CN106823308A - Environment-friendly water-based gluing closes mechanical lagging basketball - Google Patents
Environment-friendly water-based gluing closes mechanical lagging basketball Download PDFInfo
- Publication number
- CN106823308A CN106823308A CN201710040239.5A CN201710040239A CN106823308A CN 106823308 A CN106823308 A CN 106823308A CN 201710040239 A CN201710040239 A CN 201710040239A CN 106823308 A CN106823308 A CN 106823308A
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- glue
- natural gum
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- cloth
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- 238000004026 adhesive bonding Methods 0.000 title claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000003292 glue Substances 0.000 claims abstract description 76
- 239000004816 latex Substances 0.000 claims abstract description 62
- 229920000126 latex Polymers 0.000 claims abstract description 62
- 239000004744 fabric Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000010985 leather Substances 0.000 claims abstract description 19
- 230000007613 environmental effect Effects 0.000 claims abstract description 16
- 230000004224 protection Effects 0.000 claims abstract description 16
- 229920000728 polyester Polymers 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 238000012360 testing method Methods 0.000 claims abstract description 5
- 229920001206 natural gum Polymers 0.000 claims description 49
- 238000004073 vulcanization Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 9
- 238000005516 engineering process Methods 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 230000035800 maturation Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 8
- 206010039509 Scab Diseases 0.000 abstract description 7
- 239000004568 cement Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 230000033228 biological regulation Effects 0.000 abstract description 3
- 230000003796 beauty Effects 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 235000021393 food security Nutrition 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 description 16
- 230000006872 improvement Effects 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 230000036541 health Effects 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 208000009146 rhinoscleroma Diseases 0.000 description 2
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- 241001125620 Dermochelys coriacea Species 0.000 description 1
- 208000028571 Occupational disease Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 230000019771 cognition Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000028161 membrane depolarization Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
- A63B41/02—Bladders
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
- A63B41/08—Ball covers; Closures therefor
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B41/00—Hollow inflatable balls
- A63B41/10—Bladder and cover united
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J107/00—Adhesives based on natural rubber
- C09J107/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Tires In General (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
Environment-friendly water-based gluing closes mechanical lagging basketball, and it is related to leather and fur products technical field；It includes environment-friendlyinner inner tire, and the outer surface of environment-friendlyinner inner tire is closely pasted with polyester material cloth by Heveatex glue, and the outer wall of polyester material cloth is bonded with PU leather crusts by latex；From environment-friendlyinner inner tire, meet PAHs ＜ 1ppm environmental protection standards；It by it is existing quantify production in accessible highest environmental protection standard improve whole an order of magnitude；168 environmental protection tests of highest attention material that can be specified by U.S. FDA food security regulation and EU REACH Legislation；Environmental protection quality can match in excellence or beauty medical grade standard；The material structural strength and fastness that are formed are chemically crosslinked far above the product that physical solidification is bonded；Efficiency high, the skills involved in the labour requirement to operative employee is reduced；Water-base cement unit price of procurement is low, non-volatile, saves a large amount of solvent costs；Possesses environmentally friendly demonstration effect.
Description
Technical field
The present invention relates to leather and fur products technical field, and in particular to a kind of environment-friendly water-based gluing closes mechanical lagging basketball.
Background technology
Traditional glue bonds leather basketball (hereinafter referred to as gluing basketball, concrete structure refers to Fig. 1), be from inside to outside by
The inner tube of a tyre, casing play, encapsulated layer, the Rotating fields of leather 4 composition.The inner tube of a tyre plays storage gas and keeps certain air-tightness.Including
Appropriate chemical ＆ blended fabric is wrapped up or wound on tire surface or yarn constitutes casing play, then it is encapsulated be put into mould be sulfided into half into
Product --- middle tire.Middle tire surface polishing ＞ gummings ＞ applies solvent adhesive (with organic solvent erosion, swollen rubber surface), the leather back side
Also solvent adhesive is applied, mutually conjunction is finally sticked and is made final finished.
Excellent, the shortcoming of traditional product and technique：
1st, advantage：
Traditional handicraft is continued to use nearly 40 years, and product is ripe, is all being commonly used to street corner child from NBA superstar；
The volatilization of solvent glue is fast, and just viscosity is good, is easy to bonding operation；
Equipment investment is few, detective in project；Such as tire in outsourcing, small lot batch manufacture by 5-6 people is only needed；
2nd, shortcoming：
Solvent glue is mainly made up of organic solvent, synthetic rubber and resin etc., with erosion, swelling, infiltration material to be bonded
Body surface face, volatilizees with solvent and produces scleroma, bonding；Belong to volatilization curing mechanism；The PUR for attempting using in recent years is water
Property glue, using cooling and solidifying mechanism, swelling effect non-corrosive to rubber cause that bonding effect is inferior to solvent glue.
2, from macroscopically saying, belong to physical change, easily by adherend body material extend, by impacting object bend around
The factors such as deformation, variation of ambient temperature cause edge to stick up skin, degumming, and have the feature that feel is hardened after scleroma solidifies concurrently, lose
Sport balls should have comfortable slap feel and produce the problem that resilience substantially reduces, and this point is for professional and high-level ratio
It is particularly important for match sport balls.
Due to the presence of encapsulated layer, it is necessary to polish rubber before gluing to eliminate the grease that frost formation is told on surface, it is to avoid every
From effect (had bicycle tire patching experience has cognition), therefore the micro- bits of a large amount of rubber powders are produced in production；It is a large amount of to use benzene class
Based on organic solvent as glue diluent, dissolvent residual in the volatilization and finished product in production causes occupational disease and harm
The greater risk of consumer health；Gluing workshop practitioner leukaemia take place frequently and generality immunity degradation be to
" health, amusement " is the greatest satire of the sporting goods product of leading intension.
Concern to organic solvent residual in manufactured goods is not enough bigger to social danger, due to the missing and prison of law making
Pipe is ineffective, and it is ball that in the market is full of a large amount of non-environmental protections, serious harm we and follow-on health and safety.With polycyclic aromatic hydrocarbons (PAH)
(PAHs) as a example by, PAHs belongs to height carcinogen.European Union environmental protection regulation is understood, PAHs ＞ 10ppm (18 add up to) are influence
Human health, the ball product of domestic market, numerical value is generally 200-1000ppm, individually even as high as more than 2000ppm.
Currently, stepping up with environmental consciousness, various brands are researched and developed, use so-called " Environment-friendlyglue glue ", depolarization in succession
Indivedual manufacturers can produce the gluing basketball for meeting PAHs ＜ 10ppm standards, specially sell to outside Europe, and because of cost consideration, market is total
Still using non-environmental protection product as main flow, it uses the essence of organic solvent not change for physique office, and volatile matter poisons health, pollution
The situation of air is still continuing；By the warning of " malicious plastic cement race track " event, the sport ball of high standard environment-friendly type is researched and developed, promoted as early as possible
Class is very urgent.
The content of the invention
Mechanical lagging basketball is closed it is an object of the invention to provide a kind of environment-friendly water-based gluing, its low cost, quality are high, ring
Protect, environmentally friendly demonstration effect can be played.
In order to solve the problems existing in background technology, the present invention is to use following technical scheme：A kind of environment-friendly water-based glue
The mechanical lagging basketball of bonding, it includes environment-friendlyinner inner tire, and the outer surface of environment-friendlyinner inner tire is closely pasted by Heveatex glue
The outer wall for having polyester material cloth, polyester material cloth is bonded with PU leather crusts by latex.
Manufacture method of the invention is comprised the steps of：
(S1) environment-friendlyinner inner tire is selected, meets PAHs ＜ 1ppm environmental protection standards；
(S2) No. 1, No. 2 and No. 3 formula natural gum latex glue is prepared, respectively agitated ＞ presulfurizations ＞ maturations ＞ filterings
＞ tinnings are stand-by；Wherein No. 1 formula natural gum latex glue is used for high temperature vulcanized 140-150 DEG C, No. 2 formula natural gum latexes
For 80-90 DEG C of cryogenic vulcanization is used after glue and No. 3 formula natural gum latex glue scene mixing；Because PU leathers are thermoplastic
Characteristic, cryogenic vulcanization technology effectively prevent the PU leathers obvious thinning and leather surface decorative pattern particle of the leather thicknesses more than 90 DEG C
With the generation of high frequency thermoprint whole graduation；
(S3) to standard size, upper No. 1 formula natural gum latex glue dries in the shade stand-by to tire tube air-inflating；
(S4) cloth being made into from polyester material, does the constant load elongation percentage of fabric post-treatment operation to standard, after testing
After up to standard, No. 1 formula natural gum latex glue, cools down after the latex film of drying cloth surface uniform thickness on gluing machine, automatic attached
Upper PE films crimp stand-by in the lump；
(S5) cloth of excessively good glue is cut into the pieces of cloth of required size in punch press, the inner tube of a tyre table of first-class glue is uniformly attached on request
Face, being then placed in Standard Module carries out high temperature vulcanized, is made tire in infantees；
(S6) the formula natural gum latex glue+3 of tire surface spraying 2 formula natural gum latex glue in infantees, cut,
PU leathers (polyurethane leather) back side after printing also sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue
Water, enters and thickening is heated on drying tunnel streamline, and leather is well placed by press back in lagging mould, is put into tire in infantees, matched moulds
Heating carries out cryogenic vulcanization；After reaching the process stipulation time, take out i.e. production and complete, into inspection, packing department.
As a further improvement on the present invention；The weight portion formula of No. 1 described formula natural gum latex glue constitutes and is：
As a further improvement on the present invention；The weight portion formula of No. 2 described formula natural gum latex glue constitutes and is：
As a further improvement on the present invention；The weight portion formula of No. 3 described formula natural gum latex glue constitutes and is：
As a further improvement on the present invention；The cloth that described polyester material is made into is used as casing play.
As a further improvement on the present invention；Bonded by latex film between described pieces of cloth, complete to hand under high temperature action
Connection (vulcanization) reaction.
As a further improvement on the present invention；Tire is formulated Heveatex at upper No. 2 in described PU leathers crust and infantees
After+No. 3 formula natural gum latex glue of glue glue, in low-temperature catalyzed lower completion cross-linking reaction；To meet cryogenic vulcanization condition, and
It is the generation for preventing low temperature glue from going bad at normal temperatures, therefore uses+No. 3 formula Heveatexes of No. 2 formula natural gum latex glue
Glue glue latex, remixes be used in combination when in use.
After adopting the above technical scheme, the invention has the advantages that：
1st, environmental protection.Environment-friendly water-based gluing in the present invention is closed mechanical lagging basketball and can be surveyed by European Union's PAHs ＜ 1ppm environmental protection
Examination, by it is existing quantify production in accessible highest environmental protection standard improve whole an order of magnitude；Can be eaten by U.S. FDA
168 environmental protection tests of highest attention material of product security legislation and EU REACH Legislation regulation；Environmental protection quality can match in excellence or beauty medical
Level standard；
2nd, high-quality.The material structural strength and fastness that are formed are chemically crosslinked far above the product that physical solidification is bonded；
3rd, low cost.Efficiency high, the skills involved in the labour requirement to operative employee is reduced；Water-base cement unit price of procurement is low, and nothing is waved
Hair, saves a large amount of solvent costs；
4th, environmentally friendly demonstration effect：Entirety to related industry at aspects such as environment-friendly materials, environment-protective process, labor protections is improved
Led and impetus with improving undoubtedly play.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
The accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the structural representation of gluing basketball in background technology；
Fig. 2 is the sectional view of embodiment provided by the present invention；
Reference：
1-PU leather crusts；The aqueous glue-lines of 2-；3- infantees casing plays；4- environment-friendlyinner inner tires.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with specific embodiment
The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only used to explain the present invention, and
It is not used in the restriction present invention.
Fig. 2 is referred to, this specific embodiment uses following technical scheme：A kind of environment-friendly water-based gluing closes mechanical lagging basket
Ball, it includes PU leathers crust 1, aqueous glue-line 2, infantees casing play 3, environment-friendlyinner inner tire 4, and the outer surface of environment-friendlyinner inner tire 4 leads to
Cross Heveatex glue and be closely pasted with the infantees casing play 3 that polyester material cloth is made, the outer wall of infantees casing play 3 is by aqueous
Glue-line 2 is bonded with PU leathers crust 1.
The manufacture method of this specific embodiment is comprised the steps of：
(S1) environment-friendlyinner inner tire is selected, meets PAHs ＜ 1ppm environmental protection standards；
(S2) No. 1, No. 2 and No. 3 formula natural gum latex glue is prepared, respectively agitated ＞ presulfurizations ＞ maturations ＞ filterings
＞ tinnings are stand-by；Wherein No. 1 formula natural gum latex glue is used for high temperature vulcanized 140-150 DEG C, No. 2 formula natural gum latexes
For 80-90 DEG C of cryogenic vulcanization is used after glue and No. 3 formula natural gum latex glue scene mixing；Because PU leathers are thermoplastic
Characteristic, cryogenic vulcanization technology effectively prevent the PU leathers obvious thinning and leather surface decorative pattern particle of the leather thicknesses more than 90 DEG C
With the generation of high frequency thermoprint whole graduation；
(S3) to standard size, upper No. 1 formula natural gum latex glue dries in the shade stand-by to tire tube air-inflating；
(S4) cloth being made into from polyester material, does the constant load elongation percentage of fabric post-treatment operation to standard, after testing
After up to standard, No. 1 formula natural gum latex glue, cools down after the latex film of drying cloth surface uniform thickness on gluing machine, automatic attached
Upper PE films crimp stand-by in the lump；
(S5) cloth of excessively good glue is cut into the pieces of cloth of required size in punch press, the inner tube of a tyre table of first-class glue is uniformly attached on request
Face, being then placed in Standard Module carries out high temperature vulcanized, is made tire in infantees；
(S6) the formula natural gum latex glue+3 of tire surface spraying 2 formula natural gum latex glue in infantees, cut,
PU leathers (polyurethane leather) back side after printing also sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue
Water, enters and thickening is heated on drying tunnel streamline, and leather is well placed by press back in lagging mould, is put into tire in infantees, matched moulds
Heating carries out cryogenic vulcanization；After reaching the process stipulation time, take out i.e. production and complete, into inspection, packing department.
The weight portion formula of No. 1 described formula natural gum latex glue constitutes and is：
The weight portion formula of No. 2 described formula natural gum latex glue constitutes and is：
The weight portion formula of No. 3 described formula natural gum latex glue constitutes and is：
The cloth that described polyester material is made into is used as casing play.
Bonded by latex film between described pieces of cloth, crosslinking (vulcanization) reaction is completed under high temperature action.
Tire is formulated+No. 3 formula natural gum latexes of natural gum latex glue at upper No. 2 in described PU leathers crust and infantees
After glue, in low-temperature catalyzed lower completion cross-linking reaction；To meet cryogenic vulcanization condition, and to prevent low temperature glue from becoming at normal temperatures
The generation of matter, therefore+No. 3 formula natural gum latex glue latex of No. 2 formula natural gum latex glue are used, remix when in use
It is used in combination.
Principle of the invention is：
After Heveatex coordinates through the various raw materials such as homogenizing agent, anti-coagulants, accelerator, vulcanizing agent, heated completion latex
The chemical crosslinking of the intermolecular space network being made up of monosulfidic bond, cystine linkage and polysulfide bond；
Natural emulsion water-base cement can be infiltrated through largely in fabric table, form the accumulation glued membrane of thickness stabilization；
Under normal temperature, just viscosity, far away from organic solvent glue, can be obtained natural emulsion water-base cement by appropriate heating thickening
Must be more convenient for the viscosity for operating；It is stackable when i.e. cold not glue mutually, it is stained with to tear when hot and all can not tear open；
The common leathers such as PU leather, have softening point low as thermal plastic high polymer spring shape body, but are adapted to and are all high score
The characteristics of latex combination of son；(temperature is slightly higher, and that surface particles will occur is all flat not to be resistant to 100 DEG C of heating of temperatures above
Change, the phenomenon that high frequency stamp disappears；And latex is general in 140 DEG C of completion vulcanizations), the present invention has used latex in being formulated at No. 2
Room temperature vulcanization technology, normal temperature completes cross-linking reaction in lower 48 hours, can be crosslinked with relatively low temperature catalytic chemistry and quickly completed.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires to be limited rather than described above, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (8)
1. environment-friendly water-based gluing closes mechanical lagging basketball, it is characterised in that it includes environment-friendlyinner inner tire, the appearance of environment-friendlyinner inner tire
Face is closely pasted with polyester material cloth by Heveatex glue, and the outer wall of polyester material cloth is bonded with outside PU leathers by latex
Skin.
2. environment-friendly water-based gluing closes mechanical lagging basketball, it is characterised in that its manufacture method is comprised the steps of：
(S1) environment-friendlyinner inner tire is selected, meets PAHs ＜ 1ppm environmental protection standards；
(S2) No. 1, No. 2 and No. 3 formula natural gum latex glue is prepared, respectively agitated ＞ presulfurizations ＞ maturations ＞ filterings ＞ dresses
Tank is stand-by；Wherein No. 1 formula natural gum latex glue is used for high temperature vulcanized 140-150 DEG C, No. 2 formula natural gum latex glue
For 80-90 DEG C of cryogenic vulcanization is used after mixing with No. 3 formula natural gum latex glue scenes；Due to the thermoplastic spy of PU leathers
Property, cryogenic vulcanization technology effectively prevent PU leathers more than 90 DEG C leather thicknesses substantially thinning and leather surface decorative pattern particle and
The generation of high frequency thermoprint whole graduation；
(S3) to standard size, upper No. 1 formula natural gum latex glue dries in the shade stand-by to tire tube air-inflating；
(S4) cloth being made into from polyester material, does the constant load elongation percentage of fabric post-treatment operation to standard, up to standard after testing
Afterwards, No. 1 formula natural gum latex glue on gluing machine, is cooled down after the latex film of drying cloth surface uniform thickness, and PE is enclosed automatically
Film crimps stand-by in the lump；
(S5) cloth of excessively good glue is cut into the pieces of cloth of required size in punch press, the inner tyre surface of first-class glue is uniformly attached on request,
Being then placed in Standard Module carries out high temperature vulcanized, is made tire in infantees；
(S6) the formula natural gum latex glue+3 of tire surface spraying 2 formula natural gum latex glue in infantees, cuts, prints
The PU leathers back side afterwards also sprays+No. 3 formula natural gum latex glue of No. 2 formula natural gum latex glue, into drying tunnel stream
Thickening is heated on waterline, leather is well placed by press back in lagging mould, be put into tire in infantees, matched moulds heating carries out Sulfur-Vapor of Lower Temperature
Change；After reaching the process stipulation time, take out i.e. production and complete, into inspection, packing department.
3. environment-friendly water-based gluing according to claim 2 closes mechanical lagging basketball, it is characterised in that No. 1 described formula
The weight portion formula of natural gum latex glue is constituted：
4. environment-friendly water-based gluing according to claim 2 closes mechanical lagging basketball, it is characterised in that No. 2 described formulas
The weight portion formula of natural gum latex glue is constituted：
5. environment-friendly water-based gluing according to claim 2 closes mechanical lagging basketball, it is characterised in that No. 3 described formulas
The weight portion formula of natural gum latex glue is constituted：
6. environment-friendly water-based gluing according to claim 2 closes mechanical lagging basketball, it is characterised in that described polyester material
The cloth being made into is used as casing play.
7. environment-friendly water-based gluing according to claim 2 closes mechanical lagging basketball, it is characterised in that between described pieces of cloth
By latex impregnation film-forming binder, chemical crosslink reaction is completed under high temperature action.
8. environment-friendly water-based gluing according to claim 2 closes mechanical lagging basketball, it is characterised in that outside described PU leathers
It is complete under low-temperature catalyzed after tire is formulated+No. 3 formula natural gum latex glue of natural gum latex glue at upper No. 2 in skin and infantees
Into cross-linking reaction；To meet cryogenic vulcanization condition, and it is the generation for preventing low temperature glue from going bad at normal temperatures, therefore is matched somebody with somebody using No. 2
+ No. 3 formula natural gum latex glue latex of square natural gum latex glue, remix be used in combination when in use.
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| CN201710040239.5A CN106823308B (en) | 2017-01-20 | 2017-01-20 | Environment-friendly water-based gluing closes mechanical lagging basketball |
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| CN201710040239.5A CN106823308B (en) | 2017-01-20 | 2017-01-20 | Environment-friendly water-based gluing closes mechanical lagging basketball |
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| CN106823308A true CN106823308A (en) | 2017-06-13 |
| CN106823308B CN106823308B (en) | 2019-04-16 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111037825A (en) * | 2019-12-18 | 2020-04-21 | 溧阳市山湖实业有限公司 | PHC luggage case cover plate one-step forming synthesis method |
| CN116271746A (en) * | 2023-02-03 | 2023-06-23 | 厦门元保运动器材有限公司 | Double-layer ball and preparation method thereof |
| CN116392786A (en) * | 2023-04-13 | 2023-07-07 | 南通高桥体育用品有限公司 | Environment-friendly water-based glue machine-attached volleyball and production process thereof |
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| US20040229722A1 (en) * | 2003-05-14 | 2004-11-18 | Yuan-Jung Liu | Method for making a ball and the product thereof |
| CN201930476U (en) * | 2010-11-09 | 2011-08-17 | 蔡福源 | Ball |
| EP2397196A2 (en) * | 2010-06-18 | 2011-12-21 | Mikasa Corporation | Sports ball |
| CN103949040A (en) * | 2014-05-14 | 2014-07-30 | 丽水学院 | Teaching basketball |
| CN205598558U (en) * | 2016-01-26 | 2016-09-28 | 陈桂锋 | Football or volleyball |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20040229722A1 (en) * | 2003-05-14 | 2004-11-18 | Yuan-Jung Liu | Method for making a ball and the product thereof |
| EP2397196A2 (en) * | 2010-06-18 | 2011-12-21 | Mikasa Corporation | Sports ball |
| CN201930476U (en) * | 2010-11-09 | 2011-08-17 | 蔡福源 | Ball |
| CN103949040A (en) * | 2014-05-14 | 2014-07-30 | 丽水学院 | Teaching basketball |
| CN205598558U (en) * | 2016-01-26 | 2016-09-28 | 陈桂锋 | Football or volleyball |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111037825A (en) * | 2019-12-18 | 2020-04-21 | 溧阳市山湖实业有限公司 | PHC luggage case cover plate one-step forming synthesis method |
| CN116271746A (en) * | 2023-02-03 | 2023-06-23 | 厦门元保运动器材有限公司 | Double-layer ball and preparation method thereof |
| CN116271746B (en) * | 2023-02-03 | 2024-05-03 | 厦门元保运动器材有限公司 | Double-layer ball and preparation method thereof |
| CN116392786A (en) * | 2023-04-13 | 2023-07-07 | 南通高桥体育用品有限公司 | Environment-friendly water-based glue machine-attached volleyball and production process thereof |
| CN116392786B (en) * | 2023-04-13 | 2023-12-01 | 南通高桥体育用品有限公司 | Environment-friendly water-based glue machine-attached volleyball and production process thereof |
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| Publication number | Publication date |
|---|---|
| CN106823308B (en) | 2019-04-16 |
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Effective date of registration: 20200604 Address after: 226146 east side of Jiankang Road, Shuxun Town, Haimen City, Nantong City, Jiangsu Province Patentee after: NANTONG GAOQIAO SPORTING GOODS Co.,Ltd. Address before: 200333, 606-607-608, room 11, 601 lane, Nu River Road, Shanghai, Putuo District Patentee before: Zhu Yu |