CN106827703B - Macromolecule viscosity waterproof roll - Google Patents

Macromolecule viscosity waterproof roll Download PDF

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Publication number
CN106827703B
CN106827703B CN201611073689.6A CN201611073689A CN106827703B CN 106827703 B CN106827703 B CN 106827703B CN 201611073689 A CN201611073689 A CN 201611073689A CN 106827703 B CN106827703 B CN 106827703B
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China
Prior art keywords
layer
waterproof roll
upside
downside
modified asphalt
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CN201611073689.6A
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CN106827703A (en
Inventor
刘冠麟
樊哲新
黎家国
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Yunnan Glad City Defence Water Science And Technology Ltd
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Yunnan Glad City Defence Water Science And Technology Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00Layered products comprising a layer of bituminous or tarry substances
    • B32B11/10Layered products comprising a layer of bituminous or tarry substances next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00Layered products comprising a layer of bituminous or tarry substances
    • B32B11/04Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B11/046Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00Layered products comprising a layer of bituminous or tarry substances
    • B32B11/04Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B11/08Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/18Layered products comprising a layer of natural or synthetic rubber comprising butyl or halobutyl rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable

Landscapes

  • Laminated Bodies (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention belongs to waterproof roll fields, more particularly to a kind of macromolecule viscosity waterproof roll, including tire base, the upside of the tire base is equipped with the first modified asphalt layer, the upside of first modified asphalt layer is equipped with nonwoven layer, the upside of the nonwoven layer is equipped with separating film layer, the upside of the separating film layer is equipped with SBR layers, the downside of the tire base is equipped with the second modified asphalt layer, the downside of second modified asphalt layer is equipped with PVC alloy-layer, the downside of the PVC alloy-layer is equipped with SBS layers, SBS layers of the downside is equipped with fiberglass cloth, the downside of the fiberglass cloth is equipped with polyvinyl acetate layer.The waterproof roll tensile strength is high, and self-healing ability and root puncture resistant ability are strong, long service life.

Description

Macromolecule viscosity waterproof roll
Technical field
The invention belongs to waterproof roll fields, and in particular to a kind of macromolecule viscosity waterproof roll.
Background technique
Waterproof roll is mainly used for construction wall, roofing and tunnel, highway, refuse landfill etc., plays and resists The rollable flexible building material product at web-like of one kind of extraneous rainwater, underground water leakage, as between engineering foundation and building Ne-leakage connection, is the first barrier of entire engineering waterproofing, plays a crucial role to entire engineering.Waterproof roll is Pitch class or high score subclass waterproof material be immersed in and is fabricated on carcass.The tear-proof of waterproof roll in the prior art, Puncture resistant is indifferent, affects the waterproofness durability of waterproof roll entirety.
Authorized announcement date is on 2 20th, 2013, and Authorization Notice No. is the Chinese utility model patent of CN202742739U, A kind of planted roof root puncture waterproof roll is disclosed, the two sides of the compound plies of copper foil are respectively equipped with SBS modified pitch The outer surface of layer, the SBS modified asphalt layer is equipped with protective layer;The SBS modified asphalt layer is by added with chemical root resistance agent SBS modified pitch composition.The waterproof roll has waterproof and prevents the dual function of plant root puncture, but its tear-proof, Self-healing property, acid and alkali-resistance and resistance to chemical corrosion are poor.
Data of publication of application is on March 25th, 2015, and application publication number is the Chinese invention patent application of CN104441859A, A kind of waterproof roll, including waterproof layer are disclosed, the upper and lower surface of waterproof layer is respectively equipped with needle thorn nonwoven polypropylene fabric layer, knit stitch Pierce nonwoven polypropylene fabric layer;Upper needle thorn nonwoven polypropylene fabric layer is equipped with insulating layer, and insulating layer is equipped with aluminium foil layer;Knit stitch pierce polypropylene fibre without The lower surface of woven fabric layer is equipped with SBS modified asphalt layer, and the lower surface of SBS modified asphalt layer is equipped with anti-aging layer.Invention enhancing The resistance performance of waterproof roll and extend service life, but its tensile strength, puncture resistance are unsatisfactory.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of macromolecule viscosity waterproof rolls, to improve waterproof roll Tensile strength and puncture resistance.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
Macromolecule viscosity waterproof roll, including tire base, the upside of the tire base is equipped with the first modified asphalt layer, described The upside of first modified asphalt layer is equipped with nonwoven layer, and the upside of the nonwoven layer is equipped with separating film layer, the separating film layer Upside be equipped with SBR (butadiene-styrene rubber) layer, the downside of the tire base is equipped with the second modified asphalt layer, second modified pitch The downside of layer is equipped with PVC alloy-layer, and the downside of the PVC alloy-layer is equipped with SBS (s-B-S block copolymerization Object) layer, the downside of SBS (Styrene-Butadiene-Styrene Block Copolymer) layer is equipped with fiberglass cloth, the glass The downside of glass scrim cloth is equipped with polyvinyl acetate layer.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that the tire base is plant bast fiber layer. The plant bast fiber can be also possible to sisal fiber selected from flax, hemp, ramie and jute etc..Plant bast fiber Have the characteristics that anti-corrosion, wear-resisting, tough and tensile, anti-aging, stretch-proof and service life are long.Select plant bast fiber Zuo Tai base that can increase Add the tensile strength of waterproof roll, extend the service life of waterproof roll.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that the isolation film is PP or PE film.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that the separating film layer and SBR (butadiene-styrene rubber) Biological stopping area is additionally provided between layer.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that the nonwoven layer is polyester felt foundation. The polyester felt foundation has the function of chemical root resistance.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that set on the upside of SBR (butadiene-styrene rubber) layer It is equipped with flame-retardant layer;It is further preferred that the flame-retardant layer is fire-retardant polyphosphoric acid amine or flame-retardant acrylic fibre or fire resistance fibre or fire-retardant ring Oxygen resin.Flame-retardant layer is provided in waterproof roll, so that waterproof roll also has fireproof performance.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that in the biological stopping area and separating film layer Between be provided with third modified asphalt layer and the first copper foil, first copper foil is located at the upside of the third modified asphalt layer; It is further preferred that being additionally provided with self-adhesive layer on the downside of the polyvinyl acetate layer.Biological stopping area and the first copper foil combine, more Effective root puncture resistant.
In macromolecule viscosity waterproof roll provided by the invention, it is preferable that in the polyvinyl acetate layer and self-adhesion The second copper foil is additionally provided between layer.The second copper foil being arranged herein has the function of that termite-proof, preventing microorganism corrodes.
By adopting the above technical scheme, due to using plant bast fiber Zuo Tai base, the stretch-proof of waterproof roll is increased Intensity and the service life for extending waterproof roll;It is provided with three layers of modified asphalt layer in waterproof roll, increases waterproof roll Self-healing ability;The combination of nonwoven layer, biological stopping area and the first copper foil, improves the root puncture resistant ability of waterproof roll.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the macromolecule viscosity waterproof roll of one embodiment in the present invention;
Fig. 2 is the structural schematic diagram of the macromolecule viscosity waterproof roll of another embodiment in the present invention;
In figure: 1- plant bast fiber layer, the first modified asphalt layer of 2-, 3- polyester oil carpet veneer, 41-PP film layer, 42-PE Film layer, 5-SBR layers, the second modified asphalt layer of 6-, 7-PVC alloy-layer, 8-SBS layers, 9- glass layer, 10- polyvinyl acetate Ester layer, the fire-retardant polyacids amine layer of 11-, 12- biology stopping area, 13- third modified asphalt layer, the first copper foil of 14-, the second copper foil of 15-, 16- self-adhesive layer.
Specific embodiment
Specific embodiments of the present invention will be further explained with reference to the accompanying drawing.It should be noted that for The explanation of these embodiments is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, disclosed below The each embodiment of the present invention involved in technical characteristic can be combined with each other as long as they do not conflict with each other.
Embodiment 1
A kind of macromolecule viscosity waterproof roll is present embodiments provided, as shown in Figure 1, include plant bast fiber layer 1, The upside of plant bast fiber layer 1 is equipped with the first modified asphalt layer 2, and the upside of the first modified asphalt layer 2 is equipped with polyester malthoid base Layer 31 is equipped with PP film layer 41 in the upside of polyester malthoid base 31, and the upside of PP film layer 41 is equipped with SBR layer 5, plant bast fiber The downside of layer 1 is equipped with the second modified asphalt layer 6, and the downside of the second modified asphalt layer 6 is equipped with PVC alloy-layer 7, in PVC alloy-layer 7 Downside be equipped with SBS layer 8, the downside of SBS layer 8 be equipped with fiberglass cloth 9, the downside of fiberglass cloth 9 equipped with gather Vinyl acetate 10.
Embodiment 2
A kind of macromolecule viscosity waterproof roll is present embodiments provided, as shown in Fig. 2, include plant bast fiber layer 1, The upside of plant bast fiber layer 1 is equipped with the first modified asphalt layer 2, and the upside of the first modified asphalt layer 2 is equipped with polyester malthoid base Layer 3 is equipped with PE film layer 42 in the upside of polyester malthoid base 3, and the upside of PE film layer 42 is equipped with SBR layer 5, in the upside of SBR layer 5 It is provided with fire-retardant polyacids amine layer 11, biological stopping area 12 is provided between PE film layer 42 and fire-retardant polyacids amine layer 11, in PE film It is provided with third modified asphalt layer 13 and the first copper foil 14 between 42 layers and biological stopping area 12, the first copper foil 14 changes positioned at third Property bitumen layer 13 upside, the downside of plant bast fiber layer 1 be equipped with the second modified asphalt layer 6, the second modified asphalt layer 6 Downside is equipped with PVC alloy-layer 7, is equipped with SBS layer 8 in the downside of PVC alloy-layer 7, is equipped with glass fabric in the downside of SBS layer 8 Layer 9 is equipped with polyvinyl acetate layer 10 in the downside of fiberglass cloth 9, is equipped with certainly in the downside of polyvinyl acetate layer 10 Adhesion coating 16 is additionally provided with the second copper foil 15 between polyvinyl acetate layer 10 and self-adhesive layer 16.
Comparative example 1
It will be changed to mylar in plant bast fiber layer 1 in embodiment 1, remaining is consistent with embodiment 1.
Comparative example 2
Without the second modified asphalt layer 6, remaining is consistent with embodiment 1.
Comparative example 3
Without the second modified asphalt layer 6 and third modified asphalt layer 13, remaining is consistent with embodiment 2.
Comparative example 4
Without the first copper foil 14, remaining is consistent with embodiment 2.
Comparative example 5
Inanimate object stopping area 12 and the first copper foil 14, remaining is consistent with embodiment 2.
Test example
In order to verify technical effect of the invention, spy does following inspection:
As can be seen from the above table, the tensile strength of the product in comparative example 1 either laterally will be much small or longitudinal Elongation percentage and tearing strength are also far smaller than other products when other products, maximum pull.Therefore, plant bast fiber Elongation percentage and tearing strength when significantly improving tensile strength, the maximum pull of waterproof roll.
The puncture resistant ability of embodiment 2 and comparative example 3 is most strong, is secondly embodiment and comparative example 4, followed by comparative example 1 With 2, the puncture resistant ability of comparative example 5 is worst, and therefore, the combination of nonwoven layer, biological stopping area and the first copper foil can be significant Raising waterproof roll puncture resistant ability.
Embodiment 2, comparative example 4 and 5 the self-healing time be substantially less than embodiment 1, comparative example 1,2 and 3, wherein comparative example 3 self-healing time longest.Therefore, the second modified asphalt layer and third modified asphalt layer improve the self-healing energy of waterproof roll Power.
In conjunction with attached drawing, the embodiments of the present invention are described in detail above, but the present invention is not limited to described implementations Mode.For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, to these embodiments A variety of change, modification, replacement and modification are carried out, are still fallen in protection scope of the present invention.

Claims (5)

1. macromolecule viscosity waterproof roll, which is characterized in that including tire base, the upside of the tire base is equipped with the first modified drip Cyan layer, the upside of first modified asphalt layer are equipped with nonwoven layer, and the upside of the nonwoven layer is equipped with separating film layer, described The upside of separating film layer is equipped with SBR layers, and the downside of the tire base is equipped with the second modified asphalt layer, second modified asphalt layer Downside be equipped with PVC alloy-layer, the downside of the PVC alloy-layer is equipped with SBS layer, and SBS layers of the downside is equipped with glass fibre The downside of layer of cloth, the fiberglass cloth is equipped with polyvinyl acetate layer;
The tire base is plant bast fiber layer;
Biological stopping area is additionally provided between the separating film layer and SBR layers;
SBR layers of the upside is provided with flame-retardant layer;
Third modified asphalt layer and the first copper foil, first copper foil are provided between the biological stopping area and separating film layer Positioned at the upside of the third modified asphalt layer;
The flame-retardant layer is fire-retardant polyphosphoric acid amine or flame-retardant acrylic fibre or fire resistance fibre or fire retarding epoxide resin.
2. macromolecule viscosity waterproof roll according to claim 1, which is characterized in that the isolation film is PP or PE film.
3. macromolecule viscosity waterproof roll according to claim 1, which is characterized in that the nonwoven layer is polyester malthoid Base fabric.
4. macromolecule viscosity waterproof roll according to claim 1, which is characterized in that under the polyvinyl acetate layer Side is additionally provided with self-adhesive layer.
5. macromolecule viscosity waterproof roll according to claim 1, which is characterized in that in the polyvinyl acetate layer and The second copper foil is additionally provided between self-adhesive layer.
CN201611073689.6A 2016-11-29 2016-11-29 Macromolecule viscosity waterproof roll Active CN106827703B (en)

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Publication number Priority date Publication date Assignee Title
CN109504039B (en) * 2018-10-31 2021-03-19 湖北工业大学 Corrosion-resistant flexible epoxy resin root-puncture-resistant waterproof composite material
CN109677054B (en) * 2019-01-16 2020-11-24 中国电建集团山东电力建设有限公司 Anti-corrosion isolation plate for garbage power generation foundation pit and preparation method thereof
CN114249954A (en) * 2021-11-13 2022-03-29 郑州大学 Polymer waterproof coiled material and linear leakage detection method

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CN202658734U (en) * 2012-06-29 2013-01-09 山东汇源建材集团有限公司 High strength anti-aging polrvinyl chloride waterproofing coiled material
CN202787687U (en) * 2012-04-28 2013-03-13 湖北卓宝建筑节能科技有限公司 Roof waterproof coil material and polyurethane thermal-insulation integrated plate
CN203485511U (en) * 2013-09-18 2014-03-19 潍坊市华发防水材料有限公司 Root puncture resistant waterproof roll made of polyester reinforcements
CN205272737U (en) * 2015-12-18 2016-06-01 云南欣城防水科技有限公司 Root -penetration -resistant waterproof coiled material
CN206614866U (en) * 2016-11-29 2017-11-07 云南欣城防水科技有限公司 Macromolecule viscosity waterproof roll

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Publication number Priority date Publication date Assignee Title
CN101402770A (en) * 2008-10-17 2009-04-08 干方明 Polyvinyl chloride alloy
CN101818548A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Root thorn-proof and waterproof coiled material and preparation technology
CN202787687U (en) * 2012-04-28 2013-03-13 湖北卓宝建筑节能科技有限公司 Roof waterproof coil material and polyurethane thermal-insulation integrated plate
CN202658734U (en) * 2012-06-29 2013-01-09 山东汇源建材集团有限公司 High strength anti-aging polrvinyl chloride waterproofing coiled material
CN203485511U (en) * 2013-09-18 2014-03-19 潍坊市华发防水材料有限公司 Root puncture resistant waterproof roll made of polyester reinforcements
CN205272737U (en) * 2015-12-18 2016-06-01 云南欣城防水科技有限公司 Root -penetration -resistant waterproof coiled material
CN206614866U (en) * 2016-11-29 2017-11-07 云南欣城防水科技有限公司 Macromolecule viscosity waterproof roll

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