CN106808378A - A kind of resin wheel for workpiece material grinding and preparation method thereof - Google Patents
A kind of resin wheel for workpiece material grinding and preparation method thereof Download PDFInfo
- Publication number
- CN106808378A CN106808378A CN201710200383.0A CN201710200383A CN106808378A CN 106808378 A CN106808378 A CN 106808378A CN 201710200383 A CN201710200383 A CN 201710200383A CN 106808378 A CN106808378 A CN 106808378A
- Authority
- CN
- China
- Prior art keywords
- pollopas
- resin wheel
- hours
- carborundum
- grinding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000227 grinding Methods 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 26
- 229920005989 resin Polymers 0.000 title claims abstract description 24
- 239000011347 resin Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 33
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 18
- 229920002472 Starch Polymers 0.000 claims abstract description 13
- 235000019362 perlite Nutrition 0.000 claims abstract description 13
- 239000010451 perlite Substances 0.000 claims abstract description 13
- 239000008107 starch Substances 0.000 claims abstract description 13
- 235000019698 starch Nutrition 0.000 claims abstract description 13
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 11
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910001651 emery Inorganic materials 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims 1
- 238000007792 addition Methods 0.000 claims 1
- 150000002085 enols Chemical class 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 238000005829 trimerization reaction Methods 0.000 claims 1
- 210000002700 urine Anatomy 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005498 polishing Methods 0.000 description 10
- 229940068984 polyvinyl alcohol Drugs 0.000 description 8
- 239000000243 solution Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000003746 surface roughness Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000006061 abrasive grain Substances 0.000 description 2
- 235000021168 barbecue Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000003967 crop rotation Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
- B24D3/28—Resins or natural or synthetic macromolecular compounds
- B24D3/285—Reaction products obtained from aldehydes or ketones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
- B24D3/342—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
- B24D3/344—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Abstract
The invention belongs to finishing technical field, and in particular to a kind of resin wheel for workpiece material grinding and preparation method thereof.The resin wheel is made up of following raw material:Pollopas, melamine, polyvinyl alcohol, ammonium chloride, oxalic acid, carborundum, expanded perlite and starch.The present invention is modified by pollopas, it is combined with silicon carbide micro-powder and other fillers, resin wheel is obtained by sectional temperature-controlled curing, the wearability and heat resistance of product is greatly improved, suitable for various workpieces grinding, not by grinding ambient influnence, cost of material is low, preparation process is simple.
Description
Technical field
The invention belongs to finishing technical field, and in particular to it is a kind of for workpiece material grinding resin wheel and its
Preparation method.
Background technology
Urea-resion adhesive market demand is maximum, and because its raw material is cheap and easy to get, manufacturing process is simple, extensive use
In woodenware processing, the industry such as artificial board production and interior decoration.But never had for polishing grinding emery wheel and paid close attention to by people
With use, people are using vitrified abrasive grinding-polishing always for these years, but vitrified abrasive abrasive grain is thick, bonding agent solidification
Time is long, solidification temperature is high, and heating is big when polishing is used, and easily burn and scratches workpiece, and people are always ceramic sand crop rotation
Used for grinding roughing.As the demand of market high accuracy polishing needs that how many researchers start with phenolic resin, ring
Oxygen tree fat, unsaturated-resin etc. manufacture emery wheel, but in the market resin wheel price costly, most of cutting force are good
It is good, and polishing effect is unable to reach surface roughness high all the time(Finish), in the market also has various antiscuffing paste and polishings
Cloth etc., but those products can only dry tumbling, air pollution is big, and wet environment cannot be used.
The pollopas that present invention urea is generated with formaldehyde synthetic reaction, then changed with melamine and polyvinyl alcohol
Property, the pollopas more flexible after being modified also greatly improves its wearability.Abrasive material selects silicon carbide micro-powder, surpasses
Thin abrasive grain substantially increases workpiece product specification in terms of grinding and polishing.This product does not appoint dry grinding or wet method
Grinding can, not by grinding environment influenceed.Because pollopas is cheap, along with precious using expansion cheap and easy to get
Pearl rock dust end and starch material, production are with low cost.Production equipment is simple simultaneously, it is not necessary to put into what large-scale machinery
Equipment, product hardening time is short, and curing apparatus use box barbecue, and barbecue device is cheap, before extraordinary commercial Application
Scape.
The content of the invention
It is an object of the invention to provide a kind of resin wheel for workpiece material grinding.Change by pollopas
Property, it is combined with silicon carbide micro-powder and other fillers, resin wheel is obtained by sectional temperature-controlled curing, greatly carry
The wearability and heat resistance of product high, it is adaptable to which various workpieces are ground, not by grinding ambient influnence, cost of material is low, prepares work
Skill is simple.
To achieve the above object, the present invention is adopted the following technical scheme that:
A kind of resin wheel for workpiece material grinding, is made up of following raw material:Pollopas, melamine, polyvinyl alcohol,
Ammonium chloride, oxalic acid, carborundum, expanded perlite and starch.
Wherein pollopas, melamine, polyvinyl alcohol, ammonium chloride, oxalic acid are 100 in mass ratio:2~5:5~10:1.5~
2.5:1~2;Pollopas is 0.9 ~ 2.3 with carborundum mass ratio:1;Carborundum, expanded perlite and starch are 1 in mass ratio:
0.005~0.03:0.01~0.08。
Wherein pollopas is with urea and volume fraction 36.5%--37.5% formalins in molar ratio 1:1.5 add
Amount, is synthesized with the NaOH 1wt% aqueous solution as catalyst.
The preparation method of the described resin wheel for workpiece material grinding, concretely comprises the following steps:
(1)Pollopas is prepared, then adds melamine and the polyvinyl alcohol of volume fraction 10% to be modified according to proportioning;
(2)To step(1)Product adds ammonium chloride, oxalic acid, carborundum, expanded perlite and starch to mix stirring by proportioning;
(3)Then to step(2)Product vacuumizes froth breaking, then moulding by casting, and baking and curing, cooling obtains emery wheel product.
Wherein cure stage temperature adjusting is:80 DEG C 3 hours → 100 DEG C 2 hours → 120 DEG C 2 hours → 150 DEG C 5 hours
→ 160 DEG C 2 hours → 140 DEG C 1 hour → 120 DEG C 1 hour → 100 DEG C 1 hour → 80 DEG C 1 hour → shutdown terminate.Naturally it is cold
Come out of the stove when but to less than 50 DEG C.
Remarkable advantage of the invention is:
(1)Pollopas of the invention used is had good wearability by modified tool, and with excellent toughness and heat-resisting
Property, as adhesive so that the durability of resin wheel is greatly improved;Strengthen emery wheel by adding carborundum simultaneously hard
Degree, the physicochemical property of material is improved by adding expanded perlite and starch, and particularly expanded perlite hole is larger, it is easy to
Radiating, improves the thermal diffusivity of resin wheel;And the compounding of overall composition causes that the material of resin wheel is being presented wear-resisting " hard
In material " have concurrently again " softwood matter ", obtained emery wheel is particularly well-suited to polish workpiece surface.
(2)Inventive article can be with the various workpiece materials of grinding and polishing such as:Metal, glass, stone material, precision instruments, timber,
The all surfaces such as jewelry, plastics, lacquerware need roughness high(Finish)Last procedure grinding, make workpiece material surface
Roughness(Finish)Mirror effect is reached, the workpiece material surface roughness after processing<0.1 micron, meet or exceed country
Standard GB3505-83 specifies with the surface roughness of GB1031-83 highest rankings;Product of the present invention can continuously work, finishing time
Number is few, should not substantially repair, and greatlys save the working time, improves operating efficiency.
(3)Because the present invention is moulding by casting, the different products into shape can be produced into shape according to different moulds, can
For the workpiece material grinding and polishing of different field.
Specific embodiment
For further disclosure is of the invention rather than limitation, below in conjunction with example, the present invention is described in further detail.
The preparation method of the described resin wheel for workpiece material grinding, concretely comprises the following steps:
(1)Pollopas is prepared, then adds melamine and the polyvinyl alcohol of volume fraction 10% to be modified according to proportioning;
(2)To step(1)Product adds ammonium chloride, oxalic acid, carborundum, expanded perlite and starch to mix stirring by proportioning;
(3)Then to step(2)Product vacuumizes froth breaking, then moulding by casting, and baking and curing, cooling obtains emery wheel product.
Wherein cure stage temperature adjusting is:80 DEG C 3 hours → 100 DEG C 2 hours → 120 DEG C 2 hours → 150 DEG C 5 hours
→ 160 DEG C 2 hours → 140 DEG C 1 hour → 120 DEG C 1 hour → 100 DEG C 1 hour → 80 DEG C 1 hour → shutdown terminate.Naturally it is cold
Come out of the stove when but to less than 50 DEG C.
Embodiment 1
A kind of resin wheel for workpiece material grinding, is made up of the raw material of following quality:100 grams of pollopas, melamine
5 grams of amine, 10%(v/v)10 grams of poly-vinyl alcohol solution, 2 grams of ammonium chloride, 2%(v/v)It is 1.5 grams of oxalic acid solution, 43.5 grams of carborundum, swollen
3.5 grams of 0.87 gram of swollen perlite and starch.
Embodiment 2
A kind of resin wheel for workpiece material grinding, is made up of the raw material of following quality:100 grams of pollopas, melamine
3 grams of amine, 10%(v/v)8 grams of poly-vinyl alcohol solution, 1.5 grams of ammonium chloride, 2%(v/v)2 grams of oxalic acid solution, 55 grams of carborundum, expansion
2 grams of 1.5 grams of perlite and starch.
Embodiment 3
A kind of resin wheel for workpiece material grinding, is made up of the raw material of following quality:100 grams of pollopas, melamine
2 grams of amine, 10%(v/v)5 grams of poly-vinyl alcohol solution, 2.5 grams of ammonium chloride, 2%(v/v)1 gram of oxalic acid solution, 95 grams of carborundum, expansion
1 gram of 0.5 gram of perlite and starch.
Resin wheel obtained in mixed fillers formula system of the invention, can effectively reduce grinding heat, and thermal diffusivity is good,
Ensure simultaneously within dimensional accuracy 0.001mm, technical indicator is far above domestic like product, is not less than similar imported product.And
And by with pollopas as adhesive, being directed to the workpiece material of different hardness, carborundum and other fillers can be adjusted
Proportioning, the appropriate emery wheel of hardness is obtained, be more suitable for the polishing grinding of workpiece.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with
Modification, should all belong to covering scope of the invention.
Claims (4)
1. it is a kind of for workpiece material grinding resin wheel, it is characterised in that:It is made up of following raw material:Pollopas, trimerization
Cyanamide, polyvinyl alcohol, ammonium chloride, oxalic acid, carborundum, expanded perlite and starch;Wherein pollopas, melamine, poly- second
Enol, ammonium chloride, oxalic acid mass ratio are 100:2~5:5~10:1.5~2.5:1~2;Pollopas and carborundum mass ratio be 0.9 ~
2.3:1;Carborundum, expanded perlite and starch quality ratio are 1:0.005~0.03:0.01~0.08.
2. it is according to claim 1 it is a kind of for workpiece material grinding resin wheel, it is characterised in that:The urine aldehyde tree
Fat is with urea and volume fraction 36.5%--37.5% formalins in molar ratio 1:1.5 additions, with NaOH 1wt% water
Solution synthesizes as catalyst.
It is 3. a kind of to prepare the method for being used for the resin wheel that workpiece material grinds as claimed in claim 1, it is characterised in that:Tool
Body step is:
(1)Pollopas is prepared, then adds melamine and the polyvinyl alcohol of volume fraction 10% to be modified according to proportioning;
(2)To step(1)Product adds ammonium chloride, oxalic acid, carborundum, expanded perlite and starch to mix stirring by proportioning;
(3)Then to step(2)Product vacuumizes froth breaking, then moulding by casting, and solidification, cooling obtains emery wheel product.
4. the preparation method of resin wheel according to claim 3, it is characterised in that:Step(3)In cure stage temperature
Degree is regulated to:80 DEG C 3 hours → 100 DEG C 2 hours → 120 DEG C 2 hours → 150 DEG C 5 hours → 160 DEG C 2 hours → 140 DEG C 1 small
When → 120 DEG C 1 hour → 100 DEG C 1 hour → 80 DEG C 1 hour → shutdown terminate, naturally cool to less than 50 DEG C and come out of the stove.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710200383.0A CN106808378B (en) | 2017-03-30 | 2017-03-30 | A kind of resin wheel for workpiece material grinding |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710200383.0A CN106808378B (en) | 2017-03-30 | 2017-03-30 | A kind of resin wheel for workpiece material grinding |
Publications (2)
Publication Number | Publication Date |
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CN106808378A true CN106808378A (en) | 2017-06-09 |
CN106808378B CN106808378B (en) | 2019-03-15 |
Family
ID=59115887
Family Applications (1)
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CN (1) | CN106808378B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111037478A (en) * | 2020-01-11 | 2020-04-21 | 邬师荣 | Grinding tool based on chemical fermentation synthesis reaction and manufacturing method thereof |
CN112428163A (en) * | 2020-11-17 | 2021-03-02 | 东莞市晶菱磨料磨具科技有限公司 | Production formula and production process of resin polishing wheel |
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---|---|---|---|---|
CN1555390A (en) * | 2001-09-13 | 2004-12-15 | 3M | Binder for abrasive articles, abrasive articles including the same and method of making same |
US20090098805A1 (en) * | 2007-09-21 | 2009-04-16 | Saint-Gobain Abrasives, Inc. | Melamine methylol for abrasive products |
CN102786900A (en) * | 2011-05-16 | 2012-11-21 | 王瑞清 | Preparation method for urea formaldehyde wood glue powder |
CN103694431A (en) * | 2013-12-13 | 2014-04-02 | 江苏锋芒复合材料科技集团有限公司 | Method for preparing environmental-friendly urea-formaldehyde resin |
CN103770026A (en) * | 2014-01-10 | 2014-05-07 | 当涂县南方红月磨具磨料有限公司 | Ceramic black corundum grinding wheel |
CN104708542A (en) * | 2015-03-31 | 2015-06-17 | 西安科技大学 | Flexible urea resin grinding apparatus and preparation method thereof |
-
2017
- 2017-03-30 CN CN201710200383.0A patent/CN106808378B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1555390A (en) * | 2001-09-13 | 2004-12-15 | 3M | Binder for abrasive articles, abrasive articles including the same and method of making same |
US20090098805A1 (en) * | 2007-09-21 | 2009-04-16 | Saint-Gobain Abrasives, Inc. | Melamine methylol for abrasive products |
CN102786900A (en) * | 2011-05-16 | 2012-11-21 | 王瑞清 | Preparation method for urea formaldehyde wood glue powder |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111037478A (en) * | 2020-01-11 | 2020-04-21 | 邬师荣 | Grinding tool based on chemical fermentation synthesis reaction and manufacturing method thereof |
CN112428163A (en) * | 2020-11-17 | 2021-03-02 | 东莞市晶菱磨料磨具科技有限公司 | Production formula and production process of resin polishing wheel |
Also Published As
Publication number | Publication date |
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CN106808378B (en) | 2019-03-15 |
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Effective date of registration: 20200417 Address after: No.8, Qingkou Industrial Road, Minhou County, Fuzhou City, Fujian Province 350000 Patentee after: FUZHOU SHUANGYI GRINDING WHEEL Co.,Ltd. Address before: 355100, Ningde City, Fujian province Xiapu Pine Street Street Dongguan Taoyuan No. 3 District Patentee before: Wu Shirong |