CN106833402A - Glue production technique - Google Patents
Glue production technique Download PDFInfo
- Publication number
- CN106833402A CN106833402A CN201710123281.3A CN201710123281A CN106833402A CN 106833402 A CN106833402 A CN 106833402A CN 201710123281 A CN201710123281 A CN 201710123281A CN 106833402 A CN106833402 A CN 106833402A
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- China
- Prior art keywords
- parts
- valve
- glue
- raw material
- temperature
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Abstract
The present invention relates to glue production technique, belong to glue technique technical field；Raw material is prepared from by the material of following weight point：60 80 parts of natural rubber, 10 30 parts of butadiene-styrene rubber, 38 parts of polyisobutene, 28 parts of chlorosulfonated polyethylene, 38 parts of zinc oxide, 0.5 1.5 parts of hard acid ester, 13 parts of age resistor, 6 15 parts of carbon fiber, 35 parts of acrylic acid；The valve closed before drain valve, opens cooling water water intaking valve and is lowered the temperature, when being cooled to 80 82 DEG C, cooling water water intaking valve is closed, while outlet valve is closed after water is drained immediately, by temperature stabilization at 70 DEG C, part material is added, timing when beginning to cool down amounts to 80 minutes together with 70 DEG C of soaking times；Rationally, raw material proportioning is moderate, and procedure of processing is simple and clear, can effectively improve the making quality of glue for technological design, it is to avoid problems of the prior art, reduces cost, expands the application field of glue.
Description
Technical field
The present invention relates to glue production technique, belong to glue technique technical field.
Background technology
Glue is two kinds of intermediates of material of connection, is occurred with aqua more, belongs to fine chemistry industry class, and species is various, mainly with
The sorting technique of sizing, physical aspect, method for curing and adherend material.Common are instant glue (502 common alpha-cyanos third
Olefin(e) acid ethyl ester strength instant adhesive is a kind of), epoxy bond class, anaerobism glue, UV glue (ultraviolet photo-curing class),
PUR, pressure sensitive adhesive, latex class etc..
Glue is exactly that can be bonded two materials of object.Glue is not self-existent, and it must be coated in two objects
Between competence exertion bonding effect.Chemical composition in glue, in aqueous environments.Polymer body in glue is (in white glue
Vinyl acetate is one kind of petroleum derivative) all it is rounded particle, the radius of general particle is between 0.5~5 μm.Object
Bonding, realized by the pulling force between the polymer body in glue.In glue, water is exactly the load of middle polymer body
Body, water ballast polymer body and is immersed in the tissue of object at leisure.After the moisture in glue disappears, the macromolecule in glue
Body just relies on mutual pulling force, by two objects being combined together tightly.In glue when using, glue-spread excessively will
The polymer body in glue is set mutually crowded to can not produce good pulling force together, between polymer body.Polymer body is mutually gathered around
Squeeze, so as to not become attraction most strong each other.Meanwhile, the moisture between polymer body is also not easy to vapor away.Here it is
Why in bonding process the reason for " glued membrane is thicker, the bonding effect of glue is poorer ".Glue-spread is excessive, and glue is played greatly
Be " filling effect " rather than bonding effect, what the bonding between object was leaned on is not the cohesive force of glue, but " the cohesion of glue
Power ".
The range of application of glue is more and more wider, but, existing glue smell is big, and viscosity is small, high cost, in matching somebody with somebody for raw material
More unreasonable than aspect, yield rate is low, and follow-up repetition can be caused to process.
The content of the invention
Defect and deficiency it is an object of the invention to be directed to prior art, there is provided a kind of process is simple, reasonable in design, behaviour
Make convenient glue production technique.
To achieve the above object, the technical solution adopted by the present invention is：It is comprised the steps of：
1st, raw material is prepared：Raw material is prepared from by the material of following weight point：Natural rubber 60-80 parts, butadiene-styrene rubber 10-
30 parts, polyisobutene 3-8 parts, chlorosulfonated polyethylene 2-8 parts, tert butyl phenolic resin 1-3 parts, accelerator 0.2-0.8 parts, oxidation
Zinc 3-8 parts, hard acid ester 0.5-1.5 parts, age resistor 1-3 parts, carbon fiber 6-15 parts, acrylic acid 3-5 parts；
2nd, water, electricity, vapour and status of equipment are checked, the preparation before production is carried out；
3rd, check whether clean in axe, check whether each position valve is normal；
4th, after cleaning reaction ax, base fabric valve is closed, adds the running water of ormal weight；
5th, after opening stirring, regulation pH value to 3-4 (500g/t) is slow afterwards to put into part material；
6th, the valve before the drain valve of chuck bottom is opened, and checks that other valves are closed, then open steam valve, entered
Row heats up, and programming rate is maintained at 1 DEG C/min；
Steam off valve when the 7th, being warming up to (84 DEG C of summer, 86 DEG C of winter), timing when temperature continues to rise to 80-90 DEG C is protected
80-90 DEG C of temperature, time 30-40 minutes；
8th, chuck outlet valve is opened, the valve closed before drain valve is opened cooling water water intaking valve and lowered the temperature, and is cooled to
At 80-82 DEG C, cooling water water intaking valve is closed, while outlet valve is closed after water is drained immediately, by temperature stabilization in 70 DEG C, addition portion
Divide raw material, timing when beginning to cool down amounts to 80 minutes together with 70 DEG C of soaking times；
9th, cooling water water intaking valve is opened again after opening chuck outlet valve after insulation is finished, and the temperature of material is cooled to 40 DEG C
Below；
10th, to other raw materials are sequentially added after 9-10 (900g/t), feeds intake regulation pH value the stirring 15-30 that should continue after finishing
Minute, close cooling water water intaking valve；
11st, stirring is closed, turnover barrel is put well successively, open the discharging of bottom discharge valve；
12nd, the valve before drain valve is opened and is vented water；
13rd, reaction ax inside is rinsed 2-3 times with running water.
Preferably, the age resistor in the step 1 is made up of antioxidant D NP, antioxidant MB, antioxidant 4010.
Preferably, raw material in described step 5 be 70 parts of natural rubber, 20 parts of butadiene-styrene rubber, tert-butyl group phenolic aldehyde tree
2 parts of fat, 5 parts of zinc oxide, 1 part of hard acid ester, 2 parts of age resistor；
Preferably, the raw material in described step 8 is 10 parts of carbon fiber, 4 parts of acrylic acid.
Preferably, the raw material described in described step 10 is 5 parts of polyisobutene, 5 parts of chlorosulfonated polyethylene, accelerator
0.5 part.
Preferably, when adjusting temperature in described step 7, temperature first is risen into 50-60 DEG C, static heating 20 minutes
Left and right, then lift temperature to 80-90 DEG C.
Preferably, when putting into raw material in the step 5, opening agitating device, stirred when pouring into, improve the uniformity.
The present invention has the beneficial effect that：Glue production technique of the present invention, rationally, raw material proportioning is moderate for technological design,
And procedure of processing is simple and clear, can effectively improve the making quality of glue, it is to avoid problems of the prior art, reduce
Cost, expands the application field of glue.
Specific embodiment
Specific embodiment one：
This specific embodiment is comprised the steps of：
1st, raw material is prepared：Raw material is prepared from by the material of following weight point：Natural rubber 60-80 parts, butadiene-styrene rubber 10-
30 parts, polyisobutene 3-8 parts, chlorosulfonated polyethylene 2-8 parts, tert butyl phenolic resin 1-3 parts, accelerator 0.2-0.8 parts, oxidation
Zinc 3-8 parts, hard acid ester 0.5-1.5 parts, age resistor 1-3 parts, carbon fiber 6-15 parts, acrylic acid 3-5 parts；Age resistor is by age resistor
DNP, antioxidant MB, antioxidant 4010 composition.
2nd, water, electricity, vapour and status of equipment are checked, the preparation before production is carried out；
3rd, check whether clean in axe, check whether each position valve is normal；
4th, after cleaning reaction ax, base fabric valve is closed, adds the running water of ormal weight；
5th, after opening stirring, regulation pH value to 3-4 (500g/t) is slow afterwards to put into 70 parts of natural rubber, butadiene-styrene rubber 20
Part, 2 parts of tert butyl phenolic resin, 5 parts of zinc oxide, 1 part of hard acid ester, 2 parts of age resistor：
6th, the valve before the drain valve of chuck bottom is opened, and checks that other valves are closed, then open steam valve, entered
Row heats up, and programming rate is maintained at 1 DEG C/min；
Steam off valve when the 7th, being warming up to (84 DEG C of summer, 86 DEG C of winter), timing when temperature continues to rise to 80-90 DEG C is protected
80-90 DEG C of temperature, time 30-40 minutes；
8th, chuck outlet valve is opened, the valve closed before drain valve is opened cooling water water intaking valve and lowered the temperature, and is cooled to
At 80-82 DEG C, cooling water water intaking valve is closed, while closing outlet valve after water is drained immediately, by temperature stabilization at 70 DEG C, add carbon
10 parts of fiber, 4 parts of acrylic acid, timing when beginning to cool down amount to 80 minutes together with 70 DEG C of soaking times；
9th, cooling water water intaking valve is opened again after opening chuck outlet valve after insulation is finished, and the temperature of material is cooled to 40 DEG C
Below；
10th, regulation pH value is to sequentially adding 5 parts of polyisobutene, 5 parts of chlorosulfonated polyethylene, accelerator after 9-10 (900g/t)
0.5 part, feeds intake stirring 15-30 minutes that should continue after finishing, and closes cooling water water intaking valve；
11st, stirring is closed, turnover barrel is put well successively, open the discharging of bottom discharge valve；
12nd, the valve before drain valve is opened and is vented water；
14th, reaction ax inside is rinsed 2-3 times with running water.
Wherein, when adjusting temperature in described step 7, temperature is first risen into 50-60 DEG C, 20 minutes left sides of static heating
The right side, then lift temperature to 80-90 DEG C；When putting into raw material in the step 5, agitating device is opened, stirred when pouring into, improve equal
Evenness.
Specific embodiment two：
This specific embodiment is with the difference of specific embodiment one：The material system that raw material is divided by following weight
It is standby to form：60 parts of natural rubber, 10 parts of butadiene-styrene rubber, 3 parts of polyisobutene, 2 parts of chlorosulfonated polyethylene, tert butyl phenolic resin 1
Part, 0.2 part of accelerator, 3 parts of zinc oxide, 0.5 part of hard acid ester, 1 part of age resistor, 6 parts of carbon fiber, 3 parts of acrylic acid；Correspondence in step
Raw material proportioning it is identical with the weight portion of above-mentioned raw materials, other steps are identical with specific embodiment one.
Specific embodiment three：
This specific embodiment is with the difference of specific embodiment one：The material system that raw material is divided by following weight
It is standby to form：80 parts of natural rubber, 30 parts of butadiene-styrene rubber, 8 parts of polyisobutene, 8 parts of chlorosulfonated polyethylene, tert butyl phenolic resin 3
Part, 0.8 part of accelerator, 8 parts of zinc oxide, 1.5 parts of hard acid ester, 3 parts of age resistor, 15 parts of carbon fiber, 5 parts of acrylic acid；It is right in step
The raw material proportioning answered is identical with the weight portion of above-mentioned raw materials, and other steps are identical with specific embodiment one.
Rationally, raw material proportioning is moderate, and procedure of processing is simple and clear, can effectively carry for the technological design of this specific embodiment
The making quality of glue high, it is to avoid problems of the prior art, reduces cost, expands the application field of glue.
The above, is merely illustrative of the technical solution of the present invention and unrestricted, and those of ordinary skill in the art are to this hair
Other modifications or equivalent that bright technical scheme is made, without departing from the spirit and scope of technical solution of the present invention,
All should cover in the middle of scope of the presently claimed invention.
Claims (7)
1. glue production technique, it is characterised in that：It is comprised the steps of：
(1) raw material, is prepared：Raw material is prepared from by the material of following weight point：Natural rubber 60-80 parts, butadiene-styrene rubber 10-30
Part, polyisobutene 3-8 parts, chlorosulfonated polyethylene 2-8 parts, tert butyl phenolic resin 1-3 parts, accelerator 0.2-0.8 parts, zinc oxide
3-8 parts, hard acid ester 0.5-1.5 parts, age resistor 1-3 parts, carbon fiber 6-15 parts, acrylic acid 3-5 parts；
(2) water, electricity, vapour and status of equipment, are checked, the preparation before production is carried out；
(3), check whether clean in axe, check whether each position valve is normal；
(4), after cleaning reaction ax, base fabric valve is closed, adds the running water of ormal weight；
(5) after, opening stirring, regulation pH value to 3-4 (500g/t) is slow afterwards to put into part material；
(6) valve before the drain valve of chuck bottom, is opened, and checks that other valves are closed, then open steam valve, carried out
Heat up, programming rate is maintained at 1 DEG C/min；
(7) steam off valve when, being warming up to 80-86 DEG C, timing when temperature continues to rise to 80-90 DEG C, 80-90 DEG C of holding temperature,
Time 30-40 minutes；
(8) chuck outlet valve, is opened, the valve closed before drain valve is opened cooling water water intaking valve and lowered the temperature, and is cooled to 80-
At 82 DEG C, cooling water water intaking valve is closed, while closing outlet valve after water is drained immediately, by temperature stabilization at 70 DEG C, add part
Raw material, timing when beginning to cool down amounts to 80 minutes together with 70 DEG C of soaking times；
(9), insulation finish after i.e. opening chuck outlet valve after open cooling water water intaking valve again, by the temperature of material be cooled to 40 DEG C with
Under；
(10), to other raw materials are sequentially added after 9-10 (900g/t), feeds intake regulation pH value 15-30 points of the stirring that should continue after finishing
Clock, closes cooling water water intaking valve；
(11) stirring, is closed, turnover barrel is put well successively, open the discharging of bottom discharge valve；
(12), the valve before drain valve is opened and is vented water；
(13), reaction ax inside is rinsed 2-3 times with running water.
2. glue production technique according to claim 1, it is characterised in that：Age resistor in the step 1 is by age resistor
DNP, antioxidant MB, antioxidant 4010 composition.
3. glue production technique according to claim 1, it is characterised in that：Raw material in described step 5 is natural rubber
70 parts of glue, 20 parts of butadiene-styrene rubber, 2 parts of tert butyl phenolic resin, 5 parts of zinc oxide, 1 part of hard acid ester, 2 parts of age resistor.
4. glue production technique according to claim 1, it is characterised in that：Raw material in described step 8 is carbon fiber
10 parts, 4 parts of acrylic acid.
5. glue production technique according to claim 1, it is characterised in that：Raw material described in described step 10 is poly-
5 parts of isobutene, 5 parts of chlorosulfonated polyethylene, 0.5 part of accelerator.
6. glue production technique according to claim 1, it is characterised in that：When adjusting temperature in described step 7, first will
Temperature rises to 50-60 DEG C, static heating 20 minutes or so, then lifts temperature to 80-90 DEG C.
7. glue production technique according to claim 1, it is characterised in that：When putting into raw material in the step 5, opening is stirred
Device is mixed, is stirred when pouring into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710123281.3A CN106833402A (en) | 2017-02-22 | 2017-02-22 | Glue production technique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710123281.3A CN106833402A (en) | 2017-02-22 | 2017-02-22 | Glue production technique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106833402A true CN106833402A (en) | 2017-06-13 |
Family
ID=59137161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710123281.3A Pending CN106833402A (en) | 2017-02-22 | 2017-02-22 | Glue production technique |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106833402A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108031399A (en) * | 2017-11-30 | 2018-05-15 | 佛山捷利再生科技有限公司 | Application of the middle water in glue is prepared |
| CN109504322A (en) * | 2018-11-26 | 2019-03-22 | 常州市白鹭电器有限公司 | PE adhesive tape glue |
| CN112757415A (en) * | 2020-12-30 | 2021-05-07 | 江苏馨而美木业有限公司 | Method for manufacturing laminated base material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086354A (en) * | 2009-12-07 | 2011-06-08 | 戚冬梅 | Rubber adhesive |
-
2017
- 2017-02-22 CN CN201710123281.3A patent/CN106833402A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086354A (en) * | 2009-12-07 | 2011-06-08 | 戚冬梅 | Rubber adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 吴民达: "《机械产品胶接密封技术实用手册》", 31 May 1995, 辽宁科学技术出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108031399A (en) * | 2017-11-30 | 2018-05-15 | 佛山捷利再生科技有限公司 | Application of the middle water in glue is prepared |
| CN109504322A (en) * | 2018-11-26 | 2019-03-22 | 常州市白鹭电器有限公司 | PE adhesive tape glue |
| CN112757415A (en) * | 2020-12-30 | 2021-05-07 | 江苏馨而美木业有限公司 | Method for manufacturing laminated base material |
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Application publication date: 20170613 |
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