CN106832770A - A kind of epoxy glass laminate - Google Patents
A kind of epoxy glass laminate Download PDFInfo
- Publication number
- CN106832770A CN106832770A CN201611239383.3A CN201611239383A CN106832770A CN 106832770 A CN106832770 A CN 106832770A CN 201611239383 A CN201611239383 A CN 201611239383A CN 106832770 A CN106832770 A CN 106832770A
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- CN
- China
- Prior art keywords
- glass laminate
- epoxy glass
- laminate according
- epoxy
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention provides epoxy glass laminate, its raw material for including following parts by weight：Epoxy resin 70~90, curing agent 10~15, releasing agent 2~5, filler 15~30, toughener 5~10, diluent 2~5, reinforcing material 10~25.Epoxy glass laminate of the invention, the characteristics of with excellent mechanical property, resistance to surface leakage, good impact resistance.
Description
Technical field
The present invention relates to field of compound material, more particularly to a kind of epoxy glass laminate.
Background technology
Glass-reinforced plastic material is to be embedded in cured thermosetting resin by fiber glass reinforcement or be wrapped to form by it
The material of composite construction.It is molded using resin Sized glass cloth material more than the glass-reinforced plastic material of production and application in the market.
The method effect of impregnation is good, and prepared content of glass fiber is high.But due to being limited by glass cloth volume and shape, make it special
The product that uniform-compression is difficult for pipe joint, tee pipe fitting, bend pipe tools etc. is not suitable with.In addition, prepared by the method
Glass-reinforced plastic material its impact resistance it is poor, and laminated face is susceptible to layering.In order to solve the above problems, there is researcher by glass
Glass fiber cuts into Fiber Aspect Ratio for 1000 or so, length is 3~5mm glass fiber powders, then puts into glass fiber powder
It is in the mixed liquor being made up of epoxy resin, plasticizer, silane coupler then the addition filler that stirred in ball mill, solid
Agent, is thus prepared into a kind of glass-reinforced plastic material without glass cloth laying.Although the glass-reinforced plastic material gram that the method is provided
Glass cloth defect caused in itself has been taken, but because glass fibre is cut into powdery, thus its fiber is specific in itself
Physical characteristic is also weakened severely.If the mode that composite absorbs impact energy is often to be deformed with Crack Extension extremely by resin
Fracture, fiber are extracted out, 3 kinds of modes of fibrous fracture.Thus it is not difficult to find out when the glass fibre in composite is embedded in powdery
In the thermosetting resin of solidification, when by external impacts, being capable of energy absorption when mealiness fiber is no longer extracted out with fiber
Effect, while also losing the energy to be absorbed during fibrous fracture.
The content of the invention
It is above-mentioned to solve it is an object of the present invention in view of the shortcomings of the prior art, there is provided a kind of epoxy glass laminate
Technical problem.
The technical scheme that is used to achieve the above object of the present invention for：
A kind of epoxy glass laminate, its raw material for including following parts by weight：
Preferably, described diluent is diepoxy propane ethylether.
Preferably, solidfied material is peroxide.
Preferably, described toughener is dioctyl phthalate.
Preferably, described releasing agent is zinc stearate or calcium stearate.
Preferably, described reinforcing material is organic fiber.
Preferably, described reinforcing material is Graphite cloth's band.
Preferably, described reinforcing material is glass rove.
The epoxy glass laminate that the present invention is provided, with excellent mechanical property, resistance to surface leakage, good impact resistance
Feature.
Specific embodiment
Embodiment 1
A kind of epoxy glass laminate is provided, its raw material for including following parts by weight：
During specific implementation, epoxy resin, hydrogen peroxide, dioctyl phthalate first above-mentioned weight add mashing
In machine, quick stirring 10 minutes.Next, being mediated 5 minutes during the slurry for stirring is moved into kneader, then sequentially add
Mediated 20 minutes after the components such as zinc stearate, the calcium carbonate of above-mentioned weight, be eventually adding diepoxy propane ethylether, organic fiber
Continue to mediate 5 minutes after composition by weight.Obtain the epoxy glass laminate material of true qualities.Needed to add according to client
Corresponding color masterbatch is being made into the color of needs.
Embodiment 2
A kind of epoxy glass laminate is provided, its raw material for including following parts by weight：
During specific implementation, epoxy resin, cumyl peroxide first above-mentioned weight, dioctyl phthalate add
Enter in beater, quickly stir 10 minutes.Next, will the slurry that stirred move into kneader in mediate 5 minutes, then according to
Mediated 20 minutes after the components such as calcium stearate, the barium sulfate of the secondary above-mentioned weight of addition, be eventually adding diepoxy propane ethylether, stone
Continue to mediate 5 minutes after black strap composition by weight.Obtain the epoxy glass laminate material of true qualities.Needed may be used also according to client
To add corresponding color masterbatch to be made into the color of needs.
Embodiment 3
A kind of epoxy glass laminate is provided, its raw material for including following parts by weight：
During specific implementation, epoxy resin, cumyl peroxide first above-mentioned weight, dioctyl phthalate add
Enter in beater, quickly stir 10 minutes.Next, will the slurry that stirred move into kneader in mediate 5 minutes, then according to
Mediated 20 minutes after the components such as zinc stearate, the calcium sulfate of the secondary above-mentioned weight of addition, be eventually adding diepoxy propane ethylether, glass
Continue to mediate 5 minutes after glass rove composition by weight.Obtain the epoxy glass laminate material of true qualities.Needed may be used also according to client
To add corresponding color masterbatch to be made into the color of needs.
There is the performance shown in following table after tested as the unsaturated polyester die plastic obtained by above example：
Certainly, this invention can also have other to convert, it is not limited to which above-mentioned implementation method, those skilled in the art are had
Standby knowledge, can also various changes can be made without departing from the inventive concept of the premise, such change all should fall in this hair
In bright protection domain.
Claims (8)
1. a kind of epoxy glass laminate, it is characterised in that its raw material for including following parts by weight：
。
2. epoxy glass laminate according to claim 1, it is characterised in that described diluent is diepoxy propane second
Base ether.
3. epoxy glass laminate according to claim 1, it is characterised in that solidfied material is peroxide.
4. epoxy glass laminate according to claim 1, it is characterised in that described toughener is phthalic acid two
Monooctyl ester.
5. epoxy glass laminate according to claim 1, it is characterised in that described releasing agent is zinc stearate or hard
Resin acid calcium.
6. epoxy glass laminate according to claim 1, it is characterised in that described reinforcing material is organic fiber.
7. epoxy glass laminate according to claim 1, it is characterised in that described reinforcing material is Graphite cloth's band.
8. epoxy glass laminate according to claim 1, it is characterised in that described reinforcing material is glass rove.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611239383.3A CN106832770A (en) | 2016-12-28 | 2016-12-28 | A kind of epoxy glass laminate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611239383.3A CN106832770A (en) | 2016-12-28 | 2016-12-28 | A kind of epoxy glass laminate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106832770A true CN106832770A (en) | 2017-06-13 |
Family
ID=59114197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611239383.3A Pending CN106832770A (en) | 2016-12-28 | 2016-12-28 | A kind of epoxy glass laminate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106832770A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993642A (en) * | 2012-08-22 | 2013-03-27 | 常熟市筑紫机械有限公司 | Halogen-free flame retardant phenolic epoxy glass reinforced plastic molding material |
| CN102993641A (en) * | 2012-08-22 | 2013-03-27 | 常熟市筑紫机械有限公司 | Preparation method of halogen-free flame retardant phenolic epoxy glass reinforced plastic molding material |
| CN103183931A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Phenolic epoxy glass fibre reinforced plastic forming material |
| CN103254566A (en) * | 2012-02-18 | 2013-08-21 | 河北华强科技开发有限公司 | Impact-resistant glass fiber reinforced plastic material |
-
2016
- 2016-12-28 CN CN201611239383.3A patent/CN106832770A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183931A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Phenolic epoxy glass fibre reinforced plastic forming material |
| CN103254566A (en) * | 2012-02-18 | 2013-08-21 | 河北华强科技开发有限公司 | Impact-resistant glass fiber reinforced plastic material |
| CN102993642A (en) * | 2012-08-22 | 2013-03-27 | 常熟市筑紫机械有限公司 | Halogen-free flame retardant phenolic epoxy glass reinforced plastic molding material |
| CN102993641A (en) * | 2012-08-22 | 2013-03-27 | 常熟市筑紫机械有限公司 | Preparation method of halogen-free flame retardant phenolic epoxy glass reinforced plastic molding material |
Non-Patent Citations (1)
| Title |
|---|
| 贾润礼，李宁等编著: "《塑料成型加工新技术》", 31 October 2006 * |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170613 |