CN106801337A - A kind of preparation method for receiving greasy dirt Wiping material high - Google Patents
A kind of preparation method for receiving greasy dirt Wiping material high Download PDFInfo
- Publication number
- CN106801337A CN106801337A CN201611211639.XA CN201611211639A CN106801337A CN 106801337 A CN106801337 A CN 106801337A CN 201611211639 A CN201611211639 A CN 201611211639A CN 106801337 A CN106801337 A CN 106801337A
- Authority
- CN
- China
- Prior art keywords
- pure cotton
- cotton cloth
- cotton
- oil
- weaved
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/0202—Separation of non-miscible liquids by ab- or adsorption
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Abstract
The present invention relates to a kind of preparation method for receiving greasy dirt Wiping material high, belong to Wiping material preparing technical field.The present invention is first with citric acid, triethylene glycol monobutyl ester and p-methyl benzenesulfonic acid prepare transparent liquid for raw material, pure cotton is weaved cotton cloth and is immersed in transparent liquid, the structure that can be weaved cotton cloth to pure cotton is modified, make the oil suction of cotton fiber and receive oily ability to strengthen, recycle the colloidal sol obtained after teos hydrolysis, pure cotton further oleophylic of weaving cotton cloth is modified, make pure cotton fiber that there is very strong oleophylic performance, the height that the present invention is prepared receives greasy dirt Wiping material, it is with low cost, process is simple, oil sucting force is strong, oil mass of receiving is high, oil product can quickly be absorbed, can be wiped in machine machine oil, the fields such as water-oil separating are with a wide range of applications.
Description
Technical field
The present invention relates to a kind of preparation method for receiving greasy dirt Wiping material high, belong to Wiping material preparing technical field.
Background technology
High-performance clean-cloth should be able to effectively remove dust, greasy dirt and watermark without damaging by the surface of cleaning piece.Dust
It is the primary goal of cleaning, and instrument and meter, machine lathe surface, family kitchen etc. be unavoidably with the presence of greasy dirt, because
This needs the clean-cloth to have good degreasing result.Common clean-cloth has good fluid absorbent, and related
Scholar's research obtains the water imbibition of Superfine Fibre Fabric far above oil absorption, it is possible that hydrone is occupied greatly during treatment greasy dirt
Segment space, and a small amount of fluid is remained in by the phenomenon on cleaning piece surface.If clean-cloth can adsorb oil, then treatment
Remaining raffinate will become more succinct.
At present, carry out oil spilling treatment using oil absorption material and be presently the most conventional method.Oil absorption material can effectively be located
Reason marine oil spill, the features such as easily recovery with efficient, economy, oil product.Conventional oil suction material is largely divided into three major types, i.e., inorganic
Oil suction material, organic synthesis oil suction material and organic natural oil suction material.Common used material；Organic natural oil suction material includes wheat
Bar, corn ear, wood fibre, cotton are fine, mestha, bark and peat bog etc., and the oil absorbency of wherein most is all than organic synthesis tree
The oil absorbency of fat is high.
Non-woven material has larger hole is left between special three-dimensional structure, fiber, therefore such Wiping material
Structure is more loose, and the scope of thickness is big, adapts to different purposes.The non-weaving cloth reinforced by chemical adhesion, surface cure
Adhesive may make to be wiped article surface and damage, problem of environmental pollution can be also brought in process.Cotton Wiping material is more
It is hydrophilic oleophobic property, the clearance to greasy dirt is poor, receives that oily power is low, dirt-removing power is weak, greasy dirt is cleaned not thorough.
The content of the invention
The technical problems to be solved by the invention：It is generally hydrophilic oleophobic property for Wiping material, the clearance to greasy dirt is poor,
Receive that oily power is low, dirt-removing power is weak, halfway drawback is cleaned to greasy dirt, there is provided a kind of preparation side for receiving greasy dirt Wiping material high
Method, the present invention, for raw material prepares transparent liquid, pure cotton is weaved cotton cloth first with citric acid, triethylene glycol monobutyl ester and p-methyl benzenesulfonic acid
It is immersed in transparent liquid, the structure that can be weaved cotton cloth to pure cotton is modified, makes the oil suction of cotton fiber and receive oily ability to strengthen, then profit
With the colloidal sol obtained after teos hydrolysis, pure cotton further oleophylic of weaving cotton cloth is modified, makes pure cotton fiber that there is very strong parent
Oiliness energy, the height for preparing of the present invention receives greasy dirt Wiping material, and with low cost, process is simple, oil sucting force is strong, and oil mass of receiving is high,
Oil product can be quickly absorbed, can be wiped in machine machine oil, the field such as water-oil separating is with a wide range of applications.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
（1）To being separately added into 15~20g citric acids, 70~75g triethylene glycol monobutyls ester, 0.4~0.6g in four-hole boiling flask to toluene
Sulfonic acid and 50~70mL toluene, are put into oil bath pan, and 130~140 DEG C, insulated and stirred are warming up to 4~6 DEG C/min heating rates
3~4h of reaction, reaction is cooled to room temperature after terminating, and to the dropwise addition sodium hydroxide solution of mass fraction 5% in four-hole boiling flask, until
Regulation pH is 9.0~10.0, and 1~2h is stood after regulation, organic phase is collected after layering, the vacuum distillation at a temperature of 95~105 DEG C
20~30min, obtains transparent liquid liquid after distillation, standby；
（2）Weigh during 40~60g tetraethyl orthosilicates add there-necked flask, and to adding 100~120mL mass point in there-necked flask
Several 95% mass fraction ethanol solutions, are put into water-bath and are heated to 60~70 DEG C, and insulated and stirred mixes and add after 1~2h 0.5~
1.0g γ-methacryloxypropyl trimethoxy silane, continue 2~4h of stirring reaction, in the stage of reaction, every 30~
40min is cooled to room temperature, obtains colloidal sol to the ammoniacal liquor of 3~5mL mass fractions 10%, reaction are added dropwise in there-necked flask after terminating；
（3）The pure cotton for cutting 3~5 pieces of 20cm × 20cm is weaved cotton cloth, and pure cotton is weaved cotton cloth and is put into 40~60 DEG C of warm water, is dried in the air after washing
Dry, the pure cotton that will be washed after drying weaves cotton cloth in mass ratio 1:100 are immersed in above-mentioned colloidal sol, and pressure rolling is taken out after 10~15min of immersion,
Make pick-up rate for 70~80%, then place into and soak in colloidal sol, taken out after 5~10min of immersion, pressure rolling make pick-up rate for 50~
60%, the pure cotton after padding is weaved cotton cloth and is put into baking oven, and 5~10min is first heat-treated at a temperature of 90~100 DEG C, is then raised temperature to
130~150 DEG C of 2~4min of heat treatment, pure cotton after treatment are weaved cotton cloth and are put into 10~20min of cooling in clear water, are taken out after cooling and put
Enter in baking oven, 10~12h is dried at a temperature of 70~80 DEG C, obtain the modified pure cotton in surface and weave cotton cloth；
（4）Above-mentioned modified pure cotton is weaved cotton cloth in mass ratio 1:100 are immersed in step（1）It is standby in standby transparent liquid, and
To 0.1~0.3g ethylene imides are added in transparent liquid, 8~10h is placed at a temperature of being put into 0~5 DEG C, pure cotton is taken out after placement and is weaved cotton cloth,
Natural air drying, you can obtain height and receive greasy dirt Wiping material.
Obtained height of the invention receives greasy dirt Wiping material density for 100~150g/m2, oil absorbency is up to more than 90.2%, area
Shrinkage factor is 15~17%, and fracture strength is 4.26~5.04cN/dtex, and elongation at break is 30.59~38.56%, wiping
Pyatyi can be reached, pollutant holding capability is the 200~400% of deadweight, and average swelling rate is 3~5g/s.
Compared with other method, Advantageous Effects are the present invention：
（1）The height that the present invention is prepared receives greasy dirt Wiping material step simply, with low cost, products obtained therefrom oil suction easy to operate,
Oil absorbency is high；
（2）The height that the present invention is prepared receives greasy dirt Wiping material, and oil sucting force is strong, and oil mass of receiving is high, can quickly absorb oil product, can
Wiped in machine machine oil, the field such as water-oil separating is with a wide range of applications.
Specific embodiment
To being separately added into 15~20g citric acids, 70~75g triethylene glycol monobutyls ester, 0.4~0.6g in four-hole boiling flask to toluene
Sulfonic acid and 50~70mL toluene, are put into oil bath pan, and 130~140 DEG C, insulated and stirred are warming up to 4~6 DEG C/min heating rates
3~4h of reaction, reaction is cooled to room temperature after terminating, and to the dropwise addition sodium hydroxide solution of mass fraction 5% in four-hole boiling flask, until
Regulation pH is 9.0~10.0, and 1~2h is stood after regulation, organic phase is collected after layering, the vacuum distillation at a temperature of 95~105 DEG C
20~30min, obtains transparent liquid liquid after distillation；Weigh during 40~60g tetraethyl orthosilicates add there-necked flask, and in there-necked flask
The mass fraction ethanol solution of 100~120mL mass fractions 95% is added, is put into water-bath and is heated to 60~70 DEG C, insulated and stirred is mixed
0.5~1.0g γ-methacryloxypropyl trimethoxy silane is added after closing 1~2h, continues 2~4h of stirring reaction,
In the stage of reaction, the ammoniacal liquor of 3~5mL mass fractions 10% is added dropwise in 30~40min is to there-necked flask, reaction is cooled down after terminating
To room temperature, colloidal sol is obtained；The pure cotton for cutting 3~5 pieces of 20cm × 20cm is weaved cotton cloth, and pure cotton is weaved cotton cloth and is put into 40~60 DEG C of warm water, is washed
Dried after washing, the pure cotton that will be washed after drying weaves cotton cloth in mass ratio 1:100 are immersed in above-mentioned colloidal sol, are taken after 10~15min of immersion
Go out pressure rolling, make pick-up rate be 70~80%, then place into immersion in colloidal sol, taken out after 5~10min of immersion, pressure rolling makes pick-up rate
It is 50~60%, the pure cotton after padding is weaved cotton cloth and is put into baking oven, 5~10min is first heat-treated at a temperature of 90~100 DEG C, then
130~150 DEG C of 2~4min of heat treatment are warming up to, pure cotton after treatment are weaved cotton cloth and is put into 10~20min of cooling in clear water, after cooling
Taking-up is put into baking oven, and 10~12h is dried at a temperature of 70~80 DEG C, is obtained the modified pure cotton in surface and is weaved cotton cloth；Will be above-mentioned modified
Pure cotton afterwards weaves cotton cloth in mass ratio 1:100 are immersed in standby transparent liquid, standby, and to 0.1~0.3g of addition in transparent liquid
Ethylene imide, places 8~10h at a temperature of being put into 0~5 DEG C, pure cotton is taken out after placement and is weaved cotton cloth, natural air drying, you can obtain height and receive oil
Dirty Wiping material.
Example 1
To 15g citric acids, 70g triethylene glycol monobutyls ester, 0.4g p-methyl benzenesulfonic acid and 50mL toluene is separately added into four-hole boiling flask, put
Enter in oil bath pan, 130 DEG C be warming up to 4 DEG C/min heating rates, insulated and stirred reaction 3h, reaction is cooled to room temperature after terminating,
And to the sodium hydroxide solution of mass fraction 5% is added dropwise in four-hole boiling flask, until regulation pH is 9.0,1h is stood after regulation, after layering
Organic phase is collected, the vacuum distillation 20min at a temperature of 95 DEG C obtains transparent liquid liquid after distillation；Weigh 40g tetraethyl orthosilicates and add three
In mouthful flask, and to the mass fraction ethanol solution of 100mL mass fractions 95% is added in there-necked flask, it is put into water-bath and is heated to
60 DEG C, 0.5g γ-methacryloxypropyl trimethoxy silane is added after insulated and stirred mixing 1h, continue stirring reaction
2h, in the stage of reaction, is added dropwise the ammoniacal liquor of 3mL mass fractions 10% in 30min is to there-necked flask, and reaction is cooled to after terminating
Room temperature, obtains colloidal sol；The pure cotton for cutting 3 pieces of 20cm × 20cm is weaved cotton cloth, and pure cotton is weaved cotton cloth and is put into 40 DEG C of warm water, is dried after washing,
The pure cotton that will be washed after drying weaves cotton cloth in mass ratio 1:100 are immersed in above-mentioned colloidal sol, and pressure rolling is taken out after immersion 10min, make mangle
Rate is 70%, then places into immersion in colloidal sol, is taken out after immersion 5min, and pressure rolling makes pick-up rate be 50%, the pure cotton after padding
Weave cotton cloth and be put into baking oven, be first heat-treated 5min at a temperature of 90 DEG C, then raise temperature to 130 DEG C of heat treatment 2min, will be pure after treatment
Weaved cotton cloth cools down 10min in being put into clear water, is taken out after cooling and is put into baking oven, and 10h is dried at a temperature of 70 DEG C, obtains surface and is modified
Pure cotton afterwards is weaved cotton cloth；Above-mentioned modified pure cotton is weaved cotton cloth in mass ratio 1:100 are immersed in standby transparent liquid, standby, and
To 0.1g ethylene imides are added in transparent liquid, 8h is placed at a temperature of being put into 0 DEG C, pure cotton is taken out after placement and is weaved cotton cloth, natural air drying, you can
Obtain height and receive greasy dirt Wiping material.
Obtained height of the invention receives greasy dirt Wiping material density for 100g/m2, up to 90.8%, percentage reduction of area is oil absorbency
15%, fracture strength is 4.26cN/dtex, and elongation at break is 30.59%, and wiping properties reach Pyatyi, and pollutant holding capability is deadweight
200%, average swelling rate is 3g/s.
Example 2
To being separately added into 17g citric acids, 73g triethylene glycol monobutyls ester, 0.5g p-methyl benzenesulfonic acid and 50~70mL first in four-hole boiling flask
Benzene, is put into oil bath pan, and 135 DEG C are warming up to 5 DEG C/min heating rates, and insulated and stirred reaction 3.5h, reaction is cooled down after terminating
To room temperature, and to the sodium hydroxide solution of mass fraction 5% is added dropwise in four-hole boiling flask, until regulation pH is 9.5, stood after regulation
1.5h, collects organic phase after layering, the vacuum distillation 25min at a temperature of 100 DEG C, and transparent liquid liquid is obtained after distillation；Weigh the positive silicon of 50g
Acetoacetic ester is added in there-necked flask, and to the mass fraction ethanol solution of 110mL mass fractions 95% is added in there-necked flask, is put into
65 DEG C are heated in water-bath, 0.8g γ-methacryloxypropyl trimethoxy silane are added after insulated and stirred mixing 1.5h,
Continue stirring reaction 3h, in the stage of reaction, the ammoniacal liquor of 4mL mass fractions 10%, reaction are added dropwise in 35min is to there-necked flask
Room temperature is cooled to after end, colloidal sol is obtained；The pure cotton for cutting 4 pieces of 20cm × 20cm is weaved cotton cloth, and pure cotton is weaved cotton cloth and is put into 50 DEG C of warm water,
Dried after washing, the pure cotton that will be washed after drying weaves cotton cloth in mass ratio 1:100 are immersed in above-mentioned colloidal sol, are taken out after immersion 13min
Pressure rolling, makes pick-up rate be 75%, then places into immersion in colloidal sol, is taken out after immersion 7min, and pressure rolling makes pick-up rate be 55%, will soak
Pure cotton after rolling is weaved cotton cloth and is put into baking oven, is first heat-treated 7min at a temperature of 95 DEG C, then raises temperature to 140 DEG C of heat treatment 3min,
Pure cotton after treatment is weaved cotton cloth to be put into 15min is cooled down in clear water, taken out after cooling and be put into baking oven, 11h is dried at a temperature of 75 DEG C,
The modified pure cotton in surface is obtained to weave cotton cloth；Above-mentioned modified pure cotton is weaved cotton cloth in mass ratio 1:100 are immersed in standby transparent liquid
In, it is standby, and to 0.2g ethylene imides are added in transparent liquid, 9h is placed at a temperature of being put into 3 DEG C, pure cotton is taken out after placement and is weaved cotton cloth, from
So air-dry, you can obtain height and receive greasy dirt Wiping material.
Obtained height of the invention receives greasy dirt Wiping material density for 125g/m2, up to 91%, percentage reduction of area is oil absorbency
16%, fracture strength is 4.45cN/dtex, and elongation at break is 35.46%, and wiping properties reach Pyatyi, and pollutant holding capability is deadweight
300%, average swelling rate is 4g/s.
Example 3
To 20g citric acids, 75g triethylene glycol monobutyls ester, 0.6g p-methyl benzenesulfonic acid and 70mL toluene is separately added into four-hole boiling flask, put
Enter in oil bath pan, 140 DEG C be warming up to 6 DEG C/min heating rates, insulated and stirred reaction 4h, reaction is cooled to room temperature after terminating,
And to the sodium hydroxide solution of mass fraction 5% is added dropwise in four-hole boiling flask, until regulation pH is 10.0,2h is stood after regulation, after layering
Organic phase is collected, the vacuum distillation 30min at a temperature of 105 DEG C obtains transparent liquid liquid after distillation；Weigh the addition of 60g tetraethyl orthosilicates
In there-necked flask, and to the mass fraction ethanol solution of 120mL mass fractions 95% is added in there-necked flask, it is put into heating in water-bath
To 70 DEG C, 1.0g γ-methacryloxypropyl trimethoxy silane is added after insulated and stirred mixing 2h, continue stirring reaction
4h, in the stage of reaction, is added dropwise the ammoniacal liquor of 5mL mass fractions 10% in 40min is to there-necked flask, and reaction is cooled to after terminating
Room temperature, obtains colloidal sol；The pure cotton for cutting 5 pieces of 20cm × 20cm is weaved cotton cloth, and pure cotton is weaved cotton cloth and is put into 60 DEG C of warm water, is dried after washing,
The pure cotton that will be washed after drying weaves cotton cloth in mass ratio 1:100 are immersed in above-mentioned colloidal sol, and pressure rolling is taken out after immersion 15min, make mangle
Rate is 80%, then places into immersion in colloidal sol, is taken out after immersion 10min, and pressure rolling makes pick-up rate be 60%, the pure cotton after padding
Weave cotton cloth and be put into baking oven, be first heat-treated 10min at a temperature of 100 DEG C, 150 DEG C of heat treatment 4min are then raised temperature to, after treatment
Pure cotton is weaved cotton cloth to be put into clear water and cools down 20min, is taken out after cooling and is put into baking oven, and 12h is dried at a temperature of 80 DEG C, is obtained surface and is changed
Pure cotton after property is weaved cotton cloth；Above-mentioned modified pure cotton is weaved cotton cloth in mass ratio 1:100 are immersed in standby transparent liquid, standby,
And to 0.3g ethylene imides are added in transparent liquid, 10h is placed at a temperature of being put into 5 DEG C, and pure cotton is taken out after placement and is weaved cotton cloth, natural air drying,
Can obtain height and receive greasy dirt Wiping material.
Height of the invention obtained receives greasy dirt Wiping material density for 150g/m2, and up to 91.2%, percentage reduction of area is oil absorbency
17%, fracture strength is 5.04cN/dtex, and elongation at break is 38.56%, and wiping properties reach Pyatyi, and pollutant holding capability is deadweight
400%, average swelling rate is 5g/s.
Claims (1)
1. a kind of preparation method for receiving greasy dirt Wiping material high, it is characterised in that specific preparation process is：
（1）To being separately added into 15~20g citric acids, 70~75g triethylene glycol monobutyls ester, 0.4~0.6g in four-hole boiling flask to toluene
Sulfonic acid and 50~70mL toluene, are put into oil bath pan, and 130~140 DEG C, insulated and stirred are warming up to 4~6 DEG C/min heating rates
3~4h of reaction, reaction is cooled to room temperature after terminating, and to the dropwise addition sodium hydroxide solution of mass fraction 5% in four-hole boiling flask, until
Regulation pH is 9.0~10.0, and 1~2h is stood after regulation, organic phase is collected after layering, the vacuum distillation at a temperature of 95~105 DEG C
20~30min, obtains transparent liquid liquid after distillation, standby；
（2）Weigh during 40~60g tetraethyl orthosilicates add there-necked flask, and to adding 100~120mL mass point in there-necked flask
Several 95% mass fraction ethanol solutions, are put into water-bath and are heated to 60~70 DEG C, and insulated and stirred mixes and add after 1~2h 0.5~
1.0g γ-methacryloxypropyl trimethoxy silane, continue 2~4h of stirring reaction, in the stage of reaction, every 30~
40min is cooled to room temperature, obtains colloidal sol to the ammoniacal liquor of 3~5mL mass fractions 10%, reaction are added dropwise in there-necked flask after terminating；
（3）The pure cotton for cutting 3~5 pieces of 20cm × 20cm is weaved cotton cloth, and pure cotton is weaved cotton cloth and is put into 40~60 DEG C of warm water, is dried in the air after washing
Dry, the pure cotton that will be washed after drying weaves cotton cloth in mass ratio 1:100 are immersed in above-mentioned colloidal sol, and pressure rolling is taken out after 10~15min of immersion,
Make pick-up rate for 70~80%, then place into and soak in colloidal sol, taken out after 5~10min of immersion, pressure rolling make pick-up rate for 50~
60%, the pure cotton after padding is weaved cotton cloth and is put into baking oven, and 5~10min is first heat-treated at a temperature of 90~100 DEG C, is then raised temperature to
130~150 DEG C of 2~4min of heat treatment, pure cotton after treatment are weaved cotton cloth and are put into 10~20min of cooling in clear water, are taken out after cooling and put
Enter in baking oven, 10~12h is dried at a temperature of 70~80 DEG C, obtain the modified pure cotton in surface and weave cotton cloth；
（4）Above-mentioned modified pure cotton is weaved cotton cloth in mass ratio 1:100 are immersed in step（1）It is standby in standby transparent liquid, and
To 0.1~0.3g ethylene imides are added in transparent liquid, 8~10h is placed at a temperature of being put into 0~5 DEG C, pure cotton is taken out after placement and is weaved cotton cloth,
Natural air drying, you can obtain height and receive greasy dirt Wiping material.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811338841.8A CN109322151A (en) | 2016-12-25 | 2016-12-25 | The height that oil product can quickly be absorbed receives greasy dirt Wiping material |
| CN201611211639.XA CN106801337B (en) | 2016-12-25 | 2016-12-25 | A kind of high preparation method for receiving greasy dirt Wiping material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611211639.XA CN106801337B (en) | 2016-12-25 | 2016-12-25 | A kind of high preparation method for receiving greasy dirt Wiping material |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811338841.8A Division CN109322151A (en) | 2016-12-25 | 2016-12-25 | The height that oil product can quickly be absorbed receives greasy dirt Wiping material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106801337A true CN106801337A (en) | 2017-06-06 |
| CN106801337B CN106801337B (en) | 2019-07-02 |
Family
ID=58984437
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611211639.XA Expired - Fee Related CN106801337B (en) | 2016-12-25 | 2016-12-25 | A kind of high preparation method for receiving greasy dirt Wiping material |
| CN201811338841.8A Pending CN109322151A (en) | 2016-12-25 | 2016-12-25 | The height that oil product can quickly be absorbed receives greasy dirt Wiping material |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811338841.8A Pending CN109322151A (en) | 2016-12-25 | 2016-12-25 | The height that oil product can quickly be absorbed receives greasy dirt Wiping material |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN106801337B (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100537889C (en) * | 2007-07-23 | 2009-09-09 | 江南大学 | The method of a kind of cation hybrid collosol and raising printing clearness and fastness |
| CN101970545A (en) * | 2008-03-10 | 2011-02-09 | 瓦克化学股份公司 | Method for producing composite particles |
| CN102261000A (en) * | 2011-05-12 | 2011-11-30 | 四川大学 | Method for preparing aqueous polyurethane/SiO2 nano heterozygous leather finishing agent through sol-gel method |
| CN102341188A (en) * | 2009-01-30 | 2012-02-01 | 阿力泽有限公司 | Method for Attachment of Silicon-Containing Compounds to a Surface and for Synthesis of Hypervalent Silicon-Compounds |
| CN104313883A (en) * | 2014-10-20 | 2015-01-28 | 陕西科技大学 | Preparation method of environment-friendly multifunctional textile washing and finishing agent |
| CN104988728A (en) * | 2015-07-30 | 2015-10-21 | 江南大学 | Method for modifying fabric by UV light-cured responsive sol |
| CN105164332A (en) * | 2013-03-13 | 2015-12-16 | 有机点击股份公司 | Method and composition obtaining textiles showing water-repellency and repellency against water soluble dirt |
| CN105297409A (en) * | 2015-11-17 | 2016-02-03 | 梅庆波 | Hydrophobic cotton fiber textile fabric preparation method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102953268B (en) * | 2012-11-02 | 2014-07-02 | 陕西科技大学 | Super oleophilic and super hydrophobic oil-water separation terylene textile preparation method |
| CN103088629B (en) * | 2012-12-18 | 2015-06-03 | 华南理工大学 | Method for carrying out super-hydrophobic modification on PET fabric surface |
| CN104594028B (en) * | 2015-02-03 | 2017-01-11 | 上海工程技术大学 | Method for preparing durable cellulose fiber fabric with super-hydrophobic surface |
-
2016
- 2016-12-25 CN CN201611211639.XA patent/CN106801337B/en not_active Expired - Fee Related
- 2016-12-25 CN CN201811338841.8A patent/CN109322151A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100537889C (en) * | 2007-07-23 | 2009-09-09 | 江南大学 | The method of a kind of cation hybrid collosol and raising printing clearness and fastness |
| CN101970545A (en) * | 2008-03-10 | 2011-02-09 | 瓦克化学股份公司 | Method for producing composite particles |
| CN102341188A (en) * | 2009-01-30 | 2012-02-01 | 阿力泽有限公司 | Method for Attachment of Silicon-Containing Compounds to a Surface and for Synthesis of Hypervalent Silicon-Compounds |
| CN102261000A (en) * | 2011-05-12 | 2011-11-30 | 四川大学 | Method for preparing aqueous polyurethane/SiO2 nano heterozygous leather finishing agent through sol-gel method |
| CN105164332A (en) * | 2013-03-13 | 2015-12-16 | 有机点击股份公司 | Method and composition obtaining textiles showing water-repellency and repellency against water soluble dirt |
| CN104313883A (en) * | 2014-10-20 | 2015-01-28 | 陕西科技大学 | Preparation method of environment-friendly multifunctional textile washing and finishing agent |
| CN104988728A (en) * | 2015-07-30 | 2015-10-21 | 江南大学 | Method for modifying fabric by UV light-cured responsive sol |
| CN105297409A (en) * | 2015-11-17 | 2016-02-03 | 梅庆波 | Hydrophobic cotton fiber textile fabric preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 徐丽慧等: "纤维基改性SiO2柔性超疏水表面构建研究", 《硅酸盐通报》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109322151A (en) | 2019-02-12 |
| CN106801337B (en) | 2019-07-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101914206B (en) | Quaternized modified amino silicone oil softener and preparation and application thereof | |
| CN102586942B (en) | Method for preparing peanut protein composite fiber by using ionic liquid | |
| CN104072633B (en) | A kind of preparation method and application of phosphonium flame retardant | |
| CN102953147B (en) | Coffee carbon-containing anti-flaming polyester staple fiber and preparation method thereof | |
| CN1982533A (en) | Far-infrared ceramic fabric | |
| CN108560257A (en) | A kind of preparation method of flame retardant viscose fiber/seaweed fiber blending fabric | |
| CN106801337A (en) | A kind of preparation method for receiving greasy dirt Wiping material high | |
| CN106589411A (en) | Pineapple peel residue carboxymethyl cellulose/polyvinyl alcohol/mesoporous silica composite hydrogel and preparation method and application thereof | |
| CN105821651A (en) | Fiber fabric with heat-accumulation and health-care functions | |
| CN105220485B (en) | A kind of infant's modified cotton fiber and preparation method thereof based on ionic liquid | |
| CN103174021A (en) | Environment-friendly acrylic fiber oiling agent | |
| CN106592250A (en) | Fireproof antibacterial cotton cloth and making method thereof | |
| CN102174736B (en) | Method for preparing billet yarns into color yarns | |
| CN103343445A (en) | Accelerant for alkali-deweighting processing for terylene and use method for same | |
| CN106930112A (en) | A kind of preparation method of environment-friendly polyester nonwoven Moisture absorption cloth | |
| CN109011890A (en) | A method of with silane coupling agent-non-woven filtrate of ptfe emulsion modification dust-removal cloth-bag | |
| CN102321978A (en) | Preparation method for multifunctional SMS non-woven fabric | |
| CN105922662B (en) | A kind of fire resistance fibre non-woven fabrics | |
| WO2018112941A1 (en) | Multi-component composite nonwoven fabric | |
| CN103046345A (en) | Method for performing three-proof finishing on textile fabrics and garments | |
| CN108568286A (en) | A kind of preparation method of waste textile fabric base water surface oil absorption material | |
| CN208657884U (en) | A kind of retort | |
| CN112553805A (en) | Anti-wrinkle treatment device for worsted cashmere fabric | |
| CN103174019A (en) | Multifunctional chemical system used for scouring and bleaching cotton-polyester blended fabrics and dyeing polyester components in one bath | |
| CN102767081A (en) | Method for preparing hydrophilic finishing agent of polyester fabric through waste polyester |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190605 Address after: 528211 Workshop A, Sanxiang Road South, Xintian Industrial Zone, Xiqiao Town, Nanhai District, Foshan City, Guangdong Province Applicant after: Foshan Baidingda Home Appliances Co., Ltd. Address before: 213164 C 308, Tianrun science and technology building, 801 Changwu Middle Road, Wujin District, Changzhou, Jiangsu. Applicant before: Changzhou Mengtai Lighting Technology Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190702 Termination date: 20201225 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |