CN106758403B - Dacron environment-friendly type discharge printing discharge slurry and its discharge printing process - Google Patents
Dacron environment-friendly type discharge printing discharge slurry and its discharge printing process Download PDFInfo
- Publication number
- CN106758403B CN106758403B CN201611180894.2A CN201611180894A CN106758403B CN 106758403 B CN106758403 B CN 106758403B CN 201611180894 A CN201611180894 A CN 201611180894A CN 106758403 B CN106758403 B CN 106758403B
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- slurry
- discharge
- resistance
- discharge printing
- environment
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- 239000002002 slurry Substances 0.000 title claims abstract description 81
- 238000010018 discharge printing Methods 0.000 title claims abstract description 75
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 48
- 229920004934 Dacron® Polymers 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 23
- 230000008569 process Effects 0.000 title claims abstract description 12
- 230000002087 whitening effect Effects 0.000 claims abstract description 72
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 62
- 239000011248 coating agent Substances 0.000 claims abstract description 33
- 238000000576 coating method Methods 0.000 claims abstract description 33
- 238000007599 discharging Methods 0.000 claims abstract description 32
- 239000000986 disperse dye Substances 0.000 claims abstract description 32
- 239000000975 dye Substances 0.000 claims abstract description 27
- 239000004753 textile Substances 0.000 claims abstract description 23
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 claims abstract description 11
- 238000009736 wetting Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 230000000149 penetrating effect Effects 0.000 claims abstract description 6
- 238000007639 printing Methods 0.000 claims abstract description 6
- 239000000470 constituent Substances 0.000 claims abstract description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 30
- 229920000728 polyester Polymers 0.000 claims description 24
- 238000004043 dyeing Methods 0.000 claims description 22
- 230000009467 reduction Effects 0.000 claims description 19
- -1 benzimidazole ketone Chemical class 0.000 claims description 16
- 238000004140 cleaning Methods 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 16
- 239000004202 carbamide Substances 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 229920002472 Starch Polymers 0.000 claims description 11
- 235000019698 starch Nutrition 0.000 claims description 11
- 239000008107 starch Substances 0.000 claims description 11
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical group CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 230000008719 thickening Effects 0.000 claims description 9
- 238000005516 engineering process Methods 0.000 claims description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 6
- 150000004056 anthraquinones Chemical class 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 235000010413 sodium alginate Nutrition 0.000 claims description 6
- 239000000661 sodium alginate Substances 0.000 claims description 6
- 229940005550 sodium alginate Drugs 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- RQGPLDBZHMVWCH-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole Chemical compound C1=NC2=CC=NC2=C1 RQGPLDBZHMVWCH-UHFFFAOYSA-N 0.000 claims description 4
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical class C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- ZLCUIOWQYBYEBG-UHFFFAOYSA-N 1-Amino-2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=C(N)C(C)=CC=C3C(=O)C2=C1 ZLCUIOWQYBYEBG-UHFFFAOYSA-N 0.000 claims description 3
- MUERWWKQVXXPML-UHFFFAOYSA-N 3-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound ClC1=CC([N+](=O)[O-])=CC(Cl)=C1N=NC1=CC=C(N(CCC#N)CCC#N)C=C1 MUERWWKQVXXPML-UHFFFAOYSA-N 0.000 claims description 3
- ZSPPPAFDNHYXNW-UHFFFAOYSA-N 3-[n-ethyl-4-[(4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound C1=CC(N(CCC#N)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1 ZSPPPAFDNHYXNW-UHFFFAOYSA-N 0.000 claims description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000012860 organic pigment Substances 0.000 claims description 3
- 239000010979 ruby Substances 0.000 claims description 3
- 229910001750 ruby Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000009738 saturating Methods 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- BKMUDUXPSVRLFZ-UHFFFAOYSA-N 2-methyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecane Chemical compound C[SiH]1O[SiH2]O[SiH2]O[SiH2]O[SiH2]O1 BKMUDUXPSVRLFZ-UHFFFAOYSA-N 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 29
- 238000002360 preparation method Methods 0.000 description 25
- 229920004933 Terylene® Polymers 0.000 description 16
- 239000007787 solid Substances 0.000 description 12
- 239000000835 fiber Substances 0.000 description 11
- 239000000049 pigment Substances 0.000 description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N Methyl benzoate Natural products COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 2
- 229940095102 methyl benzoate Drugs 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000001119 stannous chloride Substances 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- ALXCWDABTQQKAH-UHFFFAOYSA-N 4-(1-amino-4-hydroxy-9,10-dioxoanthracen-2-yl)oxy-n-(3-ethoxypropyl)benzenesulfonamide Chemical compound C1=CC(S(=O)(=O)NCCCOCC)=CC=C1OC1=CC(O)=C(C(=O)C=2C(=CC=CC=2)C2=O)C2=C1N ALXCWDABTQQKAH-UHFFFAOYSA-N 0.000 description 1
- 241000551547 Dione <red algae> Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- AOPRFYAPABFRPU-UHFFFAOYSA-N amino(imino)methanesulfonic acid Chemical compound NC(=N)S(O)(=O)=O AOPRFYAPABFRPU-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940125717 barbiturate Drugs 0.000 description 1
- 238000002306 biochemical method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- XNEFVTBPCXGIRX-UHFFFAOYSA-N methanesulfinic acid Chemical compound CS(O)=O XNEFVTBPCXGIRX-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LKMPHZSEWBUEPW-UHFFFAOYSA-N sulfur dioxide;urea Chemical compound O=S=O.NC(N)=O LKMPHZSEWBUEPW-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- ZJHHPAUQMCHPRB-UHFFFAOYSA-N urea urea Chemical group NC(N)=O.NC(N)=O ZJHHPAUQMCHPRB-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- CAAIULQYGCAMCD-UHFFFAOYSA-L zinc;hydroxymethanesulfinate Chemical compound [Zn+2].OCS([O-])=O.OCS([O-])=O CAAIULQYGCAMCD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/20—Anthraquinone dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/155—Locally discharging the dyes with reductants
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention relates to printing in textiles field, in particular to a kind of dacron environment-friendly type discharge printing discharge slurry and its discharge printing process.A kind of dacron environment-friendly type discharge printing discharge slurry, it includes that discharge printing whitening pulp and discharge printing color pull out slurry, the discharge printing whitening pulp is by 10 ~ 30 parts by weight Environment-friendlypaste paste discharging agents, resistance to pull out of 30 ~ 60 parts by weight thickens slurry, and the rush of the wetting and penetrating agent of 5 ~ 15 parts by weight and 10 ~ 30 parts by weight pulls out agent composition；The discharge printing color pulls out slurry and is made of one of whitening pulp and following two groups, and one of two groups of constituent content is in terms of 100% by whitening pulp parts by weight: 1. 1 ~ 5% it is resistance to pull out disperse dyes, or 2. 1 ~ 5% resistance to low-temperature-based adhesive for pulling out coating and 6 ~ 20%；It is described resistance to pull out disperse dyes and resistance to pull out coating respectively be the dyestuff and coating that colour killing is restored by thiourea dioxide.
Description
Technical field
The present invention relates to printing in textiles field, in particular to a kind of dacron environment-friendly type discharge printing discharge slurry and its
Discharge printing process.
Background technique
Discharge printing has unique advantage, product shelves in design pattern fineness, color contrast, vividness etc.
Secondary and added value is high.Synthetic fibers especially polyester fiber naturally changes direction in synthetic fibers such as Silk, imitative hair, imitative fiber crops in recent years
It quickly grows, the dacron discharge printing product market demand is promoted to increase.And traditional terylene discharge printing discharging agent is moral
Gu, all there is environmental issue in woods (zinc formaldehyde sulfoxylate), stannous chloride and processing tin etc..Moral consolidates woods and belongs to formaldehyde conjunction time sulphur
Barbiturates, stability is poor, and can release free formaldehyde in use, causes damages to human health and ecological environment；
And stannous chloride contains heavy metal ion, the HCl for decomposing generation can corrode equipment, easy yellowing at dawn；Modified processing tin
Though reducing the corrosion to equipment, heavy metallic salt pollution problem is still remained, therefore urgently seeks a kind of environment-friendly type terylene and pulls out
Dye transfer flower discharging agent and its application technology.
Thiourea dioxide (Thiourea Dioxide, (NH2)2CSO2), will be slow in aqueous solution tautomerize to it is unstable
Methyl sulfinate, alkalinity or heating state under can decompose, release reproducibility strong sulphoxylic acid and urea, neither can
Increase chemical oxygen consumption (COC) (COD) and BOD (BOD), it is environment-friendly type that wherein urea, which is relatively beneficial to biochemical method processing sewage,
Reducing agent, patent CN 102704292 B, 2013.10.30 and US 9375687 B2,2016.6.28 have been invented sulfur dioxide
Urea, decamethylcyclopentaandoxane, surfactant and glycerol grinding are prepared into a kind of Environment-friendlypaste paste discharging agent, can solve two
Aminoiminomethanesulfonic acid discharge slurry in dispersing uniformity, saturating net and in terms of the problem of, the discharge slurry is suitable for
Cotton and real silk fabric discharge printing.Since dacron is typical hydrophobic fibre, fibre structure is close, and crystallinity is high, and
Hygroscopicity is small (under standard state, the official regain of cotton is 8%, silk 11%, terylene 0.4%), in discharge steaming procedure, washs
The swelling of synthetic fibre fiber is small, and discharging agent and the diffusion of ground colour disperse dyes are difficult, and discharge difficulty is big, above-mentioned based on thiourea dioxide
Effect of the Environment-friendlypaste paste discharging agent for dacron discharge printing is often difficult to reach requirement, therefore seeks suitable terylene
Fabric environment-friendly type discharge printing discharge slurry and its discharge printing process technology become inevitable.
Summary of the invention
In order to solve the above technical problems, the purpose of the present invention is to provide a kind of dacron environment-friendly type discharge printing discharges
Slurry.
The present invention also provides a kind of starched with the dacron environment-friendly type discharge printing discharge to carry out on dacron
Discharge printing process.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of dacron environment-friendly type discharge printing discharge slurry comprising discharge printing whitening pulp and discharge printing color pull out
Slurry, the discharge printing whitening pulp is by 10~30 parts by weight Environment-friendlypaste paste discharging agents, and the resistance to of 30~60 parts by weight pulls out increasing
The rush of thick slurry, the wetting and penetrating agent of 5~15 parts by weight and 10~30 parts by weight pulls out agent composition；The discharge printing color, which pulls out slurry, is
It is made of one of whitening pulp and following two groups, one of two groups of constituent content is in terms of 100% by whitening pulp parts by weight: 1. 1~
5% resistance to pulls out disperse dyes, or 2. 1~5% resistance to low-temperature-based adhesive for pulling out coating and 6~20%；It is described resistance to pull out point
It dissipates dyestuff and resistance to pulls out coating respectively and be the dyestuff and coating that cannot be restored colour killing by thiourea dioxide.It is of the present invention resistance to pull out point
Scattered dyestuff is the disperse dyes of non-azo structure, is mostly ahthraquinone disperse dye.
Preferably, the Environment-friendlypaste paste discharging agent is the Environment-friendlypaste paste discharge based on thiourea dioxide
Agent, the composition of the discharging agent is by weight are as follows: and 30~60 parts of decamethylcyclopentaandoxane, 40~70 parts of thiourea dioxide, surface
1~3 part of activating agent, 3~6 parts of glycerol.Printing in textiles in specially 102704292 B of Institutes Of Technology Of Zhejiang's patent CN is used
Environment-friendlypaste paste discharging agent.
Preferably, when discharge printing color pull out one of component of slurry be it is resistance to pull out disperse dyes when, it is described resistance to pull out thickening slurry
Be plant seed glue, sodium alginate or it is other can be compatible with discharging agent and disperse dyes thickening slurry in any one or
Any parts by weight mixing；When discharge printing color pull out one of component of slurry be it is resistance to pull out coating when, it is described it is resistance to pull out thickening slurry be it is resistance to also
The synthesis of originality thickens slurry, such as: one or more of PT-RV, TF-312C and PFL.
Preferably, the wetting and penetrating agent is urea.Urea facilitates fiber and mill base film moisture absorption when decatize, promotes
Discharging agent is spread to fibrous inside.Preferably, it is to have extruding plasticization and will not to dacron that the rush, which pulls out agent,
The small molecule compound destroyed by discharging agent, general structure are:
Wherein R1 is CnH2n+1,One of；R2、R3、R4Respectively H, CnH2n+1, OH, OR,One of, R2、R3、R4It can be identical or not identical.Due to small molecule ester in steaming environment
Class compound and terylene (polyethylene terephthalate) fiber macromolecular have the adaptability in structure, can be with small molecule
The molecular separating force formed between ester and polyester fiber (polyester fiber) macromolecular ester replaces the active force between few fibers macromolecular,
To promote the extruding of fiber macromolecular, be conducive to the diffusion and collision of discharge agent molecule and dye molecule, and then be conducive to phase
It mutually has an effect, so that the reduction colour killing of ground colour disperse dyes.
A kind of the step of method of the slurry of dacron environment-friendly type discharge printing discharge described in manufacture, this method, is as follows:
1) it according to raw material proportioning, Environment-friendlypaste paste discharging agent, wetting and penetrating agent and rush is added in thickening slurry pulls out agent in resistance to pull out,
The discharge printing whitening pulp is made after mixing；
2) according to raw material proportioning, be added in the discharge printing whitening pulp it is resistance to pull out disperse dyes, be made and pull out after mixing
Dye thickening agent color pulls out slurry；Alternatively, be added in the discharge printing whitening pulp it is resistance to pull out coating and low-temperature-based adhesive, mixing
Discharge printing coating color is made afterwards and pulls out slurry；
3) discharge printing whitening pulp, discharge printing dyes color are pulled out into slurry and discharge printing coating color pulls out slurry and is placed in 3~35 DEG C
In the environment of it is spare, as far as possible on the day of in use, in order to avoid reducing agent lose.
It is a kind of to starch the discharge printing work carried out on dacron with the dacron environment-friendly type discharge printing discharge
Skill, the technique include two ground colour dyeing, discharge printing processes, which includes the following steps:
1. ground colour dyes: using the azo type disperse dyes that can be pulled out, dyeing temperature and time are compared with conventional polyester dyeing
It is relatively low and partially short, i.e., 105~125 DEG C at a temperature of dye 15~60min；
2. discharge printing: slurry, which is pulled out, with discharge printing whitening pulp and discharge printing color respectively prints on dyed polyester textiles,
It after discharge printing, is dried at a temperature of 40~60 DEG C, in 100~135 DEG C of saturation 5~30min of decatize or 120~180 DEG C of mistakes
5~30min of decatize in hot steam；；Room temperature washing, 40~50 DEG C of hot water wash, reduction cleaning are washed, drying.
Preferably, reduction cleaning process conditions are as follows: the Na of the NaOH and 1~3g/L of 1~3g/L2S2O450 in water-bath~
5~10min is handled under the conditions of 80 DEG C.
Preferably, it is described pull out azo type disperse dyes be selected from disperse red BS, the dark red GS of dispersion, disperse orange S-ER,
Purse red disperse dye SE-GFL；Dispersed ruby S-5BL, the deep blue HGL of dispersion, disperse blue SE-2R, disperse blue XF；Disperse brown 19, disperse yellow
163, Red-1 200 45, disperse orange 25, or other azo structure disperse dyes of colour killing can be restored by thiourea dioxide.
Preferably, it is described it is resistance to pull out the disperse dyes that disperse dyes are non-azo structures, be mostly anthraquinone type dispersion dye
One of material is a variety of；The resistance to coating that pulls out is Anthraquinones, benzimidazole ketone, quinophthalone class, isoindolinone, pyrrolopyrrole
One of organic pigment of the resistance to reducing agent such as diones and quinacridine ketone is a variety of.
The beneficial effects of the present invention are:
1) terylene environment protection type discharge printing slurry provided by the invention is used for dacron discharge printing, can solve existing discharge
Agent discharges the pollution problem of free formaldehyde or heavy metal ion in the production and use process；
2) formula that dacron environment-friendly type discharge printing whitening pulp and color provided by the present invention pull out slurry is reasonable, preparation letter
Just, low in cost, storage and it is easy to use；
3) the dacron discharge printing work provided by the present invention carried out using dacron environment-friendly type discharge printing slurry
Skill is simple and reliable, and dacron can be made to have the advantages that good dawn effect, the lovely luster that color pulls out, good color fastness.
Specific embodiment
Below by specific embodiment, technical scheme of the present invention will be further explained in detail.It should be appreciated that this hair
Bright implementation is not limited by the following examples, and the accommodation in any form made to the present invention and/or changed will all be fallen
Enter the scope of the present invention.
In the present invention, if not refering in particular to, all parts, percentage are unit of weight, used equipment and raw material etc.
It is commercially available or commonly used in the art.Method in following embodiments is unless otherwise instructed the normal of this field
Rule method.
In the present invention whitening pulp and color pull out each component parts by weight in slurry number it is quasi- bright-colored according to stamp flower-shape, pattern
Degree and color fastness, contour sharpness requirement and the thickness of dacron etc. are chosen.Ground colour dyestuff of the invention is azo
Type disperse dyes, disperse red BS, the dark red GS of dispersion, disperse orange S-ER, dispersion including Jiangsu Yabang Dyestuffs Co., Ltd.
Rubine SE-GFL；Zhejiang Wanfeng Chemical Co., Ltd. dispersed ruby S-5BL, the deep blue HGL of dispersion, disperse blue SE-2R, disperse blue
XF；Disperse brown 19, disperse yellow 163, Red-1 200 45, disperse orange 25 or the other companies of Zhejiang Province Longsheng Group Co., Ltd
The azo structure disperse dyes that colour killing can be restored by thiourea dioxide of production.The preferred ground colour dyestuff of institute rub resistance, washing,
Light fastness and dawn degree etc. will be better than other dyestuffs, be suitable for dacron discharge printing.
Resistance in the present invention pulls out the disperse dyes that disperse dyes are non-azo structures, is mostly in ahthraquinone disperse dye
It is one or more, including anthraquinone kind disperse red 92, Disperse Blue-56, disperse violet 46 and phthalic anhydride series dispersion yellow 64
Deng；The resistance to coating that pulls out is Anthraquinones, benzimidazole ketone, quinophthalone class, isoindolinone, dione pyrrolo-pyrrole and quinoline a word used for translation
One of organic pigment of the resistance to reducing agent such as pyridine ketone is a variety of, including Anthraquinones pigment blue 60, benzimidazole ketone pigment
Red 185, quinophthalone class pigment yellow 13 8, isoindoline ketone pigment yellow 110, dione pyrrolo-pyrrole pigment orange 73 and quinoline
Acridine ketone pigment red 122 etc..
Embodiment 1:
(1) fabric prepares: with the disperse blue XF dyed polyester textiles of Zhejiang Wanfeng Chemical Co., Ltd. of 1% (owf),
Dyeing condition: 105 DEG C, 60min；
(2) preparation of whitening pulp: the Ciba Co., Ltd that 60g solid content is 3% is added in 200mL beaker and produces
It is resistance to pull out synthetic thickening agent PT-RV, add Environment-friendlypaste paste discharging agent (Institutes Of Technology Of Zhejiang's patented product) 10g, urea 5g,
Rush pulls out agent butyl hydroxybenzoate 20g, stirs evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp, 1g are added in 200mL beaker, and resistance to pull out coating pigment Huang 138 low with 6g
Warm type adhesive R838 is made coating color and pulls out slurry；
(4) slurry is pulled out with whitening pulp and color respectively to print on dyed polyester textiles, then dry at 40~60 DEG C；
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 120 DEG C of temperature of superheated steam decatize 30min；
(6) washing, reduction cleaning: fabric rinses (room temperature) through cold flow water after decatize, hot water wash (40~50 DEG C), and reduction is clear
Wash (the Na of the NaOH and 1~3g/L of 1~3g/L2S2O45~10min is handled in water-bath at 50~80 DEG C), it washes, drying.
Embodiment 2:
(1) fabric prepares: being knitted with the disperse blue SE-2R of 3% (owf) Jiangsu Yabang Dyestuffs Co., Ltd. dyeing terylene
Object, dyeing condition: 115 DEG C, 30min；
(2) preparation of whitening pulp: the Ciba Co., Ltd that 45g solid content is 3% is added in 200mL beaker and produces
It is resistance to pull out synthetic thickening agent PT-RV, add above-mentioned Environment-friendlypaste paste discharging agent 30g, urea 15g, rush pulls out agent butyl hydroxybenzoate
20g is stirred evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: being added that 100g whitening pulp, 5g is resistance to pulls out coating pigment red 185 and 20g in 200mL beaker
Low-temperature-based adhesive R838 is made coating color and pulls out slurry；
(4) slurry is pulled out with whitening pulp and color respectively to print on dyed polyester textiles, then dry at 40~60 DEG C.
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 180 DEG C of temperature of superheated steam decatize 5min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 3:
(1) fabric prepares: with the disperse blue XF dyed polyester textiles of 2% (owf) Zhejiang Wanfeng Chemical Co., Ltd., dyeing
Condition: 125 DEG C, 15min；
(2) preparation of whitening pulp: the resistance to of Ciba Co., Ltd production that 30g3% is added in 200mL beaker pulls out conjunction
At thickener PT-RV, above-mentioned Environment-friendlypaste paste discharging agent 20g, urea 12g are added, rush pulls out agent butyl hydroxybenzoate and to hydroxyl
Methyl benzoate is stirred evenly and whitening pulp is made with 1:1 compound 15g；
(3) color pulls out the preparation of slurry: being added that 100g whitening pulp, 3g is resistance to pulls out coating pigment red 122 and 12g in 200mL beaker
Low-temperature-based adhesive R838 is made coating color and pulls out slurry；
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 130 DEG C of temperature of superheated steam decatize 25min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 4:
(1) fabric prepares: with the disperse blue XF dyed polyester textiles of Zhejiang Wanfeng Chemical Co., Ltd. of 1% (owf),
Dyeing condition: 105 DEG C, 60min；
(2) preparation of whitening pulp: the Ciba Co., Ltd that 60g solid content is 3% is added in 200mL beaker and produces
It is resistance to pull out synthetic thickening agent PT-RV, add Environment-friendlypaste paste discharging agent (Institutes Of Technology Of Zhejiang's patented product) 10g, urea 5g,
Rush pulls out agent butyl hydroxybenzoate 20g, stirs evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp, 1g are added in 200mL beaker, and resistance to pull out coating pigment Huang 138 low with 6g
Warm type adhesive R838 is made coating color and pulls out slurry；
(4) slurry is pulled out with whitening pulp and color respectively to print on dyed polyester textiles, then dry at 40~60 DEG C；
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 130 DEG C of saturation decatize decatize 30min；
(6) washing, reduction cleaning: fabric rinses (room temperature) through cold flow water after decatize, hot water wash (40~50 DEG C), and reduction is clear
Wash (the Na of the NaOH and 1~3g/L of 1~3g/L2S2O45~10min is handled in water-bath at 50~80 DEG C), it washes, drying.
Embodiment 5:
(1) fabric prepares: being knitted with the disperse blue SE-2R of 3% (owf) Jiangsu Yabang Dyestuffs Co., Ltd. dyeing terylene
Object, dyeing condition: 115 DEG C, 30min；
(2) preparation of whitening pulp: the Ciba Co., Ltd that 45g solid content is 3% is added in 200mL beaker and produces
It is resistance to pull out synthetic thickening agent PT-RV, add above-mentioned Environment-friendlypaste paste discharging agent 30g, urea 15g, rush pulls out agent butyl hydroxybenzoate
20g is stirred evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: being added that 100g whitening pulp, 5g is resistance to pulls out coating pigment red 185 and 20g in 200mL beaker
Low-temperature-based adhesive R838 is made coating color and pulls out slurry；
(4) slurry is pulled out with whitening pulp and color respectively to print on dyed polyester textiles, then dry at 40~60 DEG C.
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 135 DEG C of temperature of saturation decatize decatize 20min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 6:
(1) fabric prepares: with the disperse blue XF dyed polyester textiles of 2% (owf) Zhejiang Wanfeng Chemical Co., Ltd., dyeing
Condition: 125 DEG C, 15min；
(2) preparation of whitening pulp: the resistance to of Ciba Co., Ltd production that 30g3% is added in 200mL beaker pulls out conjunction
At thickener PT-RV, above-mentioned Environment-friendlypaste paste discharging agent 20g, urea 12g are added, rush pulls out agent butyl hydroxybenzoate and to hydroxyl
Methyl benzoate is stirred evenly and whitening pulp is made with 1:1 compound 15g；
(3) color pulls out the preparation of slurry: being added that 100g whitening pulp, 3g is resistance to pulls out coating pigment red 122 and 12g in 200mL beaker
Low-temperature-based adhesive R838 is made coating color and pulls out slurry；
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 120 DEG C of temperature of saturation decatize decatize 25min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 7:
(1) fabric prepares: with the disperse red BS dyed polyester textiles of 1% (owf) Jiangsu Yabang Dyestuffs Co., Ltd.,
Dyeing condition: 110 DEG C, 40min；
(2) preparation of whitening pulp: the plant seed glue A-9 that 60g solid content is 9% is added in 200mL beaker, adds
Above-mentioned Environment-friendlypaste paste discharging agent 20g, urea 5g, rush pull out agent methyl p-hydroxybenzoate 20g, stir evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp is added in 200mL beaker and dyestuff color is made in the resistance to Disperse Blue-56 that pulls out of 1g
Pull out slurry；
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C；
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 145 DEG C of temperature of superheated steam decatize 10min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 8:
(1) fabric prepares: dyeing terylene with the Red-1 200 45 of 3% (owf) Zhejiang Province Longsheng Group Co., Ltd and knits
Object, dyeing condition: 115 DEG C, 40min；
(2) preparation of whitening pulp: the sodium alginate that 45g solid content is 8% is added in 200mL beaker, adds above-mentioned
Environment-friendlypaste paste discharging agent 30g, urea 15g, rush pull out agent butyl hydroxybenzoate 10g, stir evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp is added in 200mL beaker and dyestuff color is made in the resistance to disperse violet 46 of pulling out of 5g
Pull out slurry.
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 160 DEG C of temperature of superheated steam decatize 15min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 9:
(1) fabric prepares: being knitted with the deep blue HGL dyeing terylene of the dispersion of 2%.owf. Zhejiang Province Longsheng Group Co., Ltd
Object, dyeing condition: 120 DEG C, 30min；
(2) the plant seed glue A-9 and contain solid that 30g solid content is 9% preparation of whitening pulp: are added in 200mL beaker
The sodium alginate that rate is 8% adds above-mentioned Environment-friendlypaste paste discharging agent 20g, urea 12g with 1:1 compound size, and rush pulls out agent Buddhist nun
Golden butyl ester 30g is moored, stirs evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp is added in 200mL beaker and dyestuff color is made in the resistance to dispersion yellow 64 that pulls out of 3g
Pull out slurry；
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 170 DEG C of temperature of superheated steam decatize 20min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 10:
(1) fabric prepares: with the disperse red BS dyed polyester textiles of 1% (owf) Jiangsu Yabang Dyestuffs Co., Ltd.,
Dyeing condition: 110 DEG C, 40min；
(2) preparation of whitening pulp: the plant seed glue A-9 that 60g solid content is 9% is added in 200mL beaker, adds
Above-mentioned Environment-friendlypaste paste discharging agent 20g, urea 5g, rush pull out agent methyl p-hydroxybenzoate 20g, stir evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp is added in 200mL beaker and dyestuff color is made in the resistance to Disperse Blue-56 that pulls out of 1g
Pull out slurry；
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C；
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 100 DEG C of temperature of saturation decatize decatize 15min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 11:
(1) fabric prepares: dyeing terylene with the Red-1 200 45 of 3% (owf) Zhejiang Province Longsheng Group Co., Ltd and knits
Object, dyeing condition: 115 DEG C, 40min；
(2) preparation of whitening pulp: the sodium alginate that 45g solid content is 8% is added in 200mL beaker, adds above-mentioned
Environment-friendlypaste paste discharging agent 30g, urea 15g, rush pull out agent butyl hydroxybenzoate 10g, stir evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp is added in 200mL beaker and dyestuff color is made in the resistance to disperse violet 46 of pulling out of 5g
Pull out slurry.
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 135 DEG C of temperature of saturation decatize decatize 5min；
(6) washing, reduction cleaning and embodiment 1 are same.
Embodiment 12:
(1) fabric prepares: being knitted with the deep blue HGL dyeing terylene of the dispersion of 2%.owf. Zhejiang Province Longsheng Group Co., Ltd
Object, dyeing condition: 120 DEG C, 30min；
(2) the plant seed glue A-9 and contain solid that 30g solid content is 9% preparation of whitening pulp: are added in 200mL beaker
The sodium alginate that rate is 8% adds above-mentioned Environment-friendlypaste paste discharging agent 20g, urea 12g with 1:1 compound size, and rush pulls out agent Buddhist nun
Golden butyl ester 30g is moored, stirs evenly and whitening pulp is made；
(3) color pulls out the preparation of slurry: 100g whitening pulp is added in 200mL beaker and dyestuff color is made in the resistance to dispersion yellow 64 that pulls out of 3g
Pull out slurry；
(4) it pulls out to starch with whitening pulp and color respectively and prints on dyed polyester textiles and dried at 40~60 DEG C
(5) decatize: by above-mentioned PRINTED FABRIC under the conditions of 120 DEG C of temperature of saturation decatize decatize 10min；
(6) washing, reduction cleaning and embodiment 1 are same.
The resulting terylene environment protection type discharge printing discharge slurry of 1-12 of the embodiment of the present invention pulls out print in terylene white discharge and color
Spend middle implementation result as shown in table 1.
1 dacron discharge performance of table
It is verified by inventor's test of many times it is found that the terylene that terylene environment protection type discharge printing process of the invention is printed out
Fabric dawn excellent effect, coating color pull out that pull out pattern, ground colour with dyestuff color bright-coloured, and decorative pattern is exquisite, what the above various embodiments obtained
Product is tested according to AATCC61:2007, GB/T 3920-2008, GB/T 8427-2008, and by the results are shown in Table 1:
The discoloration of coating color fastness to washing is in 4 grades or more, staining fastness at 4~5 grades, and dry, fastness to wet rubbing is at 4 grades or more, light fastness 6
Grade or more；For the washable discoloration fastness of dyestuff in 4~5 grades or more, staining fastness at 4~5 grades or more, dry, fastness to wet rubbing reaches 5
Grade, 5~6 grades of light fastness or more.
Above-mentioned embodiment is only a preferred solution of the present invention, not the present invention is made in any form
Limitation, there are also other variations and modifications on the premise of not exceeding the technical scheme recorded in the claims.
Claims (8)
1. a kind of dacron environment-friendly type discharge printing discharge slurry, it is characterised in that it includes discharge printing whitening pulp and discharge print
Pattern pulls out slurry, the discharge printing whitening pulp be by 10 ~ 30 parts by weight Environment-friendlypaste paste discharging agents, 30 ~ 60 parts by weight it is resistance to
It pulls out thickening to starch, the rush of the wetting and penetrating agent of 5 ~ 15 parts by weight and 10 ~ 30 parts by weight pulls out agent composition；The discharge printing color pulls out slurry
It is made of one of whitening pulp and following two groups, one of two groups of constituent content is in terms of 100% by whitening pulp parts by weight: 1. 1 ~
5% resistance to pulls out disperse dyes, or 2. 1 ~ 5% resistance to low-temperature-based adhesive for pulling out coating and 6 ~ 20%；It is described resistance to pull out disperse dyes
With it is resistance to pull out coating respectively and be the dyestuff and coating of colour killing cannot be restored by thiourea dioxide；
When discharge printing color pull out one of component of slurry be it is resistance to pull out disperse dyes when, it is described it is resistance to pull out thickening slurry be plant seed glue,
Any one or any parts by weight in sodium alginate or other thickening slurries that can be compatible with discharging agent and disperse dyes are mixed
It closes；When discharge printing color pull out one of component of slurry be it is resistance to pull out coating when, it is described resistance to pull out the synthesis that thickening slurry is reducing resistance and increase
Thick slurry；
It is butyl hydroxybenzoate and/or methyl hydroxybenzoate that the rush, which pulls out agent,.
2. dacron environment-friendly type discharge printing discharge slurry according to claim 1, it is characterised in that: the environment-friendly type
Paste discharging agent is the Environment-friendlypaste paste discharging agent based on thiourea dioxide, and the composition of the discharging agent is by weight are as follows: ten
30 ~ 60 parts of methyl cyclopentasiloxane, 40 ~ 70 parts of thiourea dioxide, 1 ~ 3 part of surfactant, 3 ~ 6 parts of glycerol.
3. dacron environment-friendly type discharge printing discharge slurry according to claim 1, it is characterised in that: the wetting is seeped
Saturating agent is urea.
4. dacron environment-friendly type discharge printing discharge according to claim 1 slurry, it is characterised in that: described resistance to pull out point
Scattered dyestuff is the disperse dyes of non-azo structure, is mostly one of ahthraquinone disperse dye or a variety of；It is described resistance to pull out painting
Material is Anthraquinones, benzimidazole ketone, quinophthalone class, isoindoline ketone, dione pyrrolo-pyrrole and quinacridine ketone
One of organic pigment etc. resistance to reducing agent is a variety of.
5. a kind of method of the slurry of dacron environment-friendly type discharge printing discharge described in manufacturing claims 1, it is characterised in that should
The step of method, is as follows:
1) it according to raw material proportioning, Environment-friendlypaste paste discharging agent, wetting and penetrating agent and rush is added in thickening slurry pulls out agent in resistance to pull out, mix
The discharge printing whitening pulp is made afterwards；
2) according to raw material proportioning, be added in the discharge printing whitening pulp it is resistance to pull out disperse dyes, discharge print is made after mixing
Flower dyestuff color pulls out slurry；Or be added in the discharge printing whitening pulp it is resistance to pull out coating and low-temperature-based adhesive, made after mixing
It obtains discharge printing coating color and pulls out slurry；
3) discharge printing whitening pulp, discharge printing dyes color are pulled out into slurry and discharge printing coating color pulls out the environment that slurry is placed in 3 ~ 35 DEG C
Under it is spare.
6. a kind of starch the discharge carried out on dacron with dacron environment-friendly type discharge printing discharge described in claim 1
Printing technology, the technique include two ground colour dyeing, discharge printing processes, it is characterised in that the technique includes the following steps:
1. ground colour dyes: using azo type disperse dyes can be pulled out, 105 ~ 125 DEG C at a temperature of dye 15 ~ 60min；
2. discharge printing: slurry, which is pulled out, with discharge printing whitening pulp and discharge printing color respectively prints on dyed polyester textiles, discharge
It after stamp, is dried at a temperature of 40 ~ 60 DEG C, in 100 ~ 135 DEG C of saturation 5 ~ 30min of decatize or 120 ~ 180 DEG C of superheated steams
5 ~ 30min of decatize；Room temperature washing, 40 ~ 50 DEG C of hot water wash, reduction cleaning are washed, drying.
7. printing technology according to claim 6, it is characterised in that: reduction cleaning process conditions are as follows: the NaOH of 1 ~ 3g/L
With the Na of 1 ~ 3g/L2S2O45 ~ 10min is handled in water-bath under the conditions of 50 ~ 80 DEG C.
8. printing technology according to claim 6, it is characterised in that: the azo type disperse dyes that pull out are selected from dispersion
Red BS, the dark red GS of dispersion, disperse orange S-ER, purse red disperse dye SE-GFL；Dispersed ruby S-5BL, the deep blue HGL of dispersion, disperse blue SE-
2R, disperse blue XF；Disperse brown 19, disperse yellow 163, Red-1 200 45, disperse orange 25 or other can be restored by thiourea dioxide disappear
The azo structure disperse dyes of color.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611180894.2A CN106758403B (en) | 2016-12-20 | 2016-12-20 | Dacron environment-friendly type discharge printing discharge slurry and its discharge printing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611180894.2A CN106758403B (en) | 2016-12-20 | 2016-12-20 | Dacron environment-friendly type discharge printing discharge slurry and its discharge printing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106758403A CN106758403A (en) | 2017-05-31 |
| CN106758403B true CN106758403B (en) | 2019-05-31 |
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| CN107190535A (en) * | 2017-07-17 | 2017-09-22 | 绍兴市高峰印染有限公司 | One kind applies carving slurry and short route applies carver's skill |
| CN109338747B (en) * | 2018-09-28 | 2020-09-04 | 河南工程学院 | Dyeing method for reducing dye thiourea dioxide at low temperature |
| CN114164685A (en) * | 2021-12-23 | 2022-03-11 | 绍兴柯桥道合纺织有限公司 | Steaming-boiling-free washing cotton-linen fabric color stripping process |
| CN114606785A (en) * | 2022-03-25 | 2022-06-10 | 河北瑞格纺织有限公司 | Washing-free formaldehyde-free discharge printing process |
| CN115928465A (en) * | 2022-11-16 | 2023-04-07 | 广州市盛勤实业有限公司 | Light color printing process of dark color dyed chemical fiber fabric |
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| CN101408003A (en) * | 2008-11-20 | 2009-04-15 | 浙江理工大学 | Environment protection type coating discharge printing pulp and discharge printing process thereof |
| CN101429730A (en) * | 2008-12-04 | 2009-05-13 | 浙江理工大学 | Silk broadcloth non-methanal discharge printing discharge paste and its discharge printing technique |
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| CN101886346A (en) * | 2010-07-14 | 2010-11-17 | 常熟理工学院 | Assistant for resist-discharge printing of silk-like terylen fabric and preparation method thereof |
| CN102704292A (en) * | 2012-05-25 | 2012-10-03 | 浙江理工大学 | Environment-friendly paste discharge agent for textile printing and preparation method thereof |
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| CN101654876A (en) * | 2008-08-18 | 2010-02-24 | 董建圆 | Cotton cloth reactive dye discharge printing process |
| CN101408003A (en) * | 2008-11-20 | 2009-04-15 | 浙江理工大学 | Environment protection type coating discharge printing pulp and discharge printing process thereof |
| CN101429730A (en) * | 2008-12-04 | 2009-05-13 | 浙江理工大学 | Silk broadcloth non-methanal discharge printing discharge paste and its discharge printing technique |
| CN101886346A (en) * | 2010-07-14 | 2010-11-17 | 常熟理工学院 | Assistant for resist-discharge printing of silk-like terylen fabric and preparation method thereof |
| CN102704292A (en) * | 2012-05-25 | 2012-10-03 | 浙江理工大学 | Environment-friendly paste discharge agent for textile printing and preparation method thereof |
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