CN106823308B - Environment-friendly water-based gluing closes mechanical lagging basketball - Google Patents
Environment-friendly water-based gluing closes mechanical lagging basketball Download PDFInfo
- Publication number
- CN106823308B CN106823308B CN201710040239.5A CN201710040239A CN106823308B CN 106823308 B CN106823308 B CN 106823308B CN 201710040239 A CN201710040239 A CN 201710040239A CN 106823308 B CN106823308 B CN 106823308B
- Authority
- CN
- China
- Prior art keywords
- glue
- natural gum
- environment
- leather
- formula natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004026 adhesive bonding Methods 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000003292 glue Substances 0.000 claims abstract description 77
- 239000004816 latex Substances 0.000 claims abstract description 60
- 229920000126 latex Polymers 0.000 claims abstract description 60
- 239000010985 leather Substances 0.000 claims abstract description 34
- 239000004744 fabric Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 18
- 230000007613 environmental effect Effects 0.000 claims abstract description 15
- 230000004224 protection Effects 0.000 claims abstract description 14
- 229920000728 polyester Polymers 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 4
- 229920001206 natural gum Polymers 0.000 claims description 49
- 238000004073 vulcanization Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 230000035800 maturation Effects 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 241001125620 Dermochelys coriacea Species 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 8
- 239000004568 cement Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 230000003796 beauty Effects 0.000 abstract description 2
- 230000033228 biological regulation Effects 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 239000004814 polyurethane Substances 0.000 description 15
- 230000006872 improvement Effects 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 230000036541 health Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 208000009146 rhinoscleroma Diseases 0.000 description 2
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 208000028571 Occupational disease Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 230000019771 cognition Effects 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 230000028161 membrane depolarization Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
- A63B41/02—Bladders
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
- A63B41/08—Ball covers; Closures therefor
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
- A63B41/10—Bladder and cover united
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J107/00—Adhesives based on natural rubber
- C09J107/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Tires In General (AREA)
Abstract
Environment-friendly water-based gluing closes mechanical lagging basketball, it is related to leather and fur products technical field；It includes environment-friendlyinner inner tire, and the outer surface of environment-friendlyinner inner tire is closely pasted with polyester material cloth by Heveatex glue, and the outer wall of polyester material cloth is bonded with PU leather crust by latex；Environment-friendlyinner inner tire is selected, PAHs < 1ppm environmental protection standard is met；It by it is existing quantify production in accessible highest environmental protection standard improve whole an order of magnitude；The environmental protection tests of 168 highest attention substances as defined in U.S. FDA food safety regulation and EU REACH Legislation can be passed through；Environmental protection quality can match in excellence or beauty medical grade standard；It is chemically crosslinked the material structural strength formed and fastness is much higher than the product of physical solidification bonding；It is high-efficient, the skills involved in the labour of operative employee are required to reduce；Water-base cement unit price of procurement is low, non-volatile, saves a large amount of solvent costs；Has environmentally friendly demonstration effect.
Description
Technical field
The present invention relates to leather and fur products technical fields, and in particular to a kind of environment-friendly water-based mechanical lagging basketball of gluing conjunction.
Background technique
Traditional glue bonds leather basketball (hereinafter referred to as gluing basketball, specific structure please refer to Fig. 1), be from inside to outside by
4 layers of inner tube of a tyre, casing play, encapsulated layer, leather structure composition.The inner tube of a tyre plays a part of to store gas and keeps certain air-tightness.Inside
Tire surface is wrapped up or is wound suitable chemical & blended fabric or yarn and constitutes casing play, then it is encapsulated be put into mold be sulfided into half at
Product --- middle tire.Middle tire surface polishing > gumming > applies solvent adhesive (corroding with organic solvent, swollen rubber surface), the leather back side
Also solvent adhesive is applied, mutually conjunction is finally sticked and final finished is made.
Excellent, the disadvantage of traditional product and technique:
1, advantage:
Traditional handicraft is continued to use nearly 40 years, and product is mature, is all generally being used from NBA superstar to street corner child；
The volatilization of solvent glue is fast, and first viscosity is good, is convenient for bonding operation；
Equipment investment is few, detective in project；Such as tire in outsourcing, only need 5-6 people can small lot production；
2, disadvantage:
Solvent glue is mainly made of organic solvent, synthetic rubber and resin etc., with erosion, swelling, infiltration material to be bonded
Body surface face volatilizees with solvent and generates scleroma, bonding；Belong to volatilization curing mechanism；Attempting the hot melt adhesive used in recent years is water
Property glue, using cooling and solidifying mechanism, swelling effect non-corrosive to rubber make bonding effect be inferior to solvent glue.
2 from macroscopically saying, category physical change, easily by adherend body material extend, by impacting object bend around
The factors such as deformation, variation of ambient temperature cause edge to stick up skin, degumming, and have both the feature felt hard after scleroma solidifies, lose
Sport balls, which should have comfortable slap feel and lead to the problem of resilience, to be substantially reduced, this point is for profession and high-level ratio
It is particularly important for matching sport balls.
Due to the presence of encapsulated layer, it is necessary to before gluing polish rubber with eliminate surface spit frost formation grease, avoid every
From effect (had bicycle tire patching experience has cognition), therefore the micro- bits of a large amount of rubber powders are generated in production；Largely use benzene class
Based on organic solvent as glue diluent, dissolvent residual in the volatilization and finished product in production causes occupational disease and harm
The greater risk of consumer health；Gluing workshop practitioner's leukaemia take place frequently and the immunity degradation of generality be to
" health, amusement " is the greatest satire of the sporting goods product of leading intension.
It is bigger to social danger to the concern deficiency of organic solvent residual in manufactured goods, due to the missing and prison of law making
Manage ineffective, it is ball to be full of a large amount of non-environmental protections in the market, seriously endangers we and follow-on health and safety.With polycyclic aromatic hydrocarbons (PAH)
(PAHs) for, PAHs belongs to height carcinogen.European Union environmental protection regulation is interpreted, PAHs > 10ppm (18 total) influences
Human health, the ball product of domestic market, the numerical value are generally 200-1000ppm, individually even as high as 2000ppm or more.
Currently, stepping up with environmental consciousness, various brands are researched and developed, in succession using so-called " Environment-friendlyglue glue ", depolarization
Individual manufacturers can produce the gluing basketball for meeting PAHs < 10ppm standard, specially sell to outside Europe, because of cost consideration, market is total
Physique office is not changed still using non-environmental protection product as mainstream using the essence of organic solvent, and volatile matter poisons health, pollution
The situation of atmosphere is still continuing；By the warning of " malicious plastic cement race track " event, the sport ball of high standard environment-friendly type is researched and developed, promoted as early as possible
Class is very urgent.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly water-based gluings to close mechanical lagging basketball, it is at low cost, quality is high, ring
It protects, environmentally friendly demonstration effect can be played.
In order to solve the problems existing in background technology, the present invention adopts the following technical scheme: a kind of environment-friendly water-based glue
Mechanical lagging basketball is binded, it includes environment-friendlyinner inner tire, and the outer surface of environment-friendlyinner inner tire is closely pasted by Heveatex glue
There is polyester material cloth, the outer wall of polyester material cloth is bonded with PU leather crust by latex.
The manufacturing method of the present invention comprises the steps of:
(S1) environment-friendlyinner inner tire is selected, PAHs < 1ppm environmental protection standard is met；
(S2) No. 1, No. 2 and No. 3 formula natural gum latex glue is prepared, respectively agitated > presulfurization > maturation > filtering
> tinning is stand-by；Wherein No. 1 formula natural gum latex glue is high temperature vulcanized 140-150 DEG C use, No. 2 formula natural gum latexes
It is 80-90 DEG C of cryogenic vulcanization use after glue and No. 3 formula natural gum latex glue scene mixing；Since PU leather is thermoplastic
Characteristic, cryogenic vulcanization technology effectively prevent PU leather in the obvious thinning and leather surface decorative pattern particle of 90 DEG C or more leather thicknesses
With the generation of high frequency thermoprint whole graduation；
(S3) tire tube air-inflating to standard size, upper No. 1 formula natural gum latex glue is dried in the shade stand-by；
(S4) cloth for selecting polyester material to be made into, does the constant load elongation percentage of fabric post-treatment process to standard, through detecting
After up to standard, No. 1 formula natural gum latex glue on gluing machine is cooling after the latex film of drying cloth surface uniform thickness, automatic attached
Upper PE film crimps for use together；
(S5) cloth of excessively good glue is cut into the pieces of cloth of required size in punching machine, is uniformly attached to the inner tube of a tyre table of first-class glue as required
Face, be then placed in standard module carry out it is high temperature vulcanized, tire in infantees is made；
(S6) tire surface sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue in infantees, cut,
PU leather (polyurethane leather) back side after printing also sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue
Water enters and heats thickening on drying tunnel assembly line, leather is well placed by press back in lagging mold, is put into tire in infantees, molds
Heating carries out cryogenic vulcanization；After reaching the process stipulation time, takes out i.e. production and complete, into inspection, packing department.
As a further improvement of the present invention；The parts by weight formula composition of No. 1 formula natural gum latex glue are as follows:
As a further improvement of the present invention；The parts by weight formula composition of No. 2 formula natural gum latex glue are as follows:
As a further improvement of the present invention；The parts by weight formula composition of No. 3 formula natural gum latex glue are as follows:
As a further improvement of the present invention；The cloth that the polyester material is made into is as casing play.
As a further improvement of the present invention；It is bonded between the pieces of cloth by latex film, completes to hand under high temperature action
Join (vulcanization) reaction.
As a further improvement of the present invention；Tire is in upper No. 2 formulas Heveatex in the PU leather crust and infantees
After+No. 3 formula natural gum latex glue of glue glue, in low-temperature catalyzed lower completion cross-linking reaction；To meet cryogenic vulcanization condition, and
For the generation for preventing low temperature glue from going bad at normal temperature, therefore use+No. 3 formula Heveatexes of No. 2 formula natural gum latex glue
Glue glue latex, remixes be used in combination when in use.
After adopting the above technical scheme, the invention has the following advantages:
1, environmentally friendly.Environment-friendly water-based gluing in the present invention closes mechanical lagging basketball and can be surveyed by European Union's PAHs < 1ppm environmental protection
Examination, by it is existing quantify production in accessible highest environmental protection standard improve whole an order of magnitude；It can be eaten by U.S. FDA
The environmental protection tests of 168 highest attention substances as defined in product security legislation and EU REACH Legislation；Environmental protection quality can match in excellence or beauty medical
Grade standard；
2, high-quality.It is chemically crosslinked the material structural strength formed and fastness is much higher than the product of physical solidification bonding；
3, inexpensive.It is high-efficient, the skills involved in the labour of operative employee are required to reduce；Water-base cement unit price of procurement is low, and nothing is waved
Hair, saves a large amount of solvent costs；
4, environmentally friendly demonstration effect: to related industry environment-friendly materials, environment-protective process, in terms of whole improve
It is led and impetus with improving undoubtedly play.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
It obtains other drawings based on these drawings.
Fig. 1 is the structural schematic diagram of gluing basketball in background technique；
Fig. 2 is the cross-sectional view of embodiment provided by the present invention；
Appended drawing reference:
1-PU leather crust；The aqueous glue-line of 2-；3- infantees casing play；4- environment-friendlyinner inner tire.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, right below in conjunction with specific embodiment
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are only to explain the present invention, and
It is not used in the restriction present invention.
Referring to Fig. 2, present embodiment uses following technical scheme: a kind of environment-friendly water-based mechanical lagging basket of gluing conjunction
Ball, it includes PU leather crust 1, aqueous glue-line 2, infantees casing play 3, environment-friendlyinner inner tire 4, and the outer surface of environment-friendlyinner inner tire 4 is logical
It crosses Heveatex glue and is closely pasted with infantees casing play 3 made of polyester material cloth, the outer wall of infantees casing play 3 passes through aqueous
Glue-line 2 is bonded with PU leather crust 1.
The manufacturing method of present embodiment comprises the steps of:
(S1) environment-friendlyinner inner tire is selected, PAHs < 1ppm environmental protection standard is met；
(S2) No. 1, No. 2 and No. 3 formula natural gum latex glue is prepared, respectively agitated > presulfurization > maturation > filtering
> tinning is stand-by；Wherein No. 1 formula natural gum latex glue is high temperature vulcanized 140-150 DEG C use, No. 2 formula natural gum latexes
It is 80-90 DEG C of cryogenic vulcanization use after glue and No. 3 formula natural gum latex glue scene mixing；Since PU leather is thermoplastic
Characteristic, cryogenic vulcanization technology effectively prevent PU leather in the obvious thinning and leather surface decorative pattern particle of 90 DEG C or more leather thicknesses
With the generation of high frequency thermoprint whole graduation；
(S3) tire tube air-inflating to standard size, upper No. 1 formula natural gum latex glue is dried in the shade stand-by；
(S4) cloth for selecting polyester material to be made into, does the constant load elongation percentage of fabric post-treatment process to standard, through detecting
After up to standard, No. 1 formula natural gum latex glue on gluing machine is cooling after the latex film of drying cloth surface uniform thickness, automatic attached
Upper PE film crimps for use together；
(S5) cloth of excessively good glue is cut into the pieces of cloth of required size in punching machine, is uniformly attached to the inner tube of a tyre table of first-class glue as required
Face, be then placed in standard module carry out it is high temperature vulcanized, tire in infantees is made；
(S6) tire surface sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue in infantees, cut,
PU leather (polyurethane leather) back side after printing also sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue
Water enters and heats thickening on drying tunnel assembly line, leather is well placed by press back in lagging mold, is put into tire in infantees, molds
Heating carries out cryogenic vulcanization；After reaching the process stipulation time, takes out i.e. production and complete, into inspection, packing department.
The parts by weight formula composition of No. 1 formula natural gum latex glue are as follows:
The parts by weight formula composition of No. 2 formula natural gum latex glue are as follows:
The parts by weight formula composition of No. 3 formula natural gum latex glue are as follows:
The cloth that the polyester material is made into is as casing play.
It is bonded between the pieces of cloth by latex film, crosslinking (vulcanization) reaction is completed under high temperature action.
Tire is in+No. 3 formula natural gum latexes of upper No. 2 formula natural gum latexes glue in the PU leather crust and infantees
After glue, in low-temperature catalyzed lower completion cross-linking reaction；To meet cryogenic vulcanization condition, and to prevent low temperature glue from becoming at normal temperature
The generation of matter, therefore+No. 3 formula natural gum latex glue latex of No. 2 formula natural gum latex glue are used, it remixes when in use
It is used in combination.
The principle of the present invention are as follows:
Heveatex is after the various raw material cooperations such as homogenizing agent, anti-coagulants, promotor, vulcanizing agent, heated completion latex
The chemical crosslinking of the intermolecular space network being made of monosulfidic bond, cystine linkage and polysulfide bond；
Natural emulsion water-base cement can largely infiltrate through in fabric table, form the stable accumulation glue film of thickness；
Under room temperature, just viscosity can be obtained natural emulsion water-base cement far away from organic solvent glue by suitably heating thickening
The viscosity that must be more convenient to operate；Stackable when i.e. cold not glue mutually, being stained with to tear when hot all can not tear open；
PU leather etc. common leather, as thermal plastic high polymer spring shape body have softening point it is low, but be suitble to be all high score
The characteristics of latex of son combines；Not being resistant to the heating of 100 DEG C of temperatures above, (temperature is slightly higher, and that surface particles will occur is all flat
The phenomenon that change, high frequency stamp disappears；And latex generally vulcanizes in 140 DEG C of completions), the present invention has used latex in No. 2 formulas
Room temperature vulcanization technology, lower 48 hours completion cross-linking reactions of room temperature can be crosslinked with relatively low temperature catalytic chemistry and be quickly completed.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (4)
1. environment-friendly water-based gluing closes mechanical lagging basketball, which is characterized in that it includes environment-friendlyinner inner tire, the appearance of environment-friendlyinner inner tire
Face is closely pasted with polyester material cloth by Heveatex glue, and the outer wall of polyester material cloth is bonded with outside PU leather by latex
Skin；
Its manufacturing method comprises the steps of:
(S1) environment-friendlyinner inner tire is selected, PAHs < 1ppm environmental protection standard is met；
(S2) No. 1, No. 2 and No. 3 formula natural gum latex glue is prepared, respectively agitated > presulfurization > maturation > filtering > dress
Tank is stand-by；Wherein No. 1 formula natural gum latex glue is high temperature vulcanized 140-150 DEG C use, No. 2 formula natural gum latex glue
It is 80-90 DEG C of cryogenic vulcanization use after being mixed with No. 3 formula natural gum latex glue scenes；Due to the thermoplastic spy of PU leather
Property, cryogenic vulcanization technology effectively prevent PU leather 90 DEG C or more leather thicknesses are obvious thinning and leather surface decorative pattern particle and
The generation of high frequency thermoprint whole graduation；
(S3) tire tube air-inflating to standard size, upper No. 1 formula natural gum latex glue is dried in the shade stand-by；
(S4) cloth for selecting polyester material to be made into, does the constant load elongation percentage of fabric post-treatment process to standard, up to standard through detecting
Afterwards, No. 1 formula natural gum latex glue on gluing machine, it is cooling after the latex film of drying cloth surface uniform thickness, PE is enclosed automatically
Film crimps for use together；
(S5) cloth of excessively good glue is cut into the pieces of cloth of required size in punching machine, is uniformly attached to the inner tyre surface of first-class glue as required,
It is high temperature vulcanized to be then placed in standard module progress, tire in infantees is made；
(S6) tire surface sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue in infantees, cuts, prints
The PU leather back side afterwards also sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue, enters drying tunnel stream
Thickening is heated on waterline, leather is well placed by press back in lagging mold, is put into tire in infantees, and molding heating carries out Sulfur-Vapor of Lower Temperature
Change；After reaching the process stipulation time, takes out i.e. production and complete, into inspection, packing department；
The parts by weight formula composition of No. 1 formula natural gum latex glue are as follows:
The parts by weight formula composition of No. 2 formula natural gum latex glue are as follows:
The parts by weight formula composition of No. 3 formula natural gum latex glue are as follows:
2. environment-friendly water-based gluing according to claim 1 closes mechanical lagging basketball, which is characterized in that the polyester material
The cloth being made into is as casing play.
3. environment-friendly water-based gluing according to claim 1 closes mechanical lagging basketball, which is characterized in that between the pieces of cloth
By latex impregnation film-forming binder, chemical crosslink reaction is completed under high temperature action.
4. environment-friendly water-based gluing according to claim 1 closes mechanical lagging basketball, which is characterized in that outside the PU leather
Tire is complete under low-temperature catalyzed after upper+No. 3 formula natural gum latex glue of No. 2 formula natural gum latexes glue in skin and infantees
At cross-linking reaction；To meet cryogenic vulcanization condition, and the generation to prevent low temperature glue from going bad at normal temperature, therefore uses No. 2 and match
+ No. 3 formula natural gum latex glue latex of square natural gum latex glue, remix be used in combination when in use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710040239.5A CN106823308B (en) | 2017-01-20 | 2017-01-20 | Environment-friendly water-based gluing closes mechanical lagging basketball |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710040239.5A CN106823308B (en) | 2017-01-20 | 2017-01-20 | Environment-friendly water-based gluing closes mechanical lagging basketball |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106823308A CN106823308A (en) | 2017-06-13 |
| CN106823308B true CN106823308B (en) | 2019-04-16 |
Family
ID=59123906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710040239.5A Active CN106823308B (en) | 2017-01-20 | 2017-01-20 | Environment-friendly water-based gluing closes mechanical lagging basketball |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106823308B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111037825A (en) * | 2019-12-18 | 2020-04-21 | 溧阳市山湖实业有限公司 | PHC luggage case cover plate one-step forming synthesis method |
| CN116271746B (en) * | 2023-02-03 | 2024-05-03 | 厦门元保运动器材有限公司 | Double-layer ball and preparation method thereof |
| CN116392786B (en) * | 2023-04-13 | 2023-12-01 | 南通高桥体育用品有限公司 | Environment-friendly water-based glue machine-attached volleyball and production process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201930476U (en) * | 2010-11-09 | 2011-08-17 | 蔡福源 | Ball |
| EP2397196A2 (en) * | 2010-06-18 | 2011-12-21 | Mikasa Corporation | Sports ball |
| CN103949040A (en) * | 2014-05-14 | 2014-07-30 | 丽水学院 | Teaching basketball |
| CN205598558U (en) * | 2016-01-26 | 2016-09-28 | 陈桂锋 | Football or volleyball |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040229722A1 (en) * | 2003-05-14 | 2004-11-18 | Yuan-Jung Liu | Method for making a ball and the product thereof |
-
2017
- 2017-01-20 CN CN201710040239.5A patent/CN106823308B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2397196A2 (en) * | 2010-06-18 | 2011-12-21 | Mikasa Corporation | Sports ball |
| CN201930476U (en) * | 2010-11-09 | 2011-08-17 | 蔡福源 | Ball |
| CN103949040A (en) * | 2014-05-14 | 2014-07-30 | 丽水学院 | Teaching basketball |
| CN205598558U (en) * | 2016-01-26 | 2016-09-28 | 陈桂锋 | Football or volleyball |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106823308A (en) | 2017-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106823308B (en) | Environment-friendly water-based gluing closes mechanical lagging basketball | |
| CN103951965B (en) | Color TPU (thermoplastic polyurethane) foam material and preparation method and application thereof as well as method for preparing molding body, sheet and shoe material by using same | |
| KR102476210B1 (en) | curing agent | |
| CN106009028B (en) | A kind of preparation method of colored or double-colored TPU expanded beads molding bonded body | |
| FR2643823A1 (en) | SPORTS OR LEISURE BALLS, COMPRISING AN OUTER LAYER OF FULL SKIN FOAM AND THEIR PROCESS | |
| US11760835B2 (en) | Curative and method | |
| KR101718314B1 (en) | Artificial leather using a polyester and the manufacturing method thereof | |
| CN103935058B (en) | Novel machine pastes the manufacture craft of basketball | |
| CN104044240B (en) | Injection moulding fag end and preparation method thereof | |
| CN109177370A (en) | Three layers of composite water-proof breathable fabric of one kind and preparation method thereof | |
| CN104262940A (en) | Colorful TPU (thermoplastic polyurethane) foaming material, method for preparing shoe material by colorful TPU foaming material and application | |
| CN103556485A (en) | Method for preparing environment-friendly outdoor sofa leather | |
| CN109337029A (en) | A kind of high abrasion TPU/ material silica gel composite and preparation method thereof | |
| CN104404785A (en) | Process for producing color-changed leather | |
| CN103422359A (en) | Artificial leather preparation technology and artificial leather | |
| CN107529494A (en) | A kind of environmentally friendly artificial synthetic leather and its manufacture method with adsorption function | |
| CN111469419A (en) | Processing technology of waterproof oil-proof anti-scalding TPU tablecloth pad | |
| CN204875329U (en) | Dry process is scalded and is pressed polyurethane synthetic leather that discolours | |
| CN103535958B (en) | A kind of waistband corium and preparation method thereof | |
| TW201431670A (en) | Composite laminated structure for shoe stiffener and preparing method thereof | |
| CN106881880B (en) | A kind of moulding of vehicle steering wheel and the manufacture craft for coating carbon fiber | |
| CN107183801A (en) | A kind of silk cotton body, silk cotton mold cup and its manufacture method | |
| CN104875396A (en) | Production method of auxiliary material for clothing and footwear | |
| CN112537107A (en) | High-performance styrene-butadiene block copolymer-based superfine fiber synthetic leather and production method thereof | |
| CN105904752A (en) | Method for integrally molding midsole and outsole in midsole production process, and sole made through method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200604 Address after: 226146 east side of Jiankang Road, Shuxun Town, Haimen City, Nantong City, Jiangsu Province Patentee after: NANTONG GAOQIAO SPORTING GOODS Co.,Ltd. Address before: 200333, 606-607-608, room 11, 601 lane, Nu River Road, Shanghai, Putuo District Patentee before: Zhu Yu |
|
| TR01 | Transfer of patent right |