CN110591523A - High-flash-point alkyd resin protective coating and preparation method and application thereof - Google Patents

High-flash-point alkyd resin protective coating and preparation method and application thereof Download PDF

Info

Publication number
CN110591523A
CN110591523A CN201910898201.0A CN201910898201A CN110591523A CN 110591523 A CN110591523 A CN 110591523A CN 201910898201 A CN201910898201 A CN 201910898201A CN 110591523 A CN110591523 A CN 110591523A
Authority
CN
China
Prior art keywords
alkyd resin
protective coating
parts
flash
resin protective
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201910898201.0A
Other languages
Chinese (zh)
Inventor
谢海
胡明
钱金均
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Champion Technology Group Co Ltd
Original Assignee
Jiangsu Champion Technology Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Champion Technology Group Co Ltd filed Critical Jiangsu Champion Technology Group Co Ltd
Priority to CN201910898201.0A priority Critical patent/CN110591523A/en
Publication of CN110591523A publication Critical patent/CN110591523A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2262—Oxides; Hydroxides of metals of manganese
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2289—Oxides; Hydroxides of metals of cobalt
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates

Abstract

The invention provides a high-flash-point alkyd resin protective coating as well as a preparation method and application thereof, belonging to the technical field of coatings. The invention provides a high-flash-point alkyd resin protective coating which comprises the following components in parts by weight: 60-65 parts of alkyd resin; 15-20 parts of titanium dioxide; 5-15 parts of barium sulfate; 5-10 parts of alcohol ether solvent; 0.3-0.4 part of fumed silica; 0.2-0.4 part of wetting agent; 0.3-0.5 part of a dispersing agent; 0.7-1 part of a drier; 0.2-0.3 part of anti-skinning agent. The alkyd resin protective coating is prepared by taking alkyd resin as a main body, adding an alcohol ether solvent, titanium dioxide, barium sulfate and fumed silica, and under the action of a wetting agent, a dispersing agent, a drier and an anti-skinning agent, the obtained alkyd resin protective coating is high in flash point and is safer in the production, transportation and use processes; excellent acid resistance, alkali resistance, weather resistance and other properties; and the toxicity is low, and the environment is protected.

Description

High-flash-point alkyd resin protective coating and preparation method and application thereof
Technical Field
The invention relates to the technical field of coatings, and particularly relates to a high-flash-point alkyd resin protective coating as well as a preparation method and application thereof.
Background
The solvent-based coating has high decoration, durable protection and multifunction, and is widely applied in the fields of modern industry, national defense, information, biochemistry, new materials, aerospace, ocean development, renewable energy development, environmental protection and the like. The organic solvent in the solvent-based paint plays a critical role, for example, the organic solvent can reduce the surface tension of the paint, improve the wetting and dispersing performance of the pigment, adjust the viscosity of film-forming material resin and the paint, improve the fluidity of the paint and the like, so that the paint product meets different paint making requirements and construction requirements.
However, most of organic solvents adopted by the existing solvent-based paint are flammable and volatile, pollute the environment and are harmful to human bodies, and especially the low flash point of the organic solvents causes great potential safety hazards to the paint in the production, transportation and use processes; in addition, in the processes of production, construction, drying, curing and film forming of the solvent-based coating, Volatile Organic Compounds (VOC) contained in the solvent-based coating are emitted into the air in the form of gaseous molecules, so that the environment pollution is caused, and meanwhile, the threat to the human health is also formed.
Disclosure of Invention
The invention aims to provide a high-flash-point alkyd resin protective coating, and a preparation method and application thereof.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a high flash point alkyd resin protective coating which comprises the following components in parts by weight:
60-65 parts of alkyd resin;
15-20 parts of titanium dioxide;
5-15 parts of barium sulfate;
5-10 parts of an alcohol ether solvent;
0.3-0.4 part of fumed silica;
0.2-0.4 part of wetting agent;
0.3-0.5 part of a dispersing agent;
0.7-1 part of a drier;
0.2-0.3 part of anti-skinning agent.
Preferably, the alkyd resin is prepared by high-temperature reaction of natural vegetable oil; the high-temperature reaction is carried out at the temperature of 180-200 ℃ for 14-15 h.
Preferably, the titanium dioxide is rutile titanium dioxide.
Preferably, the particle size of the barium sulfate is 1100-1300 meshes.
Preferably, the alcohol ether solvent comprises one or more of diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, diethylene glycol ethyl ether and tripropylene glycol methyl ether.
Preferably, the drier comprises one or more of metal oxide, metal salt and rare earth drier.
Preferably, the metals in the metal oxide and metal salt independently comprise cobalt, manganese, iron, zinc or calcium.
The invention provides a preparation method of the high-flash-point alkyd resin protective coating, which comprises the following steps:
mixing and grinding part of alcohol ether solvent, part of alkyd resin, wetting agent, dispersing agent, fumed silica, titanium dioxide and barium sulfate to obtain slurry;
and mixing the slurry, the residual alkyd resin, the drier, the residual alcohol ether solvent and the anti-skinning agent to obtain the alkyd resin protective coating.
Preferably, the partial alcohol ether solvent accounts for 75-85% of the total mass of the alcohol ether solvent;
the part of alkyd resin accounts for 65-75% of the total mass of the alkyd resin;
the fineness of the solid particles of the slurry is less than or equal to 30 mu m.
The invention also provides application of the high-flash-point alkyd resin protective coating or the alkyd resin protective coating prepared by the preparation method in industrial corrosion prevention.
The invention provides a high flash point alkyd resin protective coating which comprises the following components in parts by weight: 60-65 parts of alkyd resin; 15-20 parts of titanium dioxide; 5-15 parts of barium sulfate; 5-10 parts of alcohol ether solvent; 0.3-0.4 part of fumed silica; 0.2-0.4 part of wetting agent; 0.3-0.5 part of a dispersing agent; 0.7-1 part of a drier; 0.2-0.3 part of anti-skinning agent. The alkyd resin protective coating is prepared by taking alkyd resin as a main body, adding an alcohol ether solvent, titanium dioxide, barium sulfate and fumed silica, and under the action of a wetting agent, a dispersing agent, a drier and an anti-skinning agent, has a high flash point, is safer in the production, transportation and use processes, and belongs to a safe protective coating; excellent acid resistance, alkali resistance, weather resistance and other properties; and the toxicity is low, and the environment is protected.
The invention provides a preparation method of the high-flash-point alkyd resin protective coating, which is simple to operate and suitable for large-scale production.
Detailed Description
The invention provides a high flash point alkyd resin protective coating which comprises the following components in parts by weight:
60-65 parts of alkyd resin;
15-20 parts of titanium dioxide;
5-15 parts of barium sulfate;
5-10 parts of an alcohol ether solvent;
0.3-0.4 part of fumed silica;
0.2-0.4 part of wetting agent;
0.3-0.5 part of a dispersing agent;
0.7-1 part of a drier;
0.2-0.3 part of anti-skinning agent.
In the present invention, all the raw material components are commercially available products well known to those skilled in the art unless otherwise specified.
In the invention, the raw materials for preparing the high-flash-point alkyd resin protective coating comprise, by weight, 60-65 parts of alkyd resin, preferably 61-65 parts of alkyd resin, and more preferably 61 parts, 62 parts, 63 parts, 64 parts or 65 parts of alkyd resin. In the invention, the alkyd resin protective coating is not easy to dry when the dosage of the alkyd resin is too large, and the film cannot be formed and the paint film performance is poor when the dosage of the alkyd resin is too small. In the invention, the alkyd resin is preferably prepared from natural vegetable oil through a high-temperature reaction. In the invention, in the high-temperature reaction process, the natural vegetable oil is subjected to alcoholysis and then polymerization. In the present invention, the natural vegetable oil preferably includes one or more of soybean oil, linseed oil and cottonseed oil, and more preferably soybean oil, linseed oil or cottonseed oil. In the invention, the temperature of the high-temperature reaction is preferably 180-200 ℃, and more preferably 185-195 ℃; the high-temperature reaction time is preferably 14-15 h, and more preferably 15 h. After the high-temperature reaction is finished, the invention preferably also comprises the steps of adding diethylene glycol butyl ether and/or diethylene glycol methyl ether solvent to adjust the viscosity of the obtained resin; in the invention, the viscosity of the alkyd resin is preferably 250-350 s (coating-4 viscometer, 25 ℃). The paint prepared by taking the alkyd resin as a film forming substance has a higher flash point than a paint prepared by directly taking natural vegetable oil as a raw material, and the alkyd resin protective paint provided by the invention has good adhesive force, flexibility, alkali resistance, acid resistance, wear resistance and weather resistance, is high in hardness, smooth and fine in paint film, non-toxic and pollution-free, and can effectively prolong the service life of the paint film of the alkyd resin protective paint.
In the invention, on the basis of the weight parts of the alkyd resin, the raw materials for preparing the high-flash-point alkyd resin protective coating comprise 15-20 parts of titanium dioxide, preferably 16-20 parts, and more preferably 16 parts, 17 parts, 18 parts, 19 parts or 20 parts. In the invention, the film forming effect of the alkyd resin protective coating can be influenced by excessive use of the titanium dioxide, and the color of the alkyd resin protective coating can be influenced by excessive use of the titanium dioxide. In the invention, the titanium dioxide is preferably rutile type titanium dioxide, and more preferably chloride rutile type titanium dioxide. According to the invention, the titanium dioxide is used in combination with other raw materials, so that the performance of the alkyd resin protective coating can be improved.
In the invention, the raw materials for preparing the high flash point alkyd resin protective coating comprise, by weight, 5-15 parts of barium sulfate, preferably 6-15 parts of barium sulfate, and more preferably 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts of barium sulfate. In the present invention, the particle size of the barium sulfate is preferably 1100 to 1300 mesh, more preferably 1150 to 1250 mesh, and most preferably 1200 mesh. In the present invention, the barium sulfate functions as a filler; the film forming effect of the alkyd resin protective coating can be influenced by too much barium sulfate, and the mechanical property of a paint film of the alkyd resin protective coating can be influenced by too little barium sulfate. The invention uses the barium sulfate and other raw materials in a matching way, and can improve the performance of the alkyd resin protective coating.
In the invention, based on the weight parts of the alkyd resin, the raw materials for preparing the high-flash-point alkyd resin protective coating comprise 5-10 parts of alcohol ether solvent, preferably 6-10 parts, and more preferably 6 parts, 7 parts, 8 parts, 9 parts or 10 parts. In the invention, the alcohol ether solvent preferably comprises one or more of diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, diethylene glycol ethyl ether and tripropylene glycol methyl ether. In the invention, too much or too little of the alcohol ether solvent can affect the viscosity of the alkyd resin protective coating, and further affect the film forming effect and performance of the alkyd resin protective coating. The alcohol ether solvent is matched with other raw materials for use, so that the performance of the alkyd resin protective coating can be improved.
In the invention, the raw materials for preparing the high flash point alkyd resin protective coating comprise, by weight, 0.3-0.4 part of fumed silica, preferably 0.32-0.4 part, more preferably 0.32 part, 0.34 part, 0.36 part, 0.38 part or 0.40 part of fumed silica. In the present invention, the fumed silica functions to prevent precipitation of other raw materials; the excessive using amount of the fumed silica can cause the viscosity of the alkyd resin protective coating to be too high, and the excessive using amount cannot achieve the anti-settling effect. According to the invention, the fumed silica is used in combination with other raw materials, so that the performance of the alkyd resin protective coating can be improved.
In the invention, the raw materials for preparing the high flash point alkyd resin protective coating comprise 0.2-0.4 part of wetting agent, preferably 0.22-0.4 part, more preferably 0.25 part, 0.3 part, 0.35 part or 0.40 part by weight of alkyd resin. The present invention is not particularly limited with respect to the specific kind of the wetting agent, and any wetting agent known in the art, such as silicone oil, may be used. In the invention, the wetting agent is used for wetting pigment and filler, so that the grinding efficiency of titanium dioxide and barium sulfate and the coating of alkyd resin on other raw materials are improved, and the raw materials such as titanium dioxide and barium sulfate are prevented from flooding; too much of the wetting agent can cause shrinkage cavity of the alkyd resin protective paint film, and too little of the wetting agent can cause the paint film of the alkyd resin protective paint to be colored. The wetting agent is matched with other raw materials for use, so that the performance of the alkyd resin protective coating can be improved.
In the invention, the raw materials for preparing the high flash point alkyd resin protective coating comprise 0.3-0.5 part of dispersant, preferably 0.35-0.5 part, more preferably 0.35 part, 0.4 part, 0.45 part or 0.5 part by weight of alkyd resin. In the present invention, the dispersant preferably includes a phosphate-based dispersant. In the present invention, the dispersant functions to disperse the pigment filler; when the amount of the dispersant is too much, the drying of a paint film of the alkyd resin protective paint is slow, and when the amount of the dispersant is too little, the paint film of the alkyd resin protective paint is loose and the paint is precipitated. The invention uses the dispersant and other raw materials in a matching way, and can improve the performance of the alkyd resin protective coating.
In the invention, the raw materials for preparing the high flash point alkyd resin protective coating comprise, by weight, 0.7-1 part of a drier, preferably 0.75-1 part, more preferably 0.75 part, 0.8 part, 0.85 part, 0.9 part, 0.95 part or 1 part of an alkyd resin. In the invention, the drier comprises one or more of metal oxide, metal salt and rare earth drier; the metal in the metal oxide and metal salt independently comprises cobalt, manganese, iron, zinc or calcium. In the invention, the drier is used for accelerating the drying of a paint film of the alkyd resin protective paint; the alkyd resin protective coating is easy to crust when the usage amount of the drier is too much, and the paint film of the alkyd resin protective coating is not easy to dry when the usage amount is too little. The invention uses the drier and other raw materials in a matching way, and can improve the performance of the alkyd resin protective coating.
In the invention, the raw materials for preparing the high flash point alkyd resin protective coating comprise 0.2-0.3 part of anti-skinning agent, preferably 0.22-0.3 part, more preferably 0.22 part, 0.24 part, 0.26 part, 0.28 part or 0.3 part by weight of alkyd resin. The invention has no special limitation on the type of the anti-skinning agent, and the anti-skinning agent well known in the art can be adopted, such as methyl ethyl ketoxime. In the invention, the anti-skinning agent is used for preventing the alkyd resin protective paint from skinning during storage; the anti-skinning agent is used in an excessive amount, so that a paint film of the alkyd resin protective paint is not dried, and the anti-skinning effect cannot be achieved due to the use of an excessive amount. The anti-skinning agent is matched with other raw materials, so that the performance of the alkyd resin protective coating can be improved.
The alkyd resin protective coating is prepared by taking alkyd resin as a main body, adding an alcohol ether solvent, titanium dioxide, barium sulfate and fumed silica, and under the action of a wetting agent, a dispersing agent, a drier and an anti-skinning agent, the obtained alkyd resin protective coating is high in flash point and is safer in the production, transportation and use processes; excellent acid resistance, alkali resistance, weather resistance and other properties; and the toxicity is low, and the environment is protected.
The invention also provides a preparation method of the high flash point alkyd resin protective coating, which comprises the following steps:
mixing and grinding part of alcohol ether solvent, part of alkyd resin, wetting agent, dispersing agent, fumed silica, titanium dioxide and barium sulfate to obtain slurry;
and mixing the slurry, the residual alkyd resin, the drier, the residual alcohol ether solvent and the anti-skinning agent to obtain the alkyd resin protective coating.
In the invention, partial alcohol ether solvent, partial alkyd resin, wetting agent, dispersing agent, fumed silica, titanium dioxide and barium sulfate are mixed and ground to obtain slurry.
In the present invention, the part of the alkyd resin preferably accounts for 65 to 75% of the total mass of the alkyd resin, more preferably 68 to 72%, and most preferably 70%. In the invention, the part of the alcohol ether solvent preferably accounts for 75-85% of the total mass of the alcohol ether solvent, more preferably 78-82%, and most preferably 80%.
In the invention, the mixing is preferably stirring mixing, and the stirring mixing speed is preferably 800-1000 rpm, more preferably 850-1000 rpm, and most preferably 900-1000 rpm; the invention adopts high stirring speed, and can improve the dispersion uniformity of the raw materials. In the invention, the mixing sequence is preferably that part of alkyd resin and part of alcohol ether solvent are subjected to first stirring and mixing, the wetting agent, the dispersing agent and the fumed silica are sequentially added for second stirring and mixing, and then the titanium dioxide and the barium sulfate are added for third stirring and mixing. In the invention, the time for the first stirring and mixing, the second stirring and mixing and the third stirring and mixing is not specially limited, and the raw materials can be uniformly mixed. The invention adopts the mixing sequence, and can improve the dispersion uniformity of each raw material.
In the present invention, the fineness of the solid particles of the slurry is preferably 30 μm or less. In the invention, the grinding is preferably carried out in a sand mill, the rotating speed of the grinding machine is preferably 500-600 rpm, the grinding time is not particularly limited, and the fineness of solid particles in the slurry can be ensured to meet the requirement.
After the sizing agent is obtained, the sizing agent, the residual alkyd resin, the drier, the residual alcohol ether solvent and the anti-skinning agent are mixed to obtain the alkyd resin protective coating.
In the invention, the residual alkyd resin preferably accounts for 25-35% of the total mass of the alkyd resin, more preferably 28-32%, and most preferably 30%; the total mass of the partial alkyd resin and the residual alkyd resin is 100%. In the invention, the part of the alcohol ether solvent preferably accounts for 15-25% of the total mass of the alcohol ether solvent, more preferably 18-22%, and most preferably 20%; the total mass of the partial alcohol ether solvents and the alcohol ether solvents is 100 percent.
In the present invention, the mixing is preferably stirring mixing, and the stirring mixing speed in the present invention is not particularly limited, and a stirring speed well known in the art may be used.
In the invention, the mixing sequence is preferably that the slurry, the rest alkyd resin and the drier are stirred and mixed, the rest alcohol ether solvent is added to adjust the viscosity, and then the anti-skinning agent is added to be stirred and mixed for 15 min.
After the mixing is completed, the present invention preferably further comprises packaging the resulting alkyd protective coating. The present invention is not particularly limited to the packaging, and the packaging method well known in the art may be used.
The viscosity of the alkyd resin protective coating provided by the invention is preferably 190-210 s at 25 ℃.
The preparation method provided by the invention has the advantages that the alkyd resin is added twice, the first addition of the alkyd resin is to uniformly disperse the alkyd resin with a wetting agent, a dispersing agent, fumed silica, titanium dioxide and barium sulfate, and the second addition of the alkyd resin is to improve the properties of the coating, such as gloss, hardness, weather resistance and the like; if the additive is added at one time, firstly, the dispersion time is increased, the dispersion is not uniform, the dispersion efficiency of each raw material in the coating is influenced, the loss of electricity, cooling water and equipment is caused, and the production cost is greatly improved; secondly, the performance of the coating is not up to standard. The preparation method provided by the invention has simple process, and the prepared alkyd resin protective paint is harmless to the environment and human body, green, safe and environment-friendly.
The invention also provides application of the high-flash-point alkyd resin protective coating in the technical scheme or the high-flash-point alkyd resin protective coating prepared by the preparation method in the technical scheme in industrial corrosion prevention, preferably application in steel structure protection.
The technical solution of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
(1) Reacting soybean oil at 180 ℃ for 14h, and adjusting the viscosity of the resin to 300s by using diethylene glycol butyl ether to obtain alkyd resin;
(2) pre-dispersing: adding 6.3 parts of mixed alcohol ether solvent and 45.5 parts of alkyd resin into a feeding dispersion cylinder according to parts by weight, and uniformly stirring; sequentially adding 0.25 part of wetting agent, 0.5 part of dispersing agent and 0.3 part of fumed silica, and dispersing at high speed for 15min under the condition of 1000 rpm; then, adding 15 parts of titanium dioxide and 10 parts of barium sulfate in sequence, and stirring at a high speed under the condition of 1000rpm to be in a uniform state; wherein the alcohol ether solvent is a mixed solvent of diethylene glycol methyl ether, tripropylene glycol methyl ether and diethylene glycol ethyl ether, and the volume ratio of the diethylene glycol methyl ether to the tripropylene glycol methyl ether to the diethylene glycol ethyl ether is 4:4: 2;
(3) grinding: sucking the obtained material into a sand mill by using a diaphragm pump or a gear pump, and grinding the material under the condition of 550rpm until the fineness of solid particles in the slurry is less than or equal to 30 mu m to obtain the slurry in a stable state;
(4) paint mixing: and pumping the slurry into a paint mixing cylinder through a diaphragm pump or a gear pump, adding 19.5 parts of alkyd resin and 0.8 part of cobalt oxide/ferric oxide drier, uniformly stirring and mixing, adding 1.6 parts of alcohol ether solvent, mixing until the viscosity is qualified, adding 0.25 part of anti-skinning agent, stirring for 15min, and packaging to obtain the alkyd resin protective paint.
Example 2
(1) Enabling linseed oil to react for 15 hours at 190 ℃, and adjusting the viscosity of the resin to 280s by using diethylene glycol butyl ether to obtain alkyd resin;
(2) pre-dispersing: adding 5.8 parts of mixed alcohol ether solvent and 42 parts of alkyd resin into a feeding dispersion cylinder according to parts by weight, and uniformly stirring; sequentially adding 0.2 part of wetting agent, 0.4 part of dispersing agent and 0.3 part of fumed silica, and dispersing at high speed for 15min under the condition of 1000 rpm; then, adding 16 parts of titanium dioxide and 15 parts of barium sulfate in sequence, and stirring at a high speed under the condition of 1000rpm to be in a uniform state; wherein, the alcohol ether solvent is diethylene glycol monobutyl ether: the mixed solvent of the dipropylene glycol butyl ether, the volume ratio of the diethylene glycol butyl ether to the dipropylene glycol butyl ether is 3: 7;
(3) grinding: sucking the obtained material into a sand mill by using a diaphragm pump or a gear pump, and grinding the material under the condition of 550rpm until the fineness of solid particles in the slurry is less than or equal to 30 mu m to obtain the slurry in a stable state;
(4) paint mixing: and pumping the slurry into a paint mixing cylinder through a diaphragm pump or a gear pump, adding 18 parts of alkyd resin and 0.7 part of zinc oxide/calcium oxide/manganese oxide drier, uniformly stirring and mixing, adding 1.4 parts of alcohol ether solvent, adjusting viscosity until the viscosity is qualified, adding 0.22 part of anti-skinning agent, stirring for 15min, and packaging to obtain the alkyd resin protective paint.
Example 3
(1) Reacting cottonseed oil for 15h at 200 ℃, and adjusting the viscosity of the resin to 340s by using diethylene glycol butyl ether to obtain alkyd resin;
(2) pre-dispersing: adding 7.9 parts of mixed alcohol ether solvent and 44 parts of alkyd resin into a feeding dispersion cylinder according to parts by weight, and uniformly stirring; sequentially adding 0.3 part of wetting agent, 0.5 part of dispersing agent and 0.35 part of fumed silica, and dispersing at high speed for 15min under the condition of 1000 rpm; then, adding 16 parts of titanium dioxide and 5 parts of barium sulfate in sequence, and stirring at a high speed under the condition of 1000rpm to be in a uniform state; wherein the alcohol ether solvent is a mixed solvent of diethylene glycol methyl ether, diethylene glycol ethyl ether and tripropylene glycol methyl ether, and the volume ratio of the diethylene glycol methyl ether, the diethylene glycol ethyl ether and the tripropylene glycol methyl ether is 3:3: 4;
(3) grinding: sucking the obtained material into a sand mill by using a diaphragm pump or a gear pump, and grinding the material under the condition of 550rpm until the fineness of solid particles in the slurry is less than or equal to 30 mu m to obtain the slurry in a stable state;
(4) paint mixing: and pumping the slurry into a paint mixing cylinder through a diaphragm pump or a gear pump, adding 19 parts of alkyd resin and 0.75 part of drier, uniformly stirring and mixing, adding 2 parts of alcohol ether solvent, mixing until the viscosity is qualified, adding 0.2 part of anti-skinning agent, stirring for 15min, and packaging to obtain the alkyd resin protective paint.
Example 4
(1) Reacting cotton seed oil and soybean oil at 200 ℃ for 15h, and adjusting the resin viscosity to 290s by using diethylene glycol butyl ether to obtain alkyd resin;
(2) pre-dispersing: adding 5.5 parts of mixed alcohol ether solvent and 42.7 parts of alkyd resin into a feeding dispersion cylinder according to parts by weight, and uniformly stirring; sequentially adding 0.3 part of wetting agent, 0.3 part of dispersing agent and 0.3 part of fumed silica, and dispersing at high speed for 15min under the condition of 1000 rpm; then, adding 16 parts of titanium dioxide and 6 parts of barium sulfate in sequence, and stirring at a high speed under the condition of 1000rpm to be in a uniform state; wherein the alcohol ether solvent is a mixed solvent of dipropylene glycol methyl ether and diethylene glycol ethyl ether, and the volume ratio of the dipropylene glycol methyl ether to the diethylene glycol ethyl ether is 1: 1;
(3) grinding: sucking the obtained material into a sand mill by using a diaphragm pump or a gear pump, and grinding the material under the condition of 550rpm until the fineness of solid particles in the slurry is less than or equal to 30 mu m to obtain the slurry in a stable state;
(4) paint mixing: and pumping the slurry into a paint mixing cylinder through a diaphragm pump or a gear pump, adding 18.3 parts of alkyd resin and 1 part of cobalt oxide/manganese oxide/iron oxide/zinc oxide drier, uniformly stirring and mixing, adding 1.4 parts of alcohol ether solvent, mixing until the viscosity is qualified, adding 0.3 part of anti-skinning agent, stirring for 15min, and packaging to obtain the alkyd resin protective paint.
Comparative example 1
An alkyd protective coating was prepared as in example 1, except that a conventional alkyd resin prepared from fatty acids was used as the starting material.
Test example 1
The alkyd resin protective coatings prepared in examples 1-4 and comparative example 1 were subjected to performance tests, and the test results are shown in table 1.
TABLE 1 Performance test results of alkyd resin protective coatings prepared in examples 1-4 and comparative example 1
As can be seen from Table 1, the flash point of the high-flash-point alkyd resin protective coating provided by the invention is greatly higher than the required index, and other technical indexes also meet the requirements. The alkyd resin protective coating provided by the invention has the advantages of high flash point and safety in the processes of production, transportation and use; excellent acid resistance, alkali resistance, weather resistance and other properties; and the toxicity is low, and the environment is protected.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (10)

1. The high-flash-point alkyd resin protective coating is characterized by comprising the following components in parts by weight:
60-65 parts of alkyd resin;
15-20 parts of titanium dioxide;
5-15 parts of barium sulfate;
5-10 parts of alcohol ether solvent;
0.3-0.4 part of fumed silica;
0.2-0.4 part of wetting agent;
0.3-0.5 part of a dispersing agent;
0.7-1 part of a drier;
0.2-0.3 part of anti-skinning agent.
2. The high flash alkyd protective coating of claim 1, wherein the alkyd resin is prepared from natural vegetable oil by high temperature reaction;
the high-temperature reaction is carried out at the temperature of 180-200 ℃ for 14-15 h.
3. The high flash alkyd resin protective coating of claim 1, wherein the titanium dioxide is rutile titanium dioxide.
4. The high flash point alkyd protective coating of claim 1, wherein the barium sulfate has a particle size of 1100-1300 mesh.
5. The high flash alkyd protective coating of claim 1, wherein the alcohol ether based solvent comprises one or more of diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol butyl ether, diethylene glycol ethyl ether, and tripropylene glycol methyl ether.
6. The high flash alkyd protective coating of claim 1, wherein the drier comprises one or more of a metal oxide, a metal salt, and a rare earth drier.
7. The high flash alkyd protective coating of claim 6, wherein the metal of the metal oxide and metal salt independently comprises cobalt, manganese, iron, zinc, or calcium.
8. The method for preparing the high flash point alkyd resin protective coating of any one of claims 1 to 7, comprising the following steps:
mixing and grinding part of alcohol ether solvent, part of alkyd resin, wetting agent, dispersing agent, fumed silica, titanium dioxide and barium sulfate to obtain slurry;
and mixing the slurry, the residual alkyd resin, the drier, the residual alcohol ether solvent and the anti-skinning agent to obtain the alkyd resin protective coating.
9. The preparation method according to claim 8, wherein the partial alcohol ether solvent accounts for 75-85% of the total mass of the alcohol ether solvent;
the part of alkyd resin accounts for 65-75% of the total mass of the alkyd resin;
the fineness of solid particles in the slurry is less than or equal to 30 mu m.
10. Use of the high flash point alkyd resin protective coating of any one of claims 1 to 7 or the high flash point alkyd resin protective coating prepared by the preparation method of any one of claims 8 to 9 in industrial anticorrosion.
CN201910898201.0A 2019-09-23 2019-09-23 High-flash-point alkyd resin protective coating and preparation method and application thereof Withdrawn CN110591523A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910898201.0A CN110591523A (en) 2019-09-23 2019-09-23 High-flash-point alkyd resin protective coating and preparation method and application thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201910898201.0A CN110591523A (en) 2019-09-23 2019-09-23 High-flash-point alkyd resin protective coating and preparation method and application thereof
PCT/CN2020/097470 WO2021057126A1 (en) 2019-09-23 2020-06-22 High flash point alkyd resin protective coating and preparatin method thereof

Publications (1)

Publication Number Publication Date
CN110591523A true CN110591523A (en) 2019-12-20

Family

ID=68862169

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910898201.0A Withdrawn CN110591523A (en) 2019-09-23 2019-09-23 High-flash-point alkyd resin protective coating and preparation method and application thereof

Country Status (2)

Country Link
CN (1) CN110591523A (en)
WO (1) WO2021057126A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111205754A (en) * 2020-03-18 2020-05-29 哈尔滨市雪鹰工程材料有限公司 High-flash-point alkyd resin magnetic protective coating
CN111548669A (en) * 2020-05-28 2020-08-18 江苏冠军科技集团股份有限公司 High-flash-point exemption diluent and preparation method and application thereof
CN112358782A (en) * 2020-11-13 2021-02-12 江苏冠军科技集团股份有限公司 High-flash-point acrylic acid anticorrosive finish paint and preparation method thereof
CN112409893A (en) * 2020-11-17 2021-02-26 江苏冠军科技集团股份有限公司 High-solid-content low-VOC protective coating and preparation method and application thereof
WO2021057126A1 (en) * 2019-09-23 2021-04-01 江苏冠军科技集团股份有限公司 High flash point alkyd resin protective coating and preparatin method thereof
CN113185903A (en) * 2021-05-26 2021-07-30 河北晨虹油漆有限公司 Safe alkyd paint and preparation method thereof
CN113402956A (en) * 2021-06-17 2021-09-17 江苏冠军科技集团股份有限公司 High-flash-point odor-free coating and preparation method and application thereof
CN113755082A (en) * 2021-10-18 2021-12-07 无锡市造漆厂有限公司 High-flash-point safe alkyd anticorrosive paint and preparation process thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1472263A (en) * 2003-05-08 2004-02-04 同济大学 Steel-structure anti-corrosion coating and preparing mehtod thereof
CN105062336A (en) * 2015-07-23 2015-11-18 安吉祺隆新型建材有限公司 Alkyd paint preparation method
CN106700044A (en) * 2016-11-16 2017-05-24 任会平 Alkyd resin with stronger weathering resistance and heat stability and preparation method thereof
CN106867375A (en) * 2017-03-02 2017-06-20 江苏冠军涂料科技集团股份有限公司 A kind of natural plants oil-modified alkyd paint and its preparation technology
CN107474683A (en) * 2017-02-17 2017-12-15 德阳烯碳科技有限公司 A kind of preparation method of anticorrosive paint
CN107603437A (en) * 2017-09-30 2018-01-19 江苏冠军科技集团股份有限公司 A kind of high solid steel structure anti-corrosion paint and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110591523A (en) * 2019-09-23 2019-12-20 江苏冠军科技集团股份有限公司 High-flash-point alkyd resin protective coating and preparation method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1472263A (en) * 2003-05-08 2004-02-04 同济大学 Steel-structure anti-corrosion coating and preparing mehtod thereof
CN105062336A (en) * 2015-07-23 2015-11-18 安吉祺隆新型建材有限公司 Alkyd paint preparation method
CN106700044A (en) * 2016-11-16 2017-05-24 任会平 Alkyd resin with stronger weathering resistance and heat stability and preparation method thereof
CN107474683A (en) * 2017-02-17 2017-12-15 德阳烯碳科技有限公司 A kind of preparation method of anticorrosive paint
CN106867375A (en) * 2017-03-02 2017-06-20 江苏冠军涂料科技集团股份有限公司 A kind of natural plants oil-modified alkyd paint and its preparation technology
CN107603437A (en) * 2017-09-30 2018-01-19 江苏冠军科技集团股份有限公司 A kind of high solid steel structure anti-corrosion paint and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021057126A1 (en) * 2019-09-23 2021-04-01 江苏冠军科技集团股份有限公司 High flash point alkyd resin protective coating and preparatin method thereof
CN111205754A (en) * 2020-03-18 2020-05-29 哈尔滨市雪鹰工程材料有限公司 High-flash-point alkyd resin magnetic protective coating
CN111548669A (en) * 2020-05-28 2020-08-18 江苏冠军科技集团股份有限公司 High-flash-point exemption diluent and preparation method and application thereof
CN112358782A (en) * 2020-11-13 2021-02-12 江苏冠军科技集团股份有限公司 High-flash-point acrylic acid anticorrosive finish paint and preparation method thereof
CN112409893A (en) * 2020-11-17 2021-02-26 江苏冠军科技集团股份有限公司 High-solid-content low-VOC protective coating and preparation method and application thereof
WO2022105204A1 (en) * 2020-11-17 2022-05-27 江苏冠军科技集团股份有限公司 High-solid-content low-voc protective coating, preparation method therefor and use thereof
CN113185903A (en) * 2021-05-26 2021-07-30 河北晨虹油漆有限公司 Safe alkyd paint and preparation method thereof
CN113402956A (en) * 2021-06-17 2021-09-17 江苏冠军科技集团股份有限公司 High-flash-point odor-free coating and preparation method and application thereof
CN113755082A (en) * 2021-10-18 2021-12-07 无锡市造漆厂有限公司 High-flash-point safe alkyd anticorrosive paint and preparation process thereof

Also Published As

Publication number Publication date
WO2021057126A1 (en) 2021-04-01

Similar Documents

Publication Publication Date Title
CN110591523A (en) High-flash-point alkyd resin protective coating and preparation method and application thereof
CN105542644A (en) Nanometer silica-modified aqueous polyurethane waterproof paint and preparation method thereof
CN101775245B (en) Multifunctional putty
CN103031038A (en) Low-temperature cured cathode electrophoretic coating, and preparation method and use method thereof
CN102533029A (en) Aqueous asphalt imitation anticorrosion coating for container chassis and preparation method thereof
CN103436120B (en) A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof
CN103483995B (en) A kind of PE gloss varnish and preparation method thereof
CN110894394A (en) Water-based polyester amino baking varnish coating and preparation method and application thereof
CN107987698B (en) Water-based anticorrosive paint containing modified graphene oxide and preparation method thereof
CN111019453A (en) Environment-friendly waterproof coating and preparation method thereof
CN103131298A (en) Flame retardant powder coating with hydrated zinc borate
CN107033750A (en) A kind of groove pipe fitting watersoluble baking dip painting and preparation method thereof
CN111334160A (en) Water-based anticorrosive primer and preparation method thereof
AU2021106937A4 (en) Protective coating with high solid and low voc, and preparation method and use thereof
CN106280932A (en) Universal alcohol acid antirust paint in a kind of bottom surface and preparation method thereof
CN101747827B (en) Environment-friendly alkyd coating
CN103665942A (en) Attapulgite nano complex iron oxide brown for easily-dispersible water-based paint
CN111253825B (en) Water-based acrylic acid graft modified polysiloxane coating, preparation method and application
CN107365547B (en) Bright water-based epoxy floor paint and preparation method thereof
CN109943197A (en) A kind of water-based antirusting paint operable with rust and preparation method thereof
CN101701127A (en) One-component air-dry water-based industrial paint
CN104277656A (en) Synthesis process of water-soluble phenolic resin antirust coating
CN110016246A (en) One kind building yellow finishing coat and preparation method thereof in machine environmentally friendly functional
CN109294423B (en) Water-based nano polyaniline-polyurethane conductive anticorrosive paint and preparation method thereof
CN111440495A (en) Water-based amino baking paint and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20191220