CN106830375A - A kind of hot-water boiler antisludging agent and its application method - Google Patents

A kind of hot-water boiler antisludging agent and its application method Download PDF

Info

Publication number
CN106830375A
CN106830375A CN201710059563.1A CN201710059563A CN106830375A CN 106830375 A CN106830375 A CN 106830375A CN 201710059563 A CN201710059563 A CN 201710059563A CN 106830375 A CN106830375 A CN 106830375A
Authority
CN
China
Prior art keywords
water
boiler
hot
antisludging agent
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710059563.1A
Other languages
Chinese (zh)
Other versions
CN106830375B (en
Inventor
檀伟伟
张琪
赵尔冰
张敬波
石佳玉
张玉绣
刘明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Chaoyang District Special Equipment Inspection & Testing Institute
Tianjin Normal University
Original Assignee
Beijing Chaoyang District Special Equipment Inspection & Testing Institute
Tianjin Normal University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Chaoyang District Special Equipment Inspection & Testing Institute, Tianjin Normal University filed Critical Beijing Chaoyang District Special Equipment Inspection & Testing Institute
Priority to CN201710059563.1A priority Critical patent/CN106830375B/en
Publication of CN106830375A publication Critical patent/CN106830375A/en
Application granted granted Critical
Publication of CN106830375B publication Critical patent/CN106830375B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/05Conductivity or salinity
    • C02F2209/055Hardness
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/07Alkalinity

Abstract

The invention discloses a kind of hot-water boiler antisludging agent, it is made up of the component of following parts by weight:0.023~0.090 part of 0.200~0.820 part of aliphatic alcohol polyethenoxy (15) ether and tannin extract.Antisludging agent of the present invention uses pure organic component, is complexed by with calcium ion and magnesium ion etc., prevents these ions from forming slightly solubility precipitation generation incrustation scale, does not produce grain slag, easy to use;Inventive formulation composition is simple, and raw materials used low cost is conducive to the industrially scalable application in future.

Description

A kind of hot-water boiler antisludging agent and its application method
Technical field
The present invention relates to boiler water-treatment technology field, it particularly relates to a kind of hot-water boiler antisludging agent and its use Method.
Background technology
With continuing to develop and progressive for society, the continuous improvement of commercial production scale and people's living standard is Chinese Boiler for producing is more and more with use.Boiler water quality treatment is to ensure boiler plant safety, an important process of economical operation Content.The purpose of boiler water process is to prevent gyp, corrosion, it is ensured that boiler working condition and quality is good.Do well at boiler water Reason to ensure safe and economical boiler run, economize on resources, environmental protection it is all significant.The water temperature of hot-water boiler is higher, pot The easy fouling of stove water, influences heat transfer efficiency and the safe operation of boiler, therefore, the research of hot-water boiler mitigation and antiscaling technology is with more important Practical significance.
Conventional hot-water boiler mitigation and antiscaling technology is to add medicament in the water in boiler at present, that is, add antisludging agent.Scale inhibition The inhibitor mechanism of agent is that chemically or physically chemical action occurs with the scale forming matter such as the calcium in boiler water, magnesium salts, and generation is loose Grain slag, reached by boiler blow-off prevent or mitigate gyp and corrosion purpose.Also life can be made by processes such as complexings Reaction into scale forming matter is difficult to carry out, and reaches the purpose of the generation for slowing down foulant.General antisludging agent is divided into inorganic inhibitors With the class of organic inhibitor agent two.Inorganic inhibitors are mainly including NaOH, sodium carbonate and phosphate etc.;Organic inhibitor agent is mainly wrapped Include sodium humate, organic phosphonate, organic carboxylate and some natural organic matters for containing tannin etc..The scale inhibition of these antisludging agents Mechanism is different, scale-inhibiting properties are also different.In addition, phosphorus-containing compound has harm to environment, to avoid making as far as possible in actual production Use these antisludging agents.
In the prior art, number of patent application 201110131224.2 discloses a kind of boiler scale inhibitor, the boiler scale-inhibition Agent is made up of HPMA, sodium dihydrogen phosphate, sodium polyacrylate, zinc sulfate, BTA and water.The pot of the invention Stove antisludging agent, can act at normal temperatures, and can be used under wider pH value.
And for example number of patent application 201610893177.8 is related to a kind of boiler recirculated water antisludging agent, belongs to boiler water process Technical field, the preferred technical scheme of the invention is:A kind of boiler recirculated water antisludging agent, it is characterised in that contain ethylenediamine Tetramethylene pitches Alendronate 6-8%, hydroxy ethylene diphosphonic acid 4-7%, disodium ethylene diamine tetraacetate 17-19%, polycyclic oxygen amber Amber acid 6-8.2%, balance of deionized water is adjusted to pH value 7.6-8.5 with sodium hydroxide solution.
The hot-water boiler antisludging agent that above-mentioned patent application is used is unfavorable for environmental protection based on acidic materials composition.
And for example number of patent application 201510967926.2 discloses a kind of descaling method of steam boiler, the steam boiler Interior setting ultrasonic generator, the descaling method of the steam boiler is comprised the following steps:A, injection scale remover;B, unlatching are described super Acoustic generator;C, by the steam copper furnace gas discharge;Liquid in D, discharge steam boiler.Steam boiler of the invention Descaling method, by using ultrasonic cleaning method, can quick, comprehensive and effectively remove obstinate incrustation scale, and scale remover Can be environmentally friendly domestic type formula, using safely, be readily available, corrosivity it is small, and scale removal, scale inhibition can be played and prevent from steaming At least triple function such as boiler furnace corrosion.The descaling method that the patent application is related to needs to be equipped with special ultrasonic generator.
The content of the invention
It is an object of the invention to propose a kind of hot-water boiler antisludging agent and its application method, can be in not welding Under the premise of, reach scale inhibition performance higher.
For achieving the above object, the technical proposal of the invention is realized in this way:
A kind of hot-water boiler antisludging agent, is made up of the component of following parts by weight:
0.023~0.090 part of 0.200~0.820 part of aliphatic alcohol polyethenoxy (15) ether and tannin extract.
Further, aliphatic alcohol polyethenoxy (15) ether is 0.820 part, and the tannin extract is 0.046 part.
A kind of application method of hot-water boiler antisludging agent as described above, to adding the scale inhibition in the hot-water boiler Agent, and make aliphatic alcohol polyethenoxy (15) ether, tannin extract and water ratio of weight and number be 0.200~0.820:0.023~0.090: 1000。
Further, the ratio of weight and number of aliphatic alcohol polyethenoxy (15) ether, tannin extract and water is 0.820:0.046: 1000。
Further, the pH value of hot water is 7-8 in regulation boiler.
Principle of the invention:
Organic matter in aliphatic alcohol polyethenoxy (15) ether and tannin extract dissolves with the metal cation salt generation in boiler reclaimed water Property chelate, from without generation the insoluble grain slag of solid.
Beneficial effects of the present invention:
1st, using pure organic component, it is complexed by with calcium ion and magnesium ion etc., prevents these ions from forming indissoluble Property precipitation generation incrustation scale, grain slag is not produced, it is easy to use;
2nd, inventive formulation composition is simple, and raw materials used low cost is conducive to the industrially scalable application in future.
Specific embodiment
Technical scheme is clearly and completely described below.
Boiler water sample is prepared first:The bicarbonate of the calcium chloride of 1.552g, the magnesium chloride of 1.336g and 2.016g is taken respectively Sodium is dissolved in 8L water, is stirred and is divided into 8 equal portions and be put into the conical flask of 5L, and 8 conical flask orders are entered into line label, Label is specially 1,2,3,4,5,6,7 and 8.Corresponding water sample total hardness is 7mmol/L, and calcium hardness is 3.5mmol/L, and basicity is 3mmol/L。
Embodiment 1
The tannin extract of aliphatic alcohol polyethenoxy (15) ether and 0.023g that take 0.820g is added in No. 1 conical flask, 80 degree, PH value be 7 constant temperature water bath in keep 8 hours.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, with the total hardness in ethylenediamine tetra-acetic acid (EDTA) complexometric titration water, calculates scale inhibition performance, and the result that will be calculated Record is in table 1.
Embodiment 2
The tannin extract of aliphatic alcohol polyethenoxy (15) ether and 0.046g that take 0.820g is added in No. 2 conical flasks, 80 degree, PH value be 7 constant temperature water bath in keep 8 hours.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, with the total hardness in ethylenediamine tetra-acetic acid (EDTA) complexometric titration water, calculates scale inhibition performance, and the result that will be calculated Record is in table 1.
Embodiment 3
The tannin extract of aliphatic alcohol polyethenoxy (15) ether and 0.090g that take 0.820g is added in No. 3 conical flasks, 80 degree, PH value be 7 constant temperature water bath in keep 8 hours.After being cooled to room temperature, 5mL volumetric flask constant volumes are used, filtered, take out filtrate 50mL, with the total hardness in ethylenediamine tetra-acetic acid (EDTA) complexometric titration water, calculates scale inhibition performance, and the result that will be calculated Record is in table 1.
Embodiment 4
The tannin extract of aliphatic alcohol polyethenoxy (15) ether and 0.046g that take 0.820g is added in No. 4 conical flasks, 80 degree, PH value be 8 constant temperature water bath in keep 8 hours.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, with the total hardness in ethylenediamine tetra-acetic acid (EDTA) complexometric titration water, calculates scale inhibition performance, and the result that will be calculated Record is in table 1.
Embodiment 5
The tannin extract of aliphatic alcohol polyethenoxy (15) ether and 0.046g that take 0.410g is added in No. 5 conical flasks, 80 degree, PH value be 7 constant temperature water bath in keep 8 hours.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, with the total hardness in ethylenediamine tetra-acetic acid (EDTA) complexometric titration water, calculates scale inhibition performance, and the result that will be calculated Record is in table 1.
Embodiment 6
The tannin extract of aliphatic alcohol polyethenoxy (15) ether and 0.046g that take 0.200g is added in No. 6 conical flasks, 80 degree, PH value be 7 constant temperature water bath in keep 8 hours.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, with the total hardness in ethylenediamine tetra-acetic acid (EDTA) complexometric titration water, calculates scale inhibition performance, and the result that will be calculated Record is in table 1.
Reference example 1
Aliphatic alcohol polyethenoxy (15) ether for taking 0.820g is added in No. 7 conical flasks, in the perseverance that 80 degree, pH value are 7 Kept for 8 hours in warm water bath.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, use ethylenediamine tetraacetic Total hardness in acetic acid (EDTA) complexometric titration water, the scale inhibition performance 65.4% for calculating.
Reference example 2
Aliphatic alcohol polyethenoxy (15) ether for taking 0.046g is added in No. 8 conical flasks, in the perseverance that 80 degree, pH value are 7 Kept for 8 hours in warm water bath.After being cooled to room temperature, 5L volumetric flask constant volumes are used, filtered, take out filtrate 50mL, use ethylenediamine tetraacetic Total hardness in acetic acid (EDTA) complexometric titration water, the scale inhibition performance 25.5% for calculating.
The test result of embodiment 1 to the scale inhibition performance of embodiment 6 is as shown in table 1:
Table 1
From above example scale inhibition result, antisludging agent of the invention has good scale inhibition effect, maximum scale inhibition performance More than 80% is reached, is a kind of simple, efficient, the environmentally friendly hot-water boiler antisludging agent of component.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.

Claims (5)

1. a kind of hot-water boiler antisludging agent, it is characterised in that be made up of the component of following parts by weight:
0.023~0.090 part of 0.200~0.820 part of aliphatic alcohol polyethenoxy (15) ether and tannin extract.
2. hot-water boiler antisludging agent according to claim 1, it is characterised in that aliphatic alcohol polyethenoxy (15) ether is 0.820 part, the tannin extract is 0.046 part.
3. a kind of application method of hot-water boiler antisludging agent as claimed in claim 1, it is characterised in that to the hot-water boiler It is interior to add the antisludging agent, and make the ratio of weight and number of aliphatic alcohol polyethenoxy (15) ether, tannin extract and water be 0.200~0.820: 0.023~0.090:1000.
4. method according to claim 3, it is characterised in that aliphatic alcohol polyethenoxy (15) ether, tannin extract and water Ratio of weight and number is 0.820:0.046:1000.
5. the method according to claim 3 or 4, it is characterised in that the pH value of hot water is 7-8 in regulation boiler.
CN201710059563.1A 2017-01-24 2017-01-24 Scale inhibitor for hot water boiler and application method thereof Expired - Fee Related CN106830375B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710059563.1A CN106830375B (en) 2017-01-24 2017-01-24 Scale inhibitor for hot water boiler and application method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710059563.1A CN106830375B (en) 2017-01-24 2017-01-24 Scale inhibitor for hot water boiler and application method thereof

Publications (2)

Publication Number Publication Date
CN106830375A true CN106830375A (en) 2017-06-13
CN106830375B CN106830375B (en) 2020-06-30

Family

ID=59123024

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710059563.1A Expired - Fee Related CN106830375B (en) 2017-01-24 2017-01-24 Scale inhibitor for hot water boiler and application method thereof

Country Status (1)

Country Link
CN (1) CN106830375B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110872152A (en) * 2019-11-29 2020-03-10 武汉钢铁有限公司 Composite scale inhibitor for blast furnace gas washing water and preparation and use methods thereof

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1066432A (en) * 1991-05-07 1992-11-25 朱朝木 Scale removal, scale inhibitor prescription and production method
CN1068802A (en) * 1991-07-13 1993-02-10 牡丹江市洗涤原料厂 Multifunctional water treating agent contg. organic phosphine
CN1175552A (en) * 1996-09-04 1998-03-11 高艳东 Antiscaling compound and its preparing method
CN101928073A (en) * 2010-08-30 2010-12-29 山东天地人锅炉制造安装有限公司 Descaling preservative for boilers
CN103030223A (en) * 2011-09-29 2013-04-10 中国石油化工股份有限公司 Treatment process of circulating cooling water with leaked ammonia nitrogen
CN103183416A (en) * 2011-12-27 2013-07-03 王炜 Steam boiler water treatment agent and preparation method and application method thereof
CN103525599A (en) * 2013-09-23 2014-01-22 杨桂望 Boiler scale remover
CN105036205A (en) * 2015-06-25 2015-11-11 庄秋荣 Solid agentia for boiler water treatment and preparation method thereof
CN105776589A (en) * 2016-04-25 2016-07-20 苏州能华节能环保科技有限公司 Non-phosphorus type environment-friendly slow-release scaling inhibitor
CN106219775A (en) * 2016-07-25 2016-12-14 江苏盛源燃气动力机械有限公司 A kind of electric kettle scale dissolver

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1066432A (en) * 1991-05-07 1992-11-25 朱朝木 Scale removal, scale inhibitor prescription and production method
CN1068802A (en) * 1991-07-13 1993-02-10 牡丹江市洗涤原料厂 Multifunctional water treating agent contg. organic phosphine
CN1175552A (en) * 1996-09-04 1998-03-11 高艳东 Antiscaling compound and its preparing method
CN101928073A (en) * 2010-08-30 2010-12-29 山东天地人锅炉制造安装有限公司 Descaling preservative for boilers
CN103030223A (en) * 2011-09-29 2013-04-10 中国石油化工股份有限公司 Treatment process of circulating cooling water with leaked ammonia nitrogen
CN103183416A (en) * 2011-12-27 2013-07-03 王炜 Steam boiler water treatment agent and preparation method and application method thereof
CN103525599A (en) * 2013-09-23 2014-01-22 杨桂望 Boiler scale remover
CN105036205A (en) * 2015-06-25 2015-11-11 庄秋荣 Solid agentia for boiler water treatment and preparation method thereof
CN105776589A (en) * 2016-04-25 2016-07-20 苏州能华节能环保科技有限公司 Non-phosphorus type environment-friendly slow-release scaling inhibitor
CN106219775A (en) * 2016-07-25 2016-12-14 江苏盛源燃气动力机械有限公司 A kind of electric kettle scale dissolver

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110872152A (en) * 2019-11-29 2020-03-10 武汉钢铁有限公司 Composite scale inhibitor for blast furnace gas washing water and preparation and use methods thereof
CN110872152B (en) * 2019-11-29 2022-04-29 武汉钢铁有限公司 Composite scale inhibitor for blast furnace gas washing water and preparation and use methods thereof

Also Published As

Publication number Publication date
CN106830375B (en) 2020-06-30

Similar Documents

Publication Publication Date Title
JPS58199878A (en) Method and composition for inhibiting corrosion and sedimentation in aqueous system
CN102515373B (en) Green corrosion and scale inhibitor for hot-water boiler
JP5946363B2 (en) Silica scale prevention method and scale inhibitor in water system, and water treatment method and water treatment agent that suppress silica scale and suppress metal corrosion
CN103466814A (en) High temperature resisting composite water treatment agent and preparation method thereof
CN104556427A (en) Composite efficient corrosion and scale inhibitor for ammonia still water treatment
CN104692545A (en) Scale inhibitor for boiler and water supply pipeline
CN103241846A (en) Composite scale and corrosion inhibitor
CN102344206A (en) Antiscaling boiler water treatment agent
JP5099884B2 (en) Corrosion inhibitor
CN113388456B (en) Medium-high pressure boiler anti-corrosion and scale-inhibiting cleaning agent and preparation method thereof
CN102534641A (en) Organic acid cleaning agent and manufacture method thereof
CN102897925A (en) Corrosion and scale inhibitor
CN102344202A (en) Multifunctional water treatment agent
CN106830375A (en) A kind of hot-water boiler antisludging agent and its application method
CN102084033A (en) Boiler water treatment agent and method for the treatment of water
CN107176703A (en) A kind of compound boiler scale-inhibition corrosion inhibitor and its preparation method and application
CN106434047A (en) Rapid anti-scaling agent of boiler
JP2848672B2 (en) High-temperature water-based corrosion inhibitor
EP0363439A1 (en) Treatment for water systems to inhibit corrosion and scale formation
CN106967537A (en) Treatment of Industrial Water device is removed contamination scale remover and preparation method thereof
CN102344205A (en) Boiler water treatment agent
JP5826622B2 (en) Metal anticorrosive
CN102491542B (en) Method for preparing corrosion and scale inhibitor
JPS6056080A (en) Anticorrosive for metal preventing formation of scale
JP5925593B2 (en) Metal anticorrosive and treatment method for boiler water system

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20200630

CF01 Termination of patent right due to non-payment of annual fee