
（1）By shepardite, illite and pyrophyllite be placed in immersion treatment 15 in the sodium hydroxide solution that mass fraction is 3% ~
18min, is rinsed well with deionized water rear standby after taking-up；
（2）By step（1）Shepardite, illite and pyrophyllite after treatment are placed in temperature to be calcined under conditions of 420 ~ 440 DEG C
After 20 ~ 23min for the treatment of, then temperature is risen to 630 ~ 650 DEG C, take out standby after 6 ~ 8min of calcination processing；
（3）By step（2）Shepardite, illite and the same strontium carbonate of pyrophyllite after treatment, ammonium fluozirconate, sodium acetate, six water chlorine
Change magnesium, diethanol amine, triphenyl phosphate mixing, 200 mesh are crossed after continuous ball milling.
4. a kind of mobile phone as claimed in claim 1 or 2 preparation method of wear and shock-resistant cover-plate glass, it is characterised in that
Comprise the following steps：
（1）By quartz sand, calcium carbonate, kaolin, antimony oxide, aluminium hydroxide, zirconium sulfate, cerium oxide, barium chloride, titanium carbide and add
Plus agent obtains compound standby by mixing after weight portion is weighed is corresponded to after 3 ~ 4h of ball-milling treatment；
（2）By step（1）The compound of gained obtains glass metal after 5 ~ 7h of melt process is incubated under conditions of being placed in 1430 ~ 1480 DEG C
It is standby；
（3）By step（2）It is standby that the glass metal of gained obtains plate glass after being pressed；
（4）To step（3）Obtained plate glass is annealed, is cut, being polished, deburring, inspection, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611068623.8A CN106854038A (en) | 2016-11-29 | 2016-11-29 | A kind of mobile phone wear and shock-resistant cover-plate glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611068623.8A CN106854038A (en) | 2016-11-29 | 2016-11-29 | A kind of mobile phone wear and shock-resistant cover-plate glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106854038A true CN106854038A (en) | 2017-06-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611068623.8A Pending CN106854038A (en) | 2016-11-29 | 2016-11-29 | A kind of mobile phone wear and shock-resistant cover-plate glass |
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| CN (1) | CN106854038A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164136A (en) * | 2017-12-29 | 2018-06-15 | 安徽杜氏高科玻璃有限公司 | A kind of anti-corrosion impact resistance glass |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659518A (en) * | 2009-06-16 | 2010-03-03 | 北京盛康宁科技开发有限公司 | Microcrystalline glass with high transparency and high heat resistance and preparation method thereof |
| CN104402224A (en) * | 2014-10-26 | 2015-03-11 | 青岛智谷创新技术有限公司 | Toughened glass formula |
| CN104402223A (en) * | 2014-10-26 | 2015-03-11 | 青岛智谷创新技术有限公司 | Stable toughened glass |
| CN106045308A (en) * | 2016-05-27 | 2016-10-26 | 明光市富域玻璃有限公司 | Touch screen glass containing zirconium |
| CN106082652A (en) * | 2016-05-27 | 2016-11-09 | 明光市富域玻璃有限公司 | A kind of handset touch panel safety glass |
-
2016
- 2016-11-29 CN CN201611068623.8A patent/CN106854038A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659518A (en) * | 2009-06-16 | 2010-03-03 | 北京盛康宁科技开发有限公司 | Microcrystalline glass with high transparency and high heat resistance and preparation method thereof |
| CN104402224A (en) * | 2014-10-26 | 2015-03-11 | 青岛智谷创新技术有限公司 | Toughened glass formula |
| CN104402223A (en) * | 2014-10-26 | 2015-03-11 | 青岛智谷创新技术有限公司 | Stable toughened glass |
| CN106045308A (en) * | 2016-05-27 | 2016-10-26 | 明光市富域玻璃有限公司 | Touch screen glass containing zirconium |
| CN106082652A (en) * | 2016-05-27 | 2016-11-09 | 明光市富域玻璃有限公司 | A kind of handset touch panel safety glass |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164136A (en) * | 2017-12-29 | 2018-06-15 | 安徽杜氏高科玻璃有限公司 | A kind of anti-corrosion impact resistance glass |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170616 |
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| RJ01 | Rejection of invention patent application after publication |