CN106760166B - A kind of glass fiber reinforced cement composite thermo-insulating wall board and preparation method thereof - Google Patents

A kind of glass fiber reinforced cement composite thermo-insulating wall board and preparation method thereof Download PDF

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Publication number
CN106760166B
CN106760166B CN201710196909.2A CN201710196909A CN106760166B CN 106760166 B CN106760166 B CN 106760166B CN 201710196909 A CN201710196909 A CN 201710196909A CN 106760166 B CN106760166 B CN 106760166B
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water
parts
glass fiber
reducing agent
fiber reinforced
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CN106760166A (en
Inventor
麻建锁
刘永伟
蔡焕琴
常青
麻海栋
马相楠
齐梦
陈硕
程岚
张敏
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Tangshan Hongbo Thermal Insulation Material Co.,Ltd.
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Hebei University of Architecture
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/288Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and concrete, stone or stone-like material
    • E04C2/2885Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and concrete, stone or stone-like material with the insulating material being completely surrounded by, or embedded in, a stone-like material, e.g. the insulating material being discontinuous
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G21/00Preparing, conveying, or working-up building materials or building elements in situ; Other devices or measures for constructional work
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/244Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Finishing Walls (AREA)

Abstract

A kind of glass fiber reinforced cement composite thermo-insulating wall board and preparation method thereof, the wallboard includes heat preservation core plate and outline border, outline border is made of glass fiber reinforced cement, heat preservation core plate is made of modified concrete, the raw material of modified concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, by the corn stover of modification, polystyrene foam particles, latex powder and water-reducing agent, the raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass fibre, naphthalene series high-efficiency water-reducing agent and water.The production method includes preparing raw material, production heat preservation core plate and prefabricated plate body in a mold.Production simple production process of the invention reduces working procedure, reduces wallboard cost, reduces environmental pollution, it can be achieved that building industrialization produces.The present invention is suitable for structural envelope, heat preservation and the decoration of frame structure building exterior wall.

Description

A kind of glass fiber reinforced cement composite thermo-insulating wall board and preparation method thereof
Technical field
The invention belongs to building element, more particularly to a kind of novel glass fiber enhance cement composite heat preserving wallboard and its Production method.
Background technique
For frame structure building, building enclosure itself does not need to bear very big load, it is only necessary to which satisfaction is gone along with sb. to guard him The function of main structure.Common practice is first to be puzzled the wall of building enclosure using light block etc., then in wall The construction of insulating layer is carried out outside body.The method of this outer patch insulating layer on building enclosure exterior wall, long construction period, environment are dirty Dye is big, and overall cost is high, is particularly present the defects of service life is short, fire protecting performance is poor, external decoration is influenced by the external world.Also adopt With light steel skeleton heat-insulation system or polyurethane foam technology, although light steel skeleton heat-insulation system solves above-mentioned defect, But due to cost height, it is difficult to promote the use of;The problems such as polyurethane foam technology is inconvenient there is also construction simultaneously, promote the use of by To certain limitation.
In addition, the straw refuse quantity that China's agricultural generates is very big, but its utilization rate is very low.In many regions, people Stalk is burned in the ground directly, the waste of stalk resource had both been caused in this way, and also seriously polluted environment.
Polystyrene products are also seen everywhere, but the utilization rate of poly styrene wastes is extremely low, polystyrene products It is completely degraded in nature and needs long time, while can also cause secondary pollution to natural resources such as soil, water sources.
In recent years, with the rapid development of our country's economy, required resource also increased severely therewith, especially the mine of industry pair Producing resources requirement is even more to greatly increase, and which results in excess load minings, has in turn resulted in a large amount of tailing accumulation.Tail For mine as a kind of mine solid waste, utilization rate is very low.The accumulation of tailing, occupies a large amount of arable land, and the heavy metal of discharge has Malicious harmful substance etc. causes serious pollution to natural resources such as soil, water sources.
Therefore how asking for building enclosure external thermal insulation is solved by waste utilizations such as stalk, polystyrene, tailings and simultaneously Topic, becomes urgent problem to be solved.
Summary of the invention
The object of the present invention is to provide a kind of glass fiber reinforced cement composite thermo-insulating wall boards and preparation method thereof, to solve That there are service lifes is short for the insulating layer of existing retaining wall, fire protecting performance is poor, long construction period, external decoration are difficult to and wallboard at This high technical problem;Also solve that straw, polystyrene, the reuse ratio of tailing waste thing are low, and environmental pollution is serious The technical issues of.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of glass fiber reinforced cement composite thermo-insulating wall board, including heat preservation core plate and it is enclosed in heat preservation core plate side surrounding Outline border, the outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, and the modification is mixed The raw material for coagulating soil include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, corn stover, polystyrene foam particles, latex powder and subtract Aqua, the corn stover are the corn straw modifications successively impregnated by sodium hydroxide solution with sodium silicate solution sprinkling.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
560 parts~570 parts of ordinary portland cement;
100 parts~110 parts of CHARACTERISTICS OF TAILINGS SAND;
330 parts~350 parts of water;
0.5 part~1.0 parts of latex powder;
0.5 part~1.0 parts of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.0%~3.2% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 50%~55% of modified concrete total volume.
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
840 parts~850 parts of ordinary portland cement;
145 parts~155 parts of flyash;
1000 parts~1200 parts of fine sand;
800 parts~1000 parts of coarse sand;
12 parts~17 parts of naphthalene series high-efficiency water-reducing agent;
420 parts~440 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.1%~2.3% of glass fiber reinforced cement total volume;
The outline border includes the front side board made of glass fiber reinforced cement, back side panel, left side plate and right end plate, described The inside of front side board and back side panel is embedded with galvanized steel wire netting.
Alignment setting before and after the front side board and back side panel, the left side of the left side of the left side plate with respect to two side plates Concordantly, the right side of the protrusion perhaps indent right end plate is concordant with respect to the right side of two side plates, protrudes or indent.
A kind of production method of glass fiber reinforced cement composite thermo-insulating wall board, making step are as follows:
Step 1 prepares modified concrete: including first ordinary portland cement, tailing by the raw material of modified concrete Sand is mixed evenly by the corn stover of modification, polystyrene foam particles and latex powder by design proportion, then The water and water-reducing agent that accordingly match is added, stirs evenly that form concrete slurry stand-by;
Step 2 makes heat preservation core plate: according to design size, the coagulation in step 1 is poured on the mold of heat preservation core plate It is conserved after soil paste material, completes heat preservation core plate production;
Step 3 prepares glass fiber reinforced cement: first by portland cement, flyash, fine sand, coarse sand, glass fibre, It is mixed evenly by design proportion, the water and water-reducing agent accordingly matched is then added, stir evenly that form cement slurry stand-by;
Step 4, according to design size, one layer of galvanized steel wire netting of first laying on outer frame mould, then in galvanized steel wire netting Cement slurry in one layer of step 3 of upper laying tiling wraps up galvanized steel wire netting, and vibration makes on rear side of the closely knit smooth formation of cement slurry Plate (4);
Step 5 after having certain intensity to the back side panel in step 4, is placed in step 2 in upside and has been made The heat preservation core plate performed;
Step 6, another layer of galvanized steel wire netting of laying on the upside of heat preservation core plate, respectively in the left and right sides of heat preservation core plate, plating The cement slurry package of cement slurry on zinc steel wire in formed by integrally casting step 3, the laying tiling on the upside of heat preservation core plate is zinc-plated Steel wire, vibration make cement slurry is closely knit smooth to form left side plate, right end plate and front side board;
Step 7 conserves entire wall 24~48 hours at normal temperature, and room temperature conserves one week again after demoulding.
In the step 1, corn stover passes through modification, and the process of modification includes being first using concentration 3.5% sodium hydroxide solution soaking corn stalk 8~12 hours, then with concentration be 1.0% sodium silicate solution be sprayed at through Cross the corn stover surface impregnated.
Compared with prior art the invention has the characteristics that and the utility model has the advantages that
Discarded straw, EPS particle is reasonably utilized in the present invention, reduces environmental pollution;Discarded plant straw Stalk, EPS particle can greatly reduce the thermal coefficient of modified concrete, improve the thermal insulation property of core plate.The present invention is reasonable Discarded CHARACTERISTICS OF TAILINGS SAND is utilized in ground, and the natural sand for replacing price relatively high with CHARACTERISTICS OF TAILINGS SAND is greatly reduced to natural sand Exploitation, not only protects environment, but also economize on resources.The utilization of the wastes such as discarded straw, EPS particle, CHARACTERISTICS OF TAILINGS SAND is so that enclose The cost of protection structure exterior wall substantially reduces, and has good economic benefit and environmental benefit, is worth promoting.
The present invention solves that outer viscous insulation board service life is short, fire protecting performance is poor, environmental pollution is big, and external decoration difficulty etc. is asked Topic is formed using prefabricated inside holding core plate in the surrounding setting fully wrapped around heat preservation core plate of glass fiber reinforcement outline border of core plate The wallboard that building enclosure uses, the center fire protecting performance that heat preservation core plate is located at wall is good, and thermal insulation property is prominent, and thermal coefficient is about 25% or so of stack pile normal concrete wallboard;The wallboard unit mass is lighter simultaneously, about the 75% of normal concrete wallboard Left and right.
Production simple production process of the invention reduces working procedure, reduces wallboard cost, reduces environmental pollution, can be real Existing building industrialization production.The present invention is suitable for structural envelope, heat preservation and the decoration of frame structure building exterior wall.
Detailed description of the invention
The present invention will be further described in detail with reference to the accompanying drawing.
Fig. 1 is the structural schematic diagram of the embodiment of the present invention one, two.
Fig. 2 is the cross section structure schematic diagram of Fig. 1.
Fig. 3 is the structural schematic diagram of the embodiment of the present invention three, four.
Fig. 4 is the cross section structure schematic diagram of Fig. 3.
Fig. 5 is the structural schematic diagram of the embodiment of the present invention five, six.
Fig. 6 is the cross section structure schematic diagram of Fig. 5.
Appended drawing reference: 1- galvanized steel wire netting, 2- heat preservation core plate, 3- front side board, 4- back side panel, 5- left side plate, 6- Right end plate.
Specific embodiment
Embodiment one
Referring to shown in Fig. 1-2, a kind of glass fiber reinforced cement composite thermo-insulating wall board, including heat preservation core plate 2 and be enclosed in The outline border of heat preservation core plate side surrounding, the outline border include the front side board 3 made of glass fiber reinforced cement, back side panel 4, a left side The inside of end plate 5 and right end plate 6, the front side board 3 and back side panel 4 is embedded with galvanized steel wire netting 1.The front side board 3 is with after Setting is aligned before and after side plate 4.For the reliable of connection and conveniently, the left end of the left side of the left side plate 5 with respect to two side plates It is protruded with respect to the right side of two side plates the right side of face indent, the right end plate 6.
In the present embodiment, the thickness of wallboard can be 200mm, and width may be designed as two kinds of specifications of 780mm and 810mm, height For 2700mm, the width and height that wallboard arrives can also be voluntarily adjusted according to demand in actual production.Front side board 3 and back side panel 4 Thickness be 40mm, the size of galvanized steel wire netting 1 is 100mm × 100mm, is the zinc-coated wire grid system for being 4mm by diameter At.
The outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, the modification The raw material of concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the corn stover by modification, polystyrene bubble Foam particle, latex powder and water-reducing agent.
Described is primarily referred to as the modification of corn stover: being soaked first using the sodium hydroxide solution that concentration is 3.5% Bubble corn stalk 8~12 hours, to remove the organic matter composition in corn stover;Then the sodium metasilicate for being 1.0% with concentration is molten Liquid is uniformly sprayed at the surface of above-mentioned corn stover, carries out chemistry and promotees to block, to increase between corn stover and concrete Cohesive force.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
565 parts of ordinary portland cement;
100 parts of CHARACTERISTICS OF TAILINGS SAND;
340 parts of water;
0.8 part of latex powder;
1.0 parts of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.0% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 50% of modified concrete total volume;
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
845 parts of ordinary portland cement;
145 parts of flyash;
1100 parts of fine sand;
900 parts of coarse sand;
14 parts of water-reducing agent;
440 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.1% of glass fiber reinforced cement total volume.
Embodiment two
Referring to shown in Fig. 3-4, panel structure is the same as example 1.
The outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, the modification The raw material of concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the corn stover by modification, polystyrene bubble Foam particle, latex powder and water-reducing agent.Described is primarily referred to as the modification of corn stover: the use of concentration being first 3.5% Sodium hydroxide solution soaking corn stalk 8~12 hours, to remove the organic matter composition in corn stover;Then it is with concentration 1.0% sodium silicate solution is uniformly sprayed at the surface of above-mentioned corn stover, carries out chemistry and promotees to block, to increase corn stover Cohesive force between concrete.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
570 parts of ordinary portland cement;
105 parts of CHARACTERISTICS OF TAILINGS SAND;
330 parts of water;
1.8 parts of latex powder;
0.8 part of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.1% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 53% of modified concrete total volume.
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
850 parts of ordinary portland cement;
142 parts of flyash;
1000 parts of fine sand;
1000 parts of coarse sand;
15 parts of water-reducing agent;
430 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.2% of glass fiber reinforced cement total volume.
Embodiment three
Referring to shown in Fig. 3-4, what is different from the first embodiment is that a left side of the left side of the left side plate 5 with respect to two side plates End face is concordant, and the right side of the right end plate 6 is protruded with respect to the right side of two side plates.
The outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, the modification The raw material of concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the corn stover by modification, polystyrene bubble Foam particle, latex powder and water-reducing agent.Described is primarily referred to as the modification of corn stover: the use of concentration being first 3.5% Sodium hydroxide solution soaking corn stalk 8~12 hours, to remove the organic matter composition in corn stover;Then it is with concentration 1.0% sodium silicate solution is uniformly sprayed at the surface of above-mentioned corn stover, carries out chemistry and promotees to block, to increase corn stover Cohesive force between concrete.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
560 parts of ordinary portland cement;
110 parts of CHARACTERISTICS OF TAILINGS SAND;
345 parts of water;
0.6 part of latex powder;
0.5 part of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.1% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 55% of modified concrete total volume
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
840 parts of ordinary portland cement;
155 parts of flyash;
1150 parts of fine sand;
950 parts of coarse sand;
17 parts of water-reducing agent;
420 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.1% of glass fiber reinforced cement total volume.
Example IV
Referring to shown in Fig. 3-4, panel structure is identical as embodiment three.
The outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, the modification The raw material of concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the corn stover by modification, polystyrene bubble Foam particle, latex powder and water-reducing agent.Described is primarily referred to as the modification of corn stover: the use of concentration being first 3.5% Sodium hydroxide solution soaking corn stalk 8~12 hours, to remove the organic matter composition in corn stover;Then it is with concentration 1.0% sodium silicate solution is uniformly sprayed at the surface of above-mentioned corn stover, carries out chemistry and promotees to block, to increase corn stover Cohesive force between concrete.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
565 parts of ordinary portland cement;
105 parts of CHARACTERISTICS OF TAILINGS SAND;
350 parts of water;
0.5 part of latex powder;
0.7 part of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.0% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 52% of modified concrete total volume
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
842 parts of ordinary portland cement;
150 parts of flyash;
1200 parts of fine sand;
800 parts of coarse sand;
16 parts of water-reducing agent;
435 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.3% of glass fiber reinforced cement total volume.
Embodiment five
Referring to shown in Fig. 5-6, what is different from the first embodiment is that a left side of the left side of the left side plate 5 with respect to two side plates The right side of end face indent, the right end plate 6 is concordant with respect to the right side of two side plates.
The outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, the modification The raw material of concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the corn stover by modification, polystyrene bubble Foam particle, latex powder and water-reducing agent.Described is primarily referred to as the modification of corn stover: the use of concentration being first 3.5% Sodium hydroxide solution soaking corn stalk 8~12 hours, to remove the organic matter composition in corn stover;Then it is with concentration 1.0% sodium silicate solution is uniformly sprayed at the surface of above-mentioned corn stover, carries out chemistry and promotees to block, to increase corn stover Cohesive force between concrete.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
560 parts of ordinary portland cement;
100 parts of CHARACTERISTICS OF TAILINGS SAND;
335 parts of water;
0.7 part of latex powder;
0.6 part of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.2% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 54% of modified concrete total volume
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
844 parts of ordinary portland cement;
152 parts of flyash;
1050 parts of fine sand;
850 parts of coarse sand;
13 parts of water-reducing agent;
425 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.2% of glass fiber reinforced cement total volume.
Embodiment six
Referring to shown in Fig. 5-6, panel structure is identical as embodiment five.Wallboard in the present embodiment can be with embodiment one- Four wallboard is used in combination, using mortise-tenon joint.
The outline border is made of glass fiber reinforced cement, and the heat preservation core plate is made of modified concrete, the modification The raw material of concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the corn stover by modification, polystyrene bubble Foam particle, latex powder and water-reducing agent.Described is primarily referred to as the modification of corn stover: the use of concentration being first 3.5% Sodium hydroxide solution soaking corn stalk 8~12 hours, to remove the organic matter composition in corn stover;Then it is with concentration 1.0% sodium silicate solution is uniformly sprayed at the surface of above-mentioned corn stover, carries out chemistry and promotees to block, to increase corn stover Cohesive force between concrete.
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
570 parts of ordinary portland cement;
110 parts of CHARACTERISTICS OF TAILINGS SAND;
345 parts of water;
0.6 part of latex powder;
0.9 part of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.2% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 51% of modified concrete total volume
The raw material of the glass fiber reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber, naphthalene series high-efficiency water-reducing agent and water.
In the glass fiber reinforced cement, ordinary portland cement, flyash, fine sand, coarse sand, water-reducing agent and water weight It is as follows to measure part:
847 parts of ordinary portland cement;
145 parts of flyash;
1100 parts of fine sand;
900 parts of coarse sand;
12 parts of water-reducing agent;
435 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.3% of glass fiber reinforced cement total volume.
Wherein, the connection of adjacent two blocks of wallboards can be used adaptable protrusion and indent and carry out mortise-tenon joint in the present invention.
Wallboard in embodiment one, two can be used in combination with the wallboard of embodiment one-six, using mortise-tenon joint.
Wallboard in embodiment three, four can be used in combination with the wallboard of embodiment one, two, five and six, using Tenon Connection.
Wallboard in embodiment five, six can be used in combination with the wallboard of embodiment one, two, three and four, using Tenon Connection.
The production method of above kind of glass fiber reinforced cement composite thermo-insulating wall board, making step is identical, as follows:
Step 1 prepares modified concrete: including first ordinary portland cement, tailing by the raw material of modified concrete Sand is mixed evenly by the corn stover of modification, polystyrene foam particles and latex powder by design proportion, then The water and water-reducing agent that accordingly match is added, stirs evenly that form concrete slurry stand-by;
Wherein modification corn stover process is as follows: the sodium hydroxide solution soaking corn for the use of concentration being first 3.5% Stalk 8~12 hours, to remove the organic matter composition in corn stover;Then the sodium silicate solution for being 1.0% with concentration is uniform It is sprayed at the surface of above-mentioned corn stover, chemistry is carried out and promotees to block, to increase the cohesive force between corn stover and concrete.
Step 2 makes heat preservation core plate: according to design size, the coagulation in step 1 is poured on the mold of heat preservation core plate It is conserved after soil paste material, completes heat preservation core plate production;
Step 3 prepares glass fiber reinforced cement: first by ordinary portland cement, flyash, fine sand, coarse sand, glass Fiber is mixed evenly by design proportion, the water and water-reducing agent accordingly matched is then added, stirs evenly to form cement slurry For use;
Step 4, according to design size, one layer of galvanized steel wire netting of first laying on outer frame mould, then in galvanized steel wire netting Cement slurry in one layer of step 3 of upper laying tiling wraps up galvanized steel wire netting, and vibration makes on rear side of the closely knit smooth formation of cement slurry Plate 4;
Step 5 after having certain intensity to the back side panel 4 in step 4, is placed in step 2 in upside and has been made The heat preservation core plate performed;
Step 6, another layer of galvanized steel wire netting of laying on the upside of heat preservation core plate, respectively in the left and right sides of heat preservation core plate, plating The cement slurry package of cement slurry on zinc steel wire in formed by integrally casting step 3, the laying tiling on the upside of heat preservation core plate is zinc-plated Steel wire, vibration make cement slurry is closely knit smooth to form left side plate 5, right end plate 6 and front side board 3;
Step 7 conserves entire wall 24~48 hours at normal temperature, and room temperature conserves one week again after demoulding.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of glass fiber reinforced cement composite thermo-insulating wall board, it is characterised in that: including heat preservation core plate (2) and be enclosed in heat preservation The outline border of core plate side surrounding, the outline border are made of glass fiber reinforced cement, and the heat preservation core plate is by modified concrete system At the raw material of the modified concrete include ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, corn stover, polystyrene foam Grain, latex powder and water-reducing agent, the corn stover are successively to impregnate to change with what sodium silicate solution sprayed by sodium hydroxide solution Property corn stover.
2. glass fiber reinforced cement composite thermo-insulating wall board according to claim 1, it is characterised in that:
In the modified concrete, ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, water, the parts by weight of latex powder and water-reducing agent are as follows:
560 parts~570 parts of ordinary portland cement;
100 parts~110 parts of CHARACTERISTICS OF TAILINGS SAND;
330 parts~350 parts of water;
0.5 part~1.0 parts of latex powder;
0.5 part~1.0 parts of water-reducing agent;
The water-reducing agent uses high performance water reducing agent of polyocarboxy acid;
The length of the corn stover is 8mm~12mm, and incorporation volume is the 3.0%~3.2% of modified concrete total volume;
The incorporation volume of the polystyrene foam particles is the 50%~55% of modified concrete total volume.
3. glass fiber reinforced cement composite thermo-insulating wall board according to claim 1 or 2, it is characterised in that: the glass The raw material of fibre reinforced cement include ordinary portland cement, flyash, fine sand, coarse sand, glass fibre, naphthalene series high-efficiency diminishing Agent and water.
4. glass fiber reinforced cement composite thermo-insulating wall board according to claim 3, it is characterised in that: the glass fibre Enhance in cement, ordinary portland cement, flyash, fine sand, coarse sand, the parts by weight of water-reducing agent and water are as follows:
840 parts~850 parts of ordinary portland cement;
145 parts~155 parts of flyash;
1000 parts~1200 parts of fine sand;
800 parts~1000 parts of coarse sand;
12 parts~17 parts of water-reducing agent;
420 parts~440 parts of water;
The water-reducing agent uses naphthalene series high-efficiency water-reducing agent;
The incorporation volume of the glass fibre is the 2.1%~2.3% of glass fiber reinforced cement total volume.
5. glass fiber reinforced cement composite thermo-insulating wall board according to claim 1 or 2 or 4, it is characterised in that: described outer Frame includes the front side board made of glass fiber reinforced cement (3), back side panel (4), left side plate (5) and right end plate (6), before described The inside of side plate (3) and back side panel (4) is embedded with galvanized steel wire netting (1).
6. glass fiber reinforced cement composite thermo-insulating wall board according to claim 5, it is characterised in that: the front side board (3) and before and after back side panel (4) it is aligned setting, the left side of the left side plate (5) is concordant with respect to the left side of two side plates, protrudes Perhaps the right side of the indent right end plate (6) is concordant with respect to the right side of two side plates, protrusion or indent.
7. the production method of glass fiber reinforced cement composite thermo-insulating wall board according to claim 5 or 6, feature exist In making step is as follows:
Step 1 prepares modified concrete: including first ordinary portland cement, CHARACTERISTICS OF TAILINGS SAND, warp by the raw material of modified concrete Corn stover, polystyrene foam particles and the latex powder for crossing modification are mixed evenly by design proportion, are then added The water and water-reducing agent accordingly matched, stirs evenly that form concrete slurry stand-by;
Step 2 makes heat preservation core plate: according to design size, the concrete grout in step 1 is poured on the mold of heat preservation core plate It is conserved after material, completes heat preservation core plate production;
Step 3 prepares glass fiber reinforced cement: first by ordinary portland cement, flyash, fine sand, coarse sand, glass fibre, It is mixed evenly by design proportion, the water and water-reducing agent accordingly matched is then added, stir evenly that form cement slurry stand-by;
Step 4, according to design size, one layer of galvanized steel wire netting of first laying, is then applied in zinc-coated wire on the net on outer frame mould If the cement slurry in the one layer of step 3 that tile wraps up galvanized steel wire netting, vibration makes the closely knit smooth formation back side panel of cement slurry (4);
Step 5 after having certain intensity to the back side panel (4) in step 4, is placed in step 2 in upside and has been made Good heat preservation core plate;
Step 6, another layer of galvanized steel wire netting of laying on the upside of heat preservation core plate, respectively in the left and right sides of heat preservation core plate, galvanized steel The cement slurry of cement slurry on silk screen in formed by integrally casting step 3, the laying tiling on the upside of heat preservation core plate wraps up zinc-coated wire Net, vibration make cement slurry is closely knit smooth to form left side plate (5), right end plate (6) and front side board (3);
Step 7 conserves entire wall 24~48 hours at normal temperature, and room temperature conserves one week again after demoulding.
8. the production method of glass fiber reinforced cement composite thermo-insulating wall board according to claim 7, it is characterised in that: institute It states in step 1, corn stover passes through modification, and the process of modification includes the hydroxide for the use of concentration being first 3.5% Then sodium solution soaking corn stalk 8~12 hours is sprayed at the corn by immersion with the sodium silicate solution that concentration is 1.0% Stalk surface.
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CN107859233A (en) * 2017-11-27 2018-03-30 云南昆船设计研究院 A kind of composite plate for building and its production technology
CN109057139A (en) * 2018-08-31 2018-12-21 江苏金贸科技发展有限公司 Prefabricated assembled " sandwich " building wall board of one kind and its preparation process
CN117306773A (en) * 2018-11-28 2023-12-29 河南建筑职业技术学院 Preparation method of prefabricated wallboard for building external heat preservation
CN110056119A (en) * 2019-04-16 2019-07-26 武汉大学 It is prefabricated to exempt to decorate the corrosion-resistant heat-insulation wall plate of cracking resistance
CN110821032A (en) * 2019-10-31 2020-02-21 中建材料技术研究成都有限公司 Light heat-preservation high-toughness cement-based composite wallboard and preparation process thereof
CN111087201A (en) * 2019-12-24 2020-05-01 北京大学 Solid waste light partition wall board material and preparation method thereof
CN111689756A (en) * 2020-05-29 2020-09-22 安徽埃科博秸秆科技有限公司 Plant fiber composite cement wallboard and preparation method thereof
CN112983226A (en) * 2021-03-25 2021-06-18 安必安新材料集团有限公司 Fireproof door leaf and processing technology thereof
CN113216504A (en) * 2021-05-14 2021-08-06 福建新华夏建工集团有限公司 Preparation method of glass fiber reinforced cement composite thermal insulation wallboard
CN115259887B (en) * 2022-08-11 2023-05-19 启东海中港建材有限公司 High-strength aerated renewable concrete

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Patentee before: HEBEI University OF ARCHITECTURE