CN106832444A - A kind of modified abrasion resistant oil resistant flame retardant rubber - Google Patents
A kind of modified abrasion resistant oil resistant flame retardant rubber Download PDFInfo
- Publication number
- CN106832444A CN106832444A CN201611165381.4A CN201611165381A CN106832444A CN 106832444 A CN106832444 A CN 106832444A CN 201611165381 A CN201611165381 A CN 201611165381A CN 106832444 A CN106832444 A CN 106832444A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame retardant
- retardant rubber
- abrasion resistant
- modified abrasion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention proposes a kind of modified abrasion resistant oil resistant flame retardant rubber, and the modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：40 50 parts of natural rubber, 4 third 20 35 parts of fluorubber, 49 parts of cellulose acetate propionate, 8 15 parts of haloflex, 6 10 parts of nano zine oxide, 58 parts of ceramic, 48 parts of hydrated alumina, 39 parts of waterglass, 6 12 parts of compounded mix, 14 parts of age resistor, 25 parts of vulcanizing agent, the present invention is with 4 third good fluorubber of natural rubber and oil resistivity as primary raw material, by adding supporting material, fire retardant, age resistor, vulcanizer etc. carries out cross-linking modified, obtained product has excellent wearability, oil resistivity and anti-flammability, mechanical property is strong, it is applied widely.
Description
Technical field
The present invention relates to rubber technical field, and in particular to one kind changes surname wear-resistance and oil-resistance flame retardant rubber.
Background technology
Rubber refers to the strong flexible polymer material with reversible deformation.High resilience at room temperature, in the external force of very little
Effect is lower to be produced compared with large deformation, remove resilient after external force.Rubber industry be national economy important foundation industry it
One, it not only provides daily life the indispensable light industry rubber product such as daily, medical for people, and to digging, traffic,
The heavy industry such as building, machinery, electronics and new industry provide various rubber system production equipments or rubber components, it is seen then that rubber row
The product category of industry is various, and backward industry is very wide.The function of current rubber is relatively simple, some essence only with itself
Attribute, in face of the different demands of all trades and professions, we generally require to carry out rubber different material modifications and then meet production
Demand.
The content of the invention
For above-mentioned problem, the present invention is proposed a kind of has changing for excellent wearability, oil resistivity and anti-flammability
Property wear-resistance and oil-resistance flame retardant rubber.
In order to realize above-mentioned purpose, the present invention uses following technical scheme：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：Natural rubber 40-50 parts, 4 third fluorubber
20-35 parts, cellulose acetate propionate 4-9 parts, haloflex 8-15 parts, nano zine oxide 6-10 parts, ceramic 5-8 parts,
Hydrated alumina 4-8 parts, waterglass 3-9 parts, compounded mix 6-12 parts, age resistor 1-4 parts, vulcanizing agent 2-5 parts.
Preferably, modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：Natural rubber 45-50 parts, 4 third fluorine
Rubber 30-35 parts, cellulose acetate propionate 6-9 parts, haloflex 12-15 parts, nano zine oxide 8-10 parts, ceramic 7-
8 parts, hydrated alumina 6-8 parts, waterglass 6-9 parts, compounded mix 10-12 parts, age resistor 2-4 parts, vulcanizing agent 4-5 parts.
Preferably, the compounded mix includes nano graphene oxide, snake stone powder and semi-reinforcing hydrocarbon black.
Preferably, the mass ratio of nano graphene oxide, snake stone powder and semi-reinforcing hydrocarbon black is 2:3:1.5.
Preferably, the age resistor is the mixture of antioxidant 4010NA and antioxidant A W.
Preferably, the mass ratio of antioxidant 4010NA and antioxidant A W is 1.5:2.
Preferably, the vulcanizing agent is 2,5- dimethyl -2,5- bis(t-butylperoxy)s hexane, the different trimerization of triallyl
The combination of one or two and the above in cyanate ester, cumyl peroxide, trimethoxy silane, hydroxy propyl methacrylate
Thing.
Due to using above-mentioned technical scheme, the beneficial effects of the invention are as follows：The present invention is with natural rubber and 4 third fluorine rubbers
Glue is primary raw material, and 4 third fluorubber have certain oil resistant, high temperature resistant and resistance to acids and bases in itself, coordinate haloflex, vinegar
Sour cellulose propionate significantly improves the oil resistance of rubber, and haloflex also has good anti-flammability and compatible
Property, being conducive to improving rubber fire-resistant and stability, ceramic has good dispersiveness, corrosion resistance, chemical stability,
Be conducive to elevating mechanism performance, hydrated alumina has good fire-retardant fireproof, received in the compounded mix of addition with waterglass
Rice graphene oxide has hydrophilic oleophobic property, has very strong isolation for oil-based solvent, and serpentine has heat-resisting, anti-corruption
Erosion, wearability, enhance the wearability of rubber.
The present invention with 4 third good fluorubber of natural rubber and oil resistivity as primary raw material, by add supporting material, resistance
Combustion agent, age resistor, vulcanizer etc. carry out cross-linking modified, and obtained product has excellent wearability, oil resistivity and anti-flammability, power
Learn performance strong, it is applied widely.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
Embodiment 1：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：45 parts of natural rubber, 4 third fluorubber 27
Part, 8 parts of cellulose acetate propionate, 12 parts of haloflex, 8 parts of nano zine oxide, 6 parts of ceramic, 4 parts of hydrated alumina,
6 parts of waterglass, 12 parts of compounded mix, 2 parts of age resistor, 4 parts of vulcanizing agent.
Embodiment 2：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：47 parts of natural rubber, 4 third fluorubber 32
Part, 6 parts of cellulose acetate propionate, 15 parts of haloflex, 10 parts of nano zine oxide, 7 parts of ceramic, 5 parts of hydrated alumina,
5 parts of waterglass, 10 parts of compounded mix, 3 parts of age resistor, 5 parts of vulcanizing agent.
Embodiment 3：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：50 parts of natural rubber, 4 third fluorubber 35
Part, 9 parts of cellulose acetate propionate, 13 parts of haloflex, 9 parts of nano zine oxide, 8 parts of ceramic, 5 parts of hydrated alumina,
4 parts of waterglass, 8 parts of compounded mix, 4 parts of age resistor, 3 parts of vulcanizing agent.
Embodiment 4：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：42 parts of natural rubber, 4 third fluorubber 30
Part, 7 parts of cellulose acetate propionate, 8 parts of haloflex, 6 parts of nano zine oxide, 5 parts of ceramic, 8 parts of hydrated alumina, water
9 parts of glass, 6 parts of compounded mix, 1 part of age resistor, 2 parts of vulcanizing agent.
Embodiment 5：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：40 parts of natural rubber, 4 third fluorubber 25
Part, 4 parts of cellulose acetate propionate, 10 parts of haloflex, 7 parts of nano zine oxide, 8 parts of ceramic, 7 parts of hydrated alumina,
8 parts of waterglass, 9 parts of compounded mix, 2 parts of age resistor, 4 parts of vulcanizing agent.
Embodiment 6：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：46 parts of natural rubber, 4 third fluorubber 20
Part, 5 parts of cellulose acetate propionate, 9 parts of haloflex, 8 parts of nano zine oxide, 6 parts of ceramic, 6 parts of hydrated alumina, water
3 parts of glass, 10 parts of compounded mix, 3 parts of age resistor, 3 parts of vulcanizing agent.
Embodiment 7：
A kind of modified abrasion resistant oil resistant flame retardant rubber is made up of following mass fraction：48 parts of natural rubber, 4 third fluorubber 22
Part, 7 parts of cellulose acetate propionate, 12 parts of haloflex, 9 parts of nano zine oxide, 5 parts of ceramic, 6 parts of hydrated alumina,
6 parts of waterglass, 11 parts of compounded mix, 3 parts of age resistor, 5 parts of vulcanizing agent.
Embodiment of the present invention product carries out performance test：
1) the embodiment product obtained by just having prepared, performance data (average value) is as follows：
Shore hardness：58HA
Tensile strength：21.5MPa
Tearing strength：64.2kN/m
Elongation rate of tensile failure：312.4%
2) by obtained 120 DEG C × 72h of embodiment product it is aging after, performance data (average value) is as follows：
Shore hardness：65HA
Tensile strength：18.6MPa
Tearing strength：54.1kN/m
Elongation rate of tensile failure：284.5%
3) by obtained -40 DEG C of embodiment product × 72h it is aging after, performance data (average value) is as follows：
Shore hardness：73HA
Tensile strength：18.3MPa
Tearing strength：53.2kN/m
Elongation rate of tensile failure：271.4%
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention has been described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic；And these modification or
Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.
Claims (7)
1. a kind of modified abrasion resistant oil resistant flame retardant rubber, it is characterised in that the modified abrasion resistant oil resistant flame retardant rubber is by following quality
Number is made：Natural rubber 40-50 parts, 4 third fluorubber 20-35 parts, cellulose acetate propionate 4-9 parts, haloflex 8-15
Part, nano zine oxide 6-10 parts, ceramic 5-8 parts, hydrated alumina 4-8 parts, waterglass 3-9 parts, compounded mix 6-12 parts,
Age resistor 1-4 parts, vulcanizing agent 2-5 parts.
2. modified abrasion resistant oil resistant flame retardant rubber according to claim 1, it is characterised in that the modified abrasion resistant oil resistant is fire-retardant
Rubber is made up of following mass fraction：Natural rubber 45-40 parts, 4 third fluorubber 30-35 parts, cellulose acetate propionate 6-9 parts,
Haloflex 12-15 parts, nano zine oxide 8-10 parts, ceramic 7-8 parts, hydrated alumina 6-8 parts, waterglass 6-9 parts,
Compounded mix 10-12 parts, age resistor 2-4 parts, vulcanizing agent 4-5 parts.
3. modified abrasion resistant oil resistant flame retardant rubber according to claim 1, it is characterised in that：The compounded mix includes nanometer
Graphene oxide, nano imvite and semi-reinforcing hydrocarbon black.
4. modified abrasion resistant oil resistant flame retardant rubber according to claim 3, it is characterised in that：Nano graphene oxide, nanometer
Montmorillonite is 2 with the mass ratio of semi-reinforcing hydrocarbon black:3:1.5.
5. modified abrasion resistant oil resistant flame retardant rubber according to claim 1, it is characterised in that：The age resistor is age resistor
The mixture of 4010NA and antioxidant A W.
6. modified abrasion resistant oil resistant flame retardant rubber according to claim 5, it is characterised in that：Antioxidant 4010NA and age resistor
The mass ratio of AW is 1.5:2.
7. modified abrasion resistant oil resistant flame retardant rubber according to claim 1, it is characterised in that：The vulcanizing agent is 2,5- diformazans
Base -2,5- bis(t-butylperoxy)s hexane, triallyl fulminuric acid fat, cumyl peroxide, trimethoxy silane,
The composition of one or two and the above in hydroxy propyl methacrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611165381.4A CN106832444A (en) | 2016-12-16 | 2016-12-16 | A kind of modified abrasion resistant oil resistant flame retardant rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611165381.4A CN106832444A (en) | 2016-12-16 | 2016-12-16 | A kind of modified abrasion resistant oil resistant flame retardant rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106832444A true CN106832444A (en) | 2017-06-13 |
Family
ID=59140390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611165381.4A Pending CN106832444A (en) | 2016-12-16 | 2016-12-16 | A kind of modified abrasion resistant oil resistant flame retardant rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106832444A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116333384B (en) * | 2023-03-14 | 2023-12-19 | 温州市优联新材料有限公司 | Wear-resistant heat-resistant high-elastic rubber outsole |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101387357A (en) * | 2007-09-11 | 2009-03-18 | E.I.内穆尔杜邦公司 | High strength fibre reinforced ventilating duct and use thereof |
| CN101616869A (en) * | 2007-03-02 | 2009-12-30 | 大塚化学株式会社 | Set has titanate, its manufacture method of alkali metal titanate and contains the resin combination that set has the titanate of alkali metal titanate |
| CN102791655A (en) * | 2010-03-05 | 2012-11-21 | 吉美特株式会社 | Ceramic composition, porous ceramic heat insulating material using same, and preparation method thereof |
| CN106147048A (en) * | 2015-03-31 | 2016-11-23 | 3M创新有限公司 | Sealing compositions and application thereof |
-
2016
- 2016-12-16 CN CN201611165381.4A patent/CN106832444A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101616869A (en) * | 2007-03-02 | 2009-12-30 | 大塚化学株式会社 | Set has titanate, its manufacture method of alkali metal titanate and contains the resin combination that set has the titanate of alkali metal titanate |
| CN101387357A (en) * | 2007-09-11 | 2009-03-18 | E.I.内穆尔杜邦公司 | High strength fibre reinforced ventilating duct and use thereof |
| CN102791655A (en) * | 2010-03-05 | 2012-11-21 | 吉美特株式会社 | Ceramic composition, porous ceramic heat insulating material using same, and preparation method thereof |
| CN106147048A (en) * | 2015-03-31 | 2016-11-23 | 3M创新有限公司 | Sealing compositions and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116333384B (en) * | 2023-03-14 | 2023-12-19 | 温州市优联新材料有限公司 | Wear-resistant heat-resistant high-elastic rubber outsole |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103665496B (en) | Flame resistance rubber | |
| CN102250437B (en) | Acidproof, alkali-proof and hydrogen-sulphide-corrosion-resistant aflas composite | |
| CN102417668A (en) | Cable sheath material for wind power generation and production method thereof | |
| CN106146926B (en) | A kind of heat-resisting ageing-resisting cable sheath material | |
| CN106046464A (en) | Oil-resistant and high-temperature-resistant mining cable sheath material and method for preparing same | |
| CN104046030A (en) | High temperature-resistant oil-resistant rubber | |
| CN104059264A (en) | Rubber material with fire resistance | |
| CN104961929A (en) | Low-smoke flame-retardant rubber cable material and preparation method thereof | |
| CN108102233A (en) | A kind of fire-retardant ageing-resistant sealing joint strip | |
| CN103665459B (en) | Fatigue-resisting rubber | |
| CN104059252A (en) | Rubber resisting thermal ageing | |
| CN103980601A (en) | Flame retardant and anti-aging cable sheath material | |
| CN204102597U (en) | A kind of waterproof anti-corrosion halogen-free high flame-retardant EVA electric wire | |
| CN106832444A (en) | A kind of modified abrasion resistant oil resistant flame retardant rubber | |
| CN104217797B (en) | Expansion halogen-free flame-retardant PP/EVA (polypropylene/ethylene-vinyl acetate) wire and cable composition and method for manufacturing same | |
| CN104356456A (en) | Fireproof rubber | |
| CN103242609A (en) | Multidimensional composite inorganic particle/tetrafluoroethylene-propylene rubber composite material | |
| CN108690293A (en) | A kind of high-low temperature resistant high strength PVC cable material | |
| CN112592537A (en) | High-elasticity cable protection pipe and preparation method thereof | |
| CN102070800B (en) | Nitrile rubber protective sleeve | |
| CN109762216A (en) | Fire-resistant corrosion-resistant rubber | |
| CN110862591A (en) | High-low temperature resistant anti-aging chloroprene rubber | |
| CN104072835A (en) | Fire-resistant rubber | |
| CN115612214A (en) | Low-Mooney high-hardness ethylene propylene diene monomer composite material and preparation method thereof | |
| CN109535505A (en) | A kind of instrument seal washer nitile-butadiene rubber composite material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170613 |
|
| RJ01 | Rejection of invention patent application after publication |