CN106833707A - For manufacturing the mixed coal of cupola coke and the cupola coke including it and its manufacture method - Google Patents

For manufacturing the mixed coal of cupola coke and the cupola coke including it and its manufacture method Download PDF

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Publication number
CN106833707A
CN106833707A CN201710048327.XA CN201710048327A CN106833707A CN 106833707 A CN106833707 A CN 106833707A CN 201710048327 A CN201710048327 A CN 201710048327A CN 106833707 A CN106833707 A CN 106833707A
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China
Prior art keywords
coal
coke
cupola
coking
mixed
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CN201710048327.XA
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Chinese (zh)
Inventor
宋峰
杨大庆
罗时政
郭宪英
栾义涛
张贵财
王毅志
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Qingdao United Metallurgical Research Institute Co Ltd
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Qingdao United Metallurgical Research Institute Co Ltd
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Priority to CN201710048327.XA priority Critical patent/CN106833707A/en
Publication of CN106833707A publication Critical patent/CN106833707A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/08Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps and the like

Abstract

The invention discloses a kind of mixed coal for manufacturing cupola coke and cupola coke and its manufacture method including it.Include 50% 65% rich coal, 25% 35% meager coal and 5% 10% petroleum coke by weight percentage for manufacturing the mixed coal of cupola coke, or include 50% 65% rich coal and coking coal, 25% 35% meager coal and 5% 10% petroleum coke by weight percentage, wherein, the content of coking coal is 30% the 50% of the gross weight of rich coal.It is more as mixed coal production cupola coke cost decline by the use of rich coal, meager coal, petroleum coke, and cooperation pit ash, sulphur content has been reached the requirement of production cupola coke according to the present invention.In addition, the cupola coke porosity of the invention is low, lumpiness big, the quality criteria requirements of national cupola coke are fully achieved.

Description

For manufacturing the mixed coal of cupola coke and the cupola coke including it and its manufacture method
Technical field
The present invention relates to a kind of mixed coal for manufacturing cupola coke and cupola coke and its manufacture method including it, more Say body, be related to a kind of using meager coal manufacture cupola coke and its method.
Background technology
Cupola coke is the primary raw material of furnace cupola molten iron, for melting batch, and overheats molten iron, also acts as supporting material Post, it is ensured that good gas permeability and confession carbon effect.Cupola coke is generally used in iron casting production melting abroad, bonded hard ferrite magnet is high In 1500 DEG C;And in domestic iron casting production, bulk metallurgical coke product as an alternative, cupola coke application percentage are commonly used during melting Deficiency, bonded hard ferrite magnet of coming out of the stove is mostly 1400 DEG C or so, and this has had a strong impact on the quality of molten iron in melting, causes casting iron defect, Casting quality level has very big gap compared with foreign countries.
Superior casting coke requirement ash content is low, sulphur content is low, reactivity is low, the porosity is low, cold strength is high and lumpiness big and equal It is even.One of most important property of cupola coke is reactivity, and the specific surface area of the low namely coke of the porosity is small, the reactivity of coke Also it is low.Temperature Distribution of the reactivity influence of coke in the speed and stove of cupola tuyere zonal combustion.In addition, cupola coke is another One important properties is the lumpiness and cold strength of cupola coke, and the cupola coke of big lumpiness and high intensity can improve coke burning effect Rate and molten iron temperature, are also beneficial to desulfurizing iron and carburizing.
When cupola coke is produced, cupola coke is generally produced by the use of anthracite as raw material, but anthracite hardness is big, needs Separating twice is wanted, the electric power of consumption is more, big to disintegrating machine abrasion, price is relatively high.Accordingly, it would be desirable to a kind of new cupola coke.
The content of the invention
It is an object of the present invention to provide a kind of mixed coal for manufacturing cupola coke and the cupola coke including it and Its manufacture method.
According to an aspect of the present invention, there is provided a kind of mixed coal for manufacturing cupola coke, the mixed coal by weight hundred Divide includes the petroleum coke of the rich coal of 50%-65%, the meager coal of 25%-35% and 5%-10% than meter, or by weight percentage Meter includes the petroleum coke of the rich coal of 50%-65% and coking coal, the meager coal of 25%-35% and 5%-10%, wherein, the content of coking coal It is the 30%-50% of the gross weight of rich coal.
Exemplary embodiment of the invention, the technical indicator of the rich coal is as follows:Moisture 8%-14%, ash content 7.5%-9.5%, sulphur content 0.4%-0.62%, volatile matter 27%-32%, G value 90-100, Y value 23mm-31mm.The meager coal Technical indicator it is as follows:Ash content<12%th, sulphur content<8%th, volatile matter 10%-20%, G value≤5.The technical indicator of the petroleum coke It is as follows:Moisture 0.5%-30%, ash content 0.5%-8.5%, sulphur content 0.2%-0.8%, volatile matter 0.5%-11%.
Exemplary embodiment of the invention, in terms of butt, the technical indicator of the mixed coal is as follows:Ash content<12%th, Sulphur content<0.6%th, volatile matter 17-22%, moisture 9%-11%, G value 50-70, Y value 12mm-17mm.
Exemplary embodiment of the invention, in terms of butt, particle diameter accounts for mixed coal total amount in the mixed coal of below 3mm More than 90%.
According to another aspect of the present invention, there is provided a kind of cupola coke, the cupola coke is made up of mixed coal, wherein, it is described The petroleum coke of mixed coal rich coal, the meager coal of 25%-35% and 5%-10% including 50%-65% by weight percentage, or The petroleum coke of rich coal and coking coal, the meager coal of 25%-35% and 5%-10% of the person by weight percentage including 50%-65%, Wherein, the content of coking coal is the 30%-50% of the gross weight of rich coal.
According to another aspect of the invention, there is provided a kind of method for manufacturing cupola coke, methods described includes:Percentage by weight Than by the rich coal of 50%-65%, the petroleum coke of the meager coal of 25%-35% and 5%-10% or by weight percentage will The petroleum coke mixing of the rich coal and coking coal, the meager coal of 25%-35% and 5%-10% of 50%-65%, to obtain mixed coal, its In, the content of coking coal is the 30%-50% of the gross weight of rich coal;Mixed coal is made briquette;Coking treatment is carried out to briquette, with Obtain cupola coke.
Exemplary embodiment of the invention, bulk density is made in 0.95t/m by mixed coal3Briquette above.
Exemplary embodiment of the invention, to briquette from 850 between including from 10h to 120h the step of coking is processed DEG C stage be warming up to 1020 DEG C and at a temperature of 1020 DEG C coking treatment until coking is ripe.
Exemplary embodiment of the invention, methods described also includes:Before coking treatment is carried out to briquette, utilize Briquette is divided into multiple layers by separate layer.
Exemplary embodiment of the invention, the thickness of each layer is 200mm-300mm.Separate layer is including thickness The brown paper of 0.05mm-0.4mm.
It is as under mixed coal production cupola coke cost by the use of rich coal, meager coal, petroleum coke and/or coking coal according to the present invention Drop is more, and cooperation pit ash, sulphur content has been reached the requirement of production cupola coke.In addition, cupola coke stomata of the invention Rate is low, lumpiness is big, and the quality criteria requirements of national cupola coke are fully achieved.
Brief description of the drawings
By description below in conjunction with the accompanying drawings to exemplary embodiment, these and/or other side will be clear and more It is readily appreciated that, in the accompanying drawings:
Fig. 1 is the flow chart of the method for the manufacture cupola coke of exemplary embodiment of the invention.
Fig. 2 is the process chart of the method for the manufacture cupola coke of exemplary embodiment of the invention.
Specific embodiment
Below in conjunction with exemplary embodiment, principle of the invention is described in further detail, so that technology of the invention is solved Scheme becomes apparent from.
Mixed coal for manufacturing cupola coke of the invention by weight percentage including 50%-65% rich coal, The meager coal of 25%-35% and the petroleum coke of 5%-10%, or the rich coal including 50%-65% and Jiao by weight percentage The petroleum coke of coal, the meager coal of 25%-35% and 5%-10%, wherein, the content of coking coal is the 30%- of the gross weight of rich coal 50%.In a preferred embodiment, it is of the invention to include by weight percentage for manufacturing the mixed coal of cupola coke 60% rich coal, 33% meager coal and 7% petroleum coke, or including 30% rich coal, 30% coking coal, 33% meager coal and 7% petroleum coke, but the invention is not restricted to this.
Rich coal is the active ingredient for manufacturing cupola coke.In exemplary embodiments of the present invention, the technical indicator of rich coal is as follows: Moisture 8%-14%, ash content 7.5%-9.5%, sulphur content 0.4%-0.62%, volatile matter 27%-32%, G value 90-100, Y Value 23mm-31mm.However, the invention is not restricted to this, it is possible to use the rich coal of any suitable technical indicator.
Mixed coal of the invention, the mixed coal produced for manufacturing cupola coke using meager coal and/or coking coal can drop Low production cost.It is, for example possible to use the following meager coal of technical indicator:Ash content<12%th, sulphur content<8%th, volatile matter 10%- 20%th, G value≤5, however, the invention is not restricted to this, it is possible to use the meager coal of any suitable technical indicator.
Additionally, the content control of meager coal can still be produced in the 25%-35% of mixed coal total amount satisfactory Cupola coke.If the content of meager coal cannot be effectively reduced production cost less than the 25% of mixed coal total amount;If meager coal Content then leads to not higher than the 35% of mixed coal total amount because excessive meager coal cannot form coke button in follow-up coking Produce satisfactory cupola coke.In an exemplary embodiment of the present invention, the content of meager coal can 26%-34%, In the range of 28%-34%, 29%-33%, or in any range of the above-mentioned numerical definiteness for being given, for example, 25%-30% or 33%.
Petroleum coke primarily serves the effect of leaning agent in mixed coal.In an exemplary embodiment of the present invention, can make With the following petroleum coke of technical indicator:Moisture 0.5%-30%, ash content 0.5%-8.5%, sulphur content 0.2%-0.8%, wave Hair point 0.5%-11%, however, the invention is not restricted to this, it is possible to use the petroleum coke of any suitable technical indicator.
The petroleum coke of such as particulate is added in the stronger rich coal of caking property can not only reduce cooperation pit ash, sulphur Part, volatilization grade and comply with requirement, but also can reduce the crackle and porosity of cupola coke, reduce the reaction of cupola coke Property, increase the mechanical strength and post reaction strength of cupola coke.Additionally, most obvious with coal characteristic and coking conditions after adding petroleum coke Change be reduction of and the Ji Shi maximum fluidities of coal blending and reduce furnace pressure because petroleum coke is used as a kind of typical case Coal blending leaning agent can make shove charge coal coking process Semicoke Contraction stage Volatile speed reduce, alleviate semicoke receipts Contracting, reduces thermal stress, reduces charge of coke crackle.In the bonding stage of coking process, petroleum coke particles adsorption suitable The liquid product of part pyrolysis of coal generation, reduces amount of liquid phase in plastic body, and fluidity and dilation are reduced, pyrogenous origin gas Body is easily separated out from plastic body, and the particle and distortion particle of residual is easily mutually assembled, and the resolidification generation porosity is low, and stomata wall thickness Semicoke reduces the reactivity of coke, increased the post reaction strength of coke, improves the lumpiness of coke, meets foundry coke low Ash, low-sulfur, the reactive low, porosity are low, the big quality requirement of lumpiness.
In an exemplary embodiment of the present invention, the content of petroleum coke is the 5%-10% of mixed coal total amount, for example, oil Burnt content can in the range of 5%-9%, 6%-9%, 7%-8%, or the above-mentioned numerical definiteness for being given any range It is interior, for example, 6%-10%, 7%-10% or 7%.
In non-limiting example of the invention, the granularity of petroleum coke can be controlled in 0.1mm or so.
In non-limiting example of the invention, the granularity of rich coal, meager coal and petroleum coke reaches 100% less than 3mm, and And granularity accounts for more than 95% less than 2mm.
Mixed coal including said components is in terms of butt, and its technical indicator is as follows:Ash content<12%th, sulphur content<0.6%th, volatilize Divide 17-22%, moisture 9%-11%, G value 50-70, Y value 12mm-17mm.Additionally, exemplary implementation of the invention Example, in terms of butt, particle diameter accounts for more than the 90% of mixed coal total amount in the mixed coal of below 3mm.
In non-limiting example of the invention, when one-level cupola coke is produced, mixed coal needs to meet following technology Index:Ash content<9.5%th, sulphur content<0.6%;When two grades of cupola cokes are produced, mixed coal needs to meet following technical indicator:Ash content <12%th, sulphur content<0.5%.Furthermore, it is possible to the respective technical indicator according to rich coal, meager coal and petroleum coke be weighted come Meet the technical indicator of the mixed coal required by the rank of cupola coke, thus rich coal, meager coal and petroleum coke are according to the cooperation for calculating Than being mixed to obtain mixed coal, so as to produce satisfactory cupola coke.
It is as under mixed coal production cupola coke cost by the use of rich coal, meager coal, petroleum coke and/or coking coal according to the present invention Drop is more, and the technical indicators such as cooperation pit ash, sulphur content has been reached the requirement of production cupola coke.
The method for describing manufacture cupola coke of the invention in detail below with reference to accompanying drawings.
Fig. 1 is the flow chart of the method for the manufacture cupola coke of exemplary embodiment of the invention.Fig. 2 is according to this hair The process chart of the method for the manufacture cupola coke of bright exemplary embodiment.
Reference picture 1, the method for manufacture cupola coke of the invention includes preparing mixed coal (S100), is made mixed coal Briquette (S200) and coking treatment (S300) is carried out to briquette.
In mixed coal (S100) is prepared, the mixed coal can use mixed coal as described above, therefore, will not herein Repeated.
In mixed coal to be made briquette (S200), mixed coal can be made bulk density in 0.95t/m3Coal above Cake.In the present invention, mixed coal is made bulk density in 0.95t/m3Briquette above so that the distance between coal grain reduces, The relative reduction of liquid product quantity needed for filling coal intergranular gap after being heated so as to coal charge.Additionally, the bulk density of increase briquette, also The resistance of pyrolysis gas spilling is increased, the air impermeability and the bulbs of pressure of gel is increased, such that it is able to relatively abundant Using the caking property of coal charge, final cupola coke shows the advantages of increase of air vent wall intensity, coke structure densification.Of the invention In non-limiting example, the bulk density of briquette is in 0.95t/m3-1.05t/m3Between or in 1.05t/m3More than.
In coking treatment (S300) is carried out to briquette, briquette is carried out at coking at a temperature of 850 DEG C -1020 DEG C Reason, to form cupola coke.Specifically, in the temperature control of carbonization chamber at 900 ± 100 DEG C, tetrad encircles temperature≤1220 to briquette DEG C, gas-collecting branch pipe temperature≤1050 DEG C, main temperature≤1000 DEG C.
The coke of high intensity is obtained during the coking such as half inert substance in adapted petroleum coke it is necessary to make such as rich coal Active material and half inert substance firm physical chemistry is formed in process of coking and is combined.Heat recovery coke oven coking time is long Up to 120 hours or so, coking rate was more much lower than big machine Jiao, and low heating rate makes half inert substance of petroleum coke etc. and rich coal Deng active material increase in the bioactive molecule that high-temperature region produces time that is bonded to each other, also make the interval overlap of generation bioactive molecule Region increases.Therefore, low coking speed causes the activity that the rank coal high such as half inert substance is produced in the coking middle and later periods Molecule has the long period to be reacted with the active material of rich coal pyrolysis generation.Therefore, in an exemplary embodiment of the present invention, Can from 10h to 120h between 1020 DEG C and the coking treatment at a temperature of 1020 DEG C are warming up to from 850 DEG C of stages to briquette Until coking is ripe.For example, coking treatment can be carried out according to the time in table 1 and temperature:
Table 1
Temperature/DEG C Time/h
830-890 10-40
890-940 40-80
890-980 80-120
980-1020 120- is ripe
In coking processing procedure, a part of gas can be flowed up through coke (such as cupola coke) along the wall of coke oven, There is twice decomposition in this portion gas, the carbon with active bond is produced, fully on the air vent wall of coke when through coke layer Deposition, and produce chemically combined bridge with the part after active component Semicoke Contraction as the part after inert component pyrolysis Beam, so as to increase the cold strength of coke.
In an exemplary embodiment of the present invention, the method for manufacture cupola coke is additionally may included in and briquette is carried out at coking Before reason (S300), the step of briquette is divided into multiple layers using separate layer (S400).In exemplary embodiment of the invention In, the thickness of each layer can be 200mm-300mm.It is the brown paper of 0.05mm-0.4mm by briquette that such as thickness can be utilized Such as 6 layers are stacked as, wherein, the thickness of ground floor to layer 5 can be 220mm, and the thickness of layer 6 can be 200mm. In the present invention, briquette is stacked as multiple layers and causes that in coking each layer produces different convergent-divergent stress, and can be with Discharged along separate layer, and the longitudinal crack of different layers is also divided the lumpiness and intensity that layer cutting increases cupola coke.
In non-limiting example of the invention, after coking treatment is carried out to briquette, STRENGTH ON COKE carries out quenching, cool Burnt, sieve is burnt, so as to obtain cupola coke.
Additionally, in an exemplary embodiment of the present invention, manufacturing the method for cupola coke can also include treating coking The heat produced in journey is recycled.Specifically, reference picture 2, feed coal (rich coal, meager coal, petroleum coke and/coking coal) is broken Broken, coal blending, to obtain mixed coal;Briquette is made to mixed coal;Briquette is loaded into coke oven through coal-charging pusher machine and performs coking, with To coke;STRENGTH ON COKE carries out quenching, cool burnt, sieve Jiao, to obtain cupola coke and metallurgical coke;High-temperature flue gas in coke oven are returned Receive, in waste heat boiler;The steam obtained through waste heat boiler is used to generate electricity;It is used to remove through the low-temperature flue gas after waste heat boiler Discharged after dirt desulfurization.
Mixed coal for manufacturing cupola coke of the invention, the cupola coke comprising it and its manufacture method can be obtained At least one of following effect:
1st, it is more as mixed coal production cupola coke cost decline by the use of rich coal, meager coal, petroleum coke and/or coking coal, and Cooperation pit ash, sulphur content is set to have reached the requirement of production cupola coke.
2nd, cupola coke of the invention has the spies such as low ash, low-sulfur, cold strength are high, reactivity is low, the porosity is low, lumpiness is big Point, is fully achieved the quality criteria requirements of national cupola coke.
3rd, cupola coke of the invention can be widely applied for the industries such as machine-building, hot investment casting.
4th, the method according to the invention process of coking negative-pressure operation, reduces the uncontrollable discharge of exhaust gas dust.
5th, the high-temperature flue gas concentration extraction that the method according to the invention is produced carries out exhaust heat recovery power generation, so as to reduce to ring The pollution in border.
6th, the method according to the invention avoids the generation and treatment of phenol, cyanogen sewage.
Cupola coke of the invention is described in more detail with reference to embodiment.
Embodiment 1:The preparation of cupola coke
60% rich coal, 33% meager coal and 7% petroleum coke are mixed, to obtain mixed coal;Mixed coal is made heap Proportion is 1.05t/m3Briquette;Briquette is added in coke oven, and briquette is stacked as 6 layers and ground floor extremely using brown paper The thickness of layer 5 is 200mm, and the thickness of layer 6 is 220mm;Time and temperature according to table 1 carry out coking to briquette, with Obtain coke;STRENGTH ON COKE performs quenching, cool burnt, sieve Jiao, to obtain cupola coke (such as one-level is burnt).The quality of mixed coal shows In table 2, the quality of cupola coke is shown in table 3.
Embodiment 2:The preparation of cupola coke
In addition to being mixed according to the raw material proportioning of table 2, casting is manufactured using the method identical method with embodiment 1 Make burnt (two grades of Jiao).The quality of mixed coal shows that in table 2 quality of cupola coke is shown in table 3.
Embodiment 3:The preparation of cupola coke
In addition to being mixed according to the raw material proportioning of table 2, casting is manufactured using the method identical method with embodiment 1 Make burnt (two grades of Jiao).The quality of mixed coal shows that in table 2 quality of cupola coke is shown in table 3.
Table 2
Table 3
From table 3 it can be seen that under by the use of rich coal, meager coal, petroleum coke and/or coking coal as mixed coal production cupola coke cost Drop is more, and cooperation pit ash, sulphur content has been reached the requirement of production cupola coke.Additionally, cupola coke of the invention has The features such as low ash, low-sulfur, cold strength are high, reactivity is low, the porosity is low, lumpiness is big, is fully achieved the quality of national cupola coke Standard requirement.
The ash content of cupola coke is according to GB 2002-80《The assay method of smelter coke ash content》The measure that carries out of regulation.Casting The volatile matter of Jiao is made according to GB 2003-80《The assay method of smelter coke volatile matter》The measure that carries out of regulation.Drum strength According to GB 2006-80《The assay method of smelter coke mechanical strength》The measure that carries out of regulation, wherein, test into bulging lumpiness It is more than 80mm.Drop strength is according to GB 4511.2-84《The assay method of coke drop strength》The measure that carries out of regulation. The apparent porosity of cupola coke is according to GB 4511.84《The assay method of coke apparent porosity》The measure that carries out of regulation.Cupola coke Lumpiness according to GB 2005-80《The assay method of the burnt screening composition of the breeze content and bulk of smelter coke》Regulation carry out Measure.Note:Broken burnt rate, cupola coke sieves on 40mm × 40mm square hole screens, its screenings account for the weight ratio of original sample with Percentage is represented.
Although being specifically illustrated in reference to exemplary embodiment of the invention and describing the present invention, this area is general Logical technical staff will be understood that, not depart from the spirit and scope of the present invention that are limited such as claim and their equivalent In the case of, can herein make the various changes in form and details.Should only in the sense that descriptive rather than for The purpose of limitation considers embodiment.Therefore, the scope of the present invention is limited by specific embodiment of the invention, but It is defined by the claims, all differences in the range of this are to be interpreted as being included in the invention.

Claims (10)

1. a kind of mixed coal for manufacturing cupola coke, it is characterised in that the mixed coal includes 50%- by weight percentage The petroleum coke of 65% rich coal, the meager coal of 25%-35% and 5%-10%, or include 50%-65% by weight percentage Rich coal and coking coal, the meager coal of 25%-35% and 5%-10% petroleum coke, wherein, the content of coking coal is the gross weight of rich coal 30%-50%.
2. mixed coal according to claim 1, it is characterised in that:
The technical indicator of the rich coal is as follows:Moisture 8%-14%, ash content 7.5%-9.5%, sulphur content 0.4%-0.62%, Volatile matter 27%-32%, G value 90-100, Y value 23mm-31mm;
The technical indicator of the meager coal is as follows:Ash content<12%th, sulphur content<8%th, volatile matter 10%-20%, G value≤5;
The technical indicator of the petroleum coke is as follows:Moisture 0.5%-30%, ash content 0.5%-8.5%, sulphur content 0.2%- 0.8%th, volatile matter 0.5%-11%.
3. mixed coal according to claim 1, it is characterised in that in terms of butt, the technical indicator of the mixed coal is as follows: Ash content<12%th, sulphur content<0.6%th, volatile matter 17-22%, moisture 9%-11%, G value 50-70, Y value 12mm-17mm.
4. mixed coal according to claim 1, it is characterised in that in terms of butt, particle diameter is accounted in the mixed coal of below 3mm matches somebody with somebody Close more than the 90% of coal total amount.
5. a kind of cupola coke, the cupola coke is made up of mixed coal, wherein, the mixed coal includes by weight percentage The petroleum coke of the rich coal of 50%-65%, the meager coal of 25%-35% and 5%-10%, or include 50%- by weight percentage The petroleum coke of 65% rich coal and coking coal, the meager coal of 25%-35% and 5%-10%, wherein, the content of coking coal is the total of rich coal The 30%-50% of weight.
6. it is a kind of manufacture cupola coke method, it is characterised in that methods described includes:
By weight percentage by the rich coal of 50%-65%, the petroleum coke of the meager coal of 25%-35% and 5%-10% or by weight Percentages mix the petroleum coke of the rich coal and coking coal, the meager coal of 25%-35% and 5%-10% of 50%-65%, to obtain Mixed coal, wherein, the content of coking coal is the 30%-50% of the gross weight of rich coal;
Mixed coal is made briquette;
Coking treatment is carried out to briquette, to obtain cupola coke.
7. method according to claim 6, it is characterised in that mixed coal is made bulk density in 0.95t/m3Coal above Cake.
8. method according to claim 6, it is characterised in that the step of coking is processed is right between including from 10h to 120h Briquette be warming up to 1020 DEG C from 850 DEG C of stages and at a temperature of 1020 DEG C coking treatment until coking maturation.
9. method according to claim 6, it is characterised in that methods described also includes:Coking treatment is being carried out to briquette Before, briquette is divided into multiple layers using separate layer.
10. method according to claim 9, it is characterised in that the thickness of each layer is 200mm-300mm;
The separate layer includes that thickness is the brown paper of 0.05mm-0.4mm.
CN201710048327.XA 2017-01-20 2017-01-20 For manufacturing the mixed coal of cupola coke and the cupola coke including it and its manufacture method Pending CN106833707A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575033A (en) * 2020-05-11 2020-08-25 山西沁新能源集团股份有限公司 Formed coke and preparation method and application thereof
RU2769188C1 (en) * 2020-11-19 2022-03-29 Публичное Акционерное Общество "Новолипецкий металлургический комбинат" Composition of charge for producing metallurgical coke

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1140196A (en) * 1995-07-07 1997-01-15 翼城县城关镇焦化厂 Method for dispensing coal in producing superior casting coke from weak bound coal
CN1145394A (en) * 1996-08-29 1997-03-19 冶金工业部鞍山热能研究院 Tech. for prodn. of casting coke mainly using weak coal
CN1153810A (en) * 1996-10-25 1997-07-09 翼城县煤炭工业管理局 Cast coke briquette produced with anthracite and its production process
CN1952041A (en) * 2006-10-18 2007-04-25 上海长德冶金工程技术有限公司 First grade metallurgical coke produced from ordinary coking coal and its production method
WO2009088321A1 (en) * 2008-01-09 2009-07-16 Boris Anatolievich Musokhranov Method for forming coal mixtures for producing coking burden and a composition of said mixtures
CN103756699A (en) * 2014-01-07 2014-04-30 神华集团有限责任公司 Blended coal for producing foundry coke and production method of foundry coke

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1140196A (en) * 1995-07-07 1997-01-15 翼城县城关镇焦化厂 Method for dispensing coal in producing superior casting coke from weak bound coal
CN1145394A (en) * 1996-08-29 1997-03-19 冶金工业部鞍山热能研究院 Tech. for prodn. of casting coke mainly using weak coal
CN1153810A (en) * 1996-10-25 1997-07-09 翼城县煤炭工业管理局 Cast coke briquette produced with anthracite and its production process
CN1952041A (en) * 2006-10-18 2007-04-25 上海长德冶金工程技术有限公司 First grade metallurgical coke produced from ordinary coking coal and its production method
WO2009088321A1 (en) * 2008-01-09 2009-07-16 Boris Anatolievich Musokhranov Method for forming coal mixtures for producing coking burden and a composition of said mixtures
CN103756699A (en) * 2014-01-07 2014-04-30 神华集团有限责任公司 Blended coal for producing foundry coke and production method of foundry coke

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
马名杰: "《低阶烟煤制焦及其炭化机理研究》", 31 March 2013, 煤炭工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575033A (en) * 2020-05-11 2020-08-25 山西沁新能源集团股份有限公司 Formed coke and preparation method and application thereof
RU2769188C1 (en) * 2020-11-19 2022-03-29 Публичное Акционерное Общество "Новолипецкий металлургический комбинат" Composition of charge for producing metallurgical coke

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