CN106827142A - A kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method - Google Patents

A kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method Download PDF

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Publication number
CN106827142A
CN106827142A CN201710001850.7A CN201710001850A CN106827142A CN 106827142 A CN106827142 A CN 106827142A CN 201710001850 A CN201710001850 A CN 201710001850A CN 106827142 A CN106827142 A CN 106827142A
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bamboo mat
bamboo
antibacterial
nano silver
solution
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CN106827142B (en
Inventor
于海霞
徐漫平
方崇荣
庄晓伟
杨伟明
王增
张建
潘炘
徐田
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Zhejiang Academy of Forestry
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ZHEJIANG PROV FOREST PRODUCT QUALITY INSPECTION STATION
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00—Chemical or physical treatment of reed, straw, or similar material
    • B27K9/002—Cane, bamboo
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/007—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows comprising deodorising, fragrance releasing, therapeutic or disinfecting substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G2009/001—Anti-allergen; Anti-mite
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G2400/00—Details not otherwise provided for in A47G19/00-A47G23/16
    • A47G2400/02—Hygiene
    • A47G2400/022—Antibacterial materials or layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/20—Removing fungi, molds or insects

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to provide a kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method; with the water extract or distilled water squeezeding juice of the natural biomass materials such as bamboo leaf, peanut shell, pomelo peel and orange peel as reducing agent and protective agent; reduction reaction is carried out to silver nitrate weak solution; form Silver Nanoparticles homogeneous solution; loaded on bamboo mat by the technique such as bamboo silk dipping or the brushing of bamboo mat top layer, play antibacterial, anti-mite effect.The internal package activated carbon of cellulose fibre at the bamboo mat back side, the formaldehyde to the release in bamboo mat glue-line and auxiliary material catches in time, reduces the release of formaldehyde.The E of the regulations of GB GB 18,580 2001 is can reach by bamboo mat burst size of methanal obtained in the inventive method1Level is required；Antibiotic property presses the tests of GB/T 20944.1 2007, and antibacterial bandwidth is more than 1mm, does not have bacterial reproduction, is tested by GB/T 20944.2 2007, antibacterial value >=1.With broad spectrum high-effect biocidal property, biomass material used originates wide, cheap and easy to get, environmental protection, reaction condition gently, with important application prospect.

Description

A kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method
(1) technical field
The present invention relates to a kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method.
(2) background technology
Bamboo mat is China's temperature, the upper essential product of tropical summer bed.The top layer of bamboo mat is establishment bamboo silk curtain, rich in nutrition Material, such as starch (2%~6%), protein (1.5%~6%), carbohydrate 2% and fat and wax (2%~4%), suitable Under the conditions of suitable temperature and humidity, it is easy to go mouldy and damage by worms.Additionally, bamboo mat is inconvenient to wash, as bedding, if Lack and dry (need to be exposed to the sun) environment or custom, the gap of bamboo mat and concave-convex surface position are easy to grow mite in use Worm, can cause the hidden danger such as allergic, be detrimental to health.
At present, most common bamboo mat is increased by bamboo curtain splint, gauze and back side reinforcement material up of three layers, gauze and the back side on the market Strong material carries out gluing by adhesive and bamboo curtain splint.Current enterprise's production bamboo mat uses urea-formaldehyde resin adhesive, glued to increase Intensity, formaldehyde applied amount is more, causes bamboo mat burst size of methanal (content) exceeded.The burst size of methanal World Health Organization (WHO) International cancer research institution (IARC) be defined as carcinogenic substance.With human body intimate contact during bamboo mat use, formaldehyde will Directly it is detrimental to health.Mainly take the development to the modified of Lauxite, Novel adhesive at present, and to its press-paste technique and The aspects such as subsequent treatment are improved, but have also been proposed new problem simultaneously, i.e., when burst size of methanal is reduced, back side reinforcing material Gluing between bamboo curtain splint is undesirable, is susceptible to degumming layering.Additionally, the back side reinforcement material of bamboo mat, i.e., so-called " rattan Grass " be really regenerated celulose fibre, have in process addition containing aldehyde adhesive possibility, be bamboo mat formaldehyde another come Source.
(3) content of the invention
A kind of technical barrier that the present invention exists for existing bamboo mat product, there is provided antibacterial, anti-mite, except aldehyde bamboo mat system Method is made, with the water extract of the natural biomass materials such as bamboo leaf, peanut shell, pomelo peel and orange peel as reducing agent and protection Agent, reduction reaction is carried out to silver nitrate weak solution, forms Silver Nanoparticles homogeneous solution, by bamboo silk dipping or bamboo mat top layer The techniques such as brushing are loaded on bamboo mat, play antibacterial, anti-mite effect.The internal package activity of cellulose fibre at the bamboo mat back side Charcoal, the formaldehyde to the release in bamboo mat glue-line and auxiliary material catches in time.
The technical solution adopted by the present invention is：
A kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method, methods described includes：
(1) fresh plant material is selected, is cleaned up, is dried, add 10~30min of boiling or plus distilled water in boiling water Squeeze the juice, filter, take filtrate constant volume, obtain natural extract solution A, (i.e. 10~50g plants are former for plant material crude drug content in extract solution Material, final to obtain 1L extract solutions) it is 10~50g/L；The plant material is one of following, but not limited to this：Bamboo leaf, peanut Shell, pomelo peel and orange peel；
(2) extract solution A is added in the silver nitrate solution B of 0.02~2mol/L of concentration, regulation pH value is to 7~12, then adds Enter appropriate distilled water, stir, obtain Nano Silver reaction liquid C, the silver ion final concentration of 0.8 in Nano Silver reaction liquid C ~1.5mmol/L, the extract solution A volumes of addition account for the 0.4%~20% of Nano Silver reaction liquid C volume；It is anti-under normal temperature condition Answer 8~24h or be heated to 70~100 DEG C of 15~60min of reaction, obtain dark Nano silver solution D；
(3) at normal temperatures and pressures, will prepare bamboo mat raw material bamboo silk after 2~6h of thorough impregnation in Nano silver solution D again It is made finished product bamboo mat, or in finished product bamboo mat surface spraying or brushes Nano silver solution D, is dried under normal temperature or cryogenic conditions to aqueous Rate is 7~11% (w/w)；
(4) bamboo mat back side cellulose fiber surface first applies one layer of tung oil, then dispersed active carbon powder, then wraps up again Cotton thread or folding, finally carry out compress, cutting edge, bound edge, obtain it is described it is antibacterial, anti-mite, except aldehyde bamboo mat finished product.
Silver is most widely used one kind in inorganic bacteriostatic agent, can reach elimination by haptoreaction and light-catalyzed reaction Hundreds of bacteriums and acarid class are had lethal by the effect of bacterium, and especially in the environment of warm moist, silver ion has Activity very high, is 120 times of general nano material bactericidal potency.Had using nano silver antibacterial agent obtained in plant extraction liquid There are strong and broad-spectrum antibacterial, hypotoxicity, a fast light hot, long-lasting, easily disperse, and bacterium is the characteristics of will not develop immunity to drugs.
It is in strip that bamboo mat back side reinforcing material is typically folded using regenerated celulose fibre parcel cotton thread in strip or directly Woven again to form, the present invention first applies one layer of tung oil, then dispersed active carbon powder on regenerated cellulose surface, then wraps again Wrap up in folding.Activated carbon internally can be breathed freely, the formaldehyde of the glue-line release regenerated celulose fibre and its between bamboo curtain splint Caught, had preferable effect to removal Form aldehyde release.
The plant material is preferably bamboo leaf.
Concentration of silver ions is 0.8~1.2mmol/L in the Nano Silver reaction liquid C, and the particle diameter of the Nano Silver of synthesis is 10 ~30nm.
Preferably, using nanoscale aperture active carbon powder, consumption is 20~50g/m to step (4)2Bamboo mat is (with bamboo mat face Integrating).
The beneficial effects are mainly as follows：The bamboo mat as obtained in the inventive method have strong and broad-spectrum antibacterial, Hypotoxicity, fast light hot, long-lasting, easily disperse, and bacterium is the characteristics of will not develop immunity to drugs.The present invention is fine at the bamboo mat back side The internal package activated carbon of cellulose fiber, the formaldehyde to the release in bamboo mat glue-line and auxiliary material catches in time so that finished product formaldehyde Burst size reaches standard requirement, and raw material sources are wide, cheap and easy to get, environmental protection, reaction condition are gentle, before important application Scape.
(4) illustrate
Fig. 1 is the inventive method flow chart.
(5) specific embodiment
With reference to specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in This：
Embodiment 1：
(1) fresh bamboo leaf is selected, is cleaned up, 80 DEG C of drying of baking oven take 2g and 15min is boiled in boiling water, and filtering is simultaneously Constant volume obtains bamboo leaf extract A to 100mL volumetric flasks, used as reducing agent and protective agent that Nano Silver synthesizes.Solution A is 2~6 Dark place is placed at a temperature of DEG C standby, the term of validity is 10 days.
(2) silver nitrate storing liquid B concentration is 0.05mol/L, takes 10mL silver nitrate storing liquids, adds 5mL bamboos leaf to extract Liquid A, with the H that concentration is 0.1N3PO4Regulation pH value is settled to 50mL, mixed liquor stirring 2min to 9, then with distilled water, is received The silver-colored reaction liquid C (between 10~30nm, concentration is 1.0mmol/L to Nano Silver particle diameter) of rice, reaction condition is 90 DEG C of water-baths 15min, the synthesis of Nano silver solution D is completed when solution colour is from yellow to dark brown.Nano silver particles in the solution D Stabilization can be kept in 3 months.
(3) at normal temperatures and pressures, by bamboo silk thorough impregnation 4h in solution D, dried under normal temperature after taking-up, be to moisture content 9%, it is made finished product bamboo mat according still further to common process；
(4) cellulose fiber surface of bamboo mat back side strengthening material first applies one layer of tung oil, then dispersed aperture is nanoscale Active carbon powder (particle diameter is in 10~50nm, the production of Hangzhou Heng Xing activated carbons Co., Ltd), then wraps up cotton thread again；
(5) operations such as compress, cutting edge, bound edge are carried out according to common process, completes the manufacture of bamboo mat.
Bamboo mat obtained by the inventive method has strong and broad-spectrum antibacterial, hypotoxicity, fast light hot, long-lasting, easily point Property is dissipated, and bacterium is the characteristics of will not develop immunity to drugs, after testing its burst size of methanal≤0.8mg/L.Antibiotic property presses GB/T 20944.1-2007 requirements, using a kind of gram-positive bacterium：Staphylococcus aureus (Staphylococcus Aureus), two kinds of gramnegative bacteriums：Friedlander's bacillus (Klebsiella pneumoniae) Escherichia coli (Escherichia coli) is tested, and antibacterial bandwidth is more than 1mm, does not have bacterial reproduction.Press GB/T 20944.2- simultaneously 2007 regulations, using a kind of gram-positive bacterium：Staphylococcus aureus (Staphylococcus aureus), two kinds of leather Gram-negative bacteria：Friedlander's bacillus (Klebsiella pneumoniae) Escherichia coli (Escherichia coli) Tested, antibacterial value ＞ 1.Mildew resistance by LY/T 2330-2013 requirements, using aspergillus niger (Aspergillus niger V.Tiegh), aspergillus flavus (Aspergillus flavus LK.), Penicillium citrinum (Penicillam citrinum Thom), green Wood fungus (Trichoderma viride Pers.ex Fr.), Aureobasidium pullulans (Aureobasidiumpullulans (de Bary) Arn.) and 6 kinds of moulds of chaetomium globosum (Chaetomium globosum Kunze ex Fr.) tested, test knot Fruit reaches 0 grade of requirement (surface does not have fungus growth, and low power (50 ×) Photobiology basis of microscopic observation also has no fungus growth).
Embodiment 2：
(1) fresh orange peel, is cleaned up, and takes 50g, adds 200mL distilled waters, and mixed liquor is squeezed the juice and obtains tangerine after filtering Sub- juice extract A, extract A place standby in 2~6 DEG C of temperature and dark place, and the term of validity is 10 days.
(2) silver nitrate storing liquid B is 0.01mol/L, takes 5mL silver nitrate solutiones, adds 0.5mL bamboo leaf extract A, is obtained Handy concentration of silver ions is the Nano Silver reaction liquid C of 1mmol/L, and pH value is adjusted to 11.5 with the NaOH solution that concentration is 0.1N, 50mL (between 10~30nm, concentration is 1mmol/L to Nano Silver particle diameter) uniform stirring 2min is settled to distilled water again, is reacted Condition is 80 DEG C of water-bath 15min, and the synthesis of Nano silver solution D is completed when solution colour is from yellow to dark brown.The solution In nano silver particles can in 3 months keep stabilization.
(3) at normal temperatures and pressures, by bamboo silk thorough impregnation 4h in solution D, dried under normal temperature after taking-up, be to moisture content 7~11%, it is made finished product bamboo mat according still further to common process；
(4) cellulose fiber surface of bamboo mat back side strengthening material first applies one layer of tung oil, then dispersed nano level active charcoal Powder (particle diameter is in 10~50nm, the production of Hangzhou Heng Xing activated carbons Co., Ltd), then wraps up cotton thread (or directly folding) again；
(5) operations such as compress, cutting edge, bound edge are carried out according to common process, completes the manufacture of bamboo mat.
Bamboo mat obtained by the inventive method has strong and broad-spectrum antibacterial, hypotoxicity, fast light hot, long-lasting, easily point Property is dissipated, and bacterium is the characteristics of will not develop immunity to drugs, and detected by GB 18580-2001, its burst size of methanal≤1.2mg/L.It is anti- Bacterium property by GB/T 20944.1-2007 requirements, using a kind of gram-positive bacterium：Staphylococcus aureus (Staphylococcus aureus), two kinds of gramnegative bacteriums：Friedlander's bacillus (Klebsiella Pneumoniae) Escherichia coli (Escherichia coli) are tested, and antibacterial bandwidth is more than 1mm, does not have bacterial reproduction. Specify by GB/T 20944.2-2007 simultaneously, using a kind of gram-positive bacterium：Staphylococcus aureus (Staphylococcus aureus), two kinds of gramnegative bacteriums：Friedlander's bacillus (Klebsiella Pneumoniae) Escherichia coli (Escherichia coli) are tested, antibacterial value ＞ 1.Mildew resistance presses LY/T 2330- 2013 require, using aspergillus niger (Aspergillus niger V.Tiegh), aspergillus flavus (Aspergillus flavus LK.), Penicillium citrinum (Penicillam citrinum Thom), green wood fungus (Trichoderma viride Pers.ex Fr.), Aureobasidium pullulans (Aureobasidiumpullulans (de Bary) Arn.) and chaetomium globosum (Chaetomium Globosum Kunze ex Fr.) 6 kinds of moulds are tested, and test result reaches 0 grade of requirement, and (surface does not have fungus growth, low (50 ×) Photobiology basis of microscopic observation also has no fungus growth again).
Summarize：
1st, the present invention adds nano level active charcoal in the reinforcing material of the bamboo mat back side, effectively catches formaldehyde in bamboo mat, without Burst size of methanal is the bamboo mat of 1.5~5.0mg/L before improving, national strong by that after active carbon absorption technology treatment, can reach Standard requirement (GB 18580-2001 ,≤1.5mg/L) processed.
2nd, be reducing agent reduction silver nitrate synthesizing nano-silver solution with Bamboo leaf extraction, be supported on bamboo mat surface have it is strong and (germ and mould are planted to Escherichia coli, staphylococcus, bacillus subtilis etc. more than 600 preferably suppression effect to broad-spectrum antibacterial Really), fungus resistance (has preferably resistance to aspergillus niger, aspergillus flavus, Penicillium citrinum, green wood fungus, Aureobasidium pullulans, chaetomium globosum etc. Effect), also there is certain prevention effect to acarid.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (4)

1. a kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacture method, methods described includes：
(1) fresh plant material is selected, is cleaned up, is dried, 10~30min boiled in addition boiling water or adds distilled water to squeeze the juice, Filtering, takes filtrate constant volume, obtains plant extraction liquid A, and plant material crude drug content is 10~50g/L in extract solution；The plant is former Expect for one of following：Bamboo leaf, peanut shell, pomelo peel and orange peel；
(2) extract solution A is added in the silver nitrate solution B of 0.02~2mol/L of concentration, regulation pH value is added suitable to 7~12 The distilled water of amount, stirs, and obtains Nano Silver reaction liquid C, and the silver ion final concentration of 0.8 in Nano Silver reaction liquid C~ 1.5mmol/L, the extract solution A volumes of addition account for the 0.4%~20% of Nano Silver reaction liquid C volume；Nano Silver reaction liquid C is normal Warm 8~24h of conditioned response is heated to 70~100 DEG C of 15~60min of reaction, obtains dark Nano silver solution D；
(3) at normal temperatures and pressures, the raw material bamboo silk that will prepare bamboo mat is made again after 2~6h of thorough impregnation in Nano silver solution D Finished product bamboo mat, or in finished product bamboo mat surface spraying or Nano silver solution D is brushed, it is 7~11% to dry to moisture content；
(4) bamboo mat back side cellulose fiber surface first applies one layer of tung oil, then dispersed active carbon powder, and cotton thread is then wrapped up again Or directly fold, finally carry out compress, cutting edge, bound edge, obtain it is described it is antibacterial, anti-mite, except aldehyde bamboo mat finished product.
2. the method for claim 1, it is characterised in that the plant material is bamboo leaf.
3. the method for claim 1, it is characterised in that in Nano Silver reaction liquid C concentration of silver ions be 0.8~ 1.2mmol/L, the particle diameter of the Nano Silver of synthesis is 10~30nm.
4. the method for claim 1, it is characterised in that activated carbon is preferably nanoscale aperture activated carbon powder in step (4) End, load capacity is 20~50g/m2Bamboo mat.
CN201710001850.7A 2017-01-03 2017-01-03 A kind of antibacterial, anti-mite, except aldehyde bamboo mat manufacturing method Active CN106827142B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107447495A (en) * 2017-06-16 2017-12-08 宁波东方席业有限公司 A kind of flame-proof antibiotic plastics mat and preparation method thereof
CN109440454A (en) * 2018-11-07 2019-03-08 温州格蕾斯服饰有限公司 A kind of method for sorting of antibacterial shirt
CN109750895A (en) * 2018-11-20 2019-05-14 盐城市昶桦户外用品股份有限公司 A kind of long-lived bamboo tent frames
CN112428380A (en) * 2020-11-18 2021-03-02 霍山泓浩竹艺有限公司 Preparation method of antibacterial environment-friendly bamboo basket

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Publication number Priority date Publication date Assignee Title
CN101733983A (en) * 2009-12-08 2010-06-16 德华兔宝宝装饰新材股份有限公司 Inorganic nano-silver mildew-proof antibacterial healthy decorative veneer and manufacturing method thereof
CN202191076U (en) * 2011-08-01 2012-04-18 启东连庭竹制品销售有限公司 Novel bamboo mat
CN103949658A (en) * 2014-05-09 2014-07-30 武汉纺织大学 Green synthesis method of nano-silver by utilizing eucommia ulmoides water extract
CN105291237A (en) * 2015-09-18 2016-02-03 安徽创业机电设备有限公司 Manufacturing process of wood handle having sterilization function

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101733983A (en) * 2009-12-08 2010-06-16 德华兔宝宝装饰新材股份有限公司 Inorganic nano-silver mildew-proof antibacterial healthy decorative veneer and manufacturing method thereof
CN202191076U (en) * 2011-08-01 2012-04-18 启东连庭竹制品销售有限公司 Novel bamboo mat
CN103949658A (en) * 2014-05-09 2014-07-30 武汉纺织大学 Green synthesis method of nano-silver by utilizing eucommia ulmoides water extract
CN105291237A (en) * 2015-09-18 2016-02-03 安徽创业机电设备有限公司 Manufacturing process of wood handle having sterilization function

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107447495A (en) * 2017-06-16 2017-12-08 宁波东方席业有限公司 A kind of flame-proof antibiotic plastics mat and preparation method thereof
CN109440454A (en) * 2018-11-07 2019-03-08 温州格蕾斯服饰有限公司 A kind of method for sorting of antibacterial shirt
CN109750895A (en) * 2018-11-20 2019-05-14 盐城市昶桦户外用品股份有限公司 A kind of long-lived bamboo tent frames
CN112428380A (en) * 2020-11-18 2021-03-02 霍山泓浩竹艺有限公司 Preparation method of antibacterial environment-friendly bamboo basket

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