CN106808378B - A kind of resin wheel for workpiece material grinding - Google Patents
A kind of resin wheel for workpiece material grinding Download PDFInfo
- Publication number
- CN106808378B CN106808378B CN201710200383.0A CN201710200383A CN106808378B CN 106808378 B CN106808378 B CN 106808378B CN 201710200383 A CN201710200383 A CN 201710200383A CN 106808378 B CN106808378 B CN 106808378B
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- CN
- China
- Prior art keywords
- pollopas
- silicon carbide
- grinding
- resin wheel
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
- B24D3/28—Resins or natural or synthetic macromolecular compounds
- B24D3/285—Reaction products obtained from aldehydes or ketones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
- B24D3/342—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
- B24D3/344—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Abstract
The invention belongs to finishing technical fields, and in particular to a kind of resin wheel and preparation method thereof for workpiece material grinding.The resin wheel is prepared from the following raw materials: pollopas, melamine, polyvinyl alcohol, ammonium chloride, oxalic acid, silicon carbide, expanded perlite and starch.The present invention passes through the modification to pollopas, it is combined with silicon carbide micro-powder and other fillers, resin wheel is made by sectional temperature-controlled curing method, the wearability and heat resistance of product is greatly improved, it is ground suitable for various workpieces, it is not influenced by grinding environment, cost of material is low, and preparation process is simple.
Description
Technical field
The invention belongs to finishing technical fields, and in particular to it is a kind of for workpiece material grinding resin wheel and its
Preparation method.
Background technique
Urea-resion adhesive market demand is maximum, and since its raw material is cheap and easy to get, manufacturing process is simple, is widely applied
It is processed in woodenware, the industries such as artificial board production and interior decoration.But it is never paid close attention to by people for polishing grinding grinding wheel
With use, people are using always vitrified abrasive grinding-polishing for these years, but vitrified abrasive abrasive grain is thick, bonding agent solidification
Time is long, solidification temperature is high, and fever is big when polishing uses, and is easy burn and scratches workpiece, people are always ceramic sand crop rotation
For grinding roughing come using.As the demand of market high-precision polishing needs how many researchers to start with phenolic resin, ring
Oxygen resin, unsaturated-resin etc. manufacture grinding wheel, but resin wheel price in the market is more expensive, and most of cutting force are good
It is good, and polishing effect is unable to reach high surface roughness (finish) always, also there is various antiscuffing paste and polishing in the market
Cloth etc., but those products can only dry tumbling, air pollution is big, and wet environment is not available.
The pollopas that present invention urea and formaldehyde synthetic reaction generate, then changed with melamine and polyvinyl alcohol
Property, the pollopas more flexible after being modified also greatly improves its wearability.Abrasive material selects silicon carbide micro-powder, surpasses
Thin abrasive grain substantially increases workpiece product class in terms of grinding and polishing.This product does not appoint dry grinding or wet process
Grinding is ok, and is not influenced by grinding environment.It is precious along with expansion cheap and easy to get is used since pollopas is cheap
Pearl rock powder end and starch material, production are low in cost.Production equipment is simple simultaneously, does not need that large-scale machinery put into
Equipment, product curing time is short, and curing apparatus uses box barbecue, and barbecue device is cheap, before having extraordinary industrial application
Scape.
Summary of the invention
The purpose of the present invention is to provide a kind of resin wheels for workpiece material grinding.By changing to pollopas
Property, it is combined with silicon carbide micro-powder and other fillers, resin wheel is made by sectional temperature-controlled curing method, is greatly mentioned
The wearability and heat resistance of high product are suitable for various workpieces and grind, and are not influenced by grinding environment, and cost of material is low, prepares work
Skill is simple.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of resin wheel for workpiece material grinding, is prepared from the following raw materials: pollopas, melamine, poly- second
Enol, ammonium chloride, oxalic acid, silicon carbide, expanded perlite and starch.
Wherein pollopas, melamine, polyvinyl alcohol, ammonium chloride, oxalic acid be in mass ratio 100:2 ~ 5:5 ~ 10:1.5 ~
2.5:1~2;Pollopas and silicon carbide mass ratio are 0.9 ~ 2.3:1;Silicon carbide, expanded perlite and starch are 1 in mass ratio:
0.005~0.03:0.01~0.08。
Wherein pollopas is with urea and volume fraction 36.5%--37.5% formalin, in molar ratio 1:1.5 addition
Amount uses sodium hydroxide 1wt% aqueous solution to synthesize as catalyst.
The preparation method of the resin wheel for workpiece material grinding, specific steps are as follows:
(1) pollopas is prepared, melamine then is added according to the proportion and 10% polyvinyl alcohol of volume fraction is changed
Property;
(2) ammonium chloride, oxalic acid, silicon carbide, expanded perlite and starch mixing are added according to the ratio to step (1) product to stir
It mixes;
(3) defoaming, then moulding by casting, baking and curing then are vacuumized to step (2) product, cooling obtains grinding wheel product.
Wherein cure stage temperature regulate and control are as follows: 80 DEG C 3 hours → 100 DEG C 2 hours → 120 DEG C 2 hours → 150 DEG C 5 hours
→ 160 DEG C 2 hours → 140 DEG C 1 hour → 120 DEG C 1 hour → 100 DEG C 1 hour → 80 DEG C 1 hour → shutdown terminate.Naturally cold
It comes out of the stove when but to 50 DEG C or less.
Remarkable advantage of the invention is:
(1) pollopas used in the present invention is had good wearability by modified tool, and with excellent toughness and
Heat resistance, as adhesive, so that the durability of resin wheel greatly improves;Sand is enhanced by addition silicon carbide simultaneously
Hardness to be taken turns, improves the physicochemical property of material by addition expanded perlite and starch, especially expanded perlite hole is larger,
It is easy to radiate, improves the thermal diffusivity of resin wheel;And the compounding of overall composition is so that the material of resin wheel is wear-resisting in presentation
Had both again " in hard material " " softwood matter ", grinding wheel obtained especially suitable for polish workpiece surface.
(2) inventive article can be with the various workpiece materials of grinding and polishing such as: metal, glass, stone material, precision instruments, timber,
The all surfaces such as jewelry, plastics, lacquerware need last procedure grinding of high roughness (finish), make workpiece material surface
Roughness (finish) reaches mirror effect, and workpiece material surface roughness < 0.1 micron after processing meets or exceeds country
The surface roughness of standard GB3505-83 and GB1031-83 highest level provides;Product of the present invention energy continuous work, finishing time
Number is few, not modify substantially, the working time is greatly saved, improve work efficiency.
(3) since the present invention is moulding by casting, the different products at shape can be produced at shape according to different molds, it can
With the workpiece material grinding and polishing for different field.
Specific embodiment
Further to disclose rather than the present invention is limited, the present invention is described in further detail below in conjunction with example.
The preparation method of the resin wheel for workpiece material grinding, specific steps are as follows:
(1) pollopas is prepared, melamine then is added according to the proportion and 10% polyvinyl alcohol of volume fraction is changed
Property;
(2) ammonium chloride, oxalic acid, silicon carbide, expanded perlite and starch mixing are added according to the ratio to step (1) product to stir
It mixes;
(3) defoaming, then moulding by casting, baking and curing then are vacuumized to step (2) product, cooling obtains grinding wheel product.
Wherein cure stage temperature regulate and control are as follows: 80 DEG C 3 hours → 100 DEG C 2 hours → 120 DEG C 2 hours → 150 DEG C 5 hours
→ 160 DEG C 2 hours → 140 DEG C 1 hour → 120 DEG C 1 hour → 100 DEG C 1 hour → 80 DEG C 1 hour → shutdown terminate.Naturally cold
It comes out of the stove when but to 50 DEG C or less.
Embodiment 1
A kind of resin wheel for workpiece material grinding, is made: 100 grams of pollopas, three of the raw material of following quality
5 grams of poly cyanamid, 10%(v/v) 10 grams of poly-vinyl alcohol solution, 2 grams of ammonium chloride, 2%(v/v) 1.5 grams of oxalic acid solution, silicon carbide 43.5
Gram, 0.87 gram of expanded perlite and 3.5 grams of starch.
Embodiment 2
A kind of resin wheel for workpiece material grinding, is made: 100 grams of pollopas, three of the raw material of following quality
3 grams of poly cyanamid, 10%(v/v) 8 grams of poly-vinyl alcohol solution, 1.5 grams of ammonium chloride, 2%(v/v) 2 grams of oxalic acid solution, 55 grams of silicon carbide,
1.5 grams and 2 grams of starch of expanded perlite.
Embodiment 3
A kind of resin wheel for workpiece material grinding, is made: 100 grams of pollopas, three of the raw material of following quality
2 grams of poly cyanamid, 10%(v/v) 5 grams of poly-vinyl alcohol solution, 2.5 grams of ammonium chloride, 2%(v/v) 1 gram of oxalic acid solution, 95 grams of silicon carbide,
0.5 gram and 1 gram of starch of expanded perlite.
Grinding heat can be effectively reduced in resin wheel made from mixed fillers formula system of the invention, and thermal diffusivity is good,
Guarantee within dimensional accuracy 0.001mm simultaneously, technical indicator is much higher than domestic similar product, is not less than similar imported product.And
And by using pollopas as adhesive, being directed to the workpiece material of different hardness, adjustable silicon carbide and other fillers
Proportion, be made hardness grinding wheel appropriate, be more suitable for the polishing grinding of workpiece.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, is all covered by the present invention.
Claims (2)
1. a kind of resin wheel for workpiece material grinding, it is characterised in that: be prepared from the following raw materials: pollopas, trimerization
Cyanamide, polyvinyl alcohol, ammonium chloride, oxalic acid, silicon carbide, expanded perlite and starch;Wherein pollopas, melamine, poly- second
Enol, ammonium chloride, oxalic acid mass ratio are 100:2 ~ 5:5 ~ 10:1.5 ~ 2.5:1 ~ 2;Pollopas and silicon carbide mass ratio be 0.9 ~
2.3:1;Silicon carbide, expanded perlite and starch quality ratio are 1:0.005 ~ 0.03:0.01 ~ 0.08;Specific preparation step are as follows:
(1) pollopas is prepared, melamine then is added according to the proportion and 10% polyvinyl alcohol of volume fraction is modified;
(2) ammonium chloride, oxalic acid, silicon carbide, expanded perlite and starch are added according to the ratio to step (1) product and mix stirring;
(3) defoaming, then moulding by casting then are vacuumized to step (2) product, solidified, cooling obtains grinding wheel product;
Cure stage temperature regulation in step (3) are as follows: 80 DEG C 3 hours → 100 DEG C 2 hours → 120 DEG C 2 hours → 150 DEG C 5 small
When → 160 DEG C 2 hours → 140 DEG C 1 hour → 120 DEG C 1 hour → 100 DEG C 1 hour → 80 DEG C 1 hour → shutdown terminate, it is natural
50 DEG C or less are cooled to come out of the stove.
2. a kind of resin wheel for workpiece material grinding according to claim 1, it is characterised in that: the urine aldehyde tree
Rouge is to use urea and volume fraction 36.5%--37.5% formalin, in molar ratio 1:1.5 additional amount, with sodium hydroxide 1wt% water
Solution is synthesized as catalyst.
Priority Applications (1)
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CN201710200383.0A CN106808378B (en) | 2017-03-30 | 2017-03-30 | A kind of resin wheel for workpiece material grinding |
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CN201710200383.0A CN106808378B (en) | 2017-03-30 | 2017-03-30 | A kind of resin wheel for workpiece material grinding |
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CN106808378A CN106808378A (en) | 2017-06-09 |
CN106808378B true CN106808378B (en) | 2019-03-15 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111037478B (en) * | 2020-01-11 | 2021-11-02 | 邬师荣 | Grinding tool based on chemical fermentation synthesis reaction and manufacturing method thereof |
CN112428163A (en) * | 2020-11-17 | 2021-03-02 | 东莞市晶菱磨料磨具科技有限公司 | Production formula and production process of resin polishing wheel |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1555390A (en) * | 2001-09-13 | 2004-12-15 | 3M | Binder for abrasive articles, abrasive articles including the same and method of making same |
CN102786900A (en) * | 2011-05-16 | 2012-11-21 | 王瑞清 | Preparation method for urea formaldehyde wood glue powder |
CN103694431A (en) * | 2013-12-13 | 2014-04-02 | 江苏锋芒复合材料科技集团有限公司 | Method for preparing environmental-friendly urea-formaldehyde resin |
CN103770026A (en) * | 2014-01-10 | 2014-05-07 | 当涂县南方红月磨具磨料有限公司 | Ceramic black corundum grinding wheel |
CN104708542A (en) * | 2015-03-31 | 2015-06-17 | 西安科技大学 | Flexible urea resin grinding apparatus and preparation method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AR068500A1 (en) * | 2007-09-21 | 2009-11-18 | Saint Gobain Abrasives Inc | MELAMINE METHYLOL FOR ABRASIVE PRODUCTS |
-
2017
- 2017-03-30 CN CN201710200383.0A patent/CN106808378B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1555390A (en) * | 2001-09-13 | 2004-12-15 | 3M | Binder for abrasive articles, abrasive articles including the same and method of making same |
CN102786900A (en) * | 2011-05-16 | 2012-11-21 | 王瑞清 | Preparation method for urea formaldehyde wood glue powder |
CN103694431A (en) * | 2013-12-13 | 2014-04-02 | 江苏锋芒复合材料科技集团有限公司 | Method for preparing environmental-friendly urea-formaldehyde resin |
CN103770026A (en) * | 2014-01-10 | 2014-05-07 | 当涂县南方红月磨具磨料有限公司 | Ceramic black corundum grinding wheel |
CN104708542A (en) * | 2015-03-31 | 2015-06-17 | 西安科技大学 | Flexible urea resin grinding apparatus and preparation method thereof |
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Effective date of registration: 20200417 Address after: No.8, Qingkou Industrial Road, Minhou County, Fuzhou City, Fujian Province 350000 Patentee after: FUZHOU SHUANGYI GRINDING WHEEL Co.,Ltd. Address before: 355100, Ningde City, Fujian province Xiapu Pine Street Street Dongguan Taoyuan No. 3 District Patentee before: Wu Shirong |