CN106758546A - A kind of composite wall paper easy to clean and preparation method thereof - Google Patents
A kind of composite wall paper easy to clean and preparation method thereof Download PDFInfo
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- CN106758546A CN106758546A CN201611103542.7A CN201611103542A CN106758546A CN 106758546 A CN106758546 A CN 106758546A CN 201611103542 A CN201611103542 A CN 201611103542A CN 106758546 A CN106758546 A CN 106758546A
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- top layer
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
The invention belongs to interior decoration technical field, and in particular to a kind of composite wall paper easy to clean and preparation method thereof, it is followed successively by top layer by bottom：Bottom, printing layer and top layer, wherein top layer are made up of the raw material of following weight portion：PVC, molecular weight are 2200 chitooligosaccharide-, palladium nano-particles/graphene oxide nano composite material, Anshan iron and steel plant atomized iron powder, ZPT, the difluoro-benzoic acid of 2 chlorine 4,5, heat stabilizer.The present invention has advantages below compared to existing technology：Addition in the present invention using the chitooligosaccharide- that molecular weight is 2200 improves the fungus resistance on top layer, it is polymerized using palladium nano-particles/graphene oxide nano composite material, Anshan iron and steel plant atomized iron powder and ZPT, improve the degree of polymerization on top layer, so as to improve the wearability and tensile strength on top layer, seepage of water is relatively low, can do, wet being wiped repeatedly does not result in metope damage or go mouldy, the spot easy cleaning on top layer is with strong applicability.
Description
Technical field
The invention belongs to interior decoration technical field, and in particular to a kind of composite wall paper easy to clean and preparation method thereof.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of widely used house decorative material.Because wallpaper have changing style,
Color is various, pattern is abundant, safety and environmental protection, easy construction, affordable, various other house decorative material institutes such as be easily changed
Incomparable the characteristics of, therefore obtain considerable degree of popularization in developed countries and regions such as America and Europe, Southeast Asia, Japan and Korea S.With me
The lifting of state's living standards of the people, wallpaper is extensively favored because of its color and the diversity of style by consumer, especially obtains
The high praise of more and more young men for pursuing individual characteies；It is ripe day by day with China's wallpaper industry, and people's safety and environmental protection
The reinforcement of consciousness, while people's concern wallpaper color is with style varied, focuses more on practicality and safety and environmental protection of product etc.
Performance.With scratch-resistant, easy to clean, ageing-resistant, high temperature resistant, fire prevention, waterproof, the novel wall paper except the function such as formaldehyde, deodorant, open
Beginning sells well market, and Related product is mainly coated with by wallpaper layer top layer, bonding, hot melt or be combined one or more layers function and apply
Layer reaches the functions such as corresponding fire-retardant, easy cleaning, insulation, scratch-resistant, waterproof, therefore should be correspondingly improved.
The content of the invention
The purpose of the present invention is directed to existing problem, there is provided a kind of composite wall paper easy to clean and preparation method thereof.
The present invention is achieved by the following technical solutions：A kind of composite wall paper easy to clean, by bottom to top layer successively
For：Bottom, printing layer and top layer, wherein top layer are made up of the raw material of following weight portion：PVC1000 parts, molecular weight be 2200
Chitooligosaccharide- 8-12 parts, palladium nano-particles/4-7 parts of graphene oxide nano composite material, 1-3 parts of Anshan iron and steel plant atomized iron powder, pyrrole
0.1-0.2 parts, heat stabilizer 0.4-0.6 parts of 0.2-0.4 parts of sulphur zinc, 2- chloro- 4,5- difluoro-benzoic acids；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
The mass concentration of 6-8% is the palladium dichloride solution of 0.02mol/L, then with the sodium hydroxide solution that mass concentration is 1mol/L
Regulation pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 55-60 DEG C,
Stirring 8-10 hours, filters after reaction, with deionized water rinsing 5-8 minutes, is vacuum dried 12 hours at 75 DEG C, obtains final product.
Used as further improvement of these options, the heat stabilizer is fatty acid heat stabilizer, organic tin heat
Any one in stabilizer or composite type heat stabilizer.
Used as further improvement of these options, the bottom is wood pulp paper or non-woven paper.
A kind of preparation method of composite wall paper easy to clean, comprises the following steps：
（1）Surplus stock is added in PVC slurries, is stirred continuously in adition process, continue to stir 5- after all adding
10 minutes, obtain mixed slurry standby；
（2）Printing layer is printed on bottom, then by step（1）In be obtained mixed slurry be uniformly coated on printing layer top,
Coating weight is 400-450g/ ㎡；
（3）Drying is heated after the completion of coating, drying temperature is 120-140 DEG C, and drying time is 60-80 seconds.
The present invention has advantages below compared to existing technology：Adding using the chitooligosaccharide- that molecular weight is 2200 in the present invention
Plus the fungus resistance on raising top layer, using palladium nano-particles/graphene oxide nano composite material, Anshan iron and steel plant atomized iron powder and pyrrole sulphur
Zinc is polymerized, and improves the degree of polymerization on top layer, so as to improve the wearability and tensile strength on top layer, seepage of water is relatively low, Ke Yigan, wet
It is wiped repeatedly and does not result in metope damage or go mouldy, the spot easy cleaning on top layer is with strong applicability.
Specific embodiment
Embodiment 1
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, 8 parts of chitooligosaccharide-, the palladium nano-particles/graphene oxide that molecular weight is 2200
It is 7 parts of nano composite material, 1 part of Anshan iron and steel plant atomized iron powder, 0.2 part of ZPT, 0.2 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, thermally-stabilised
0.4 part of agent；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
6% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 60 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 8 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Wherein, the heat stabilizer is fatty acid heat stabilizer, organic tin heat stabilizer or composite type heat stabilizer
In any one；The bottom is wood pulp paper or non-woven paper.
A kind of preparation method of composite wall paper easy to clean, comprises the following steps：
（1）Surplus stock is added in PVC slurries, is stirred continuously in adition process, continue to stir 5- after all adding
10 minutes, obtain mixed slurry standby；
（2）Printing layer is printed on bottom, then by step（1）In be obtained mixed slurry be uniformly coated on printing layer top,
Coating weight is 400-450g/ ㎡；
（3）Drying is heated after the completion of coating, drying temperature is 120-140 DEG C, and drying time is 60-80 seconds.
Embodiment 2
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, 12 parts of chitooligosaccharide-, the palladium nano-particles/graphene oxide that molecular weight is 2200
It is 4 parts of nano composite material, 3 parts of Anshan iron and steel plant atomized iron powder, 0.2 part of ZPT, 0.1 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, thermally-stabilised
0.6 part of agent；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
7% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 55 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 5 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Its preparation method is in the same manner as in Example 1.
Embodiment 3
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, 10 parts of chitooligosaccharide-, the palladium nano-particles/graphene oxide that molecular weight is 2200
It is 6 parts of nano composite material, 2 parts of Anshan iron and steel plant atomized iron powder, 0.3 part of ZPT, 0.2 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, thermally-stabilised
0.5 part of agent；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
5% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 55 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 7 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Its preparation method is in the same manner as in Example 1.
Embodiment 4
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, palladium nano-particles/7 parts of graphene oxide nano composite material, Anshan iron and steel plant atomization iron
1 part of powder, 0.2 part of ZPT, 0.2 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, 0.4 part of heat stabilizer；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
6% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 60 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 8 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Its preparation method is in the same manner as in Example 1.
Embodiment 5
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, 8 parts of the chitooligosaccharide- that molecular weight is 2200,7 parts of graphene oxide nano material,
1 part of Anshan iron and steel plant atomized iron powder, 0.2 part of ZPT, 0.2 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, 0.4 part of heat stabilizer；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
6% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 60 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 8 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Its preparation method is in the same manner as in Example 1.
Embodiment 6
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, 8 parts of chitooligosaccharide-, the palladium nano-particles/graphene oxide that molecular weight is 2200
7 parts of nano composite material, 0.2 part of ZPT, 0.2 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, 0.4 part of heat stabilizer；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
6% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 60 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 8 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Its preparation method is in the same manner as in Example 1.
Embodiment 7
A kind of composite wall paper easy to clean, is followed successively by by bottom to top layer：Bottom, printing layer and top layer, wherein top layer is by following
The raw material of weight portion is made：PVC1000 parts, 8 parts of chitooligosaccharide-, the palladium nano-particles/graphene oxide that molecular weight is 2200
7 parts of nano composite material, 1 part of Anshan iron and steel plant atomized iron powder, 0.2 part of chloro- 4, the 5- difluoro-benzoic acids of 2-, 0.4 part of heat stabilizer；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
6% mass concentration is the palladium dichloride solution of 0.02mol/L, is then adjusted with the sodium hydroxide solution that mass concentration is 1mol/L
Section pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 60 DEG C, stirs 8-
10 hours, filtered after reaction, with deionized water rinsing 8 minutes, be vacuum dried 12 hours at 75 DEG C, obtained final product.
Its preparation method is in the same manner as in Example 1.
In order to verify effect in the present invention, the wallpaper performance to the various embodiments described above is detected, obtains following result：
Table 1
Data can be seen that the wallpaper that prepared by method in the present invention and can not resulted in through repeatedly scouring, easy cleaning from table 1
Wallpaper is damaged, and makes wallpaper easy to maintain in use, strong applicability.
Claims (4)
1. a kind of composite wall paper easy to clean, it is characterised in that be followed successively by top layer by bottom：Bottom, printing layer and top layer, its
Middle top layer is made up of the raw material of following weight portion：PVC1000 parts, 8-12 parts of the chitooligosaccharide- that molecular weight is 2200, palladium nanometer
4-7 parts of grain/graphene oxide nano composite material, 1-3 parts of Anshan iron and steel plant atomized iron powder, ZPT 0.2-0.4 parts, 2- chloro- 4,
0.1-0.2 parts, heat stabilizer 0.4-0.6 parts of 5- difluoro-benzoic acids；
Wherein, the preparation method of palladium nano-particles/graphene oxide nano composite material is：Graphene oxide is distributed to
In equivalent to its 5 times of water of weight, ultrasonically treated 2 hours, it is added dropwise under agitation equivalent to graphene oxide weight
The mass concentration of 6-8% is the palladium dichloride solution of 0.02mol/L, then with the sodium hydroxide solution that mass concentration is 1mol/L
Regulation pH value is subsequently adding the sodium borohydride equivalent to 20 times of graphene oxide weight to 10, under conditions of 55-60 DEG C,
Stirring 8-10 hours, filters after reaction, with deionized water rinsing 5-8 minutes, is vacuum dried 12 hours at 75 DEG C, obtains final product.
2. as claimed in claim 1 a kind of composite wall paper easy to clean, it is characterised in that the heat stabilizer be fatty acid heat
Any one in stabilizer, organic tin heat stabilizer or composite type heat stabilizer.
3. as claimed in claim 1 a kind of composite wall paper easy to clean, it is characterised in that the bottom be wood pulp paper or nonwoven
Paper.
4. a kind of preparation method of composite wall paper easy to clean as claimed in claim 1, it is characterised in that comprise the following steps：
（1）Surplus stock is added in PVC slurries, is stirred continuously in adition process, continue to stir 5- after all adding
10 minutes, obtain mixed slurry standby；
（2）Printing layer is printed on bottom, then by step（1）In be obtained mixed slurry be uniformly coated on printing layer top,
Coating weight is 400-450g/ ㎡；
（3）Drying is heated after the completion of coating, drying temperature is 120-140 DEG C, and drying time is 60-80 seconds.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611103542.7A CN106758546B (en) | 2016-12-05 | 2016-12-05 | A kind of composite wall paper easy to clean and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611103542.7A CN106758546B (en) | 2016-12-05 | 2016-12-05 | A kind of composite wall paper easy to clean and preparation method thereof |
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| CN106758546A true CN106758546A (en) | 2017-05-31 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109208388A (en) * | 2017-07-03 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of oil-stain-preventing wallpaper |
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| CN103161277A (en) * | 2013-03-25 | 2013-06-19 | 南通亿华塑胶有限公司 | High-strength environment-friendly decorative wall cloth and application thereof |
| CN105464326A (en) * | 2014-08-19 | 2016-04-06 | 青岛炜烨锻压机械有限公司 | High-strength environment-friendly decorative wall cloth and application thereof |
| CN104213473A (en) * | 2014-09-05 | 2014-12-17 | 浙江华川实业集团有限公司 | Mildew-proof antibacterial food packaging paper and preparation method thereof |
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| CN109208388A (en) * | 2017-07-03 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of oil-stain-preventing wallpaper |
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| CN106758546B (en) | 2019-02-15 |
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