CN106833772B - The production method of combustion adjuvant, high efficiency composition fuel oil and the high efficiency composition fuel oil - Google Patents

The production method of combustion adjuvant, high efficiency composition fuel oil and the high efficiency composition fuel oil Download PDF

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CN106833772B
CN106833772B CN201710130330.6A CN201710130330A CN106833772B CN 106833772 B CN106833772 B CN 106833772B CN 201710130330 A CN201710130330 A CN 201710130330A CN 106833772 B CN106833772 B CN 106833772B
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fuel oil
combustion adjuvant
high efficiency
efficiency composition
composition fuel
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CN106833772A (en
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吴敬忠
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Liaoning Future Clean Energy Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1233Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/1258Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof hydrogen peroxide, oxygenated water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1266Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

Abstract

The invention discloses the production methods of a kind of combustion adjuvant, a kind of high efficiency composition fuel oil containing the combustion adjuvant and the high efficiency composition fuel oil, wherein the combustion adjuvant is the aqueous solution containing small molecule organic amine and ammonia, and the usage ratio of each raw material is:Small molecule organic amine 1.0ml, saturation ammonium hydroxide 1.0ml, water supply 100ml;The high efficiency composition fuel oil is made of the raw material of following mass percent:Polynary low-carbon alcohols 20 60%, combustion adjuvant 10 50%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.The invention has the beneficial effects that:(1) stable in physicochemical property under combustion adjuvant normal temperature state, good with other components intersolubility, physicochemical property is active under the condition of high temperature, fuel oil can be promoted fully to burn;(2) composite fuel oil introduces after combustion adjuvant, substantially increases the efficiency of combustion of combustible, more complete due to burning, so the thermal energy not only provided is more, but also the gas discharged also more cleans.

Description

The production method of combustion adjuvant, high efficiency composition fuel oil and the high efficiency composition fuel oil
Technical field
The present invention relates to a kind of combustion adjuvant, a kind of high efficiency composition fuel oil and the high efficiency composition containing the combustion adjuvant The production method of fuel oil, belongs to technical field of chemistry.
Background technology
Existing composite fuel oil, since long-chain hydrocarbon content is higher, when burning, is insufficient contact with oxygen, so its burning effect Rate is not high.
Since existing hybrid fuel oil firing is not complete enough, so cannot not only provide more thermal energy, but also discharge Gas in containing more pollutant (such as:Carbon, carbon monoxide etc.).
Invention content
First of the present invention be designed to provide stable in physicochemical property under a kind of normal temperature state, with other components intersolubility Good, physicochemical property is active under the condition of high temperature, can promote the clean-burning combustion adjuvant of fuel oil.
Second object of the present invention is to provide a kind of high efficiency composition fuel oil having compared with high burning efficiency, Yi Jisheng The method for producing the high efficiency composition fuel oil.
In order to realize that first aim, the present invention adopt the following technical scheme that:
A kind of combustion adjuvant, which is characterized in that be the aqueous solution containing small molecule organic amine and ammonia, the usage ratio of each raw material For:
Small molecule organic amine 1.0ml,
Saturation ammonium hydroxide 1.0ml,
Water supplies 100ml.
Combustion adjuvant above-mentioned, which is characterized in that aforementioned small molecule organic amine is ethylenediamine or ethanol amine.
Combustion adjuvant above-mentioned, which is characterized in that aforementioned small molecule organic amine is the mixture of ethylenediamine and ethanol amine, the two Between mixed with arbitrary proportion.
In order to realize that second target, the present invention adopt the following technical scheme that:
A kind of high efficiency composition fuel oil, which is characterized in that containing combustion adjuvant above-mentioned, and by the original of following mass percent Material composition:
High efficiency composition fuel oil above-mentioned, which is characterized in that aforementioned polynary low-carbon alcohols are ethylene glycol.
High efficiency composition fuel oil above-mentioned, which is characterized in that aforementioned higher aliphatic is 8-13 carbon alcohol.
High efficiency composition fuel oil above-mentioned, which is characterized in that production method is:
(1) methanol and ferrocene are sequentially added in No.1 material-compound tank, stir 20 minutes for use;
(2) polynary low-carbon alcohols, toluene, ethyl alcohol, higher aliphatic, methyl tertiary butyl ether(MTBE) are sequentially added into No. two dispensings In tank, 30 minutes are stirred for use;
(3) combustion adjuvant, hydrogen peroxide are sequentially added into No. three material-compound tanks, stir 30 minutes for use;
(4) component prepared in No.1 material-compound tank, No. two material-compound tanks, No. three material-compound tanks is sequentially put into No. four It in tank, stirs 40 minutes, squeezes into finished pot, production is accused and completed.
The invention has the beneficial effects that:
(1) combustion adjuvant
(1) combustion adjuvant is micromolecular compound, and property is very active at high temperature, can allow fuel oil drops quickly and environment In oxygen come into full contact with, make its completely burned;
(2) combustion-supporting agent molecule contains strong hydrogen bonding, and physical property and chemical property are all sufficiently stable under normal temperature state;
(3) combustion adjuvant is liquid at normal temperatures, fine with other component intersolubilities.
(2) composite fuel oil
It introducing after combustion adjuvant, combustion adjuvant can allow fuel oil drops quickly to be come into full contact with the oxygen in environment at high temperature, Make its completely burned, substantially increase the efficiency of combustion of combustible, more complete due to burning, the thermal energy not only provided is more It is more, and the gas discharged also more cleans.
(3) preparation method of composite fuel oil
It is easy to operate, it is easy to accomplish, it is suitble to large-scale production.
Specific implementation mode
Specific introduce is made to the present invention below in conjunction with specific embodiment.
One, combustion adjuvant
Embodiment 1
1.0ml ethylenediamines and 1.0ml saturated ammonia water is soluble in water, and it is settled to 100ml.
Embodiment 2
1.0ml ethanol amines and 1.0ml saturated ammonia water is soluble in water, and it is settled to 100ml.
Embodiment 3
0.5ml ethylenediamines, 0.5ml ethanol amines and 1.0ml saturated ammonia water is soluble in water, and it is settled to 100ml.
Obtained combustion adjuvant is at normal temperatures liquid, due to being the aqueous solution of small molecule organic amine and ammonia, so with Other component intersolubilities are fine.
Further, since each component in combustion adjuvant contains hydrogen-oxygen key or hydrogen bound to nitrogen, so making its object under normal temperature state Rationality matter and chemical property are all sufficiently stable.
Combustion-supporting principle:Since obtained combustion adjuvant is micromolecular compound, low boiling point is easy gasification, so at high temperature Property is very active, and since the boiling point of saturation ammonium hydroxide, water and small molecule organic amine (ethylenediamine, ethanol amine) improves successively, So the fuel oil breakup of drop can be disperseed in a manner of " explosion " in different combustion phases combustion adjuvants, make fuel oil drops fast Speed, adequately come into full contact with the oxygen in environment, make its completely burned.
Two, composite fuel oil
1, prepare raw material
Polynary low-carbon alcohols (ethylene glycol), combustion adjuvant, methanol, toluene, ethyl alcohol, higher aliphatic (8-13 carbon alcohol), methyl- tert Butyl ether, hydrogen peroxide, ferrocene.
In above-mentioned each raw material, methanol, toluene, ethyl alcohol and higher aliphatic are the main body of composite fuel oil, polynary low-carbon Alcohol is used for improving the low-temperature stability of composite fuel oil, and hydrogen peroxide is conducive to light composite fuel oil, and combustion adjuvant is used for allowing fuel Oil drops quickly come into full contact with that fuel oil completely burned, methyl tertiary butyl ether(MTBE) and ferrocene is made to be used for carrying with the oxygen in environment The stability of height burning.
Embodiment 4
Polynary low-carbon alcohols (ethylene glycol) 20%, combustion adjuvant 50%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic (8 carbon alcohol) 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.
Embodiment 5
Polynary low-carbon alcohols (ethylene glycol) 35%, combustion adjuvant 35%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic (10 carbon alcohol) 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.
Embodiment 6
Polynary low-carbon alcohols (ethylene glycol) 60%, combustion adjuvant 10%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic (13 carbon alcohol) 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.
In embodiment 4, embodiment 5 and embodiment 6,3 obtained combustion adjuvant of embodiment is used.
2, production method
(1) methanol and ferrocene are sequentially added in No.1 material-compound tank, stir 20 minutes for use.
(2) polynary low-carbon alcohols, toluene, ethyl alcohol, higher aliphatic, methyl tertiary butyl ether(MTBE) are sequentially added into No. two dispensings In tank, 30 minutes are stirred for use.
(3) combustion adjuvant, hydrogen peroxide are sequentially added into No. three material-compound tanks, stir 30 minutes for use.
(4) component prepared in No.1 material-compound tank, No. two material-compound tanks, No. three material-compound tanks is sequentially put into No. four It in tank, stirs 40 minutes, squeezes into finished pot, production is accused and completed.
Three, the burn test results of composite fuel oil
Test group:Composite fuel oil (embodiment 4, embodiment 5 and embodiment 6) containing combustion adjuvant.
Control group:Composite fuel oil without containing combustion adjuvant.
Through combustion test, find:
(1) tail gas of test group discharge is colourless, tasteless, illustrates that burning is abundant;
(2) contain black dust in the tail gas of control group discharge, illustrate that burning is not enough.
Four, conclusion
It can be seen that introducing after combustion adjuvant, the efficiency of combustion of combustible is substantially increased, since burning more adds Entirely, so the thermal energy not only provided is more, but also the gas discharged also more cleans, while greatly reducing unit cost.
It should be noted that the invention is not limited in any way for above-described embodiment, it is all to use equivalent replacement or equivalent change The technical solution that the mode changed is obtained, all falls in protection scope of the present invention.

Claims (7)

1. a kind of combustion adjuvant, which is characterized in that be the aqueous solution containing small molecule organic amine and ammonia, the usage ratio of each raw material For:
Small molecule organic amine 1.0ml,
Saturation ammonium hydroxide 1.0ml,
Water supplies 100ml.
2. combustion adjuvant according to claim 1, which is characterized in that the small molecule organic amine is ethylenediamine or ethanol amine.
3. combustion adjuvant according to claim 1, which is characterized in that the small molecule organic amine is ethylenediamine and ethanol amine Mixture is mixed with arbitrary proportion therebetween.
4. a kind of high efficiency composition fuel oil, which is characterized in that containing combustion adjuvant described in claim 1, and by following quality hundred Divide the raw material composition of ratio:
5. high efficiency composition fuel oil according to claim 4, which is characterized in that the polynary low-carbon alcohols are ethylene glycol.
6. high efficiency composition fuel oil according to claim 4, which is characterized in that the higher aliphatic is 8-13 carbon alcohol.
7. according to the high efficiency composition fuel oil described in claim 4,5 or 6, which is characterized in that production method is:
(1) methanol and ferrocene are sequentially added in No.1 material-compound tank, stir 20 minutes for use;
(2) polynary low-carbon alcohols, toluene, ethyl alcohol, higher aliphatic, methyl tertiary butyl ether(MTBE) are sequentially added into No. two material-compound tanks In, stir 30 minutes for use;
(3) combustion adjuvant, hydrogen peroxide are sequentially added into No. three material-compound tanks, stir 30 minutes for use;
(4) component prepared in No.1 material-compound tank, No. two material-compound tanks, No. three material-compound tanks is sequentially put into No. four tanks In, it stirs 40 minutes, squeezes into finished pot, production is accused and completed.
CN201710130330.6A 2017-03-07 2017-03-07 The production method of combustion adjuvant, high efficiency composition fuel oil and the high efficiency composition fuel oil Active CN106833772B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1542099A (en) * 2003-11-07 2004-11-03 陆翼德 Additive for emulsified oil and method for preparing the same
CN102634384A (en) * 2012-04-17 2012-08-15 罗浩南 Novel vehicle alcohols environment-friendly fuel
CN103232867A (en) * 2012-04-16 2013-08-07 齐齐哈尔北坤合成高分子材料有限公司 Novel high-heat anticorrosive biomass alcohol-based fuel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1542099A (en) * 2003-11-07 2004-11-03 陆翼德 Additive for emulsified oil and method for preparing the same
CN103232867A (en) * 2012-04-16 2013-08-07 齐齐哈尔北坤合成高分子材料有限公司 Novel high-heat anticorrosive biomass alcohol-based fuel
CN102634384A (en) * 2012-04-17 2012-08-15 罗浩南 Novel vehicle alcohols environment-friendly fuel

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