CN106835716B - For handling wool or the smooth brightening agent containing wool fabric and preparation method thereof - Google Patents
For handling wool or the smooth brightening agent containing wool fabric and preparation method thereof Download PDFInfo
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- CN106835716B CN106835716B CN201710115027.9A CN201710115027A CN106835716B CN 106835716 B CN106835716 B CN 106835716B CN 201710115027 A CN201710115027 A CN 201710115027A CN 106835716 B CN106835716 B CN 106835716B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of smooth brightening agent for handling wool or containing wool fabric, it is characterized in that, the concrete component of the smooth brightening agent is as follows: double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%, 8810 5%-10% of polyoxyethylene ether, polyethers 6%-9%, silane coupling agent KN-550 3%-5%, polyester 2%-5%, D4 octamethylcy-clotetrasiloxane 23%-26%, catalyst 1.5-2%, cold acetic acid 0.5%-1.5%, surplus are deionized water.The preparation method of the smooth brightening agent is that raw material is weighed by formula rate, made using interim stirring, heating reaction of the invention for handling wool or the smooth brightening agent containing wool fabric improves smooth, the soft feel of wool or wool fabric, it is used in wool fabric post-treatment, plays the effect that good increasing is deep, increasing is gorgeous, adds lustre to.
Description
Technical field
The present invention relates to articles for washing technical fields, more particularly to a kind of for handling wool or putting down containing wool fabric
Sliding brightening agent and preparation method thereof.
Background technique
The Wool Textile Industry of China is the third-largest weaving pillar industry after cotton spinning and chemical fibre in textile industry, is
Produce the industry of grade textiles.China's woolen industry is held a safe lead in world's wool industry at present, and scouring of wool ability, wool top add
Work, spinning and weaving, garment production column first place in the world.China is maximum raw wool importer and country of consumption in the world, in state
Border wool occupies the critical role of price leadership in the market, with the continuous appearance of wool fabric new product, textile auxiliary market
It will also rapidly develop, therefore, the demand of textile auxiliary can also be increase accordingly.Currently, dye industry is by national supervisor portion
Door is determined as heavy polluted industry, and textile auxiliary can not be ignored environment and ecological bring influence in production and application process,
So Devoting Major Efforts To Developing meets the environmentally friendly auxiliary agent of ecodevelopment, to auxiliary industry whole competitiveness is improved, the production of textile auxiliary is promoted
Quality and technical level are particularly important, meanwhile, as people increasingly pay close attention to Green Textiles and environmental and ecological protection, ring
Guarantor's type textile auxiliary has become the Main way of current textile auxiliary development.International Textile ecological study and inspection association are
It is distinctly claimed, textile auxiliary also needs to meet other than having necessary use technique applicability, application performance and secured performance
The requirement of environment-friendly quality.
Currently, due to a large amount of uses of domestic dyestuff and a large amount of appearance of new structure fabric, in actual production process
In, the fabric color after dyeing is not bright-coloured enough, and burnt hair obfuscation causes the class of fabric product to reduce, and competitiveness decline contaminates in fact
Color depth is higher, and light fastness is also better, and when dye is light, light fastness is often unqualified.And existing organic silicon in the market
Or though non-silicon class deep-dyeing agent, brightening agent can make moderate progress to shade fabric, it is poor to increase deep brightening effect, increase the general feux rouges of dark light,
Fabrics smooth, soft feel are poor, and product stability shortcoming cannot still reach promising result, and fabric after washing several times after color
Pool is decreased obviously, and loses efficiency.With the increasingly rapid growth of increase and domestic consumption market of textile exports amount, textile industry
Demand to this product is also increasing, while the requirement for meeting environmental protection is also proposed to product.Therefore, the country must increase
Research and development to fabric brightening agent auxiliary agent, develop high-effect, and environmentally friendly, durability is strong, and has to fabric feeling
The corresponding product improved.
Summary of the invention
It is in view of the deficiencies in the prior art or insufficient, the present invention innovatively propose it is a kind of for handle wool or
Smooth brightening agent containing wool fabric and preparation method thereof, the brightening agent improve smooth, the soft hand of wool or wool fabric
Sense, uses in wool fabric post-treatment, plays the effect that good increasing is deep, increasing is gorgeous, adds lustre to.
The technical scheme of the present invention is realized as follows:
A kind of smooth brightening agent for handling wool or containing wool fabric, which is characterized in that the brightening agent by weighing as follows
The component of amount percentage is prepared: double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%；Polyoxyethylene ether 8810
5%-10%；Polyethers 6%-9%；Silane resin acceptor kh-550 3%-5%；Polyester 2%-5%；D4 octamethylcy-clotetrasiloxane 23%-
26%；Catalyst 1.5%-2%；Cold acetic acid 0.5%-1.5%；Deionized water surplus.
Preferably, the specific weight percent of the brightening agent component is as follows: double fatty alkyl ester group hydroxyethyl methyl sulfuric acid
Ammonium methyl 6%；Polyoxyethylene ether 8,810 8.5%；Polyethers 8%；Silane resin acceptor kh-550 4%；Polyester 3%；D4 prestox ring four
Siloxanes 25%；Catalyst 1.8%；Cold acetic acid 1%；Deionized water surplus.
Optimization, the catalyst is sodium hydrate aqueous solution.
A kind of preparation method of the smooth brightening agent for handling wool or containing wool fabric, comprising the following steps:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 45-
50 DEG C, after temperature is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 23%-26% is added to reaction kettle, is opened
Agitating device, agitating device revolving speed is 100-200rpm, mixing time 30-50min, until stir evenly, it, will in whipping process
The temperature of reaction kettle is warming up to 95 DEG C；
(3), after stirring, continue to control temperature of reaction kettle at 95 DEG C, be successively 5%-10%'s by weight percent
Polyoxyethylene ether 8810,6%-9% polyethers be added to reaction kettle, open agitating device, agitating device revolving speed be 150-
200rpm, mixing time 20-30min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 3%-5% by weight percent, is at the uniform velocity added dropwise to reaction in a manner of instillation
In kettle, the whole process used time is maintained at 40min；It is simultaneously the sodium hydroxide of 1.5%-2% by weight percent in a manner of instillation
Aqueous solution is at the uniform velocity added dropwise in reaction kettle, and the time of dropwise addition controls in 15-25min；
(5), the polyester that weight percent is 2%-5% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens stirring dress
It sets, agitating device revolving speed is 200-300rpm, mixing time 20-30min；
(6), after temperature of reaction kettle being cooled to 45-55 DEG C, the double fatty alkyl ester group hydroxyls for being 5%-8% by weight percent
Ethyl-methyl sulfate methyl ammonium is added to reaction kettle, opens agitating device, agitating device revolving speed is 200-350rpm, when stirring
Between be 20-25min, until after mixing evenly, filtering and discharging；
It (7), is 7- with the pH value that mixing liquid is made in the glacial acetic acid debugging step (6) that weight percent is 0.5%-1.5%
9, obtain the muddy lotion with yellow light, as finished product.
Preferably, a kind of preparation method of the smooth brightening agent for handling wool or containing wool fabric, including walk as follows
It is rapid:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 47
DEG C, after temperature is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 25% is added to reaction kettle, opens stirring dress
It sets, agitating device revolving speed is 150rpm, mixing time 40min, until stirring evenly, in whipping process, by the temperature of reaction kettle
It is warming up to 95 DEG C；
(3), after stirring, continue to control temperature of reaction kettle at 95 DEG C, successively by weight percent be 8.5% it is poly-
The polyethers of ethylene oxide ether 8810,8% is added to reaction kettle, opens agitating device, agitating device revolving speed is 180rpm, when stirring
Between be 25min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 4% by weight percent, is at the uniform velocity added dropwise to reaction kettle in a manner of instillation
Interior, the whole process used time is maintained at 40min；The sodium hydrate aqueous solution for being simultaneously 1.8% by weight percent in a manner of instillation
It is at the uniform velocity added dropwise in reaction kettle, the time of dropwise addition controls in 20min；
(5), the polyester that weight percent is 3% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens agitating device,
Agitating device revolving speed is 260rpm, mixing time 25min；
(6), after temperature of reaction kettle being cooled to 50 DEG C, the double fatty alkyl ester group ethoxy first for being 6% by weight percent
Base sulfate methyl ammonium is added to reaction kettle, open agitating device, agitating device revolving speed be 300rpm, mixing time 23min,
To after mixing evenly, filtering and discharging；
(7), the pH value that mixing liquid is made in the glacial acetic acid debugging step (6) for being 1% with weight percent is 8, is had
The muddy lotion of yellow light, as finished product.
Compared with prior art, the beneficial effects of the present invention are:
The invention discloses a kind of for handling wool or the smooth brightening agent containing wool fabric and preparation method thereof, the increasing
Gorgeous dose uses in wool fabric post-treatment, plays the effect that good increasing is deep, increasing is gorgeous, adds lustre to, and it is dark poor up to △ E ≈ to increase
1.29-2.46, the depth shown increase 16.83-29.33%, reduce the dosage of dyestuff, are equivalent to and increase by 15% left side of amount of dye
The right side does not influence the color fastness of fabric, hence it is evident that promotes half grade of fastness to wet rubbing of fabric or more.
Smooth brightening agent of the invention improves smooth, the soft feel of wool or wool fabric, wool or wool fabric
Washability it is splendid, after repeatedly washing, fabric can still keep not washing preceding 90% or more color；The product is without even
The group of the unfavorable environmental protection such as nitrogen, phenol, wool fabric fabric is high to brightening agent absorptivity, no discharge contact scar, biology itself
Degradability is good, can also directly reduce dye for fabrics dosage, meet very much environmental requirement.
Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammoniums in brightening agent of the present invention are a kind of novel cation tables
Face activating agent has excellent softness, antistatic property, yellowing-resistant.Without APEO, formaldehyde, easily biological-degradable is environmentally protective.
Dosage is few, and effect is good, and it is convenient to prepare, and overall cost is low, has high cost performance；Sodium hydrate aqueous solution synthesis when, from
Sub- uniform diameter, stable product quality.
Specific embodiment
With reference to embodiment, technical solution of the present invention is clearly and completely described, it is clear that retouched
The embodiment stated is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, originally
Field those of ordinary skill every other embodiment obtained without creative efforts, belongs to the present invention
The range of protection.
A kind of smooth brightening agent for handling wool or containing wool fabric, which is characterized in that the brightening agent by weighing as follows
The component of amount percentage is prepared: double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%；Polyoxyethylene ether 8810
5%-10%；Polyethers 6%-9%；Silane resin acceptor kh-550 3%-5%；Polyester 2%-5%；D4 octamethylcy-clotetrasiloxane 23%-
26%；Catalyst 1.5%-2%；Cold acetic acid 0.5%-1.5%；Deionized water surplus.
Preferably, the specific weight percent of the brightening agent component is as follows: double fatty alkyl ester group hydroxyethyl methyl sulfuric acid
Ammonium methyl 6%；Polyoxyethylene ether 8,810 8.5%；Polyethers 8%；Silane resin acceptor kh-550 4%；Polyester 3%；D4 prestox ring four
Siloxanes 25%；Catalyst 1.8%；Cold acetic acid 1%；Deionized water surplus.
Optimization, the catalyst is sodium hydrate aqueous solution.
Embodiment one:
A kind of preparation method of the smooth brightening agent for handling wool or containing wool fabric, comprising the following steps:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 45
DEG C, after temperature is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 23% is added to reaction kettle, opens stirring dress
It sets, agitating device revolving speed is 100rpm, mixing time 30min, until stirring evenly, in whipping process, by the temperature of reaction kettle
It is warming up to 95 DEG C；
(3), after stirring, continue to control temperature of reaction kettle the polyoxy for being successively 5% by weight percent at 95 DEG C
The polyethers of vinethene 8810,6% is added to reaction kettle, opens agitating device, and agitating device revolving speed is 150rpm, mixing time
For 20min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 3% by weight percent, is at the uniform velocity added dropwise to reaction kettle in a manner of instillation
Interior, the whole process used time is maintained at 40min；The sodium hydrate aqueous solution for being simultaneously 1.5% by weight percent in a manner of instillation
It is at the uniform velocity added dropwise in reaction kettle, the time of dropwise addition controls in 15min；
(5), the polyester that weight percent is 2% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens agitating device,
Agitating device revolving speed is 200rpm, mixing time 20min；
(6), after temperature of reaction kettle being cooled to 45 DEG C, the double fatty alkyl ester group ethoxy first for being 5% by weight percent
Base sulfate methyl ammonium is added to reaction kettle, open agitating device, agitating device revolving speed be 200rpm, mixing time 20min,
To after mixing evenly, filtering and discharging；
(7), it is 7 with the pH value that weight percent is the obtained mixing liquid of 0.5% glacial acetic acid debugging step (6), is had
The muddy lotion of yellow light, as finished product.
Embodiment two:
A kind of preparation method of the smooth brightening agent for handling wool or containing wool fabric, comprising the following steps:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 47
DEG C, after temperature is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 25% is added to reaction kettle, opens stirring dress
It sets, agitating device revolving speed is 150rpm, mixing time 40min, until stirring evenly, in whipping process, by the temperature of reaction kettle
It is warming up to 95 DEG C；
(3), after stirring, continue to control temperature of reaction kettle at 95 DEG C, successively by weight percent be 8.5% it is poly-
The polyethers of ethylene oxide ether 8810,8% is added to reaction kettle, opens agitating device, agitating device revolving speed is 180rpm, when stirring
Between be 25min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 4% by weight percent, is at the uniform velocity added dropwise to reaction kettle in a manner of instillation
Interior, the whole process used time is maintained at 40min；The sodium hydrate aqueous solution for being simultaneously 1.8% by weight percent in a manner of instillation
It is at the uniform velocity added dropwise in reaction kettle, the time of dropwise addition controls in 20min；
(5), the polyester that weight percent is 3% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens agitating device,
Agitating device revolving speed is 260rpm, mixing time 25min；
(6), after temperature of reaction kettle being cooled to 50 DEG C, the double fatty alkyl ester group ethoxy first for being 6% by weight percent
Base sulfate methyl ammonium is added to reaction kettle, open agitating device, agitating device revolving speed be 300rpm, mixing time 23min,
To after mixing evenly, filtering and discharging；
(7), the pH value that mixing liquid is made in the glacial acetic acid debugging step (6) for being 1% with weight percent is 8, is had
The muddy lotion of yellow light, as finished product.
Embodiment three:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 50
DEG C, after temperature is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 26% is added to reaction kettle, opens stirring dress
It sets, agitating device revolving speed is 200rpm, mixing time 50min, until stirring evenly, in whipping process, by the temperature of reaction kettle
It is warming up to 95 DEG C；
(3), after stirring, continue to control temperature of reaction kettle the polyoxy for being successively 10% by weight percent at 95 DEG C
The polyethers of vinethene 8810,9% is added to reaction kettle, opens agitating device, and agitating device revolving speed is 200rpm, mixing time
For 30min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 5% by weight percent, is at the uniform velocity added dropwise to reaction kettle in a manner of instillation
Interior, the whole process used time is maintained at 40min；It is in a manner of instillation that weight percent is even for 2% sodium hydrate aqueous solution simultaneously
Speed is added dropwise in reaction kettle, and the time of dropwise addition controls in 25min；
(5), the polyester that weight percent is 5% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens agitating device,
Agitating device revolving speed is 300rpm, mixing time 30min；
(6), after temperature of reaction kettle being cooled to 55 DEG C, the double fatty alkyl ester group ethoxy first for being 8% by weight percent
Base sulfate methyl ammonium is added to reaction kettle, open agitating device, agitating device revolving speed be 350rpm, mixing time 25min,
To after mixing evenly, filtering and discharging；
(7), the pH value that mixing liquid is made in the glacial acetic acid debugging step (6) for being 1.5% with weight percent is 9, obtains band
There are the muddy lotion of yellow light, as finished product.
The foregoing is merely the preferred embodiments of invention, are not intended to limit the invention, all in spirit of the invention
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (5)
1. a kind of smooth brightening agent for handling wool or containing wool fabric, which is characterized in that the brightening agent is by following weight
The component of percentage is prepared:
Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammonium 5%-8%；
8810 5%-10% of polyoxyethylene ether；
Polyethers 6%-9%；
Silane resin acceptor kh-550 3%-5%；
Polyester 2%-5%；
D4 octamethylcy-clotetrasiloxane 23%-26%；
Catalyst 1.5-2%；
Cold acetic acid 0.5%-1.5%；
Deionized water surplus.
2. according to claim 1 for handling wool or the smooth brightening agent containing wool fabric, which is characterized in that the increasing
The specific weight percent of gorgeous dose of component is as follows:
Double fatty alkyl ester group hydroxyethyl methyl sulfate methyl ammoniums 6%；
Polyoxyethylene ether 8,810 8.5%；
Polyethers 8%；
Silane resin acceptor kh-550 4%；
Polyester 3%；
D4 octamethylcy-clotetrasiloxane 25%；
Catalyst 1.8%；
Cold acetic acid 1%；
Deionized water surplus.
3. according to claim 1 or 2 for handling wool or the smooth brightening agent containing wool fabric, which is characterized in that
The catalyst is sodium hydrate aqueous solution.
4. it is according to claim 3 for handling the preparation method of wool or the smooth brightening agent containing wool fabric, it is special
Sign is, comprising the following steps:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 45-50 DEG C,
After temperature is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 23%-26% is added to reaction kettle, opens stirring dress
It sets, agitating device revolving speed is 100-200rpm, mixing time 30-50min, until stirring evenly, in whipping process, by reaction kettle
Temperature be warming up to 95 DEG C；
(3), after stirring, continue to control temperature of reaction kettle the polyoxy for being successively 5%-10% by weight percent at 95 DEG C
Vinethene 8810,6%-9% polyethers be added to reaction kettle, open agitating device, agitating device revolving speed be 150-200rpm, stir
Mixing the time is 20-30min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 3%-5% by weight percent, is at the uniform velocity added dropwise in reaction kettle in a manner of instillation,
The whole process used time is maintained at 40min；It is simultaneously the sodium hydrate aqueous solution of 1.5%-2% by weight percent in a manner of instillation
It is at the uniform velocity added dropwise in reaction kettle, the time of dropwise addition controls in 15-25min；
(5), the polyester that weight percent is 2%-5% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens agitating device,
Agitating device revolving speed is 200-300rpm, mixing time 20-30min；
(6), after temperature of reaction kettle being cooled to 45-55 DEG C, the double fatty alkyl ester group ethoxys for being 5%-8% by weight percent
Methylsulfuric acid ammonium methyl is added to reaction kettle, opens agitating device, and agitating device revolving speed is 200-350rpm, and mixing time is
20-25min, until after mixing evenly, filtering and discharging；
(7), the pH value of mixing liquid is made with the glacial acetic acid debugging step (6) that weight percent is 0.5%-1.5% is 7-9, is obtained
To the muddy lotion for having yellow light, as finished product.
5. it is according to claim 4 for handling the preparation method of wool or the smooth brightening agent containing wool fabric, it is special
Sign is, includes the following steps:
(1), it weighs: according to requiring to examine various raw materials, being weighed according to formula rate spare after various raw materials；
(2), deionized water is added in the reaction kettle configured with agitating device, the temperature of reaction kettle is adjusted to 47 DEG C, temperature
After degree is stablized, the D4 octamethylcy-clotetrasiloxane that weight percent is 25% is added to reaction kettle, agitating device is opened, stirs
Mixing device rotary speed is that in whipping process, the temperature of reaction kettle is warming up to until stirring evenly by 150rpm, mixing time 40min
95℃；
(3), after stirring, continue to control temperature of reaction kettle the polyoxy second for being successively 8.5% by weight percent at 95 DEG C
The polyethers of alkene ether 8810,8% is added to reaction kettle, opens agitating device, and agitating device revolving speed is 180rpm, and mixing time is
25min, until stirring evenly；
(4), the silane resin acceptor kh-550 for being 4% by weight percent, is at the uniform velocity added dropwise in reaction kettle in a manner of instillation, whole
A process used time is maintained at 40min；Simultaneously in a manner of instillation by weight percent be 1.8% sodium hydrate aqueous solution at the uniform velocity
It is added dropwise in reaction kettle, the time of dropwise addition controls in 20min；
(5), the polyester that weight percent is 3% is added to reaction kettle, 95 DEG C of reactor constant temperature, opens agitating device, stirring
Device rotary speed is 260rpm, mixing time 25min；
(6), after temperature of reaction kettle being cooled to 50 DEG C, the double fatty alkyl ester group hydroxyethyl methyl sulphur for being 6% by weight percent
Sour ammonium methyl is added to reaction kettle, opens agitating device, agitating device revolving speed is 300rpm, mixing time 23min, until stirring
After mixing uniformly, filtering and discharging；
(7), the pH value that mixing liquid is made in the glacial acetic acid debugging step (6) for being 1% with weight percent is 8, is obtained with Huang
The muddy lotion of light, as finished product.
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| CN109537293B (en) * | 2018-11-27 | 2021-06-08 | 纤化（上海）生物化工股份有限公司 | All-round brightener for denim fabric and preparation method and application thereof |
| CN111101379A (en) * | 2019-12-30 | 2020-05-05 | 无锡太平针织有限公司 | Super-soft antistatic auxiliary agent and application thereof in bionic fiber product |
| CN113186740A (en) * | 2021-05-26 | 2021-07-30 | 德州竹洋洗涤科技有限公司 | Fabric brightening agent |
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