CN106833042B - Special coating for hot steel billet marking machine - Google Patents

Special coating for hot steel billet marking machine Download PDF

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Publication number
CN106833042B
CN106833042B CN201710098992.XA CN201710098992A CN106833042B CN 106833042 B CN106833042 B CN 106833042B CN 201710098992 A CN201710098992 A CN 201710098992A CN 106833042 B CN106833042 B CN 106833042B
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China
Prior art keywords
nano
steel billet
special coating
steel
hot steel
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CN201710098992.XA
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Chinese (zh)
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CN106833042A (en
Inventor
饶刚
吴栋
郭锋
邹鹏超
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Yingkou Ccid Technology Co Ltd
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Yingkou Ccid Technology Co Ltd
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Priority to CN201710098992.XA priority Critical patent/CN106833042B/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

The special coating for hot steel billet number spraying machine comprises, by weight, 10-15% of nano titanium dioxide, 2-5% of nano zirconium oxide, 2-5% of sodium dihydrogen phosphate, 5-10% of nano barium sulfate, 5-15% of nano rare earth micro powder, 2-5% of dispersant, 2-5% of aluminum sulfate and the balance of water. The paint is used for spraying codes, marks and writing marks are clear, and the paint is wear-resistant, waterproof and not easy to fall off. No toxicity and pollution, and its temp. resistance is up to 2000 deg.C. The spray gun is suitable for high-temperature environments of steel plants, can be applied to imported and domestic various spray gun lengths, does not block the spray gun, is non-toxic, environment-friendly, pollution-free, flame-retardant and antioxidant. The steel mixing accident caused by unclear marks in the steel plant is completely avoided.

Description

Special coating for hot steel billet marking machine
Technical Field
The invention relates to a special coating for a hot steel billet marking machine, belonging to the technical field of metal material surface spraying.
Background
With the rapid development of the steel industry, metal castings are more and more widely applied under the condition of high-temperature working conditions. After the continuous casting and drawing billet comes out, the surface is required to be marked, and the steel mixing event of various materials caused by unclear marks is eliminated. The marking materials applied at present in China comprise paint, aluminum wires and copper wires. In practical application, the temperature of the coating can generally resist about 300 ℃, and the effect is not ideal when the temperature is higher than 300 ℃, because the components are generally phenolic aldehyde, modified epoxy coating and organosilicon coating, the temperature resistance is poor, and the coating is inflammable. And materials such as aluminum, copper and the like have high cost, a large amount of electric energy needs to be consumed to dissolve the materials into liquid to spray, the mechanical failure rate is high, and the actual production requirements cannot be met.
Disclosure of Invention
In order to solve the existing problems, the invention provides a special coating for a hot steel billet marking machine, which can resist high temperature up to 2000 ℃.
The purpose of the invention is realized by the following technical scheme: the special coating for the hot steel billet number spraying machine is characterized by comprising, by weight, 10-15% of nano titanium dioxide, 2-5% of nano zirconium oxide, 2-5% of sodium dihydrogen phosphate, 5-10% of nano barium sulfate, 5-15% of nano rare earth micro powder, 2-5% of a dispersing agent, 2-5% of aluminum sulfate and the balance of water.
The preferable mixture ratio is as follows: 15% of nano titanium dioxide, 5% of nano zirconium oxide, 3% of sodium dihydrogen phosphate, 10% of nano barium sulfate, 10% of nano rare earth micro powder, 2% of dispersing agent, 3% of aluminum sulfate and 52% of water.
The special coating for the hot steel billet marking machine comprises the following preparation methods: the preparation method comprises the steps of preparing the raw materials except water according to the ratio by metering, premixing the prepared raw materials for 3-5 minutes by using stirring equipment, adding water for stirring, stirring for 10-20 minutes to obtain a coating, and filling by using a filling machine.
The invention has the beneficial effects that: the invention adopts the scheme, is an innovation for the high-temperature coating, and the selected materials have heat resistance and non-combustibility. When the paint is used, the paint and the surface of steel react quickly to generate an inorganic polymer with a three-dimensional structure, the coating and the surface of steel are connected into a whole, and the paint is used for spraying codes, labels and handwriting marks clearly, is wear-resistant and waterproof and is not easy to fall off. No toxicity and pollution, and its temp. resistance is up to 2000 deg.C. The spray gun is suitable for high-temperature environments of steel plants, can be applied to imported and domestic various spray gun lengths, does not block the spray gun, is non-toxic, environment-friendly, pollution-free, flame-retardant and antioxidant. The steel mixing accident caused by unclear marks in the steel plant is completely avoided.
Detailed Description
The special coating for the hot steel billet spray marking machine comprises the following components in percentage by weight:
example 1 Example 2 Example 3
Nano titanium dioxide 15% 10% 12%
Nano zirconium oxide 5% 2% 5%
Sodium dihydrogen phosphate 3% 3% 5%
Nano barium sulfate 10% 6% 5%
Nano rare earth micro powder 10% 8% 15%
Dispersing agent 2% 5% 2%
Aluminium sulphate 3% 5% 2%
Water (W) 52% 61% 54%
The preparation process comprises the following steps: the preparation method comprises the steps of preparing the raw materials except water according to the ratio by metering, premixing the prepared raw materials for 3-5 minutes by using stirring equipment, adding water for stirring, stirring for 10-20 minutes to obtain a coating, and filling by using a filling machine.
The performance indexes of the special coating for the hot steel billet spray marking machine prepared in the embodiment are shown in the following table:
serial number Item Technical index Test method
1 Density g/cm3 1.17 GB/T1724
2 Solid content by volume 63% GB/T1725
3 Appearance of coating film Smooth, milky white and matt GB/T1729
4 Fineness of mum ≤ 55 GB/T1724
5 Viscosity (25 ℃) scribble-4 viscometer 25 GB/T1723
6 Drying time (25 +/-1 ℃) h Surface dryness is less than or equal to 0.5; solid stem is less than or equal to 2 GB/T1728
7 Grade of adhesion 1 GB/T1720
8 Hardness H of coating film ≥ 8 GB/T6739
9 Heat resistance (several hours at 2000 ℃) without falling off GB/T1733
The special coating for the hot steel billet number spraying machine prepared by the method can be directly sprayed on hot steel billets, steel pieces, continuous casting slabs and hot rolling coils at the temperature of 200-2000 ℃, and the sprayed marks are not easy to fall off and are not discolored.

Claims (2)

1. The special coating for the hot steel billet number spraying machine is characterized by comprising the following components, by weight, 10% of nano titanium dioxide, 2% of nano zirconium oxide, 3% of sodium dihydrogen phosphate, 6% of nano barium sulfate, 8% of nano rare earth micro powder, 5% of a dispersing agent, 5% of aluminum sulfate and 61% of water.
2. The special coating for the hot steel billet spray marking machine according to claim 1, which is prepared by the following steps: the preparation method comprises the steps of preparing the raw materials except water according to the ratio by metering, premixing the prepared raw materials for 3-5 minutes by using stirring equipment, adding water for stirring, stirring for 10-20 minutes to obtain a coating, and filling by using a filling machine.
CN201710098992.XA 2017-02-23 2017-02-23 Special coating for hot steel billet marking machine Active CN106833042B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710098992.XA CN106833042B (en) 2017-02-23 2017-02-23 Special coating for hot steel billet marking machine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710098992.XA CN106833042B (en) 2017-02-23 2017-02-23 Special coating for hot steel billet marking machine

Publications (2)

Publication Number Publication Date
CN106833042A CN106833042A (en) 2017-06-13
CN106833042B true CN106833042B (en) 2020-01-10

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Application Number Title Priority Date Filing Date
CN201710098992.XA Active CN106833042B (en) 2017-02-23 2017-02-23 Special coating for hot steel billet marking machine

Country Status (1)

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CN (1) CN106833042B (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101462858A (en) * 2009-01-16 2009-06-24 中国科学院过程工程研究所 Inorganic coating for high temperature steel member label
CN104673054A (en) * 2015-03-10 2015-06-03 江苏欣安新材料技术有限公司 Nano magnesium-aluminum anti-corrosion coating and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013139257A1 (en) * 2012-03-19 2013-09-26 东莞市海格瑞化工有限公司 Burn-free colored glaze material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101462858A (en) * 2009-01-16 2009-06-24 中国科学院过程工程研究所 Inorganic coating for high temperature steel member label
CN104673054A (en) * 2015-03-10 2015-06-03 江苏欣安新材料技术有限公司 Nano magnesium-aluminum anti-corrosion coating and preparation method thereof

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