CN106832646A - 一种耐磨阻燃的电线电缆材料 - Google Patents

一种耐磨阻燃的电线电缆材料 Download PDF

Info

Publication number
CN106832646A
CN106832646A CN201510878276.4A CN201510878276A CN106832646A CN 106832646 A CN106832646 A CN 106832646A CN 201510878276 A CN201510878276 A CN 201510878276A CN 106832646 A CN106832646 A CN 106832646A
Authority
CN
China
Prior art keywords
parts
electric wire
abrasion resistant
cable material
resistant fire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510878276.4A
Other languages
English (en)
Inventor
毛莹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yuyao Jiefei Electric Appliance Co Ltd
Original Assignee
Yuyao Jiefei Electric Appliance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yuyao Jiefei Electric Appliance Co Ltd filed Critical Yuyao Jiefei Electric Appliance Co Ltd
Priority to CN201510878276.4A priority Critical patent/CN106832646A/zh
Publication of CN106832646A publication Critical patent/CN106832646A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Insulated Conductors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

本发明公开了一种耐磨阻燃的电线电缆材料，包括耐磨层和阻燃层，所述耐磨层包裹阻燃层，所述耐磨层由以下重量份数比组成：聚氯乙烯35-60份、碳纳米管40-55份、滑石粉25-40份、稳定剂3-8份、润滑剂5-8份、耐磨剂2-6份、二甲基硅油2-6份、环烷烃油10-12份和复合填料10-15份，所述阻燃层由以下重量份数比组成：聚苯醚树脂8-15份、聚烯烃树脂20-25份、硅橡胶12-18份、二氧化硅5-8份、阻燃剂1-4份、抗氧剂2-3份、交联剂1-4份和偶联剂2-4份；该耐磨阻燃的电线电缆材料能够解决目前电线电缆外护套易磨损和电线电缆易燃的问题。

Description

一种耐磨阻燃的电线电缆材料
技术领域
本发明涉及一种耐磨阻燃的电线电缆材料。
背景技术
阻燃电缆，是指在规定试验条件下，试样被燃烧，在撤去试验火源后，火焰的蔓延仅在限定范围内，残焰或残灼在限定时间内能自行熄灭的电缆。根本特性是 ：在火灾情况下有可能被烧坏而不能运行，但可阻止火势的蔓延。通俗地讲，电线万一失火，能够把燃烧限制在局部范围内，不产生蔓延，保住其他的各种设备，避免造成更大的损失。
目前市场上室外电动工具橡胶电源线，如切割机，经常在硬质地面上来回拖动，随着使用时间的延续，橡胶电源线高温老化，气候老化，电线外护套被摩擦变薄，一旦外护套被磨破，则绝缘外露出现安全隐患 , 并且大功率电器、电动工具长期使用发热对耐高温的要求越来越高，因此需要设计一种具有耐高温且超耐磨的电线电缆护套胶料。
发明内容
本发明所要解决的技术问题是提供一种耐磨阻燃的电线电缆材料，来解决目前电线电缆外护套易磨损和电线电缆易燃的问题。
本发明的目的通过下述技术方案予以实现：
一种耐磨阻燃的电线电缆材料，包括耐磨层和阻燃层，所述耐磨层包裹阻燃层，所述耐磨层由以下重量份数比组成：聚氯乙烯35-60份、碳纳米管40-55份、滑石粉25-40份、稳定剂3-8份、润滑剂5-8份、耐磨剂2-6份、二甲基硅油2-6份、环烷烃油10-12份和复合填料10-15份，所述阻燃层由以下重量份数比组成：聚苯醚树脂8-15份、聚烯烃树脂20-25份、硅橡胶12-18份、二氧化硅5-8份、阻燃剂1-4份、抗氧剂2-3份、交联剂1-4份和偶联剂2-4份。
进一步的，所述润滑剂为聚乙烯蜡。
进一步的，所述滑石粉为 1200 目，粒径 40% 分布在 1 ～ 5µm，盐酸不溶物大于或等于 80%，氧化镁含量大于或等于 35% 的滑石粉。
进一步的，所述复合填料由下列重量份的原料制成：粘土 13-16份、轻质碳酸钙 2-3份、氮化铝 1-2份、海泡石粉 3-4份、氢氧化镁 10-12份、二甲基硅油1-2份、石英砂 4-5份、柠檬酸三丁酯 2-3份、氢氧化铝8-10份。
进一步的，所述聚苯醚树脂的粘度为30～40g/cm3。
进一步的，所述硅橡胶为二甲基硅橡胶、甲基乙烯基硅橡胶或甲基苯基乙烯基硅橡胶中的一种或一种以上的混合物。
进一步的，所述阻燃剂为聚磷酸铵。
本发明的有益效果是：耐磨层采用了碳纳米管，给产品性能带来极大的改善，使得产品具有良好的强度、弹性、抗疲劳性，且具有较强的耐压耐磨性能，阻燃层能够起到阻燃耐火作用，即使超过耐火极限燃烧仍能烧蚀形成坚硬的保护壳，保护壳能够防止火焰进一步向电线内部延伸，从而保护位于陶瓷化硅橡胶耐火层内的导体不受损坏，确保电线的正常使用功能。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合具体实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
实施例
一种耐磨阻燃的电线电缆材料，包括耐磨层和阻燃层，所述耐磨层包裹阻燃层，所述耐磨层由以下重量份数比组成：聚氯乙烯35份、碳纳米管40份、滑石粉25份、稳定剂3份、润滑剂5份、耐磨剂2份、二甲基硅油2份、环烷烃油10份和复合填料10份，所述阻燃层由以下重量份数比组成：聚苯醚树脂8份、聚烯烃树脂20份、硅橡胶12份、二氧化硅5份、阻燃剂1份、抗氧剂2份、交联剂1份和偶联剂2份。
所述润滑剂为聚乙烯蜡。
所述滑石粉为 1200 目，粒径 40% 分布在 1 ～ 5µm，盐酸不溶物大于或等于 80%，氧化镁含量大于或等于 35% 的滑石粉。
所述复合填料由下列重量份的原料制成：粘土 13份、轻质碳酸钙 2份、氮化铝 1份、海泡石粉 3份、氢氧化镁 10份、二甲基硅油1份、石英砂 4份、柠檬酸三丁酯 2份、氢氧化铝8份。
所述聚苯醚树脂的粘度为30～40g/cm3。
所述硅橡胶为二甲基硅橡胶、甲基乙烯基硅橡胶或甲基苯基乙烯基硅橡胶中的一种或一种以上的混合物。
所述阻燃剂为聚磷酸铵。
本发明的有益效果是：耐磨层采用了碳纳米管，给产品性能带来极大的改善，使得产品具有良好的强度、弹性、抗疲劳性，且具有较强的耐压耐磨性能，阻燃层能够起到阻燃耐火作用，即使超过耐火极限燃烧仍能烧蚀形成坚硬的保护壳，保护壳能够防止火焰进一步向电线内部延伸，从而保护位于陶瓷化硅橡胶耐火层内的导体不受损坏，确保电线的正常使用功能。
以上所述，仅为本发明的具体实施方式，但本发明的保护范围并不局限于此，任何不经过创造性劳动想到的变化或替换，都应涵盖在本发明的保护范围内。

Claims (7)

1.一种耐磨阻燃的电线电缆材料，其特征在于：包括耐磨层和阻燃层，所述耐磨层包裹阻燃层，所述耐磨层由以下重量份数比组成：聚氯乙烯35-60份、碳纳米管40-55份、滑石粉25-40份、稳定剂3-8份、润滑剂5-8份、耐磨剂2-6份、二甲基硅油2-6份、环烷烃油10-12份和复合填料10-15份，所述阻燃层由以下重量份数比组成：聚苯醚树脂8-15份、聚烯烃树脂20-25份、硅橡胶12-18份、二氧化硅5-8份、阻燃剂1-4份、抗氧剂2-3份、交联剂1-4份和偶联剂2-4份。
2.如权利要求1所述的一种耐磨阻燃的电线电缆材料，其特征在于:所述润滑剂为聚乙烯蜡。
3.如权利要求1所述的一种耐磨阻燃的电线电缆材料，其特征在于:所述滑石粉为 1200 目，粒径 40% 分布在 1 ～ 5µm，盐酸不溶物大于或等于 80%，氧化镁含量大于或等于 35% 的滑石粉。
4.如权利要求1所述的一种耐磨阻燃的电线电缆材料，其特征在于:所述复合填料由下列重量份的原料制成：粘土 13-16份、轻质碳酸钙 2-3份、氮化铝 1-2份、海泡石粉 3-4份、氢氧化镁 10-12份、二甲基硅油1-2份、石英砂 4-5份、柠檬酸三丁酯 2-3份、氢氧化铝8-10份。
5.如权利要求1所述的一种耐磨阻燃的电线电缆材料，其特征在于:所述聚苯醚树脂的粘度为30～40g/cm3。
6.如权利要求1所述的一种耐磨阻燃的电线电缆材料，其特征在于:所述硅橡胶为二甲基硅橡胶、甲基乙烯基硅橡胶或甲基苯基乙烯基硅橡胶中的一种或一种以上的混合物。
7.如权利要求1所述的一种耐磨阻燃的电线电缆材料，其特征在于:所述阻燃剂为聚磷酸铵。
CN201510878276.4A 2015-12-04 2015-12-04 一种耐磨阻燃的电线电缆材料 Pending CN106832646A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510878276.4A CN106832646A (zh) 2015-12-04 2015-12-04 一种耐磨阻燃的电线电缆材料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510878276.4A CN106832646A (zh) 2015-12-04 2015-12-04 一种耐磨阻燃的电线电缆材料

Publications (1)

Publication Number Publication Date
CN106832646A true CN106832646A (zh) 2017-06-13

Family

ID=59148960

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510878276.4A Pending CN106832646A (zh) 2015-12-04 2015-12-04 一种耐磨阻燃的电线电缆材料

Country Status (1)

Country Link
CN (1) CN106832646A (zh)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107325562A (zh) * 2017-08-04 2017-11-07 安徽远征电缆科技有限公司 一种电缆用阻燃硅橡胶
CN107383687A (zh) * 2017-08-03 2017-11-24 安徽新智电力科技有限公司 一种用于电缆的阻燃增强剂
CN107556704A (zh) * 2017-09-30 2018-01-09 四会市启德信息咨询服务有限公司 一种无卤膨胀型阻燃电缆护套的制作工艺
CN108003502A (zh) * 2017-12-18 2018-05-08 苏州人为峰软件科技有限公司 一种耐磨型汽车线束料
CN108129863A (zh) * 2017-11-22 2018-06-08 新宇电缆集团股份有限公司 一种防火型耐高温电缆阻燃层
CN108389648A (zh) * 2018-01-22 2018-08-10 储微微 一种变电站用变频电缆

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107383687A (zh) * 2017-08-03 2017-11-24 安徽新智电力科技有限公司 一种用于电缆的阻燃增强剂
CN107325562A (zh) * 2017-08-04 2017-11-07 安徽远征电缆科技有限公司 一种电缆用阻燃硅橡胶
CN107556704A (zh) * 2017-09-30 2018-01-09 四会市启德信息咨询服务有限公司 一种无卤膨胀型阻燃电缆护套的制作工艺
CN108129863A (zh) * 2017-11-22 2018-06-08 新宇电缆集团股份有限公司 一种防火型耐高温电缆阻燃层
CN108003502A (zh) * 2017-12-18 2018-05-08 苏州人为峰软件科技有限公司 一种耐磨型汽车线束料
CN108389648A (zh) * 2018-01-22 2018-08-10 储微微 一种变电站用变频电缆

Similar Documents

Publication Publication Date Title
CN106832646A (zh) 一种耐磨阻燃的电线电缆材料
CN103065709A (zh) 一种耐火阻燃电线
CN103606410A (zh) 一种纳米型超a类阻燃耐火控制电缆
CN103709538A (zh) 一种电线绝缘材料
CN105801992B (zh) 一种耐火电缆用低烟无卤隔热防火电缆料及其制备方法和用途
CN107936566A (zh) 一种用于阻燃电缆的可陶瓷化硅橡胶复合材料及其制造方法
CN104021866A (zh) 散热型扁电缆
KR102549469B1 (ko) 내화 케이블
CN102347105A (zh) 轨道交通用高容量耐火电力电缆
CN105913957A (zh) 一种高可靠性矿用电缆
CN203102899U (zh) 一种矿物绝缘防火电缆
CN106832872A (zh) 一种防火阻燃的电线电缆材料
CN205789175U (zh) 柔性矿物绝缘防火电缆
CN109148019A (zh) 一种防火阻燃硅橡胶电缆
CN102220002A (zh) 纳米级耐高温陶瓷化硅胶
CN205384898U (zh) 一种铝合金芯灭火电缆
CN209607444U (zh) 一种速散热高载流电缆
CN107731414A (zh) 一种新型耐热硅橡胶绝缘控制电缆
CN106397946A (zh) 一种耐热性低烟无卤阻燃电线护套料配方
CN203787127U (zh) 一种环保型本安型仪表电缆
CN204423966U (zh) 一种新型防火电线
CN208157144U (zh) 一种新型阻燃电力电缆
CN103413608B (zh) 一种耐高温冶金用软电缆及其护套材料
CN206921540U (zh) 一种安全环保低烟无卤布电线
CN105489299A (zh) 通信电源用高阻燃高耐火软电缆

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170613

WD01 Invention patent application deemed withdrawn after publication