CN106833247A - A kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof - Google Patents
A kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof Download PDFInfo
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- CN106833247A CN106833247A CN201710115877.9A CN201710115877A CN106833247A CN 106833247 A CN106833247 A CN 106833247A CN 201710115877 A CN201710115877 A CN 201710115877A CN 106833247 A CN106833247 A CN 106833247A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention provides a kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：80 100 parts of acrylic acid modified fluorocarbon resin emulsion, 24 parts of alkynol analog assistant, 36 parts of graphene oxide powder, 6 10 parts of nano-silica powder, 10 15 parts of coalescents, 37 parts of salt spray resistance agent, 6 12 parts of pigment, 5 15 parts of talcum powder, 50 80 parts of deionized water；Product adhesive force of the present invention is extremely strong, coating is strong with basal body binding force, metal oxide nano-material, graphene powder help coating to form an interface transition layer for densification in coating composition, its comprehensive macroscopic property is set to match with matrix, sagging phenomenon can not be produced in arbitrary surface, inclined-plane and spray mo(u)lding on vertical plane.
Description
Technical field
The invention belongs to water paint field, more particularly to a kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof.
Background technology
World today's environmental problem is increasingly severe, and substantial amounts of harmful substance is discharged in the processing of coating and production process
Environmental pollution can be caused and the healthy of workmen is damaged.In order to control to pollute and protect the health of workmen, China
Formulate the use that a series of measures limits VOC coating high.So environment friendly anti-corrosive paint turns into the emphasis of paint development.Numerous
In environment-friendly type coating, water paint is the important directions of development.But current water paint also has that some are technical,
So improve water paint anti-corrosive properties oneself turn into the developing emphasis of environmental protection coating material.
The all excellent of traditional coating is almost covered and surmounted to fluorocarbon coating as a kind of brand-new surface decoration material
Performance, such as super-weathering resistance, excellent chemical proofing, NBC protective performance, excellent environmental suitability are (cold-hot alternation, resistance to dry
Wet alternate) and it is ornamental.The excellent physical and chemical performance of fluorocarbon coating is allowed in the anti-sticking, demoulding, building, color steel, heavy antisepsis, print
The application in the field such as brush circuit and space flight and aviation expands day by day.But, all kinds of fluoropolymers often have the shortcomings that itself again,
As polytetrafluoroethylene (PTFE) (PTFE) and poly- inclined difluoro alkene (PVDF) need high-temperature fusion to solidify, PVF-vinyl ethers (FEVE) and
, although realizing normal temperature cure, the compatibility with other coating is poor, and price is higher in addition, limits for multi-fluoro polyether (PFPE)
The application of fluorocarbon coating.More fully to play and embodying the performance of fluorocarbon coating, while new varieties row are continually developed,
Many researchs are conceived to fluororesin are modified.
Acrylic resin is high through one kind of homopolymerization or copolymerization by esters of acrylic acid and its vinyl unsaturated monomer
Molecularly Imprinted Polymer, acrylic resin backbone structure stabilization, without oxidizable and hydrolysising group, therefore has with its film for preparing
Color is shallow, protect light, protect color, light, it is weather-proof, corrosion-resistant the features such as, its film is to metal (steel, aluminium etc.), ceramics, glass, concrete
Excellent adhesive force is respectively provided with timber isopolarity ground, chemical resistance and electrical insulation capability are excellent, numerous in variety, valency
It is honest and clean to be easy to get.But fluorocarbon coating is modified with acrylic resin prepare acrylic acid modified fluorocarbon coating report it is also little,
It is one important research direction of paint field to develop such high-performance aqueous coating.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof, the painting
Expect to be water paint, environmental-protecting performance is good, and be a kind of high performance acrylic acid modified fluorocarbon coating possess excellent super resistance to
Hou Xing, chemical proofing, and it is ornamental strong, and antiseptic property is splendid.
To solve the above problems, the technical solution adopted by the present invention is：
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Acrylic acid modified fluorine
80-100 parts of carbon resin emulsion, 2-4 parts of alkynol analog assistant, 3-6 parts of graphene oxide powder, nano-silica powder 6-10 parts, into
10-15 parts of film auxiliary agent, 3-7 parts, pigment 6-12 parts, talcum powder 5-15 parts, deionized water 50-80 parts of salt spray resistance agent.
Further preferably, 90 parts of acrylic acid modified fluorocarbon resin emulsion, 3 parts of alkynol analog assistant, 5 parts of graphene oxide powder,
8 parts of nano-silica powder, 12 parts of coalescents, 5 parts of salt spray resistance agent, 9 parts of pigment, 12 parts of talcum powder, 70 parts of deionized water.
Wherein, the preparation method of the acrylic acid modified fluorocarbon resin emulsion is：(1) added in autoclave appropriate
Deionized water 80wt%, NPE 4.8wt%, CTFE 15wt% and sodium acid carbonate 0.2wt%, stirring
After being uniformly dissolved, mixed emulsion is obtained；(2) mixed emulsion is heated to 65 DEG C in taking step (1), adds equivalent to described in (1)
The initiator solution of mixed emulsion quality 20wt%, control temperature is reacted 5-10 minutes at 75 DEG C, is subsequently adding equivalent to (1)
Described in mixed emulsion quality 10wt% hydroxy acid copolymer, continue react 10-30min, under treating system pressure progressively
2 atmospheric pressure are down to, reaction terminates, are cooled to less than 40 DEG C, add ammoniacal liquor, adjust pH, filtering, discharging, packaging is obtained propylene
The fluorocarbon modified resin emulsion of acid.
The initiator is azo-bis-isobutyl cyanide.
The alkynol analog assistant is propilolic alcohol and pentyne alcohol.
The coalescents be selected from polyethylene glycol, one or more the group in propane diols phenylate, butyl glycol ether
Close.
The salt spray resistance agent is ZT-719 salt spray resistance agent.
The pigment is in trbasic zinc phosphate, aluminium triphosphate, zinc aluminophosphate, Ion exchange anticorrosive pigment and phosphorus zinc silicate
One or more mixing.
In addition, the preparation method of environment-friendly type fluorine carbon anticorrosive paint of the present invention, concretely comprises the following steps：By formula will first go from
Sub- water is added in the container of agitator, and agitator is started with the rotating speed of 1800r/min, is separately added into graphene oxide powder, nanometer
Silicon dioxide powder, talcum powder after stirring 20-30min, adds acrylic acid modified fluorocarbon resin emulsion, alkynol analog assistant and into
Film auxiliary agent stirs 20-30min, salt spray resistance agent is added afterwards and pigment continues to stir 40-60min, filters barrelling, obtains final product described
Environment-friendly type fluorine carbon anticorrosive paint.
Technique effect of the invention is：(1) present invention is modified by acrylic resin to fluorine carbon emulsion, is on the one hand possessed
Traditional fluorocarbon resin drying speed, hardness high, good toughness, weather-proof and chemicals-resistant a little, on the other hand due to introducing third
Olefin(e) acid resin, hence it is evident that improve the antiseptic property and dicoration of fluorocarbon resin；(2) product thickness of dry film of the present invention is then in 300um
More than, with remarkable weatherability, anti-aging, wear-resisting, impact resistance and heat endurance, can at -50 DEG C -200 DEG C long-term use；
(3) product adhesive force of the present invention is extremely strong, and coating is strong with basal body binding force, metal oxide nano-material, stone in coating composition
Black alkene powder helps coating to form an interface transition layer for densification, its comprehensive macroscopic property is matched with matrix, can be
Arbitrary surface, inclined-plane and spray mo(u)lding on vertical plane, sagging phenomenon is not produced.
Specific embodiment
Technical scheme is further elaborated with reference to embodiment：
Embodiment 1
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Acrylic acid modified fluorine
90 parts of carbon resin emulsion, 3 parts of alkynol analog assistant propilolic alcohol, 5 parts of graphene oxide powder, 8 parts of nano-silica powder, coalescents
12 parts of polyethylene glycol, 5 parts of salt spray resistance agent ZT-719 salt spray resistances agent, 9 parts of pigment zinc aluminophosphate, 12 parts of talcum powder, deionized water 70
Part.
Embodiment 2
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Acrylic acid modified fluorine
80 parts of carbon resin emulsion, 2 parts of alkynol analog assistant propilolic alcohol, 3 parts of graphene oxide powder, 6 parts of nano-silica powder, coalescents
10 parts of propane diols phenylate, 3 parts of salt spray resistance agent ZT-719 salt spray resistances agent, 6 parts of pigment phosphorus zinc silicate, 5 parts of talcum powder, deionized water 50
Part.
Embodiment 3
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Acrylic acid modified fluorine
100 parts of carbon resin emulsion, 4 parts of alkynol analog assistant pentyne alcohol, 6 parts of graphene oxide powder, 10 parts of nano-silica powder, film forming is helped
15 parts of agent butyl glycol ether, 7 parts of salt spray resistance agent ZT-719 salt spray resistances agent, 12 parts of pigment phosphorus zinc silicate, 15 parts of talcum powder, deionization
80 parts of water.
Embodiment 4
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Acrylic acid modified fluorine
85 parts of carbon resin emulsion, 3 parts of alkynol analog assistant pentyne alcohol, 4 parts of graphene oxide powder, 7 parts of nano-silica powder, coalescents
12 parts of butyl glycol ether, 4 parts of salt spray resistance agent ZT-719 salt spray resistances agent, 8 parts of pigment trbasic zinc phosphate, 8 parts of talcum powder, deionized water 60
Part.
Embodiment 5
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Acrylic acid modified fluorine
95 parts of carbon resin emulsion, 3 parts of alkynol analog assistant pentyne alcohol, 5 parts of graphene oxide powder, 9 parts of nano-silica powder, coalescents
14 parts of propane diols phenylate, 6 parts of salt spray resistance agent ZT-719 salt spray resistances agent, 10 parts of pigment aluminium triphosphate, 12 parts of talcum powder, deionization
70 parts of water.
Comparative example 1
A kind of environment-friendly type fluorine carbon anticorrosive paint, by weight, the coating is made up of following components：Fluorocarbon resin emulsion
90 parts, 3 parts of alkynol analog assistant propilolic alcohol, 5 parts of graphene oxide powder, 8 parts of nano-silica powder, coalescents polyethylene glycol 12
Part, 5 parts of salt spray resistance agent ZT-719 salt spray resistances agent, 9 parts of pigment zinc aluminophosphate, 12 parts of talcum powder, 70 parts of deionized water.
Embodiment 6
The preparation method of embodiment 1-5 and environment-friendly type fluorine carbon anticorrosive paint described in comparative example 1, concretely comprises the following steps：By matching somebody with somebody
Side first adds deionized water in the container of agitator, and agitator is started with the rotating speed of 1800r/min, is separately added into graphite oxide
Alkene powder, nano-silica powder, talcum powder after stirring 25min, adds acrylic acid modified fluorocarbon resin emulsion, and alkynol class is helped
Agent and coalescents stirring 25min, add salt spray resistance agent afterwards and pigment continues to stir 50min, filter barrelling, obtain final product described
Environment-friendly type fluorine carbon anticorrosive paint.
The environment-friendly type fluorine carbon anticorrosive paint performance prepared by above-described embodiment 1-5 and the formula of comparative example 1 is listed in table 1.
Finally it should be noted that：The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention,
Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used
Modified with to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic.
All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in of the invention
Within protection domain.
Claims (9)
1. a kind of environment-friendly type fluorine carbon anticorrosive paint, it is characterised in that by weight, the coating is made up of following components：Third
Fluorocarbon modified resin emulsion 80-100 parts of olefin(e) acid, 2-4 parts of alkynol analog assistant, 3-6 parts of graphene oxide powder, nano-silica powder
6-10 parts, coalescents 10-15 parts, 3-7 parts, pigment 6-12 parts, talcum powder 5-15 parts, deionized water 50-80 parts of salt spray resistance agent.
2. environment-friendly type fluorine carbon anticorrosive paint according to claim 1, it is characterised in that acrylic acid modified fluorocarbon resin emulsion
90 parts, 3 parts of alkynol analog assistant, 5 parts of graphene oxide powder, 8 parts of nano-silica powder, 12 parts of coalescents, salt spray resistance agent 5
Part, 9 parts of pigment, 12 parts of talcum powder, 70 parts of deionized water.
3. environment-friendly type fluorine carbon anticorrosive paint according to claim 2, it is characterised in that the acrylic acid modified fluorocarbon resin
The preparation method of emulsion is：(1) appropriate amount of deionized water 80wt%, NPE are added in autoclave
4.8wt%, CTFE 15wt% and sodium acid carbonate 0.2wt%, after stirring and dissolving is uniform, obtain mixed emulsion；(2) step is taken
Suddenly mixed emulsion is heated to 65 DEG C in (1), adds the initiator solution equivalent to mixed emulsion quality 20wt% described in (1),
Control temperature is reacted 5-10 minutes at 75 DEG C, is subsequently adding the hydroxyl third equivalent to mixed emulsion quality 10wt% described in (1)
Olefin(e) acid copolymer, continues to react 10-30min, treats that system pressure progressively drops to 2 atmospheric pressure, and reaction terminates, and is cooled to 40 DEG C
Hereinafter, ammoniacal liquor is added, pH is adjusted, filtering, discharging, packaging is obtained acrylic acid modified fluorocarbon resin emulsion.
4. environment-friendly type fluorine carbon anticorrosive paint according to claim 3, it is characterised in that the initiator is the isobutyl of azo two
Cyanogen.
5. environment-friendly type fluorine carbon anticorrosive paint according to claim 4, it is characterised in that the alkynol analog assistant is propilolic alcohol
With pentyne alcohol.
6. according to claim 1-5 environment-friendly type fluorine carbon anticorrosive paints, it is characterised in that the coalescents be selected from polyethylene glycol,
One or more combination in propane diols phenylate, butyl glycol ether.
7. environment-friendly type fluorine carbon anticorrosive paint according to claim 6, it is characterised in that the salt spray resistance agent is that ZT-719 is resistance to
Salt fog agent.
8. environment-friendly type fluorine carbon anticorrosive paint according to claim 6, it is characterised in that the pigment is trbasic zinc phosphate, trimerization
One or more mixing in aluminum phosphate, zinc aluminophosphate, Ion exchange anticorrosive pigment and phosphorus zinc silicate.
9. according to claim any one of 1-8 environment-friendly type fluorine carbon anticorrosive paint preparation method, it is characterised in that step
For：First deionized water is added by formula in the container of agitator, agitator is started with the rotating speed of 1800r/min, be separately added into
Graphene oxide powder, nano-silica powder, talcum powder after stirring 20-30min, adds acrylic acid modified fluorocarbon resin breast
Liquid, alkynol analog assistant and coalescents stirring 20-30min, add salt spray resistance agent afterwards and pigment continues to stir 40-60min,
Filtering barrelling, obtains final product the environment-friendly type fluorine carbon anticorrosive paint.
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| CN201710115877.9A CN106833247A (en) | 2017-02-28 | 2017-02-28 | A kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof |
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| CN201710115877.9A CN106833247A (en) | 2017-02-28 | 2017-02-28 | A kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof |
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Cited By (6)
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|---|---|---|---|---|
| CN108359342A (en) * | 2018-03-25 | 2018-08-03 | 王丽燕 | A kind of aqueous environment protection coating and its preparation method and application |
| CN108864884A (en) * | 2018-07-16 | 2018-11-23 | 安徽博泰氟材料科技有限公司 | A kind of environment-friendly degradable F-C paint and preparation method thereof |
| CN110229571A (en) * | 2019-06-20 | 2019-09-13 | 中国铁路广州局集团有限公司 | Novel bottom surface unification zinc alkene anticorrosive paint, preparation method and finishing system |
| CN113717603A (en) * | 2021-10-11 | 2021-11-30 | 广西民族大学 | Modified fluorocarbon anticorrosive paint and preparation method thereof |
| CN116042027A (en) * | 2023-01-08 | 2023-05-02 | 江苏考普乐新材料股份有限公司 | Temperature-resistant coating for aerospace equipment |
| CN117551369A (en) * | 2024-01-10 | 2024-02-13 | 德施普(辽宁)新材料技术有限公司 | Polychlorotrifluoroethylene-based paint and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108864884A (en) * | 2018-07-16 | 2018-11-23 | 安徽博泰氟材料科技有限公司 | A kind of environment-friendly degradable F-C paint and preparation method thereof |
| CN110229571A (en) * | 2019-06-20 | 2019-09-13 | 中国铁路广州局集团有限公司 | Novel bottom surface unification zinc alkene anticorrosive paint, preparation method and finishing system |
| CN110229571B (en) * | 2019-06-20 | 2021-06-22 | 中国铁路广州局集团有限公司 | Novel primer-topcoat zinc-olefin anticorrosive paint, preparation method and coating system |
| CN113717603A (en) * | 2021-10-11 | 2021-11-30 | 广西民族大学 | Modified fluorocarbon anticorrosive paint and preparation method thereof |
| CN113717603B (en) * | 2021-10-11 | 2022-07-12 | 广西民族大学 | Modified fluorocarbon anticorrosive paint and preparation method thereof |
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| CN117551369A (en) * | 2024-01-10 | 2024-02-13 | 德施普(辽宁)新材料技术有限公司 | Polychlorotrifluoroethylene-based paint and preparation method thereof |
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Application publication date: 20170613 |