CN106810939A - A kind of UV solidified luminous printing inks of intaglio printing and preparation method thereof - Google Patents
A kind of UV solidified luminous printing inks of intaglio printing and preparation method thereof Download PDFInfo
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- CN106810939A CN106810939A CN201611226234.3A CN201611226234A CN106810939A CN 106810939 A CN106810939 A CN 106810939A CN 201611226234 A CN201611226234 A CN 201611226234A CN 106810939 A CN106810939 A CN 106810939A
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- printing
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- solidified
- printing inks
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Luminescent Compositions (AREA)
Abstract
The present invention provides a kind of UV solidified luminous printing inks of intaglio printing, including following components：Epoxy acrylic resin, polyester acrylate resin, acrylate monomer, light trigger, long afterglow luminous powder, organosilicon micro mist wax and defoamer；And each component weight fraction is：0.3 ~ 3 part of 10 ~ 20 parts of epoxy acrylic resin, 15 ~ 25 parts of polyester acrylate resin, 20 ~ 30 parts of acrylate monomer, 3 ~ 10 parts of light trigger, 20 ~ 50 parts of long afterglow luminous powder, 2 ~ 5 parts of organosilicon micro mist wax and defoamer.The present invention also provides a kind of preparation method of the UV solidified luminous printing inks of intaglio printing.The present invention is showed by contrasting printing of the UV solidified luminous printing inks of common UV solidified luminous printing inks and present invention preparation on high-speed gravure printing machine device, the printing effect printing performance of ink of the present invention is good, abrasion to printing plate is small, continuous printing performance is substantially better than common UV solidified luminous printing inks, and printing acceptance rate is high.
Description
【Technical field】
The present invention relates to printing-ink technical field, more particularly to a kind of intaglio printing UV solidified luminous printing inks and its preparation side
Method.
【Background technology】
At present, the luminous ink of UV-curable on the market has been probably already existed for quite a long time, solid relative to non-UV
The luminous ink of change type, the luminous ink of UV curing types has the advantages that the aspect of performance of itself, but because luminous ink is used
Phosphorescent pigment, the hardness of itself is high, and density is big, so limiting the application method of itself.Luminous ink is used at present,
The construction methods such as silk-screen printing or brushing, showering can only be typically used, production efficiency is very low.If using current main flow
When mode of printing, such as offset printing, gravure printing mode are printed, can exist has very big abrasion to printing plate, in a short period of time
Printing quality accident is caused, therefore cannot normally be used always.
【The content of the invention】
The use problem for existing, the UV solidifications of present invention offer intaglio printing are used to luminous ink in current printing industry
Luminous ink, solves the problems, such as that traditional UV solidified luminous printing inks do not adapt to highspeed gravure printing, improves print production effect
Rate, realizes the synchronous raising of product quality and production efficiency.
To achieve these goals, the present invention provides a kind of UV solidified luminous printing inks of intaglio printing, including following components：
Epoxy acrylic resin, polyester acrylate resin, acrylate monomer, light trigger, long afterglow luminous powder, organosilicon micro mist wax
And defoamer；And each component weight fraction is：10 ~ 20 parts of epoxy acrylic resin, 15 ~ 25 parts of polyester acrylate resin, third
20 ~ 30 parts of olefin(e) acid ester monomer, 3 ~ 10 parts of light trigger, 20 ~ 50 parts of long afterglow luminous powder, 2 ~ 5 parts of organosilicon micro mist wax and disappear
0.3 ~ 3 part of infusion.
In a preferred embodiment, the epoxy acrylic resin is bisphenol-A epoxy acrylic resin, or is changed
Property epoxy acrylic resin.
In a preferred embodiment, the polyester acrylate resin is the polyester acrylate of 4 degrees of functionality, or
5th, the polyester resin of 6 degrees of functionality.
In a preferred embodiment, the acrylate monomer be 2 degrees of functionality monomer HDDA, TPGDA or
DPGDA, or 3 functionality monomer TMPTA or GPTA.
In a preferred embodiment, the light trigger is 184, TPO, 369 and benzophenone and benzophenone
Derivative or its mixture.
In a preferred embodiment, the long afterglow luminous powder be using activated by rare earth elements alkaline earth aluminate,
Silicate material.
In a preferred embodiment, the organosilicon micro mist wax particle diameter is at 5 ~ 15 microns.
The present invention also provides a kind of preparation method of the UV solidified luminous printing inks of intaglio printing, comprises the following steps：
Step one, light trigger is added in polyester acrylic resin and acrylate resin monomer, high-speed stirred dissolving；Its
Described in polyester acrylate resin weight fraction be 15 ~ 25 parts, the weight fraction of the acrylate monomer be 20 ~ 30
Part, the weight fraction of the light trigger are 3 ~ 10 parts；
Step 2, epoxy acrylic resin, long afterglow luminous powder, organosilicon micro mist wax, component of antifoam agent are added, disperseed at a high speed
Uniformly；The weight fraction of wherein described epoxy acrylic resin is 10 ~ 20 parts, the weight fraction of the long afterglow luminous powder is 20
~ 50 parts, the weight fraction of organosilicon micro mist wax for the weight fraction of 2 ~ 5 parts and defoamer be 0.3 ~ 3 part；
Step 3, the UV solidified luminous printing ink solidified luminous printing inks for obtaining the intaglio printing.
The present invention is recessed in high speed by contrasting UV solidified luminous printing inks prepared by common UV solidified luminous printing inks and the present invention
Printing performance on version printing machine, the printing effect printing performance of ink of the present invention is good, and the abrasion to printing plate is small, continuous printing
Performance is substantially better than common UV solidified luminous printing inks, and printing acceptance rate is high.
【Brief description of the drawings】
The preparation method flow chart of the UV solidified luminous printing inks of the intaglio printing that Fig. 1 is provided for the present invention.
【Specific embodiment】
In order that the purpose of the present invention, technical scheme and Advantageous Effects become apparent from understanding, below in conjunction with accompanying drawing and specifically
Implementation method, the present invention will be described in further detail.It should be appreciated that the specific embodiment described in this specification
Just for the sake of explaining the present invention, it is not intended to limit the present invention.
To achieve these goals, the present invention provides a kind of UV solidified luminous printing inks of intaglio printing, including following components：
Epoxy acrylic resin, polyester acrylate resin, acrylate monomer, light trigger, long afterglow luminous powder, organosilicon micro mist wax
And defoamer；And each component weight fraction is：10 ~ 20 parts of epoxy acrylic resin, 15 ~ 25 parts of polyester acrylate resin, third
20 ~ 30 parts of olefin(e) acid ester monomer, 3 ~ 10 parts of light trigger, 20 ~ 50 parts of long afterglow luminous powder, 2 ~ 5 parts of organosilicon micro mist wax and disappear
0.3 ~ 3 part of infusion.
Specifically, the epoxy acrylic resin is bisphenol-A epoxy acrylic resin, or modified epoxy acrylic acid tree
Fat.
Specifically, the polyester acrylate resin is the polyester acrylate of 4 degrees of functionality, or 5,6 degrees of functionality is poly-
Ester resin.The polyester acrylate resin is used to provide the mobility and the wetability to pigment of ink system.
Specifically, the acrylate monomer is the monomer of 2 degrees of functionality, such as HDDA（1,6- hexylene glycol double methacrylate）,
TPGDA（Tripropylene glycol double methacrylate）, DPGDA（Two contracting propane diols double methacrylates）Deng, or 3 functionality monomers
Such as TMPTA (trimethylolpropane trimethacrylate), GPTA etc..
Specifically, the light trigger is 184（1- hydroxycyclohexyl phenyl ketones）, TPO (2,4,6- trimethylbenzene first
Acyl group-diphenyl phosphine oxide), 369（2- phenyl benzyl -2- dimethyl amines -1-（4- morpholine benzyl phenyl）Butanone）And benzophenone
With the derivative of benzophenone or its mixture.
Specifically, the long afterglow luminous powder is using alkaline earth aluminate, the silicate material of activated by rare earth elements, the material
Material has extinction, Chu Guang, luminous performance, absorbs various visible rays 10 ~ 20 minutes, you can continuous luminous 12 hours in the dark
More than, while in order to reach good intaglio printing performance, it is desirable to which its fineness reaches 5 ~ 15 microns, and particle diameter distribution is as far as possible
It is narrow, few coarse granule can reduce the abrasion to intaglio plate as far as possible.The selection of long afterglow luminous powder, and to its particle
The control range of footpath distribution must reach 5 ~ 15 microns of scope, and particle diameter is too small, and noctilucence luminous efficiency is not high, and particle diameter is too big, right
The abrasion increase of gravure printing plate, it is impossible to print for a long time.
Specifically, the organosilicon micro mist wax requires its particle diameter at 5 ~ 15 microns, particle diameter distribution is as far as possible narrow, organic silicon powder
The addition of wax, its topmost effect is to provide wearability and the lubrication between printing plate and scraper to ink system, reduces scraper
With the degree of wear of printing plate, this is the important leverage that intaglio printing can run steadily in the long term.
Specifically, the defoamer can be Taiwan De Qian companies 6800 defoamers, or German enlightening it is high
（TEGO）The defoamer 432 of company, Foamex N or their mixture, preferably Taiwan moral modest 6800 and German enlightening are high
432 mixture.In other embodiments, it would however also be possible to employ other defoamers.
As shown in figure 1, the present invention also provides a kind of preparation method of the UV solidified luminous printing inks of intaglio printing, including it is following
Step：
Step one, light trigger is added in polyester acrylic resin and acrylate monomer, high-speed stirred dissolving；Wherein institute
State the weight fraction of polyester acrylate resin for the weight fraction of 15 ~ 25 parts, the acrylate monomer be 20 ~ 30 parts, institute
The weight fraction for stating light trigger is 3 ~ 10 parts；
Step 2, epoxy acrylic resin, long afterglow luminous powder, organosilicon micro mist wax, component of antifoam agent are added, disperseed at a high speed
Uniformly；The weight fraction of wherein described epoxy acrylic resin is 10 ~ 20 parts, the weight fraction of the long afterglow luminous powder is 20
~ 50 parts, the weight fraction of organosilicon micro mist wax for the weight fraction of 2 ~ 5 parts and defoamer be 0.3 ~ 3 part；
Step 3, the UV solidified luminous printing ink solidified luminous printing inks for obtaining the UV intaglio printings.
The present invention is recessed in high speed by contrasting UV solidified luminous printing inks prepared by common UV solidified luminous printing inks and the present invention
Printing performance on version printing machine, the final printing effect for confirming ink of the present invention meets the requirements of the customers, and printing performance is good, right
The abrasion of printing plate is small, and continuous printing performance is substantially better than common UV solidified luminous printing inks, and printing acceptance rate is high.
The present invention is not restricted to described in specification and implementation method, therefore for the personnel of familiar field
Additional advantage and modification are easily achieved, therefore in the essence of the universal limited without departing substantially from claim and equivalency range
In the case of god and scope, the present invention is not limited to specific details, representational equipment and shown here as the diagram with description
Example.
Claims (8)
1. a kind of UV solidified luminous printing inks of intaglio printing, including following components：Epoxy acrylic resin, polyester acrylic tree
Fat, acrylate monomer, light trigger, long afterglow luminous powder, organosilicon micro mist wax and defoamer；And each component weight fraction
For：10 ~ 20 parts of epoxy acrylic resin, 15 ~ 25 parts of polyester acrylate resin, 20 ~ 30 parts of acrylate monomer, light trigger 3 ~
0.3 ~ 3 part of 10 parts, 20 ~ 50 parts of long afterglow luminous powder, 2 ~ 5 parts of organosilicon micro mist wax and defoamer.
2. UV solidified luminous printing inks of intaglio printing as claimed in claim 1, it is characterised in that：The epoxy acrylic resin
It is bisphenol-A epoxy acrylic resin, or modified epoxy acrylate resin.
3. UV solidified luminous printing inks of intaglio printing as claimed in claim 1, it is characterised in that：The polyester acrylate resin
The polyester acrylate of 4 degrees of functionality, or 5,6 degrees of functionality polyester resin.
4. UV solidified luminous printing inks of intaglio printing as claimed in claim 1, it is characterised in that：The acrylate monomer is
The monomer HDDA, TPGDA or DPGDA of 2 degrees of functionality, or 3 functionality monomer TMPTA or GPTA.
5. UV solidified luminous printing inks of intaglio printing as claimed in claim 1, it is characterised in that：The light trigger is 184,
TPO, 369 and benzophenone and benzophenone derivative or its mixture.
6. UV solidified luminous printing inks of intaglio printing as claimed in claim 1, it is characterised in that：The long afterglow luminous powder is
Using the alkaline earth aluminate of activated by rare earth elements, silicate material.
7. UV solidified luminous printing inks of intaglio printing as claimed in claim 1, it is characterised in that：The organosilicon micro mist wax grain
Footpath is at 5 ~ 15 microns.
8. a kind of preparation method of the UV solidified luminous printing inks of intaglio printing, comprises the following steps：
Step one, light trigger is added in polyester acrylic resin and acrylate monomer, high-speed stirred dissolving；Wherein institute
State the weight fraction of polyester acrylate resin for the weight fraction of 15 ~ 25 parts, the acrylate monomer be 20 ~ 30 parts, institute
The weight fraction for stating light trigger is 3 ~ 10 parts；
Step 2, epoxy acrylic resin, long afterglow luminous powder, organosilicon micro mist wax, component of antifoam agent are added, disperseed at a high speed
Uniformly；The weight fraction of wherein described epoxy acrylic resin is 10 ~ 20 parts, the weight fraction of the long afterglow luminous powder is 20
~ 50 parts, the weight fraction of organosilicon micro mist wax for the weight fraction of 2 ~ 5 parts and defoamer be 0.3 ~ 3 part；
Step 3, the UV solidified luminous printing ink solidified luminous printing inks for obtaining the intaglio printing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611226234.3A CN106810939A (en) | 2016-12-27 | 2016-12-27 | A kind of UV solidified luminous printing inks of intaglio printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611226234.3A CN106810939A (en) | 2016-12-27 | 2016-12-27 | A kind of UV solidified luminous printing inks of intaglio printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106810939A true CN106810939A (en) | 2017-06-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611226234.3A Pending CN106810939A (en) | 2016-12-27 | 2016-12-27 | A kind of UV solidified luminous printing inks of intaglio printing and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111004567A (en) * | 2019-12-31 | 2020-04-14 | 义乌市齐彩印刷包装有限公司 | UV (ultraviolet) glazing oil and preparation method thereof |
Citations (4)
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|---|---|---|---|---|
| CN1657575A (en) * | 2005-03-22 | 2005-08-24 | 中国乐凯胶片集团公司 | UV light solidified luminous printing ink |
| CN1737067A (en) * | 2005-07-28 | 2006-02-22 | 中国印钞造币总公司 | UV cured concealed fluorescent frequency conversion ink |
| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN103613987A (en) * | 2013-11-04 | 2014-03-05 | 中钞油墨有限公司 | UV drying electroluminescent silk screen printing ink composition |
-
2016
- 2016-12-27 CN CN201611226234.3A patent/CN106810939A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1657575A (en) * | 2005-03-22 | 2005-08-24 | 中国乐凯胶片集团公司 | UV light solidified luminous printing ink |
| CN1737067A (en) * | 2005-07-28 | 2006-02-22 | 中国印钞造币总公司 | UV cured concealed fluorescent frequency conversion ink |
| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN103613987A (en) * | 2013-11-04 | 2014-03-05 | 中钞油墨有限公司 | UV drying electroluminescent silk screen printing ink composition |
Non-Patent Citations (1)
| Title |
|---|
| 向阳: "《印刷材料及适性》", 31 October 2000, 印刷工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111004567A (en) * | 2019-12-31 | 2020-04-14 | 义乌市齐彩印刷包装有限公司 | UV (ultraviolet) glazing oil and preparation method thereof |
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Application publication date: 20170609 |