The production method of combustion adjuvant, high efficiency composition fuel oil and the high efficiency composition fuel oil
Technical field
The present invention relates to a kind of combustion adjuvant, a kind of high efficiency composition fuel oil and the high efficiency composition containing the combustion adjuvant
The production method of fuel oil, belongs to technical field of chemistry.
Background technology
Existing composite fuel oil, since long-chain hydrocarbon content is higher, when burning, is insufficient contact with oxygen, so its burning effect
Rate is not high.
Since existing hybrid fuel oil firing is not complete enough, so cannot not only provide more thermal energy, but also discharge
Gas in containing more pollutant (such as:Carbon, carbon monoxide etc.).
Invention content
First of the present invention be designed to provide stable in physicochemical property under a kind of normal temperature state, with other components intersolubility
Good, physicochemical property is active under the condition of high temperature, can promote the clean-burning combustion adjuvant of fuel oil.
Second object of the present invention is to provide a kind of high efficiency composition fuel oil having compared with high burning efficiency, Yi Jisheng
The method for producing the high efficiency composition fuel oil.
In order to realize that first aim, the present invention adopt the following technical scheme that:
A kind of combustion adjuvant, which is characterized in that be the aqueous solution containing small molecule organic amine and ammonia, the usage ratio of each raw material
For:
Small molecule organic amine 1.0ml,
Saturation ammonium hydroxide 1.0ml,
Water supplies 100ml.
Combustion adjuvant above-mentioned, which is characterized in that aforementioned small molecule organic amine is ethylenediamine or ethanol amine.
Combustion adjuvant above-mentioned, which is characterized in that aforementioned small molecule organic amine is the mixture of ethylenediamine and ethanol amine, the two
Between mixed with arbitrary proportion.
In order to realize that second target, the present invention adopt the following technical scheme that:
A kind of high efficiency composition fuel oil, which is characterized in that containing combustion adjuvant above-mentioned, and by the original of following mass percent
Material composition:
High efficiency composition fuel oil above-mentioned, which is characterized in that aforementioned polynary low-carbon alcohols are ethylene glycol.
High efficiency composition fuel oil above-mentioned, which is characterized in that aforementioned higher aliphatic is 8-13 carbon alcohol.
High efficiency composition fuel oil above-mentioned, which is characterized in that production method is:
(1) methanol and ferrocene are sequentially added in No.1 material-compound tank, stir 20 minutes for use;
(2) polynary low-carbon alcohols, toluene, ethyl alcohol, higher aliphatic, methyl tertiary butyl ether(MTBE) are sequentially added into No. two dispensings
In tank, 30 minutes are stirred for use;
(3) combustion adjuvant, hydrogen peroxide are sequentially added into No. three material-compound tanks, stir 30 minutes for use;
(4) component prepared in No.1 material-compound tank, No. two material-compound tanks, No. three material-compound tanks is sequentially put into No. four
It in tank, stirs 40 minutes, squeezes into finished pot, production is accused and completed.
The invention has the beneficial effects that:
(1) combustion adjuvant
(1) combustion adjuvant is micromolecular compound, and property is very active at high temperature, can allow fuel oil drops quickly and environment
In oxygen come into full contact with, make its completely burned;
(2) combustion-supporting agent molecule contains strong hydrogen bonding, and physical property and chemical property are all sufficiently stable under normal temperature state;
(3) combustion adjuvant is liquid at normal temperatures, fine with other component intersolubilities.
(2) composite fuel oil
It introducing after combustion adjuvant, combustion adjuvant can allow fuel oil drops quickly to be come into full contact with the oxygen in environment at high temperature,
Make its completely burned, substantially increase the efficiency of combustion of combustible, more complete due to burning, the thermal energy not only provided is more
It is more, and the gas discharged also more cleans.
(3) preparation method of composite fuel oil
It is easy to operate, it is easy to accomplish, it is suitble to large-scale production.
Specific implementation mode
Specific introduce is made to the present invention below in conjunction with specific embodiment.
One, combustion adjuvant
Embodiment 1
1.0ml ethylenediamines and 1.0ml saturated ammonia water is soluble in water, and it is settled to 100ml.
Embodiment 2
1.0ml ethanol amines and 1.0ml saturated ammonia water is soluble in water, and it is settled to 100ml.
Embodiment 3
0.5ml ethylenediamines, 0.5ml ethanol amines and 1.0ml saturated ammonia water is soluble in water, and it is settled to 100ml.
Obtained combustion adjuvant is at normal temperatures liquid, due to being the aqueous solution of small molecule organic amine and ammonia, so with
Other component intersolubilities are fine.
Further, since each component in combustion adjuvant contains hydrogen-oxygen key or hydrogen bound to nitrogen, so making its object under normal temperature state
Rationality matter and chemical property are all sufficiently stable.
Combustion-supporting principle:Since obtained combustion adjuvant is micromolecular compound, low boiling point is easy gasification, so at high temperature
Property is very active, and since the boiling point of saturation ammonium hydroxide, water and small molecule organic amine (ethylenediamine, ethanol amine) improves successively,
So the fuel oil breakup of drop can be disperseed in a manner of " explosion " in different combustion phases combustion adjuvants, make fuel oil drops fast
Speed, adequately come into full contact with the oxygen in environment, make its completely burned.
Two, composite fuel oil
1, prepare raw material
Polynary low-carbon alcohols (ethylene glycol), combustion adjuvant, methanol, toluene, ethyl alcohol, higher aliphatic (8-13 carbon alcohol), methyl- tert
Butyl ether, hydrogen peroxide, ferrocene.
In above-mentioned each raw material, methanol, toluene, ethyl alcohol and higher aliphatic are the main body of composite fuel oil, polynary low-carbon
Alcohol is used for improving the low-temperature stability of composite fuel oil, and hydrogen peroxide is conducive to light composite fuel oil, and combustion adjuvant is used for allowing fuel
Oil drops quickly come into full contact with that fuel oil completely burned, methyl tertiary butyl ether(MTBE) and ferrocene is made to be used for carrying with the oxygen in environment
The stability of height burning.
Embodiment 4
Polynary low-carbon alcohols (ethylene glycol) 20%, combustion adjuvant 50%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic
(8 carbon alcohol) 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.
Embodiment 5
Polynary low-carbon alcohols (ethylene glycol) 35%, combustion adjuvant 35%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic
(10 carbon alcohol) 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.
Embodiment 6
Polynary low-carbon alcohols (ethylene glycol) 60%, combustion adjuvant 10%, methanol 15%, toluene 5%, ethyl alcohol 5%, higher aliphatic
(13 carbon alcohol) 4%, methyl tertiary butyl ether(MTBE) 0.9%, hydrogen peroxidase 10 .05%, ferrocene 0.05%.
In embodiment 4, embodiment 5 and embodiment 6,3 obtained combustion adjuvant of embodiment is used.
2, production method
(1) methanol and ferrocene are sequentially added in No.1 material-compound tank, stir 20 minutes for use.
(2) polynary low-carbon alcohols, toluene, ethyl alcohol, higher aliphatic, methyl tertiary butyl ether(MTBE) are sequentially added into No. two dispensings
In tank, 30 minutes are stirred for use.
(3) combustion adjuvant, hydrogen peroxide are sequentially added into No. three material-compound tanks, stir 30 minutes for use.
(4) component prepared in No.1 material-compound tank, No. two material-compound tanks, No. three material-compound tanks is sequentially put into No. four
It in tank, stirs 40 minutes, squeezes into finished pot, production is accused and completed.
Three, the burn test results of composite fuel oil
Test group:Composite fuel oil (embodiment 4, embodiment 5 and embodiment 6) containing combustion adjuvant.
Control group:Composite fuel oil without containing combustion adjuvant.
Through combustion test, find:
(1) tail gas of test group discharge is colourless, tasteless, illustrates that burning is abundant;
(2) contain black dust in the tail gas of control group discharge, illustrate that burning is not enough.
Four, conclusion
It can be seen that introducing after combustion adjuvant, the efficiency of combustion of combustible is substantially increased, since burning more adds
Entirely, so the thermal energy not only provided is more, but also the gas discharged also more cleans, while greatly reducing unit cost.
It should be noted that the invention is not limited in any way for above-described embodiment, it is all to use equivalent replacement or equivalent change
The technical solution that the mode changed is obtained, all falls in protection scope of the present invention.