CN106797685A - Organic electro-luminescent display unit sealant - Google Patents
Organic electro-luminescent display unit sealant Download PDFInfo
- Publication number
- CN106797685A CN106797685A CN201680002382.9A CN201680002382A CN106797685A CN 106797685 A CN106797685 A CN 106797685A CN 201680002382 A CN201680002382 A CN 201680002382A CN 106797685 A CN106797685 A CN 106797685A
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- Prior art keywords
- methyl
- mentioned
- organic
- display unit
- display element
- Prior art date
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- 239000000565 sealant Substances 0.000 title claims abstract description 61
- 150000001875 compounds Chemical class 0.000 claims abstract description 40
- 239000002245 particle Substances 0.000 claims abstract description 40
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 34
- 239000000945 filler Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000005213 imbibition Methods 0.000 claims abstract description 26
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 23
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 23
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 22
- 239000011777 magnesium Substances 0.000 claims abstract description 22
- 239000011258 core-shell material Substances 0.000 claims abstract description 17
- 238000010538 cationic polymerization reaction Methods 0.000 claims abstract description 15
- 239000003505 polymerization initiator Substances 0.000 claims abstract description 15
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000292 calcium oxide Substances 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 7
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 239000005060 rubber Substances 0.000 claims description 5
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- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000000693 micelle Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 40
- -1 alkene Hydrocarbon Chemical class 0.000 description 56
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 43
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 27
- 239000003795 chemical substances by application Substances 0.000 description 25
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 19
- 239000000758 substrate Substances 0.000 description 19
- 239000002585 base Substances 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
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- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
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- 229910000077 silane Inorganic materials 0.000 description 8
- 238000001029 thermal curing Methods 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
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- 150000003568 thioethers Chemical class 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229940117927 ethylene oxide Drugs 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
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- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- LTYMSROWYAPPGB-UHFFFAOYSA-O diphenylsulfanium Chemical compound C=1C=CC=CC=1[SH+]C1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-O 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- 235000012222 talc Nutrition 0.000 description 4
- 238000001771 vacuum deposition Methods 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 3
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical compound O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- IBHBKWKFFTZAHE-UHFFFAOYSA-N n-[4-[4-(n-naphthalen-1-ylanilino)phenyl]phenyl]-n-phenylnaphthalen-1-amine Chemical compound C1=CC=CC=C1N(C=1C2=CC=CC=C2C=CC=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C3=CC=CC=C3C=CC=2)C=C1 IBHBKWKFFTZAHE-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
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- 230000001629 suppression Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- FVCSARBUZVPSQF-UHFFFAOYSA-N 5-(2,4-dioxooxolan-3-yl)-7-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C(OC2=O)=O)C2C(C)=CC1C1C(=O)COC1=O FVCSARBUZVPSQF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- MFUCEQWAFQMGOR-UHFFFAOYSA-N 2,4-diethyl-9h-thioxanthene Chemical class C1=CC=C2CC3=CC(CC)=CC(CC)=C3SC2=C1 MFUCEQWAFQMGOR-UHFFFAOYSA-N 0.000 description 1
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- CUTQVMWEHZXEPI-UHFFFAOYSA-N 2-O-(2-hydroxy-5-prop-2-enoyloxypentyl) 1-O-methyl benzene-1,2-dicarboxylate Chemical class C(C=1C(C(=O)OC)=CC=CC=1)(=O)OCC(CCCOC(C=C)=O)O CUTQVMWEHZXEPI-UHFFFAOYSA-N 0.000 description 1
- YWLLQUWZWIKQKV-UHFFFAOYSA-N 2-[hydroxy(methoxy)phosphoryl]oxyethyl prop-2-enoate Chemical class COP(O)(=O)OCCOC(=O)C=C YWLLQUWZWIKQKV-UHFFFAOYSA-N 0.000 description 1
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical class CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
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- LVGFPWDANALGOY-UHFFFAOYSA-N 8-methylnonyl prop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C=C LVGFPWDANALGOY-UHFFFAOYSA-N 0.000 description 1
- KSMGAOMUPSQGTB-UHFFFAOYSA-N 9,10-dibutoxyanthracene Chemical class C1=CC=C2C(OCCCC)=C(C=CC=C3)C3=C(OCCCC)C2=C1 KSMGAOMUPSQGTB-UHFFFAOYSA-N 0.000 description 1
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- ZNSODMMNNTWYCS-UHFFFAOYSA-N C(C(=C)C)(=O)OCC(OC1=CCCC1)OC1=CCCC1.CC(C(=O)O)=C Chemical compound C(C(=C)C)(=O)OCC(OC1=CCCC1)OC1=CCCC1.CC(C(=O)O)=C ZNSODMMNNTWYCS-UHFFFAOYSA-N 0.000 description 1
- WSPFQBHWECSLOZ-UHFFFAOYSA-N CN(C)C.OC(C(CCCC1)C1C(O)=O)=O Chemical compound CN(C)C.OC(C(CCCC1)C1C(O)=O)=O WSPFQBHWECSLOZ-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- XACCCBDCRUUDAA-UHFFFAOYSA-N OC(O)C1=C(CC=C1)C1=CC=CC1 Chemical compound OC(O)C1=C(CC=C1)C1=CC=CC1 XACCCBDCRUUDAA-UHFFFAOYSA-N 0.000 description 1
- QSBINWBNXWAVAK-PSXMRANNSA-N PE-NMe(16:0/16:0) Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(=O)OCCNC)OC(=O)CCCCCCCCCCCCCCC QSBINWBNXWAVAK-PSXMRANNSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical group C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- UUQQGGWZVKUCBD-UHFFFAOYSA-N [4-(hydroxymethyl)-2-phenyl-1h-imidazol-5-yl]methanol Chemical class N1C(CO)=C(CO)N=C1C1=CC=CC=C1 UUQQGGWZVKUCBD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- CIZVQWNPBGYCGK-UHFFFAOYSA-N benzenediazonium Chemical compound N#[N+]C1=CC=CC=C1 CIZVQWNPBGYCGK-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical group CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical class CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical class OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- ZWLIYXJBOIDXLL-UHFFFAOYSA-N decanedihydrazide Chemical compound NNC(=O)CCCCCCCCC(=O)NN ZWLIYXJBOIDXLL-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- URQUNWYOBNUYJQ-UHFFFAOYSA-N diazonaphthoquinone Chemical compound C1=CC=C2C(=O)C(=[N]=[N])C=CC2=C1 URQUNWYOBNUYJQ-UHFFFAOYSA-N 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical group 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- DWYMPOCYEZONEA-UHFFFAOYSA-L fluoridophosphate Chemical compound [O-]P([O-])(F)=O DWYMPOCYEZONEA-UHFFFAOYSA-L 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 229940083094 guanine derivative acting on arteriolar smooth muscle Drugs 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical class OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229920001427 mPEG Polymers 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical class COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- RMVRSNDYEFQCLF-UHFFFAOYSA-O phenylsulfanium Chemical compound [SH2+]C1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-O 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical class C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- TVIVIEFSHFOWTE-UHFFFAOYSA-K tri(quinolin-8-yloxy)alumane Chemical compound [Al+3].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 TVIVIEFSHFOWTE-UHFFFAOYSA-K 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- WLOQLWBIJZDHET-UHFFFAOYSA-N triphenylsulfonium Chemical compound C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 WLOQLWBIJZDHET-UHFFFAOYSA-N 0.000 description 1
- 239000012953 triphenylsulfonium Substances 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/02—Details
- H05B33/04—Sealing arrangements, e.g. against humidity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/02—Inorganic compounds
- C09K2200/0239—Oxides, hydroxides, carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0607—Rubber or rubber derivatives
Abstract
Block and the organic electro-luminescent display unit sealant of tenacity excellent it is an object of the invention to provide solidfied material.The present invention is a kind of organic electro-luminescent display unit sealant, its water imbibition filler for containing cationically polymerizable compound, olefin-based rubber particles, light cationic polymerization initiator and alkaline-earth metal system and/or magnesium system, above-mentioned olefin-based rubber particles have core shell structure.
Description
Technical field
Block and the organic electro-luminescent display unit sealant of tenacity excellent the present invention relates to solidfied material.
Background technology
Organic electroluminescent (below, also referred to as " organic EL ") display element has between mutually opposing a pair of electrodes
The laminate construction of organic light emitting material is clamped with, electronics is injected from an electrode to the organic light emitting material and from another
One electrode injects hole to the organic light emitting material, so as to electronics is combined and carried out with hole in organic light emitting material
It is luminous.So, because organic EL display element carries out self-luminous, thus with the phase such as liquid crystal display cells for needing backlight
Than, have the advantages that visibility is good, can be thinned and can DC low-voltage drive.
Constitute the organic light emitting material of organic EL display element, electrode presence easily makes characteristic bad because of moisture, oxygen etc.
The problem of change.Therefore, in order to obtain the organic EL display element of practicality, it is necessary to by organic light emitting material, electrode and big air bound
Realize long lifetime absolutely.As by the method for organic light emitting material, electrode and atmospheric isolation, using sealant to organic EL
Display element is sealed (such as patent document 1).In the case where organic EL display element is sealed with sealant, it is
Abundant suppression moisture, oxygen etc. are passed through, and are generally used in set on the layered product with organic light emitting material and are referred to as passivating film
Inoranic membrane and the method that is sealed with sealant on the inoranic membrane.
In recent years, the bottom of the light instead of being sent by organic light emitting material from the substrate surface side extraction for being formed with light-emitting component
The organic EL display element of portion's illumination mode, organic EL of the top light emitting mode of light is taken out from the upper surface side of organic luminous layer
Display element is attracted attention.Which because aperture opening ratio is high and as low voltage drive, therefore with being conducive to long lifetime
Advantage.In the organic EL display element of such top light emitting mode, due to needing to make the upper surface side of luminescent layer transparent, because
This is close to carry out across the transparent moisture resistance base material such as transparent sealing resin laminated glass by the upper surface side in light-emitting component
Envelope (such as patent document 2).
However, in the organic EL display element of such top light emitting mode, in order to not block the extraction direction of light and
There is a problem of being configured without the space of drier, be difficult to obtain sufficient damp proof effect, lifetime.
Prior art literature
Patent document
Patent document 1:Japanese Unexamined Patent Publication 2007-115692 publications
Patent document 2:Japanese Unexamined Patent Publication 2009-051980 publications
The content of the invention
The invention problem to be solved
Block and the organic electro-luminescent display unit use of tenacity excellent it is an object of the invention to provide solidfied material
Sealant.
Means for solving the problems
The present invention is a kind of organic electro-luminescent display unit sealant, and it contains cationically polymerizable compound, alkene
Hydrocarbon system rubber particles, light cationic polymerization initiator and alkaline-earth metal system and/or the water imbibition filler of magnesium system, above-mentioned olefin-based
Rubber particles have core shell structure.
The present invention is described in detail below.
The present inventor etc. in order to improve the block (anti-penetrability) of organic EL display element sealant and to various suctions
Humectant is studied, and is as a result found:In the situation using the alkaline-earth metal systems such as calcium oxide and/or the water imbibition filler of magnesium system
Under, give play to especially excellent block.However, in the case where such water imbibition filler is used, organic EL of gained shows
Show expansion in reliability test of the solidfied material of element sealant under hot and humid condition etc., existing is carrying out roller laminating work
The problems such as being cracked because of bending when during sequence or using flexible base board.
Therefore, the result that the present inventor etc. is furtherd investigate finds:By be applied in combination as resinous principle sun from
Sub- polymerizable compound and the olefin-based rubber particles with core shell structure, and make the water suction of the alkaline-earth metal system and/or magnesium system
Property filler dispersion, the excellent organic EL display element of block and toughness both of which such that it is able to obtain solidfied material seals
Agent.So that complete the present invention.
Organic EL display element sealant of the invention contains cationically polymerizable compound.
As above-mentioned cationically polymerizable compound, can enumerate with such as epoxy radicals, oxetanylmethoxy, vinyl ether group
Deng the compound as cationic polymerizable group.
As above-mentioned cationically polymerizable compound, the preferably compound with epoxy radicals.Wherein, it is preferably selected from double
The epoxy resin of phenol skeleton, the epoxy resin of tool novolak skeleton, the epoxy resin with naphthalene skeleton and with two rings penta
At least a kind epoxy resin in the epoxy resin of diene skeleton, the more preferably epoxy resin with bisphenol backbone, further preferably
Bisphenol A type epoxy resin, bisphenol f type epoxy resin.
In addition, as above-mentioned cationically polymerizable compound, going out from the viewpoint of the generation for suppressing ease gas (ア ウ ト ガ ス)
Hair, can contain the compound shown in following formula (1) and/or the compound shown in following formula (2).
[changing 1]
In formula (1), R1~R18For hydrogen atom, halogen atom or the alkyl of oxygen atom or halogen atom can be included, it
Can be identical respectively, it is also possible to it is different.X is bonding arm, oxygen atom, the alkylidene of carbon number 1~5, Epoxide carbonyl, carbon number 2~5
Alkylene oxide group carbonyl or secondary amino group.
[changing 2]
In formula (2), R19~R21It is the alkylidene of the carbon number 2~10 of straight-chain or branched, they can be identical respectively,
Can also be different.E1~E3Separately represent following formula (3-1) or following formula (3-2) shown in organic group.
[changing 3]
In formula (3-1), R22It is hydrogen atom or methyl.
As the compound shown in the compound shown in above-mentioned formula (1) and/or above-mentioned formula (2), following formula is preferably selected from
In the compound shown in compound, following formula (4-2) shown in (4-1) and the compound shown in following formula (4-3) at least
1 kind.
[changing 4]
As commercially available product in above-mentioned cationically polymerizable compound, can enumerate for example:EPICLON EXA-
830LVP (DIC company systems);JER 4005P (Mitsubishi Chemical Ind's system);Celloxide 8000, Celloxide 2021P are (
Be Daicel company system), TEPIC-VL (Nissan Chemical company system) etc..
Organic EL display element sealant of the invention contains olefin-based rubber particles.
Above-mentioned olefin-based rubber particles have core shell structure.
By containing the above-mentioned olefin-based rubber particles with core shell structure, so that the organic EL display element of gained is used
The tenacity excellent of the solidfied material of sealant.In addition, olefin-based rubber particles due to compared with other rubber particles decomposability it is low, because
And also there is the effect of the generation for suppressing ease gas.
From the viewpoint of the dispersiveness in above-mentioned cationically polymerizable compound, above-mentioned olefin-based rubber particles preferably have
There is the stratum nucleare comprising conjugated diene rubber and carry the tree of the segment of the compound of polymerism unsaturated double-bond comprising having
The shell of fat.
As above-mentioned conjugated diene rubber, such as butadiene rubber, SBR styrene butadiene rubberses, isoamyl two can be enumerated
Alkene rubber, neoprene etc..Wherein, preferred butadiene rubber.
In addition, the glass transition temperature (Tg) of above-mentioned conjugated diene rubber is preferably less than 0 DEG C.
As the above-mentioned compound with polymerism unsaturated double-bond, can enumerate such as (methyl) acrylic compounds,
Styrenic, acrylonitrile compounds etc..Wherein, preferred (methyl) acrylic compounds.
It is explained, in this specification, above-mentioned " (methyl) Bing Xi Suan ﹡ " refers to Bing Xi Suan ﹡ and/or Jia base Bing Xi Suan ﹡.
As simple function (methyl) acrylic compounds in above-mentioned (methyl) acrylic compounds, example can be enumerated
Such as:(methyl) methyl acrylate, (methyl) ethyl acrylate, (methyl) propyl acrylate, (methyl) n-butyl acrylate, (first
Base) isobutyl acrylate, (methyl) tert-butyl acrylate, (methyl) 2-EHA, (methyl) acrylic acid is different pungent
Ester, (methyl) n-octyl, the different nonyl ester of (methyl) acrylic acid, (methyl) isodecyl acrylate, (methyl) lauryl
Ester, the different myristin of (methyl) acrylic acid, (methyl) stearyl acrylate ester, (methyl) cyclohexyl acrylate, (methyl) acrylic acid
Isobornyl thiocyanoacetate, (methyl) acrylic acid dicyclopentenyloxyethyl methacrylate, (methyl) benzyl acrylate, (methyl) acrylic acid 2- hydroxy methacrylates, (first
Base) propylene 2- hydroxy propyl esters, (methyl) acrylic acid 2- hydroxybutyls, (methyl) acrylic acid 4- hydroxybutyls, (methyl) propylene
Sour 2- methoxy acrylates, (methyl) acrylic acid 2- ethoxy ethyl esters, (methyl) acrylic acid 2- butoxyethyls, (methyl) third
Olefin(e) acid 2- phenoxy ethyls, methoxy ethyl glycol (methyl) acrylate, methoxy poly (ethylene glycol) (methyl) acrylate, benzene
Epoxide diethylene glycol (methyl) acrylate, phenoxy group polyethylene glycol (methyl) acrylate, (methyl) tetrahydrofurfuryl acrylate,
Ethyl carbitol (methyl) acrylate, (methyl) acrylic acid 2,2,2- trifluoro ethyl esters, (methyl) acrylic acid 2,2,3,3- tetra-
Fluorine propyl ester, (methyl) acrylic acid 1H, 1H, 5H- octafluoro pentyl ester, acid imide (methyl) acrylate, (methyl) acrylic acid dimethyl
Amino ethyl ester, (methyl) acrylic acid diethylamino ethyl ester, 2- (methyl) acryloyl-oxyethyls butanedioic acid, 2- (methyl) third
Alkene trimethylammonium hexahydrophthalic acid, 2- (methyl) acryloyl-oxyethyl -2- hydroxypropyl phthalates,
(methyl) glycidyl acrylate, 2- (methyl) acryloyl-oxyethyl phosphate etc..
It is explained, in this manual, above-mentioned " (methyl) acrylate " refers to acrylate or methacrylate,
Above-mentioned " (methyl) acryloyl group " refers to acryloyl group or methylacryloyl.
As 2 functions (methyl) acrylic compounds in above-mentioned (methyl) acrylic compounds, can enumerate for example
1,3- butanediols two (methyl) acrylate, 1,4- butanediols two (methyl) acrylate, 1,6- hexane diols two
(methyl) acrylate, 1,9- nonanes glycol two (methyl) acrylate, 1,10- decanediols two (methyl) acrylate,
(methyl) acrylate of 2- normal-butyl -2- ethyl -1,3- propane diols two, DPG two (methyl) acrylate, three
Propane diols two (methyl) acrylate, polypropylene glycol two (methyl) acrylate, ethylene glycol two (methyl) acrylate, diethyl two
Alcohol two (methyl) acrylate, TEG two (methyl) acrylate, polyethylene glycol two (methyl) acrylate, expoxy propane
Addition bisphenol-A two (methyl) acrylate, ethyleneoxide addition bisphenol-A two (methyl) acrylate, ethyleneoxide addition Bisphenol F
Two (methyl) acrylate, dihydroxymethyl bicyclopentadiene two (methyl) acrylate, neopentyl glycol two (methyl) acrylate,
Ethyleneoxide addition isocyanuric acid two (methyl) acrylate, 2- hydroxyls -3- (methyl) acryloxypropyl (methyl) third
Olefin(e) acid ester, carbonate diol two (methyl) acrylate, PTMEG two (methyl) acrylate, polyester-diol two (methyl) third
Olefin(e) acid ester, polycaprolactone glycol two (methyl) acrylate, polybutadiene diol two (methyl) acrylate etc..
As more than 3 functions in above-mentioned (methyl) acrylic compounds (methyl) acrylic compounds, can enumerate
For example:Pentaerythrite three (methyl) acrylate, trimethylolpropane tris (methyl) acrylate, the hydroxyl first of expoxy propane addition three
Base propane three (methyl) acrylate, ethyleneoxide addition trimethylolpropane tris (methyl) acrylate, caprolactone modification three
Hydroxymethyl-propane three (methyl) acrylate, ethyleneoxide addition isocyanuric acid three (methyl) acrylate, glycerine three (methyl)
Acrylate, expoxy propane addition glycerine three (methyl) acrylate, three (methyl) acryloyl-oxyethyl phosphates, Ji Wusi
Alcohol four (methyl) acrylate, two (trihydroxy methyl) propane four (methyl) acrylate, dipentaerythritol five (methyl) acrylic acid
Ester, dipentaerythritol six (methyl) acrylate etc..
As above-mentioned styrenic, such as styrene, AMS, divinylbenzene etc. can be enumerated.
As aforesaid propylene nitrile based compound, such as acrylonitrile, methacrylonitrile etc. can be enumerated.
As long as above-mentioned olefin-based rubber particles are the olefin-based rubber particles with above-mentioned core shell structure, then can be comprising
2 laminar structures of above-mentioned stratum nucleare and above-mentioned shell, or also with intermediate layer 3 between above-mentioned stratum nucleare and above-mentioned shell
Multilayer structure making more than layer.
The preferred lower limit of the average grain diameter of above-mentioned olefin-based rubber particles is 10nm, the preferred upper limit is 2000nm.It is logical
Crossing makes the average grain diameter of above-mentioned olefin-based rubber particles for more than 10nm, so that the organic EL display element sealant of gained
Solidfied material toughness more preferably.It is below 2000nm by making the average grain diameter of above-mentioned olefin-based rubber particles, so that shell
The covering rate of layer is uprised, and transparent more excellent when making to be used as surfacing.Above-mentioned olefin-based rubber particles it is flat
The preferred upper limit of equal particle diameter is 300nm, and the further preferred upper limit is 100nm.
It is explained, the average grain diameter of above-mentioned olefin-based rubber particles can be surveyed using such as laser diffraction formula size distribution
Determine device etc. to be measured.As above-mentioned laser diffraction formula particle size distribution device, it is possible to use Mastersizer 2000
(Malvern company systems) etc..
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the content of above-mentioned olefin-based rubber particles it is preferred
Lower limit for 5.0 weight portions, the preferred upper limit be 80 weight portions.By making the content of above-mentioned olefin-based rubber particles be 5.0 weights
More than amount part, so that the toughness of the solidfied material of the organic EL display element sealant of gained is more excellent.By making above-mentioned alkene
The content of hydrocarbon system rubber particles is below 80 weight portions, so that the solidfied material of the organic EL display element sealant of gained
Block is more excellent.The preferred lower limit of the content of above-mentioned olefin-based rubber particles is 10 weight portions, the preferred upper limit is
70 weight portions.
Organic EL display element sealant of the invention contains light cationic polymerization initiator.
As long as above-mentioned light cationic polymerization initiator is to produce Bronsted acid or lewis acidic cation poly- using light irradiation
Initiator is closed, is then not particularly limited, acid type can be produced for ionic light, or nonionic light produces acid type.
The light cationic polymerization initiator of acid type is produced as above-mentioned ionic light, can enumerate such as anionicsite by
BF4 -、PF6 -、SbF6 -Or (BX4)-(wherein, X represents the phenyl replaced by the fluorine of at least more than 2 or trifluoromethyl) is constituted
Aromatic series sulfonium salt, aromatic iodonium salts, aromatic diazonium salt, aromatic series ammonium salt or (2,4- cyclopentadiene -1- bases) ((1-
Methylethyl) benzene)-Fe salt etc..
As above-mentioned aromatic series sulfonium salt, can enumerate for example:The double hexafluorophosphates of double (4- (diphenyl sulfonium) phenyl) thioethers,
The double tetrafluoroborates of double (4- (diphenyl sulfonium) phenyl) thioethers pair hexafluoro antimonates, double (4- (diphenyl sulfonium) phenyl) thioethers,
Double (4- (diphenyl sulfonium) phenyl) thioether four (pentafluorophenyl group) borates, diphenyl -4- (thiophenyl) phenyl sulfonium hexafluorophosphoric acid
Salt, diphenyl -4- (thiophenyl) phenyl sulfonium hexafluoro antimonate, diphenyl -4- (thiophenyl) phenyl sulfonium tetrafluoroborate, two
(pentafluorophenyl group) borate of phenyl -4- (thiophenyl) phenyl sulfonium four, triphenylsulfonium hexafluorophosphate, triphenylsulfonium hexafluoro-antimonic acid
Salt, triphenylsulfonium tetrafluoroborate, triphenylsulfonium four (pentafluorophenyl group) borate, double (4- (two (4- (2- '-hydroxyethoxies
Base)) phenyl sulfonium) phenyl) thioether double hexafluorophosphate, double (4- (two (4- (2- hydroxyl-oxethyls)) phenyl sulfoniums) phenyl) sulphur
It is the double tetrafluoroborates of the double hexafluoro antimonates of ether, double (4- (two (4- (2- hydroxyl-oxethyls)) phenyl sulfoniums) phenyl) thioethers, double
(4- (two (4- (2- hydroxyl-oxethyls)) phenyl sulfoniums) phenyl) thioether four (pentafluorophenyl group) borate etc..
As above-mentioned aromatic iodonium salts, such as diphenyl iodine hexafluorophosphate, diphenyl iodine hexafluoro antimony can be enumerated
Hydrochlorate, diphenyl iodine tetrafluoroborate, diphenyl iodine four (pentafluorophenyl group) borate, double (dodecylphenyl) iodine six
Fluorophosphate, double (dodecylphenyl) iodine hexafluoro antimonates, double (dodecylphenyl) iodine tetrafluoroborates, double (ten
Dialkyl phenyl organic) iodine four (pentafluorophenyl group) borate, 4- aminomethyl phenyls -4- (1- Methylethyls) phenyl-iodide hexafluoro phosphorus
Hydrochlorate, 4- aminomethyl phenyls -4- (1- Methylethyls) phenyl-iodide hexafluoro antimonate, 4- aminomethyl phenyls -4- (1- methyl
Ethyl) phenyl-iodide tetrafluoroborate, 4- aminomethyl phenyls -4- (1- Methylethyls) phenyl-iodide four (pentafluorophenyl group) boric acid
Salt etc..
As above-mentioned aromatic diazonium salt, can enumerate for example phenyldiazonium hexafluorophosphate, phenyldiazonium hexafluoro antimonate,
Phenyldiazonium tetrafluoroborate, phenyldiazonium four (pentafluorophenyl group) borate etc..
As above-mentioned aromatic series ammonium salt, such as 1- benzyls -2- cyanopyridines hexafluorophosphate, 1- benzyls can be enumerated
Base -2- cyanopyridines hexafluoro antimonate, 1- benzyl -2- cyanopyridines tetrafluoroborate, 1- benzyl -2- cyano group
Pyridine four (pentafluorophenyl group) borate, 1- (naphthyl methyl) -2- cyanopyridines hexafluorophosphate, 1- (naphthyl first
Base) -2- cyanopyridines hexafluoro antimonate, 1- (naphthyl methyl) -2- cyanopyridines tetrafluoroborate, 1- (naphthyls
Methyl) -2- cyanopyridines four (pentafluorophenyl group) borate etc..
As above-mentioned (2,4- cyclopentadiene -1- bases) ((1- Methylethyls) benzene)-Fe salt, can enumerate for example (2,
4- cyclopentadiene -1- bases) ((1- Methylethyls) benzene)-Fe (II) hexafluorophosphate, (2,4- cyclopentadiene -1- bases)
((1- Methylethyls) benzene)-Fe (II) hexafluoro antimonate, (2,4- cyclopentadiene -1- bases) ((1- Methylethyls) benzene) -
Fe (II) tetrafluoroborate, (2,4- cyclopentadiene -1- bases) ((1- Methylethyls) benzene)-Fe (II) four (pentafluorophenyl group)
Borate etc..
The light cationic polymerization initiator of acid type is produced as above-mentioned nonionic light, such as nitrobenzyl ester, sulphur can be enumerated
Acid derivative, phosphate, sulfophenylate, diazo naphthoquinone, N- hydroxy imide sulphonic acid esters etc..
As product commercially available in above-mentioned light cationic polymerization initiator, can enumerate for example:DTS-200 (MIDORY chemistry
Company system);UVI6990, UVI6974 (are Union Carbide Corporation systems);SP-150, SP-170 (are
ADEKA company systems);FC-508, FC-512 (are 3M company systems);IRGACURE261 (BASF AG's system);PI2074
(Rhodia company systems) etc..
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the content of above-mentioned light cationic polymerization initiator
Preferred lower limit is 0.1 weight portion, the preferred upper limit is 10 weight portions.By the content for making above-mentioned light cationic polymerization initiator
More than 0.1 weight portion, so that the photo-curable of the organic EL display element sealant of gained is more excellent.It is above-mentioned by making
The content of light cationic polymerization initiator is below 10 weight portions, from the organic EL display element sealant without making gained
Curing reaction is too fast, and makes operability more excellent, can make solidfied material evenly.Above-mentioned light cationic polymerization initiator contains
The preferred lower limit of amount is 0.5 weight portion, the preferred upper limit is 5 weight portions.
Organic EL display element sealant of the invention contains the water imbibition filler of alkaline-earth metal system and/or magnesium system.It is logical
The water imbibition filler containing above-mentioned alkaline-earth metal system and/or magnesium system is crossed, so that the organic EL display element sealant of gained
Solidfied material block it is excellent.
As above-mentioned alkaline-earth metal system and/or the water imbibition filler of magnesium system, such as calcium oxide, magnesia, oxidation can be enumerated
Barium, strontium oxide strontia etc..Wherein, from from the viewpoint of water imbibition, calcium oxide and/or magnesia are preferably comprised, as above-mentioned alkaline earth gold
Belong to the water imbibition filler of system, further preferably specific surface area is less than 10.0m2The calcium oxide of/g.
In addition, in the case where combination is containing alkaline-earth metal system water imbibition filler and magnesium system water imbibition filler, preferred compositions
It is that dolomite is heated and obtained further preferably by by calcium carbonate and the double salt of magnesium carbonate containing calcium oxide and magnesia
Light dolomite.
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the water imbibition of above-mentioned alkaline-earth metal system and/or magnesium system
The preferred lower limit of the content of filler is 3.0 weight portions, the preferred upper limit is 100 weight portions.By making above-mentioned alkaline-earth metal system
And/or the content of the water imbibition filler of magnesium system is more than 3.0 weight portions, so that the organic EL display element sealant of gained
Solidfied material block it is more excellent.By making the content of the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system be 100 weights
Below amount part, so that the toughness of the solidfied material of the organic EL display element sealant of gained is improved, and make suppression crackle
Generation and panel stripping effect it is more excellent.The content of the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system is more
Preferred lower limit is 5.0 weight portions, the preferred upper limit is 80 weight portions.
In addition, the total surface area of the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system is poly- relative to above-mentioned cation
Preferred lower limit of the conjunction property compound per 100g is 10m2, the preferred upper limit be 200m2.By make above-mentioned alkaline-earth metal system and/or
The total surface area of the water imbibition filler of magnesium system is 10m2More than, so that the solidification of the organic EL display element sealant of gained
The block of thing is more excellent.By making the total surface area of the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system be 200m2With
Under, so that the toughness of the solidfied material of the organic EL display element sealant of gained is improved, and make the generation of suppression crackle
And the effect of the peeling of panel is more excellent.The total surface area of the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system it is preferred
Lower limit be 20m2, the preferred upper limit be 150m2。
It is explained, the total surface area of the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system is by above-mentioned alkaline-earth metal
The content and BET specific surface area of the water imbibition filler of system and/or magnesium system are calculated.Specifically, for example by utilizing specific surface area
Determine device (Shimadzu Seisakusho Ltd.'s company system, ASAP-2000) and BET specific surface area obtained from being measured using nitrogen is come
Calculated.
For the purposes such as cementability are improved, organic EL display element sealant of the invention can not hinder the present invention
Contain other fillers in addition to the water imbibition filler of above-mentioned alkaline-earth metal system and/or magnesium system in the range of purpose.
As above-mentioned other fillers, can enumerate for example:The inorganic fillers such as silica, talcum, aluminum oxide;Polyester micropartical,
Organic fillers such as polyurethane particulate, polyvinyl particulate, acrylic polymer particulate etc..Wherein, from making raising moisture-proof
Set out in terms of the excellent effect of property, preferably talc.
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the preferred lower limit of the content of above-mentioned other fillers
For 5 weight portions, the preferred upper limit are 100 weight portions.It is the scope by making the content of above-mentioned other fillers, so as to institute will not be made
The coating of the organic EL display element sealant for obtaining is deteriorated, and can give full play to raising cementability and other effects.It is above-mentioned other
The preferred lower limit of the content of filler is 10 weight portions, the preferred upper limit is 80 weight portions.
Organic EL display element sealant of the invention can contain thermal curing agents.As thermal curing agents, example can be enumerated
Such as hydrazide compound, imdazole derivatives, acid anhydrides, dicyandiamide, guanidine derivatives, modified aliphatic polyamine, various amine and epoxy resin
Addition compound product etc..
As above-mentioned hydrazide compound, can enumerate such as 1,3- double (diazanyl carbonyl ethyl -5- isopropyls hydantoins),
Sebacic dihydrazide, isophthalic dihydrazide, adipic dihydrazide, acid dihydrazide etc..
As above-mentioned imdazole derivatives, such as 1- cyano ethyls -2- phenylimidazoles, N- (2- (2- first can be enumerated
Base -1- imidazole radicals) ethyl) urea, 2,4- diaminourea -6- (2 '-methylimidazolyl-(1 '))-ethyl-s-triazine, N,
N '-bis- (2- methyl isophthalic acids-imidazolylethyl) urea, N, N '-(2- methyl isophthalic acids-imidazolylethyl)-adipamide,
2- phenyl -4- methyl -5- hydroxymethylimidazoles, 2- phenyl -4,5- bishydroxymethyl imidazoles etc..
As above-mentioned acid anhydrides, such as tetrabydrophthalic anhydride, ethylene glycol double (dehydration trimellitates) etc. can be enumerated.
These thermal curing agents can be used alone, it is also possible to and use two or more.
As product commercially available in above-mentioned thermal curing agents, such as SDH (Japanese FINECHEM company systems), ADH can be enumerated (big
Mound chemical company system), AMICURE VDH, AMICURE VDH-J, AMICURE UDH (be Ajinomoto Fine-
Techno company systems) etc..
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the preferred lower limit of the content of above-mentioned thermal curing agents
For 0.5 weight portion, the preferred upper limit are 30 weight portions.By making the content of above-mentioned thermal curing agents for more than 0.5 weight portion, so that
Make the Thermocurable of the organic EL display element sealant of gained more excellent.By making the content of above-mentioned thermal curing agents be 30 weights
Below amount part, so that the storage stability of the organic EL display element sealant of gained is more excellent, and make solidfied material
Moisture-proof is more excellent.The preferred lower limit of the content of above-mentioned thermal curing agents is 1 weight portion, the preferred upper limit is 15 weight
Part.
Organic EL display element sealant of the invention can contain sensitizer.Above-mentioned sensitizer has further raising
The polymerization initiation efficiency of above-mentioned light cationic polymerization initiator and further promote organic EL display element of the invention to seal
The effect of the curing reaction of agent.
As above-mentioned sensitizer, the anthracene based compounds such as such as 9,10- dibutoxy anthracenes, 2,4- diethyl thioxanthenes can be enumerated
The thioxanthones such as ketone based compound, 2,2- dimethoxy -1,2- diphenylethane -1- ketone, benzophenone, 2,4- dichloros two
Benzophenone, o-benzoyl yl benzoic acid methyl esters, 4,4 '-bis- (dimethylamino) benzophenone, the methyl of 4- benzoyls -4 '
Diphenylsulfide etc..
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the preferred lower limit of the content of above-mentioned sensitizer is
0.05 weight portion, the preferred upper limit are 3 weight portions.By making the content of above-mentioned sensitizer be more than 0.05 weight portion, so as to enter
One step plays sensitization effect.By making the content of above-mentioned sensitizer for below 3 weight portions, so that absorption will not be made excessive, can
Light is sent to deep.The preferred lower limit of the content of above-mentioned sensitizer is 0.1 weight portion, the preferred upper limit is 1 weight
Part.
For the purposes such as storage stability are improved, organic EL display element sealant of the invention preferably comprises stabilization
Agent.
As aforementioned stable agent, such as amine compound, aminobenzene phenol-type epoxy resin etc. can be enumerated.
Relative to the above-mentioned weight portion of cationically polymerizable compound 100, the preferred lower limit of the content of aforementioned stable agent is
0.001 weight portion, the preferred upper limit are 2 weight portions.It is the scope by making the content of aforementioned stable agent, so as to suppress solidification resistance
Hinder, and make the storage stability of organic EL display element sealant obtained by raising and other effects more excellent.Aforementioned stable agent
Content preferred lower limit for 0.05 weight portion, the preferred upper limit be 1 weight portion.
Organic EL display element sealant of the invention can contain silane coupler.Above-mentioned silane coupler have carry
The effect of the cementability of organic EL display element sealant of the invention high and substrate etc..
As above-mentioned silane coupler, such as 3- TSL 8330s, 3- mercaptopropyi front threes can be enumerated
TMOS, 3- glycidoxypropyltrime,hoxysilanes, 3- isocyanates propyl trimethoxy silicanes etc..These silane
Coupling agent both can be used alone, it is also possible to and with two or more.
Relative to the weight portion of cationically polymerizable compound 100, the preferred lower limit of the content of above-mentioned silane coupler is
0.1 weight portion, the preferred upper limit are 10 weight portions.By making the content of above-mentioned silane coupler for the scope, thus suppress by
Oozing out caused by remaining silane coupler, and make the effect of the cementability of organic EL display element sealant obtained by raising
Fruit is more excellent.The preferred lower limit of the content of above-mentioned silane coupler is 0.5 weight portion, the preferred upper limit is 5 weight portions.
Organic EL display element sealant of the invention can not hinder to contain surface in the range of the object of the invention
Modifying agent.By containing above-mentioned surface modifier, being applied such that it is able to be assigned with sealant to organic EL display element of the invention
The flatness of film.
As above-mentioned surface modifier, such as surfactant, levelling agent etc. can be enumerated.
As above-mentioned surfactant, above-mentioned levelling agent, the levelling agent of such as silicon systems, acrylic acid series, fluorine system etc. can be enumerated.
As commercially available product in above-mentioned surfactant, above-mentioned levelling agent, can enumerate for example:BYK-345, BYK-
340 (being BYK-CHEMIEJAPAN company systems), Surflon S-611 (AGC SEMICHEMICAL company systems) etc..
In order to improve the durability of element electrode, organic EL display element sealant of the invention can not hinder this
Contain ion exchange resin in the range of goal of the invention.
As above-mentioned ion exchange resin, it is possible to use in cation exchange, anion exchange, two ion-exchange types
It is any number of, but particularly preferably it is capable of the cation exchange or two ion-exchange types of adsorbing chlorinated thing ion.
In addition, organic EL display element sealant of the invention can not hinder basis in the range of the object of the invention
Need to contain the public affairs such as cure retarder, reinforcing agent, softening agent, plasticizer, viscosity modifier, ultra-violet absorber, antioxidant
The various additives known.
Method as organic EL display element sealant of the invention is manufactured, can enumerate for example:Use homogenous disperse
The mixers such as machine, homogeneous mixer, universal mixer, planetary-type mixer, kneader, three-roller are by cationically polymerizable chemical combination
The water imbibition filler of thing, olefin-based rubber particles, light cationic polymerization initiator, alkaline-earth metal system and/or magnesium system and according to need
Method of the additive to be added mixing etc..Above-mentioned olefin-based rubber particles can also in advance be distributed to above-mentioned cationically polymerizable
Mix with other compositions again after in compound.
Organic EL display element sealant of the invention uses E type viscosity in the case of for the purpose of face interior sealing
The preferred lower limit of the viscosity at 25 DEG C for measuring is 50mPas, the preferred upper limit is 8000mPas.It is above-mentioned by making
Viscosity is the scope, so that the coating of the organic EL display element sealant of the invention of gained, solidfied material is transparent
Property is more excellent.The preferred lower limit of above-mentioned viscosity is 60mPas, the preferred upper limit is 3000mPas, further preferably
Lower limit for 70mPas, the further preferred upper limit be 1000mPas.
It is explained, above-mentioned viscosity can be determined for example, by the following manner:Use VISCOMETER TV-22 (east
Machine industry companies system) as E type viscosimeters, using optimal moment of torsion number of the cone-plate of CP1 in each viscosity region come appropriate
Select the rotating speed of 1~100rpm.
Organic EL display element sealant of the invention uses E type viscosity in the case of the purpose for edge seal
The preferred lower limit for counting the viscosity at 25 DEG C for determining is 100Pas, the preferred upper limit is 500Pas.It is above-mentioned by making
Viscosity is the scope, so as to prevent the reduction of contact area when vacuum abutted caused by the insertion produced by pressure differential,
And make the shape stability after coating and coating more excellent.The preferred lower limit of above-mentioned viscosity is 200Pas, more excellent
The upper limit of choosing is 400Pas, and further preferred lower limit is 250Pas, the further preferred upper limit is 350Pas.
It is explained, above-mentioned viscosity can be determined for example, by the following manner:Use VISCOMETER TV-22 (east
Machine industry companies system) as E type viscosimeters, using optimal moment of torsion number of the cone-plate of CP7 in each viscosity region come appropriate
Select the rotating speed of 1~100rpm.
As the shape of the sealing formed with sealant by organic EL display element of the invention, as long as can protect
The shape that layered product with organic light emitting material influences from ambient atmos, then be not particularly limited, and can be to cover completely
Cover the shape of the layered product, it is also possible to be formed in the pattern of the edge part closure of the layered product, be additionally formed in the layered product
Edge part be provided with outs open portion shape pattern, but can perform well in seal the layered product edge part.
Invention effect
According to the present invention it is possible to provide the block of solidfied material and the organic electro-luminescent display unit of tenacity excellent with close
Envelope agent.
Specific embodiment
Embodiment is exemplified below further to be described in detail the present invention, but the present invention is not limited to these implementations
Example.
(there is the making of the olefin-based rubber particles A of core shell structure)
The weight portion of butadiene 100, deionized water 200 are put into fully except deoxidation and in having carried out the reaction vessel that nitrogen is replaced
Weight portion, the weight portion of tripotassium phosphate 0.05, the weight portion of potassium dihydrogen phosphate 0.04, the weight portion of disodium ethylene diamine tetraacetate 0.002, sulphur
The ferrous weight portion of seven hydrated salt 0.001 of acid and the weight portion of neopelex 1.5, are stirred mixing at 45 DEG C.Connect
, input hydrogen peroxide is to the weight portion of terpane 0.015 and the weight portion of sodium sulfoxylate formaldehyde 0.04, initiated polymerization.From
Additional hydrogen peroxide is put into behind 5 hours that polymerisation has started to the weight portion of terpane 0.01, disodium ethylene diamine tetraacetate
0.002 weight portion and the weight portion of iron 0.001.Residual monomer is removed behind 10 hours since polymerisation, terminates polymerization,
Obtain the latex (X-1) comprising polybutadiene rubber particle.
In the reaction vessel of the weight portion of latex (X-1) 1500 comprising polybutadiene rubber particle of gained is added
The input weight portion of deionized water 300, is stirred in nitrogen atmosphere at 50 DEG C.Add disodium ethylene diamine tetraacetate 0.01
After weight portion, the weight portion of iron 0.005 and the weight portion of sodium sulfoxylate formaldehyde 0.24, added as the methyl of grafted monomers with 2 hours
The weight portion of methyl acrylate 90 and the weight portion of TBHP 0.08, make it carry out glycerol polymerization.Opened from polymerisation
Terminate polymerization behind 2 hours for having begun, obtain the latex containing the olefin-based rubber particles A with core shell structure.
The average grain diameter of the olefin-based rubber particles A with core shell structure of gained is 100nm.
(there is the making of the olefin-based rubber particles B of core shell structure)
Except the replacement weight portion of butadiene 100 to the input weight portion of butadiene 75 and the weight of styrene 25 in reaction vessel
Beyond part, being made in the same manner as above-mentioned " (having the making of the olefin-based rubber particles A of core shell structure) ", there is stratum nucleare to include fourth
Olefin-based rubber particles B (average grain diameter 100nm) of the core shell structure of butadiene-styrene rubber.
(there is the making of the olefin-based rubber particles C of core shell structure)
The weight portion of methyl methacrylate 80 and isocyanuric acid are used except replacing the weight portion of methyl methacrylate 90
Beyond the mixture of the weight portion of triallyl 10 is as grafted monomers, " (there are the olefin-based rubber particles of core shell structure with above-mentioned
The making of A) " similarly make the olefin-based rubber particles C with core shell structure of the stratum nucleare comprising Afpol
(average grain diameter 100nm).
(embodiment 1)
In bisphenol f type epoxy resin (DIC company systems, " EPICLON EXA- as cationically polymerizable compound
830LVP ") 80 weight portions and solid-state bisphenol f type epoxy resin (Mitsubishi Chemical Ind's system, " jER 4005P ") 20 weight portions in
The made weight portions of olefin-based rubber particles A 50 with core shell structure of addition, are equably stirred mixing.Then, add
Plus as aromatic iodonium salts (Rhodia company systems, " PI2074 ") 1.0 weight portions of light cationic polymerization initiator, at 60 DEG C
Lower heating for dissolving is added as the weight portion of 9,10- dibutoxies anthracene 0.2 of sensitizer, as silane coupler after 1 hour
3- glycidoxypropyltrime,hoxysilanes (chemical industrial company of SHIN-ETSU HANTOTAI system, " KBM-403 ") 3.0 weight portions, conduct are inhaled
Calcium oxide (Ji Ze lime industrial group system, " quick lime J1P ", the specific surface area 2.5m of aqueous filler2/ g) 40 weight portions and work
It is talcum (Japanese talcum company system, " MICRO ACE FG-15 ") 50 weight portions of other fillers, uses stirring mixer
(THINKY company systems, " AR-250 "), equably stirring mixing under low whipping speed 3000rpm is fabricated to organic EL displays unit
Part sealant.
(embodiment 2~12, comparative example 1~5)
Each material of the match ratio described in table 1 and table 2 is stirred into mixing similarly to Example 1, organic EL is fabricated to
Display element sealant.
< evaluates >
Each organic EL display element to gained in embodiment and comparative example carries out following evaluation with sealant.Result is such as
Shown in table 1 and table 2.
(1) viscosity
To each organic EL display element sealant of gained in embodiment and comparative example, using E types viscosimeter, (eastern machine is produced
Industry company system, " VISCOMETER TV-22 "), determine the viscosity (initial viscosity) at 25 DEG C.
(2) block of solidfied material
To each organic EL display element sealant of gained in embodiment and comparative example, following Ca-TEST is carried out.
First, covering has the mask of the opening portion of multiple 2mm × 2mm on the glass substrate of 30mm × 30mm, utilizes
Vacuum evaporation plating machine is deposited with Ca.The condition of evaporation is:2 × 10 will be decompressed in the evaporator of vacuum deposition apparatus- 3Pa, by Ca withEvaporation rate film formingWill be deposited with have Ca glass substrate be moved to be managed to dew point (- 60 DEG C with
On) glove box in, be fitted in surface and be coated with each organic EL display element of gained in embodiment and comparative example with close
Seal the glass substrate of agent.Now, according in the side that there is the Ca of evaporation for the position of 2mm, 4mm, 6mm apart from glass substrate end face
Formula is fitted.Then, with 3000mJ/cm2The ultraviolet of 365nm is irradiated, then is heated 30 minutes at 80 DEG C, thus make sealant
Solidification, is fabricated to Ca-TEST substrates.By the Ca-TEST substrates of gained exposed to 85 DEG C, the hot and humid condition of 85%RH,
By the immersion distance of the disappearance observation moisture hourly of Ca.
The result of Ca-TEST:Time untill the immersion distance of moisture is reached into 6mm is the situation of more than 1000 hours
" ◎ " is set to, the situation by more than 500 hours and less than 1000 hours is set to "○", by more than 100 hours and less than 500 hours
Situation be set to " △ ", the situation less than 100 hours is set to "×", so as to be evaluated the block of solidfied material.
(3) toughness of solidfied material
To in embodiment and comparative example gained each organic EL display element sealant with 3000mJ/cm2Irradiation 365nm
Ultraviolet, then with 80 DEG C heat 30 minutes, thus obtain solidfied material.To the solidfied material of gained, according to JIS R1607 (IF
Method), try to achieve destruction toughness value KIC.Its result:Will destruction toughness value KICValue be that more than 1.0 situation is set to "○", by 0.8
Situation above and less than 1.0 is set to " △ ", and the situation less than 0.8 is set into "×", so as to the toughness to solidfied material is carried out
Evaluate.
(4) adhering state of panel
(being configured with the making of the substrate of the layered product with organic light emitting material)
On glass substrate (length 25mm, width 25mm, thickness 0.7mm) withThickness film forming ITO electrode
Afterwards, as substrate.Aforesaid substrate is carried out into 15 minutes ultrasonic waves with acetone, aqueous alkali, ion exchange water, isopropanol respectively clear
After washing, cleaned 10 minutes using the isopropanol for boiling, recycling UV- ozone cleaners (Japanese electronic laser company system,
" NL-UV253 ") carry out pre-treatment.
Then, the substrate is fixed on the substrate holder of vacuum deposition apparatus, N, N '-two is added in unglazed crucible
(1- naphthyls)-N, N '-diphenylbenzidine (α-NPD) 200mg, adds three (8- hydroxyl quinolines in another unglazed crucible
Quinoline) aluminium (Alq3) 200mg, 1 × 10 will be depressurized in vacuum chamber- 4Pa.Afterwards, the crucible that will be equipped with α-NPD is heated,
Make α-NPD with evaporation rateIt is stacked on substrate, film forming thicknessHole transmission layer.Then, will be equipped with
Alq3Earthenware Crucible heated, withEvaporation rate film forming thicknessOrganic light emitting material.Afterwards, by shape
In moving into another vacuum deposition apparatus into the substrate for having hole transmission layer and organic light emitting material, in the vacuum deposition apparatus
Tungsten resistance-heated boat in add lithium fluoride 200mg, the addition aluminum steel 1.0g in another tungsten boat.Afterwards, by vacuum
2 × 10 are decompressed in the evaporator of evaporation coating device- 4Pa, by lithium fluoride withEvaporation rate film formingAfterwards, by aluminium
WithSpeed film formingMake to return to normal pressure in evaporator using nitrogen, taking-up be configured with 10mm ×
The substrate of the layered product of the organic light emitting material of 10mm.
(using the coated of inorganic material film A)
In the way of the layered product entirety of the substrate for being configured with layered product obtained by covering, setting has 13mm × 13mm
Opening portion mask, form inorganic material film A using plasma CVD method.
Plasma CVD method is using SiH4Gas and nitrogen are set to SiH as unstrpped gas, respective flow4Gas
10sccm, nitrogen 200sccm, RF power are set to 10W (frequency 2.45GHz), chamber indoor temperature and are set to 100 DEG C, cavity indoor pressure
It is set to be carried out under conditions of 0.9Torr.
The thickness of the inorganic material film A for being formed is for about 1 μm.
(formation of resin protection film)
The substrate for being configured with the layered product being coated to by inorganic material film A is set in vacuum plant, vacuum holding is being arranged at
Each organic EL display element sealant 0.5g of gained in embodiment and comparative example is added in the heated boat put, is depressurized to
10Pa, to the part of the square of the 11mm × 11mm comprising layered product, is sealed with 200 DEG C of heating organic EL display elements
Agent, vacuum evaporation is carried out in the way of thickness is reached 0.5 μm.Afterwards, under vacuum conditions using high-pressure sodium lamp, with exposure
Reach 3000mJ/cm2Mode illumination wavelength 365nm ultraviolet, make organic EL display element sealant cures, form tree
Fat diaphragm.
(using the coated of inorganic material film B)
After forming resin protection film, opening with 12mm × 12mm is set in the overall mode for covering the resin protection film
The mask of oral area, inorganic material film B is formed using plasma CVD method, obtains organic EL display element.
Plasma CVD method is using SiH4Gas and nitrogen are set to SiH as unstrpped gas, respective flow4Gas
10sccm, nitrogen 200sccm, RF power are set to 10W (frequency 2.45GHz), chamber indoor temperature and are set to 100 DEG C, cavity indoor pressure
It is set to be carried out under conditions of 0.9Torr.
The thickness of the inorganic material film B for being formed is for about 1 μm.
(observation of the adhering state of panel)
After with visually observation, the organic EL display element of gained is exposed 500 hours in the environment of 85 DEG C, 85%RH
The adhering state of panel.Situation about being peeled off without panel is set to "○", will confirm that the situation that a part of panel is peeled off is set to
" △ ", will confirm that the situation that most panel is peeled off is set to "×", so that the adhering state of counter plate is evaluated.
(5) reliability of organic EL display element
The organic EL display element that to be obtained in the same manner as above-mentioned " adhering state of (4) panel " is in 85 DEG C, 85%RH
After being exposed 500 hours under environment, apply the voltage of 3V, stain (is whether there is with the luminance for visually observing organic EL display element
And pixel edge delustring).Situation without stain, edge delustring and uniformly light-emitting is set to "○", even if will confirm that a little black
Point, the situation of edge delustring are set to "×", so as to the reliability to organic EL display element is evaluated.
[table 1]
[table 2]
Industrial applicability
According to the present invention it is possible to provide the block of solidfied material and the organic electro-luminescent display unit of tenacity excellent with close
Envelope agent.
Claims (5)
1. a kind of organic electro-luminescent display unit sealant, it is characterised in that contain cationically polymerizable compound, alkene
It is rubber particles, light cationic polymerization initiator, the water imbibition filler also containing alkaline-earth metal system and/or magnesium system,
The olefin-based rubber particles have core shell structure.
2. organic electro-luminescent display unit sealant according to claim 1, it is characterised in that olefin-based rubber granule
Sub to have stratum nucleare and shell, the stratum nucleare includes conjugated diene rubber, and the shell includes to have to come from has polymerism not
The resin of the segment of the compound of saturation double bond.
3. organic electro-luminescent display unit sealant according to claim 1 and 2, it is characterised in that olefin-based rubber
The content of micelle is 5.0~80 weight portions relative to the weight portion of cationically polymerizable compound 100.
4. the organic electro-luminescent display unit sealant according to claim 1,2 or 3, it is characterised in that containing aerobic
Change calcium and/or magnesia as alkaline-earth metal system and/or the water imbibition filler of magnesium system.
5. organic electro-luminescent display unit sealant according to claim 4, it is characterised in that contain specific surface area
Less than 10.0m2The calcium oxide of/g as alkaline-earth metal system water imbibition filler.
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PCT/JP2016/055191 WO2016136715A1 (en) | 2015-02-24 | 2016-02-23 | Sealing agent for organic electroluminescence display element |
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CN110268802A (en) * | 2017-06-28 | 2019-09-20 | 积水化学工业株式会社 | Sealant and organic EL display element sealant external member in organic EL display element face |
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WO2018052006A1 (en) * | 2016-09-16 | 2018-03-22 | 積水化学工業株式会社 | Sealing agent for organic electroluminescent display element |
JP2018095679A (en) * | 2016-12-08 | 2018-06-21 | 三井化学株式会社 | Sheet-like seal material, display element seal material, surface sealing material for organic el element, organic el device, and method for manufacturing organic el device |
JP6294522B1 (en) * | 2017-02-14 | 2018-03-14 | 積水化学工業株式会社 | Sealant for organic EL display element and organic EL display element |
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- 2016-02-23 KR KR1020177001478A patent/KR102641589B1/en active IP Right Grant
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CN106797685B (en) | 2019-02-05 |
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