CN106758942A - A kind of solar energy berth lock with self-cleaning film layer - Google Patents

A kind of solar energy berth lock with self-cleaning film layer Download PDF

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Publication number
CN106758942A
CN106758942A CN201611108206.1A CN201611108206A CN106758942A CN 106758942 A CN106758942 A CN 106758942A CN 201611108206 A CN201611108206 A CN 201611108206A CN 106758942 A CN106758942 A CN 106758942A
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CN
China
Prior art keywords
hydrosol
solar energy
cleaning
nano
berth lock
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Granted
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CN201611108206.1A
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Chinese (zh)
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CN106758942B (en
Inventor
姚培荣
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Beijing Kuaishiqin Technology Co ltd
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Foshan Best Technology Co Ltd
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Priority to CN201611108206.1A priority Critical patent/CN106758942B/en
Publication of CN106758942A publication Critical patent/CN106758942A/en
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F13/00Arrangements for obstructing or restricting traffic, e.g. gates, barricades ; Preventing passage of vehicles of selected category or dimensions
    • E01F13/04Arrangements for obstructing or restricting traffic, e.g. gates, barricades ; Preventing passage of vehicles of selected category or dimensions movable to allow or prevent passage
    • E01F13/042Arrangements for obstructing or restricting traffic, e.g. gates, barricades ; Preventing passage of vehicles of selected category or dimensions movable to allow or prevent passage for controlling access to an individual parking space
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a kind of solar energy berth lock with self-cleaning film layer; it can make solar energy glass remain clean conditions; with solar energy utilization ratio higher; its solar absorption component includes the self-cleaning film layer for absorbing the absorbing energy layer of solar energy, absorbing energy layer being formed the protective layer of protection and is pasted on outside protective layer, and the self-cleaning film layer uses the coating (mass percent) of following constituent:Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 42.5% 74.5%, terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 5.5% 12.5%, the magnesium fluoride hydrosol --- 0.05% 0.15%, the hydrosol of antimony-doped stannic oxide 5% --- 0.02% 0.20%, absolute ethyl alcohol --- 0.05% 0.1%, nitric acid --- 0.05% 0.1%, ammonium nitrate --- 0.05% 0.15%, surfactant --- 0.02% 0.15%, coupling agent --- 0.05% 0.25%, deionized water --- surplus.

Description

A kind of solar energy berth lock with self-cleaning film layer
Technical field
The present invention relates to a kind of solar energy berth lock, especially a kind of solar energy berth lock with self-cleaning film layer.
Background technology
With developing rapidly for new-energy automobile industry, parking problem and charging problems become increasingly conspicuous, in order to solve this Problem, those skilled in the art propose various solutions, for example, improve shutdown system, lugs, or set up charging Stake etc., but, these are all only for the one-sided improvement project for solving parking problem or charging problems.
Wherein, publication No. is charging electric vehicle to be proposed in the application for a patent for invention of CN105421853A a kind of Embedded solar energy berth lock, its utilize parking stall berth lock collect solar energy, whereby, can not only realize berth lock from Dynamicization, and can be charging electric vehicle, can be solved the above problems with relatively good.
Simply, it still has improved space, for example, how to be improved by simple transformation being imitated to the reception of solar energy How rate, further, since berth lock is provided at outdoor, easily because pollution causes its absorption efficiency to solar energy to decline, subtract It is the current technical issues that need to address that efficiency declines problem caused by few external contamination.
The content of the invention
(1) technical problem to be solved
In order to solve the above mentioned problem of prior art, the present invention provides a kind of solar energy berth lock, and it passes through to set self-cleaning Film layer can ensure that the surface for receiving solar energy remains cleaning, and then improve solar energy utilization ratio.
(2) technical scheme
In order to achieve the above object, the main technical schemes that the present invention is used include:
A kind of solar energy berth lock, it includes:
Parking stall lock body, the released state unlocked with the lock-out state for locking parking stall and by parking stall;
Solar absorption component, located at parking stall lock body, it has first position state and second place state, first During configuration state, solar absorption component absorbs direction towards first, during second place state, solar absorption component direction second Absorb direction, wherein, solar absorption component include absorb solar energy absorbing energy layer, to absorbing energy layer formed protection protective layer and The self-cleaning film layer outside protective layer is pasted on, self-cleaning film layer uses the coating (mass percent) of following constituent:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 42.5%-74.5%, fluorine tin is terbium doped 3.5% nano-TiO2The hydrosol --- 5.5%-12.5%, the magnesium fluoride hydrosol --- 0.05%-0.15%, mix antimony titanium dioxide The hydrosol of tin 5% --- 0.02%-0.20%, absolute ethyl alcohol --- 0.05%-0.1%, nitric acid --- 0.05%-0.1%, nitre Sour ammonium --- 0.05%-0.15%, surfactant --- 0.02%-0.15%, coupling agent --- 0.05%-0.25%, go Ionized water --- surplus;
First drive mechanism, there is provided the driving force that parking stall lock body is changed between lock-out state and released state, and The driving force that solar absorption component is changed between first position state and second place state;
Central controller, as the control centre of solar energy berth lock.
In order to improve self-cleaning efficiency, while, it is to avoid the absorption efficiency to solar energy is reduced too much, preferably, self-cleaning film In coating:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 55%-65%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8%-10%;
The magnesium fluoride hydrosol --- 0.08%-0.11%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.12%-0.17%;
Absolute ethyl alcohol --- 0.07%-0.08%;
Nitric acid --- 0.07%-0.08%;
Ammonium nitrate --- 0.06%-0.08%;
Surfactant --- 0.08%-0.12%;
Coupling agent --- 0.15%-0.18%.
In order to obtain optimal self-cleaning efficiency, while, it is to avoid the absorption efficiency to solar energy is reduced too much, more preferably, In self-cleaning film coating:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 58%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8.5%;
The magnesium fluoride hydrosol --- 0.10%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.15%;
Absolute ethyl alcohol --- 0.075%;
Nitric acid --- 0.075%;
Ammonium nitrate --- 0.07%;
Surfactant --- 0.10%;
Coupling agent --- 0.17%.
The solar energy berth lock of one embodiment of the invention, wherein, in self-cleaning film coating:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol average grain diameter 15nm;
Terbium doped 3.5% nano-TiO of fluorine tin2The average grain diameter 20nm of the hydrosol;
The average grain diameter 30nm of the magnesium fluoride hydrosol;
Tin antimony mol ratio is 9 in antimony-doped stannic oxide:1.
In order to improve the receiving efficiency to sunshine as far as possible, such as moment keeps optimal or preferably receives as far as possible Efficiency, the solar energy berth lock of one embodiment of the invention, wherein:First drive mechanism include it is multiple can independent control height Retractable support mechanism, multiple retractable support mechanisms were laid in the periphery of solar absorption component, and respective height with one day The change of the irradiating angle of middle sunshine and change so that the solar absorption component side nearest from the sun is highly minimum, with More sunlights are received, efficiency is improved.
Further, retractable support mechanism include four can independent control height hydraulic package, four hydraulic packages are in Quadrangle is arranged in the periphery of solar absorption component.
Further, four hydraulic packages are respectively arranged on four orientation of East, West, South, North, or located at the southeast, southwest, Northwest, four, northeast orientation.
The solar energy berth lock of one embodiment of the invention, wherein:Retractable support mechanism include three can independent control it is high The hydraulic package of degree, is triangularly arranged in the periphery of solar absorption component, the first hydraulic package correspondence north, second Hydraulic package correspondence the southeast, the 3rd hydraulic package correspondence southwest.
In order to obtain more preferably cleaning effect, the solar energy berth lock of one embodiment of the invention, it also includes:
Cleaning assemblies, located at solar absorption component, the self-cleaning film layer to solar absorption component is cleaned;
Second drive mechanism, there is provided cleaning assemblies performs the driving force of cleaning.
The solar energy berth lock of one embodiment of the invention, wherein:Cleaning assemblies is in parking stall lock body and/or solar energy Cleaned during absorbent assembly transition status, to save energy ezpenditure.
The solar energy berth lock of one embodiment of the invention, wherein:Cleaning assemblies includes fitting in solar absorption component Scraper plate or clean arm, cleaning assemblies using scraper plate or clean arm solar absorption component is cleaned, with ensure conversion effect Rate.
Further, cleaning assemblies also includes a linked component, when drive mechanism adjusts height, interlocks scraper plate or scouring Arm performs cleaning action, to save energy ezpenditure.
Further, the cleaning action that scraper plate or scouring arm are performed includes swing, mobile or rotation.Preferably, in order to Cleaning effect is improved, rotation while also including rotation action, i.e. swing, mobile or rotation.Preferably, during rotation with it is to be cleaned The direction of motion of face tangency location is in opposite direction with movement, further to improve cleaning effect.
In order to further improve cleaning effect, cleaning assemblies is provided with scraper plate and cleans arm, the two synchronizing moving, also, Clean arm with scraper plate in the first direction synchronizing moving while, also rotate in a second direction, wherein, second direction is in cleaning assemblies Face to be cleaned tangential direction it is identical with first direction, that is, clean arm be backscrolling advance, whereby, can significantly improve Scrub effect.
Specifically, cleaning assemblies includes framework, framework has parallel the first guide rail and the second guide rail, and is led along first Rail rolls the first roller for advancing and the second roller that advance is rolled along the second guide rail, and the first roller and the second roller are synchronously rolled Dynamic, advanced in unison, scraper plate is fixedly connected the bearing of the first roller, with the first roller advanced in unison, cleans arm and is fixed on the second rolling The axle of wheel, is synchronized with the movement (i.e. synchronous rotary, advanced in unison) with the second roller.
Wherein, the first guide rail is located at lower section, and the second guide rail is above, the guide pass of the two be respectively provided with it is with teeth, i.e., two The relative tooth bar of the flank of tooth, the first roller and the second roller are gear, and the two is meshed, while each being led with the first guide rail and second Rail is engaged.
Wherein, the guide pass of the first guide rail and/or the second guide rail is inclined-plane and/or plane.
In one embodiment of the present of invention, the first guide rail and/or the second guide rail are V-arrangement, and the inner surface of V-arrangement is guide pass.
Preferably, the guide pass of the first guide rail of V-arrangement and/or the second guide rail is the flank of tooth.
In one embodiment of the present of invention, there is the inner surface of dovetail groove, dovetail groove to be for the first guide rail and/or the second guide rail Guide pass.
Preferably, the madial wall and/or inner bottom wall of the dovetail groove of the first guide rail and/or the second guide rail are the flank of tooth.
In one embodiment of the present of invention, the rolling surface of the first roller and/or the second roller is the face of cylinder and/or circular cone Face.
Preferably, the first roller and/or the second roller have positioned at the face of cylinder and the inclined-plane positioned at two ends at middle part.
Wherein, the face of cylinder that the first roller and/or the second roller are located at middle part is the cylinder flank of tooth.
Wherein, the circular conical surface that the first roller and/or the second roller are located at two ends is conical gear face.
In one embodiment of the present of invention, the first roller is meshed with the second roller with the cylinder flank of tooth at middle part.
In one embodiment of the present of invention, conical gear face and the V-way face at the first roller and/or the second roller two ends are nibbled Close.
In a preferred embodiment of the invention, the teeth top of the conical gear face at the first roller and/or the second roller two ends It is resisted against the teeth root in V-way face, the teeth root and V-way of the conical gear face at the first roller and/or the second roller two ends There is pre- fixed gap, whereby so that the motion of the first roller and/or the second roller on V-way is more between the teeth top in face Plus it is steady, smooth.
In one embodiment of the present of invention, conical gear face and the trapezoidal rails at the first roller and/or the second roller two ends Madial wall flank engagement.
In one embodiment of the present of invention, the cylinder flank of tooth and trapezoidal rails in the middle part of the first roller and/or the second roller Inner bottom wall flank engagement.
In a preferred embodiment of the invention, the teeth top of the cylinder flank of tooth in the middle part of the first roller and/or the second roller There is the circle of pre- fixed gap, the first roller and/or the second roller two ends and the teeth root of the inner bottom wall flank of tooth of trapezoidal rails between The teeth contact of the cone flank of tooth peaks at the teeth root of the madial wall flank of tooth of trapezoidal rails, whereby so that the first roller and/or the second rolling The motion taken turns in trapezoidal rails is more steady, smooth.
Further, the teeth root of the cylinder flank of tooth in the middle part of the first roller and/or the second roller is interior with trapezoidal rails With pre- fixed gap between the teeth top of the bottom wall flank of tooth, the teeth root of the conical gear face at the first roller and/or the second roller two ends There is pre- fixed gap and the teeth top of the madial wall flank of tooth of trapezoidal rails between, whereby so that the first roller and/or the second roller Motion in trapezoidal rails is more steady, smooth.
First number of rollers is two, is triangularly arranged with the second roller.
Preferably, two the first rollers and a second roller three engage two-by-two.
Second drive mechanism need to only drive the first roller to move along the first direction, you can make scraper plate move along the first direction, And clean arm while roll in a second direction with the first roller synchronizing moving in the first direction.
The solar energy berth lock of one embodiment of the invention, it also has reset assembly, makes scraper plate or cleans arm reset.Too When positive energy cell panel is laid flat, scraper plate or scouring arm playback
The solar energy berth lock of one embodiment of the invention, wherein:Cleaning assemblies also includes spray assemblies, is inhaled to solar energy Receive the face shower water to be cleaned or cleaning solution of component.
(3) beneficial effect
The beneficial effects of the invention are as follows:Solar energy berth lock of the invention in solar absorption component due to being provided with self-cleaning Film layer, can make the surface for receiving solar energy irradiation remain clean conditions, improve the receiving efficiency to solar energy, improve To the utilization rate of solar energy.
Self-cleaning film layer is while preferable clean conditions are kept, it can also be ensured that it has preferable light transmission rate, can Can more efficiently be absorbed with to the solar energy being irradiated to thereon, it is to avoid waste.
Solar energy berth lock of the invention with more appropriate angle by that to integrally-built improvement, can receive sunshine Irradiation, be effectively improved overall utilization rate of the solar energy berth lock to solar energy.
Brief description of the drawings
Fig. 1 (only shows a flexible branch for the partial structural diagram of the solar energy berth lock of one embodiment of the invention Support mechanism);
Fig. 2 is four schematic layout patterns of retractable support mechanism of the solar energy berth lock of one embodiment of the invention;
Fig. 3 is three schematic layout patterns of retractable support mechanism of the solar energy berth lock of one embodiment of the invention;
Fig. 4 is the structural representation of the cleaning assemblies in the solar energy berth lock of one embodiment of the invention;
Fig. 5 is the transmission mechanism schematic diagram of the cleaning assemblies in the solar energy berth lock of one embodiment of the invention;
Fig. 6 illustrates for the upper rail of the transmission mechanism of the cleaning assemblies in the solar energy berth lock of one embodiment of the invention Figure;
Fig. 7 illustrates for the lower guideway of the transmission mechanism of the cleaning assemblies in the solar energy berth lock of one embodiment of the invention Figure;
Fig. 8 is the structural representation of the absorbent assembly of one embodiment of the invention;
Fig. 9 is a kind of application state schematic diagram of the solar energy berth lock of one embodiment of the invention.
【Description of reference numerals】
1:Parking stall lock body;2:Absorbent assembly;21:Absorbing energy layer;22:Protective layer;23:Self-cleaning film layer;3:Retractable support machine Structure;4:Cleaning assemblies;41:Scraper plate;411:First guide rail;412:First roller;413:Bearing;414:Framework;415:Interior guide rail Face;416:Conical gear face;42:Clean arm;421:Second guide rail;422:Second roller;423:Conical gear face;424:Madial wall; 425:Inner bottom wall;426:Axle;5:Second drive mechanism;6:Ground.
Specific embodiment
In order to preferably explain the present invention, in order to understand, below in conjunction with the accompanying drawings, by specific embodiment, to this hair It is bright to be described in detail.
Referring to Fig. 1, the solar energy berth lock of one embodiment of the invention, it includes:
Parking stall lock body 1, the released state unlocked with the lock-out state (referring to Fig. 9) for locking parking stall and by parking stall;
Solar absorption component 2, located at parking stall lock body 1, it has first position state and second place state, first During location status, solar absorption component 2 absorbs direction (referring to Fig. 9) towards first, during second place state, solar absorption Component 2 absorbs direction towards second, wherein, solar absorption component 2 is including absorbing the absorbing energy layer 21 of solar energy, to absorbing energy layer 21 The self-cleaning film layer 23 (referring to Fig. 8) for forming the protective layer 22 of protection and being pasted on outside protective layer 22, self-cleaning film layer 23 can be used Any one following self-cleaning film coatings;
First drive mechanism, there is provided the driving force that parking stall lock body 1 is changed between lock-out state and released state, and The driving force that solar absorption component 2 is changed between first position state and second place state;
Central controller, as the control centre of solar energy berth lock.
The self-cleaning film coating of the embodiment of the present invention 1, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 42.5%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 5.5%;
The magnesium fluoride hydrosol --- 0.05%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.02%;
Absolute ethyl alcohol --- 0.05%;
Nitric acid --- 0.05%;
Ammonium nitrate --- 0.05%;
Surfactant --- 0.02%;
Coupling agent --- 0.05%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 2, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 74.5%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 12.5%;
The magnesium fluoride hydrosol --- 0.15%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.20%;
Absolute ethyl alcohol --- 0.1%;
Nitric acid --- 0.1%;
Ammonium nitrate --- 0.15%;
Surfactant --- 0.15%;
Coupling agent --- 0.25%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 3, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 55%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8%;
The magnesium fluoride hydrosol --- 0.08%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.12%;
Absolute ethyl alcohol --- 0.07%;
Nitric acid --- 0.07%;
Ammonium nitrate --- 0.06%;
Surfactant --- 0.08%;
Coupling agent --- 0.15%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 4, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 65%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 10%;
The magnesium fluoride hydrosol --- 0.11%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.17%;
Absolute ethyl alcohol --- 0.08%;
Nitric acid --- 0.08%;
Ammonium nitrate --- 0.08%;
Surfactant --- 0.12%;
Coupling agent --- 0.18%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 5, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 58%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8.5%;
The magnesium fluoride hydrosol --- 0.10%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.15%;
Absolute ethyl alcohol --- 0.075%;
Nitric acid --- 0.075%;
Ammonium nitrate --- 0.07%;
Surfactant --- 0.10%;
Coupling agent --- 0.17%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 6, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 49.5%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 12.5%;
The magnesium fluoride hydrosol --- 0.11%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.15%;
Absolute ethyl alcohol --- 0.07%;
Nitric acid --- 0.05%;
Ammonium nitrate --- 0.08%;
Surfactant --- 0.12%;
Coupling agent --- 0.18%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 7, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 55%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 5.5%;
The magnesium fluoride hydrosol --- 0.15%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.17%;
Absolute ethyl alcohol --- 0.075%;
Nitric acid --- 0.07%;
Ammonium nitrate --- 0.06%;
Surfactant --- 0.15%;
Coupling agent --- 0.25%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 8, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 59%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8%;
The magnesium fluoride hydrosol --- 0.05%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.20%;
Absolute ethyl alcohol --- 0.08%;
Nitric acid --- 0.075%;
Ammonium nitrate --- 0.07%;
Surfactant --- 0.02%;
Coupling agent --- 0.05%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 9, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 61%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8.5%;
The magnesium fluoride hydrosol --- 0.08%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.02%;
Absolute ethyl alcohol --- 0.1%;
Nitric acid --- 0.08%;
Ammonium nitrate --- 0.075%;
Surfactant --- 0.08%;
Coupling agent --- 0.15%;
Deionized water --- surplus.
The self-cleaning film coating of the embodiment of the present invention 10, its constituent is (mass percent):
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 69.5%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 10%;
The magnesium fluoride hydrosol --- 0.10%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.12%;
Absolute ethyl alcohol --- 0.05%;
Nitric acid --- 0.1%;
Ammonium nitrate --- 0.08%;
Surfactant --- 0.10%;
Coupling agent --- 0.17%;
Deionized water --- surplus.
In any of the above-described self-cleaning film coating of embodiment:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol average grain diameter 15nm;
Terbium doped 3.5% nano-TiO of fluorine tin2The average grain diameter 20nm of the hydrosol;
The average grain diameter 30nm of the magnesium fluoride hydrosol;
Tin antimony mol ratio is 9 in antimony-doped stannic oxide:1.
Wherein, surfactant can be lauric acid diethyl amide or lauryl sodium sulfate, and coupling agent can be had One kind or mixture in machine silicone couplet KH550, KH560, KH570.
In any of the above-described embodiment, self-cleaning film coating can make (weight portion) as follows:
First, with 5.7 parts of tetraethyl orthosilicates, 6 parts of absolute ethyl alcohols, 4 parts of nitric acid, 0.8 part of Ga (NO3)3, 0.08 part of Tb (NO3)3Mixed with 3.42 parts of deionized waters, be made the colloidal sol of clear homogeneous, then stand fills tetraethyl orthosilicate at room temperature Divide hydrolysis, form gel, then 4 parts of deionized waters are added in gel, 4 parts of ethanol water is evaporated off, be made average grain diameter 15nm Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol;
Secondly, with 50 parts of titanyl sulfates, 5 parts of butters of tin and 5 parts of terbium nitrates, ammoniacal liquor is added to make pH value be 8- under agitation 9, filtering, washing precipitate are dispersed in 15 parts of deionized waters to not sulphate-containing ion, then by precipitation, add 0.1 part of dilute nitre Acid and 0.3 part of hydrogen peroxide, generate the hydrosol, then to 8 parts of magnesium fluosilicates are added in the hydrosol, be subsequently adding 0.4 part of magnesium nitrate The hydrofluoric acid of generation is neutralized, terbium doped 3.5% nano-TiO2 sol gel of fluorine tin of average grain diameter 20nm is made;
Again by Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol, terbium doped 3.5% nano-TiO of fluorine tin2 The hydrosol, the magnesium fluoride hydrosol, the hydrosol of antimony-doped stannic oxide 5%, absolute ethyl alcohol, nitric acid, ammonium nitrate, surfactant, idol Connection agent, deionized water are mixed and made into self-cleaning film coating.
Self-cleaning film coating can be coated in the surface of protective layer 22 and form self-cleaning film layer 23 by existing method.
For example, coating is coated on solar energy glass with glass coating roller, thickness 150nm, through 80-180 DEG C of heat stepwise Solidification 3 minutes, then in 500-720 DEG C of tempering 3 minutes, then detect its water contact angle and light transmittance.
The testing result of the self-cleaning film coating of foregoing embodiments is as shown in table 1 below.
It follows that self-cleaning film coating of the invention can make solar energy glass have preferably visible light transmissivity and Less water contact angle, is favorably improved its self-cleaning property and solar energy utilization ratio.
The solar energy berth lock of one embodiment of the invention, in order that solar absorption component 2 can receive it is more Sunlight irradiation, especially can keep solar energy receiving efficiency higher in different periods, the first drive mechanism includes many It is individual can independent control height retractable support mechanism 3, multiple retractable support mechanisms 3 are laid in the periphery of solar absorption component 2, And respective height changes with the change of the irradiating angle of sunshine in a day so that solar absorption component 2 is from the sun Nearest side is highly minimum (as shown in figure 9, usually less than ground 6), to receive more sunlights, absorbs more Solar energy, improve efficiency.
As shown in Fig. 2 the solar energy berth lock of one embodiment of the invention, its retractable support mechanism 3 can be only including four The hydraulic package of vertical control height, four hydraulic packages are arranged in the periphery of solar absorption component 2 in quadrangle.
Further, four hydraulic packages are respectively arranged on four orientation of East, West, South, North, or located at the southeast, southwest, Northwest, four, northeast orientation.
As shown in figure 3, the solar energy berth lock of one embodiment of the invention, wherein:Retractable support mechanism 3 can including three The hydraulic package of independent control height, is triangularly arranged in the periphery of solar absorption component 2, first hydraulic package correspondence The north, second hydraulic package correspondence the southeast, the 3rd hydraulic package correspondence southwest.
The solar energy berth lock of one embodiment of the invention, in order to obtain more preferably cleaning effect, it also includes:
Cleaning assemblies, located at solar absorption component 2, the self-cleaning film layer 23 to solar absorption component 2 is cleaned;
Second drive mechanism, there is provided cleaning assemblies performs the driving force of cleaning.
Because self-cleaning film layer 23 itself has certain antipollution, self-cleaning ability, then coordinate cleaning assemblies 4, can play Fabulous clean effect so that solar energy berth lock can all the time be in preferable clean conditions, can better profit from being irradiated to Sunshine thereon.
As shown in figure 4, the solar energy berth lock of one embodiment of the invention, wherein:Cleaning assemblies 4 includes fitting in the sun The scraper plate 41 and scouring arm 42 of energy absorbent assembly 2, when parking stall lock body 1 and/or solar absorption 2 transition status of component, cleaning Component 4 is cleaned using scraper plate 41 or scouring arm 42 to solar absorption component 2, to ensure conversion efficiency.
Further, cleaning assemblies 4 also include a linked component, when drive mechanism adjust height when, interlock scraper plate 41 or Clean arm 42 and perform cleaning action.
Further, the cleaning action that scraper plate 41 or scouring arm 42 are performed includes swing, mobile or rotation.Preferably, In order to improve cleaning effect, rotation while also including rotation action, i.e. swing, mobile or rotation.Preferably, during rotation with treat The direction of motion of clean surface tangency location is in opposite direction with movement, further to improve cleaning effect.
As shown in figure 4, in order to further improve cleaning effect, the scraper plate 41 and scouring arm 42 of cleaning assemblies 4, the two synchronization It is mobile, also, clean arm 42 with scraper plate 41 in the first direction synchronizing moving while, also rotate in a second direction, wherein, second Tangential direction of the direction in the face to be cleaned of cleaning assemblies 4 is identical with first direction, that is, it is that backscrolling advances to clean arm 42, Whereby, scrub effect can be significantly improved.
Referring to Fig. 5, cleaning assemblies 4 includes framework 414, and framework 414 has parallel the first guide rail 411 and the second guide rail 421, and the first roller 412 for advancing is rolled along the first guide rail 411 and the second roller for advancing is rolled along the second guide rail 421 422, the first roller 412 and the synchronous rolling of the second roller 422, advanced in unison, scraper plate 41 are fixedly connected the bearing of the first roller 412 413, with the advanced in unison of the first roller 412, the axle 426 that arm 42 is fixed on the second roller 422 is cleaned, it is synchronous with the second roller 422 Motion (i.e. synchronous rotary, advanced in unison).
Wherein, the first guide rail 411 is located at lower section, and the second guide rail 421 is above, the guide pass of the two be respectively provided with it is with teeth, That is the relative tooth bar of two flank of tooth, the first roller 412 and the second roller 422 are gear, and the two is meshed, while each with first The guide rail 421 of guide rail 411 and second is engaged.
Wherein, the guide pass of the first guide rail 411 and/or the second guide rail 421 is inclined-plane and/or plane.
As shown in fig. 7, in one embodiment of the present of invention, the first guide rail 411 and/or the second guide rail 421 are V-arrangement, V-arrangement Inner surface is guide pass.
Preferably, the guide pass of the first guide rail 411 of V-arrangement and/or the second guide rail 421 is the flank of tooth.
As shown in fig. 6, in one embodiment of the present of invention, the first guide rail 411 and/or the second guide rail 421 have dovetail groove, The inner surface of dovetail groove is guide pass.
Preferably, the madial wall 424 and/or inner bottom wall 425 of the dovetail groove of the first guide rail 411 and/or the second guide rail 421 are The flank of tooth.
In one embodiment of the present of invention, the rolling surface of the first roller 412 and/or the second roller 422 for the face of cylinder and/or Circular conical surface.
Preferably, the first roller 412 and/or the second roller 422 have positioned at the face of cylinder at middle part and positioned at the oblique of two ends Face.
Wherein, the face of cylinder that the first roller 412 and/or the second roller 422 are located at middle part is the cylinder flank of tooth.
Wherein, the circular conical surface that the first roller 412 and/or the second roller 422 are located at two ends is conical gear face 416,423.
In one embodiment of the present of invention, the first roller 412 is meshed with the second roller 422 with the cylinder flank of tooth at middle part.
In one embodiment of the present of invention, the conical gear face 416,423 at the first roller 412 and/or the two ends of the second roller 422 Engaged with V-way face 415.
As shown in fig. 7, in a preferred embodiment of the invention, the first roller 412 and/or the two ends of the second roller 422 The teeth contact of conical gear face 416,423 peaks at the teeth root in V-way face 415, the first roller 412 and/or the second roller 422 There is pre- fixed gap, whereby between the teeth root of conical gear face 416,423 at two ends and the teeth top in V-way face 415 so that The motion of first roller 412 and/or the second roller 422 on V-way is more steady, smooth.
In one embodiment of the present of invention, the conical gear face 416,423 at the first roller 412 and/or the two ends of the second roller 422 With the flank engagement of madial wall 424 of trapezoidal rails.
In one embodiment of the present of invention, the cylinder flank of tooth at the first roller 412 and/or the middle part of the second roller 422 with it is trapezoidal The flank engagement of inner bottom wall 425 of guide rail.
As shown in fig. 6, in a preferred embodiment of the invention, in the middle part of the first roller 412 and/or the second roller 422 There is pre- fixed gap, the first roller 412 between the teeth root of the teeth top of the cylinder flank of tooth and the flank of tooth of inner bottom wall 425 of trapezoidal rails And/or the teeth contact of the conical gear face 416,423 at the two ends of the second roller 422 peaks at the flank of tooth of madial wall 424 of trapezoidal rails Teeth root, whereby so that the motion of the first roller 412 and/or the second roller 422 in trapezoidal rails is more steady, smooth.
Wherein, the teeth root of the cylinder flank of tooth at the first roller 412 and/or the middle part of the second roller 422 is interior with trapezoidal rails There is the conical gear face of pre- fixed gap, the first roller 412 and/or the two ends of the second roller 422 between the teeth top of the flank of tooth of bottom wall 425 416th, there is pre- fixed gap, whereby between the teeth top of the flank of tooth of madial wall 424 of 423 teeth root and trapezoidal rails so that the The motion of one roller 412 and/or the second roller 422 in trapezoidal rails is more steady, smooth.
As shown in figure 5, the solar energy berth lock of one embodiment of the invention, wherein:The quantity of first roller 412 is two, It is triangularly arranged with the second roller 422.
Preferably, two the first rollers 412 and a three of the second roller 422 engage two-by-two.
Second drive mechanism 5 need to drive the first roller 412 to move along the first direction, you can make scraper plate 41 in the first direction It is mobile, and clean while arm 42 is rolled in a second direction and the first roller 412 synchronizing moving in the first direction.
The solar energy berth lock of one embodiment of the invention, it also has reset assembly, makes scraper plate 41 or cleans arm 42 and answers Position.Preferably, when solar panel is laid flat (such as can be concordant with ground 6), scraper plate 41 or scouring arm 42 playback, and whereby may be used To save the energy of the consumption that resets.
The solar energy berth lock of one embodiment of the invention, wherein:Cleaning assemblies 4 also includes spray assemblies, to solar energy The face shower water to be cleaned or cleaning solution of absorbent assembly 2.
In sum, solar energy berth lock of the invention, not only can be with more appropriate angle by integrally-built improvement Degree receives the irradiation of sunshine, moreover, it is also possible to preferable clean conditions and light transmission rate are remained, to being irradiated to thereon Solar energy can be absorbed more efficiently, it is to avoid be wasted, and be effectively improved overall profit of the solar energy berth lock to solar energy With rate.

Claims (9)

1. a kind of solar energy berth lock, it is characterised in that it includes:
Parking stall lock body, the released state unlocked with the lock-out state for locking parking stall and by parking stall;
Solar absorption component, located at parking stall lock body, it has first position state and second place state, first position shape During state, solar absorption component absorbs direction towards first, and during second place state, solar absorption component absorbs towards second Direction, wherein, solar absorption component includes absorbing the absorbing energy layer of solar energy, the protective layer of protection is formed to absorbing energy layer and is sticked In the self-cleaning film layer outside protective layer, self-cleaning film layer uses the coating (mass percent) of following constituent:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 42.5%-74.5%, fluorine tin is terbium doped 3.5% nano-TiO2The hydrosol --- 5.5%-12.5%, the magnesium fluoride hydrosol --- 0.05%-0.15%, mix antimony titanium dioxide The hydrosol of tin 5% --- 0.02%-0.20%, absolute ethyl alcohol --- 0.05%-0.1%, nitric acid --- 0.05%-0.1%, nitre Sour ammonium --- 0.05%-0.15%, surfactant --- 0.02%-0.15%, coupling agent --- 0.05%-0.25%, go Ionized water --- surplus;
First drive mechanism, there is provided the driving force that parking stall lock body is changed between lock-out state and released state, and the sun The driving force that energy absorbent assembly is changed between first position state and second place state;
Central controller, as the control centre of solar energy berth lock.
2. solar energy berth lock as claimed in claim 1, it is characterised in that:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 55%-65%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8%-10%;
The magnesium fluoride hydrosol --- 0.08%-0.11%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.12%-0.17%;
Absolute ethyl alcohol --- 0.07%-0.08%;
Nitric acid --- 0.07%-0.08%;
Ammonium nitrate --- 0.06%-0.08%;
Surfactant --- 0.08%-0.12%;
Coupling agent --- 0.15%-0.18%;
Deionized water --- surplus.
3. solar energy berth lock as claimed in claim 2, it is characterised in that:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol --- 58%;
Terbium doped 3.5% nano-TiO of fluorine tin2The hydrosol --- 8.5%;
The magnesium fluoride hydrosol --- 0.10%;
The hydrosol of antimony-doped stannic oxide 5% --- 0.15%;
Absolute ethyl alcohol --- 0.075%;
Nitric acid --- 0.075%;
Ammonium nitrate --- 0.07%;
Surfactant --- 0.10%;
Coupling agent --- 0.17%;
Deionized water --- surplus.
4. the solar energy berth lock as described in claim 1 or 2 or 3, it is characterised in that:
Ga3+With rare earth Tb3+The Nano-meter SiO_2 of codope24.5% hydrosol average grain diameter 15nm;
Terbium doped 3.5% nano-TiO of fluorine tin2The average grain diameter 20nm of the hydrosol;
The average grain diameter 30nm of the magnesium fluoride hydrosol;
Tin antimony mol ratio is 9 in antimony-doped stannic oxide:1.
5. solar energy berth lock as claimed in claim 1, it is characterised in that:First drive mechanism can independent control including multiple The retractable support mechanism of height, multiple retractable support mechanisms are laid in the periphery of solar absorption component, and respective height with The change of the irradiating angle of sunshine in one day and change so that solar absorption component it is nearest from the sun side height most It is low, to absorb more solar energy, improve efficiency.
6. solar energy berth lock as claimed in claim 1, it is characterised in that also include:
Cleaning assemblies, located at solar absorption component, the self-cleaning film layer to solar absorption component is cleaned;
Second drive mechanism, there is provided cleaning assemblies performs the driving force of cleaning.
7. solar energy berth lock as claimed in claim 6, it is characterised in that:
Cleaning assemblies includes the scraper plate of the self-cleaning film layer for fitting in solar absorption component or cleans arm, and cleaning assemblies utilizes scraper plate Or scouring arm is cleaned to solar absorption component, the cleaning action that scraper plate or scouring arm are performed includes swing, movement or rotation Turn.
8. solar energy berth lock as claimed in claim 7, it is characterised in that:
The rotation while cleaning action that scraper plate or scouring arm are performed is also including rotation action, i.e. swing, mobile or rotation.
9. solar energy berth lock as claimed in claim 7, it is characterised in that:Scraper plate or when cleaning arm rotation with it is to be cleaned from The direction of motion of clean film layer tangency location is in opposite direction with movement.
CN201611108206.1A 2016-12-06 2016-12-06 A kind of solar energy berth lock with self-cleaning film layer Active CN106758942B (en)

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