CN106758394A - A kind of method for improving warp thread pigment dyeing effect - Google Patents

A kind of method for improving warp thread pigment dyeing effect Download PDF

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Publication number
CN106758394A
CN106758394A CN201611161330.4A CN201611161330A CN106758394A CN 106758394 A CN106758394 A CN 106758394A CN 201611161330 A CN201611161330 A CN 201611161330A CN 106758394 A CN106758394 A CN 106758394A
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warp thread
aeo
pretreatment
dye liquor
pretreatment fluid
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CN201611161330.4A
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CN106758394B (en
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曹根阳
潘恒
王运利
刘欣
徐卫林
刘菁
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Wuhan Textile University
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Wuhan Textile University
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65118Compounds containing hydroxyl groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6131Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/67341Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to a kind of method for improving warp thread pigment dyeing effect, belong to technical field of textile processing.Described method refers to pad warp thread using the pretreatment fluid prepared by ethanol, AEO reagent and ammonium hydrogen carbonate to warp thread pretreatment process in warp thread pigment dyeing technique, warp thread after padding is imported and decomposes evaporation area, second alcohol and water in pretreatment fluid progressively volatilizees, ammonium hydrogen carbonate is progressively decomposed and volatilized, fiber surface of the AEO Molecular Adsorption in warp thread.Pretreated warp thread pads coating dye liquor through deflector roll traction, the AEO molecule of fiber surface is contacted with coating dye liquor in warp thread is distributed in during padding, coating dye liquor is rapidly introduced into inside warp thread under AEO molecular action, and the warp thread for having dyeed is obtained after padding the drying of the warp thread after dye liquor.Warp thread pretreatment reduces the time that coating dye liquor is impregnated with, and increased the amount that coating dye liquor is impregnated with, and improves the effect of warp thread pigment dyeing.

Description

A kind of method for improving warp thread pigment dyeing effect
Technical field
The present invention relates to a kind of method for improving warp thread pigment dyeing effect, belong to technical field of textile processing.
Background technology
Current pigment dyeing weaving dyeing application widely, but also asked in the presence of some in pigment dyeing Topic, such as:The color depth of dyeing is inadequate, fastness is bad, feel is poor, aqueous cause easy to stick to take the phenomenons such as rolling because warp thread inside is excessive. It is that warp thread is pre-processed by 70 DEG C -80 DEG C of water and modifying agent that warp thread carries out preprocess method, so as to realize itself and coating it Between hydrophilic speed improve purpose.Surfactant also has application in pigment dyeing, such as Chinese public publication《Printing and dyeing are helped Agent》2 months times of disclosure 2013 year, article name is the preparation and application of cationic polymerizable surfactant D MMB, the document Application of the surfactant in pigment dyeing is described, the technology can reduce the cost of pigment dyeing, improve the friction of fabric Fastness.Surfactant plays a role the water being dissolved in pretreating process to fibrous inside infiltration in the process.It is not Foot part is to add water in raw material excessive, and especially with the help of surfactant, water penetration enters the amount ratio of fibrous inside not Plus the water penetration amount of surfactant is more.Cause part water to enter pigment dyeing operation, cause dope viscosity and solid content Change.When pigment dyeing technique is introduced into, moisture occupies the part of fibrous absorbent, causes the ability of fibers adsorption coating Do not change, residual moisture increases in fiber is caused by pigment dyeing technique, cause coating solid content to decline, influence life Produce normal operation.Ethanol also has application in pigment dyeing, such as Chinese public publication《Printing and dyeing》Time of disclosure in August, 2016, Article name is the pigment dyeing of bafta in ethanol-water system, and the document describes the application in pigment dyeing in ethanol, The technology can improve the anti-wear performance of fabric.Its deficiency is that ethanol is wherein to be applied to the pigment dyeing work of fabric Skill, its pretreating process needs drying to be unfavorable for the actual production needs of factory.
Chinese patent publication No. CN103469623A, date of publication on December 25th, 2013, entitled the one of innovation and creation The method that reactive dye carry out salt-free dyeing to un-scoured and unbleached cotton textile is planted, this application case discloses organic using alcohols at high proportion The pre-swollen liquid that solvent and a small amount of water are mixed carries out pre-swollen to un-scoured and unbleached cotton textile, and organic molten with alcohols at high proportion The method that agent and water are dyeed with the dye liquor that dyestuff is mixed to preswollen un-scoured and unbleached cotton textile, in application case In pre-swollen process step, alcohol organic solvent produces swelling action to wax, protein-based material at high proportion, is conducive to oozing Saturating agent and levelling agent are contacted with the cellulose layer of cotton fiber, and bleeding agent and levelling agent are then mainly to be contaminated in the infiltration of further dye and do Pretreatment, improves staining efficiency and effect.The Main Function of alcohol organic solvent is at high proportion in dyeing course:Because of dyestuff not Alcohol organic solvent at high proportion is dissolved in, in the system of alcohol organic solvent at high proportion and water, dyestuff is only soluble in the water of low ratio In, the concentration of its dye solution is far above designed concentration, then the bleeding agent contacted with fiber surface under pre-swollen effect And levelling agent, then dyestuff be easy and fast to dye eliminate traditional boiling and bleaching process.Its deficiency is the alcohol at high proportion in the method Class organic solvent Main Function is the materials such as swelling cotton wax, the fiber for being conducive to the reagents such as levelling agent bleeding agent to enter inside warp thread Surface, realizes quick upper dye.
The content of the invention
For above-mentioned problem, it is an object of the invention to provide a kind of side for improving warp thread pigment dyeing effect Method, to achieve these goals, its technical solution is:
A kind of method for improving warp thread pigment dyeing effect, including warp thread pretreatment, warp thread pad coating dye liquor, and warp thread dries Dry, described warp thread pretreatment refers to pad by ethanol, AEO reagent and bicarbonate pending warp thread The pretreatment fluid of ammonium mixed preparing.
The mass percent difference of ethanol, AEO reagent and ammonium hydrogen carbonate in described pretreatment fluid For:
Ethanol 97.5%-98.9%
AEO reagent 1%-2%
Ammonium hydrogen carbonate 0.1%-0.5%
Warp thread pads pretreatment fluid in liquid bath is pre-processed, and pads speed for 56-65m/min.Pretreatment fluid soaks in roll Enter inside warp thread during rolling, be distributed in the fiber surface in warp thread, pad the warp thread after pretreatment fluid and import to decompose and volatilize Region, decomposes the warp thread in evaporation area in the presence of temperature and negative pressure, and the second alcohol and water in pretreatment fluid progressively volatilizees, in advance Ammonium hydrogen carbonate in treatment fluid is progressively decomposed and volatilized, and the AEO Molecular Adsorption in pretreatment fluid is in warp thread Fiber surface, wherein, decompose evaporation area temperature be 30-50 DEG C, negative pressure be 5 × 104Pa-8×104Pa。
The part by weight of AEO molecular wt and water in described AEO reagent It is 7:3.
As a result of above technical scheme, the present invention is not change the premise of warp thread pretreatment coating dyeing Under, change the formula of the pretreatment fluid in warp thread pretreating process, prepared as main component using ethanol in formula and pre-processed Liquid.In warp thread preprocessing process, pad in the warp thread after pretreatment fluid containing ethanol, ammonium hydrogen carbonate and aliphatic alcohol polyethenoxy Etherifying reagent, because ethanol belongs to volatile organic solvent, and ratio is high in pretreatment fluid, and ammonium hydrogen carbonate does not dissolve in ethanol, But it is aqueous in AEO reagent, this part water can by ammonium bicarbonate solubility, ammonium hydrogen carbonate be dissolved in after water have it is good Good adsorption effect and formed and common made with hydrogen bond with the hydrophilic functional groups on AEO reagent molecule chain With the functional group for linking together, and water can realize that hydrogen bond is connected between ethanol, and then form with ethanol molecule, ammonia The micel of radical ion and AEO molecule common combination, containing the functional group of hydrophilic and water repellent in micel, So that micel is running into the fiber that fiber surface water repellent molecule also can be entered into smoothly inside warp thread.When warp thread enters into decomposition During evaporation area, under heater effect, ethanol starts volatilization, and the hydrone being combined with ethanol molecule during volatilization also can be by Take away;Ammonium hydrogen carbonate also begins to be thermally decomposed into water, ammonia and carbon dioxide, and ammonia is highly soluble in water, inherently band during its volatilization Walk part moisture content.The hydrone inside warp thread is eliminated during ethanol and Ammonia valatilization jointly.After decomposing evaporation area Warp thread in only contain AEO molecule, can be prevented effectively from warp thread because it is aqueous and caused by pigment dyeing problem. AEO molecule is then distributed in warp thread, and fiber surface of the AEO molecule in warp thread is formed Molecular film, water repellent group is connected to one with fiber surface water repellency interaction of molecules in AEO molecular structure Rise, and the hydrophilic radical in AEO molecular structure is then revealed in the outer layer of molecular film.This causes fiber through fat Acting on for fat alcohol APEO molecule imparts Hydrophilic Fiber energy, when warp thread pads coating dye liquor, the fibre in warp thread The AEO molecule in dimension table face then plays the effect that it assists the infiltration of coating dye liquor, accelerates the infiltration of coating dye liquor Efficiency.This than merely in coating dye liquor add bleeding agent realized it is better.Therefore, the technical program is employed, is changed It has been apt to the effect of warp thread pigment dyeing, and the method is processed suitable for all kinds of warp thread pigment dyeings, reduces the cost of production.
Specific embodiment
A kind of method for improving warp thread pigment dyeing effect of the invention is made further in detail with reference to specific embodiment Thin description:
A kind of method for improving warp thread pigment dyeing effect, including the warp thread pretreatment work in warp thread pigment dyeing technique Sequence, warp thread pads coating dye liquor operation, warp thread baking operation.Described warp thread pretreatment process refers to soak pending warp thread Roll by the pretreatment fluid of ethanol, AEO reagent and ammonium hydrogen carbonate mixed preparing,
Wherein, the mass percent of ethanol, AEO reagent and ammonium hydrogen carbonate is respectively in pretreatment fluid:
Ethanol 97.5%-98.9%
AEO reagent 1%-2%
Ammonium hydrogen carbonate 0.1%-0.5%
The part by weight of AEO molecular wt and water in described AEO reagent It is 7:3.
Warp thread pads pretreatment fluid in liquid bath is pre-processed, and pads speed for 56-65m/min.Pretreatment fluid soaks in roll Enter inside warp thread during rolling, be distributed in the fiber surface in warp thread, pad the warp thread after pretreatment fluid and import to decompose and volatilize Region, decomposes the warp thread in evaporation area in the presence of temperature and negative pressure, and the second alcohol and water in pretreatment fluid progressively volatilizees, in advance Ammonium hydrogen carbonate in treatment fluid is progressively decomposed and volatilized, and the AEO Molecular Adsorption in pretreatment fluid is in warp thread Fiber surface, wherein, decompose evaporation area temperature be 30-50 DEG C, negative pressure be 5 × 104Pa-8×104Pa.It is pretreated Warp thread pads coating dye liquor through deflector roll traction, the poly alkyl alcohol of fiber surface in warp thread is distributed in during padding coating dye liquor Oxygen vinyl ether molecules are contacted with coating dye liquor, and coating dye liquor is rapidly introduced into warp thread under AEO molecular action Inside, the good warp thread of pigment dyeing is obtained after padding the drying of the warp thread after coating dye liquor.Warp thread pretreatment reduces coating dye liquor The time being impregnated with, the amount that coating dye liquor is impregnated with is increased, improve the effect of warp thread pigment dyeing.
Specific embodiment
Embodiment 1
Not pretreated pure cotton warp thread is immersed in pretreatment fluid by deflector roll traction, ethanol quality hundred in pretreatment fluid Divide than being 98.9%, AEO reagent quality percentage is 1%, ammonium hydrogen carbonate mass percent is 0.1%, is soaked The pure cotton warp thread of saturating pretreatment fluid remains a part of ethanol, fat after padding the roll that speed is 56m/min and rolling in pure cotton warp thread Fat alcohol polyoxyethylene etherifying reagent and ammonium hydrogen carbonate, it is 30 DEG C that pure cotton warp thread is imported into temperature, and condition of negative pressure is 5 × 104Pa's divides Solution evaporation area.Pretreated pure cotton warp thread is immersed in coating dye liquor through deflector roll traction, pads the pure cotton after coating dye liquor The lustful pure cotton warp thread of dye is obtained after warp thread drying.Effect is shown in Table 1.
Embodiment 2
Not pretreated pure cotton warp thread is immersed in pretreatment fluid by deflector roll traction, ethanol quality hundred in pretreatment fluid Divide than being 98.2%, AEO reagent quality percentage is 1.5%, ammonium hydrogen carbonate mass percent is 0.3%, Be impregnated with the pure cotton warp thread of pretreatment fluid through pad speed be 60m/min roll roll after, remained in pure cotton warp thread a part of ethanol, AEO reagent and ammonium hydrogen carbonate, it is 40 DEG C that pure cotton warp thread is imported into temperature, and condition of negative pressure is 6.5 × 104Pa Decomposition evaporation area.Pretreated pure cotton warp thread is immersed in coating dye liquor through deflector roll traction, after padding coating dye liquor The lustful pure cotton warp thread of dye is obtained after the drying of pure cotton warp thread.Effect is shown in Table 1.
Embodiment 3
Not pretreated pure cotton warp thread is immersed in pretreatment fluid by deflector roll traction, ethanol quality hundred in pretreatment fluid Divide than being 97.5%, AEO reagent quality percentage is 2%, ammonium hydrogen carbonate mass percent is 0.5%, is soaked The pure cotton warp thread of saturating pretreatment fluid remains a part of ethanol, fat after padding the roll that speed is 65m/min and rolling in pure cotton warp thread Fat alcohol polyoxyethylene etherifying reagent and ammonium hydrogen carbonate, it is 50 DEG C that pure cotton warp thread is imported into temperature, and condition of negative pressure is 8 × 104Pa's divides Solution evaporation area.Pretreated pure cotton warp thread is immersed in coating dye liquor through deflector roll traction, pads the pure cotton after coating dye liquor The lustful pure cotton warp thread of dye is obtained after warp thread drying.Effect is shown in Table 1.
Embodiment 4
Not pretreated pure numb warp thread is immersed in pretreatment fluid by deflector roll traction, ethanol quality hundred in pretreatment fluid Divide than being 98.9%, AEO reagent quality percentage is 1%, ammonium hydrogen carbonate mass percent is 0.1%, is soaked The pure numb warp thread of saturating pretreatment fluid remains a part of ethanol, fat after padding the roll that speed is 56m/min and rolling in pure numb warp thread Fat alcohol polyoxyethylene etherifying reagent and ammonium hydrogen carbonate, it is 30 DEG C that pure numb warp thread is imported into temperature, and condition of negative pressure is waved for the decomposition of 0.1Pa Hair region.Pretreated pure numb warp thread is immersed in coating dye liquor through deflector roll traction, pads the pure numb warp thread after coating dye liquor The lustful pure numb warp thread of dye is obtained after drying.Effect is shown in Table 1.
Embodiment 5
Not pretreated pure terylene warp thread is immersed in pretreatment fluid by deflector roll traction, ethanol quality in pretreatment fluid Percentage is 98.9%, and AEO reagent quality percentage is 1%, and ammonium hydrogen carbonate mass percent is 0.1%, The pure terylene warp thread of pretreatment fluid is impregnated with after padding the roll that speed is 56m/min and rolling, and a part is remained in pure terylene warp thread Ethanol, AEO reagent and ammonium hydrogen carbonate, it is 30 DEG C that pure terylene warp thread is imported into temperature, and condition of negative pressure is The decomposition evaporation area of 0.1Pa.Pretreated pure terylene warp thread is immersed in coating dye liquor through deflector roll traction, pads coating dye The lustful pure terylene warp thread of dye is obtained after pure terylene warp thread drying after liquid.Effect is shown in Table 1.
Be contrast the technical program technological merit, do not do pre-process pure cotton, pure numb and pure terylene warp thread respectively through Deflector roll traction is immersed in coating dye liquor, pads pure cotton, the baking of pure numb and pure terylene warp thread that not doing after coating dye liquor pre-processes Dye lechery is obtained after dry does not do pure cotton, the pure numb and pure terylene warp thread for pre-processing.Obtained sample is passed through respectively as pure cotton Yarn former state, pure fiber crops former state and pure terylene are as former state.By embodiment 1-5 and pure cotton warp thread as former state, pure fiber crops as former state and pure terylene former state Rove sample is placed in constant-temperature constant-humidity environment lower 24 hours, and temperature is 20 DEG C, and humidity is 65%.Then to above-mentioned sample test K/S Value.Obtain data such as table 1:
The K/S values of the pigment dyeing warp thread sample of table 1

Claims (2)

1. a kind of method for improving warp thread pigment dyeing effect, including warp thread pretreatment, warp thread pads coating dye liquor, and warp thread dries It is dry, it is characterised in that:Described warp thread pretreatment refers to pad pending warp thread to be tried by ethanol, AEO Agent and the pretreatment fluid of ammonium hydrogen carbonate mixed preparing;
Wherein, the mass percent of ethanol, AEO reagent and ammonium hydrogen carbonate is respectively in pretreatment fluid:
Ethanol 97.5%-98.9%
AEO reagent 1%-2%
Ammonium hydrogen carbonate 0.1%-0.5%
Warp thread pads pretreatment fluid in liquid bath is pre-processed, and pads speed for 56-65m/min, and pretreatment fluid padded in roll Enter inside warp thread in journey, be distributed in the fiber surface in warp thread, pad the warp thread after pretreatment fluid and import decomposition evaporation area, The warp thread in evaporation area is decomposed in the presence of temperature and negative pressure, the second alcohol and water in pretreatment fluid progressively volatilizees, pretreatment Ammonium hydrogen carbonate in liquid is progressively decomposed and volatilized, fibre of the AEO Molecular Adsorption in pretreatment fluid in warp thread Dimension table face, wherein, the temperature for decomposing evaporation area is 30-50 DEG C, and negative pressure is 5 × 104Pa-8×104Pa。
2. a kind of method for improving warp thread pigment dyeing effect as claimed in claim 1, it is characterised in that:Described fatty alcohol AEO molecular wt and the part by weight of water in polyoxyethylene etherifying reagent are 7:3.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385961A (en) * 2017-06-23 2017-11-24 安庆市枞江汽车部件制造有限公司 A kind of high-quality ribbon reproducibility colouring method
CN107938391A (en) * 2017-12-01 2018-04-20 山东黄河三角洲纺织科技研究院有限公司 A kind of flax fiber colouring method
CN110106719A (en) * 2019-04-12 2019-08-09 武汉纺织大学 A kind of method that high-performance textile is dyed from pressurised carrier

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CN101195963A (en) * 2007-12-28 2008-06-11 武汉科技学院 Method for dyeing production of textile pigment
CN101994249A (en) * 2010-10-18 2011-03-30 武汉纺织大学 Pigment dyeing method for loose cotton fiber
CN103469627A (en) * 2013-09-25 2013-12-25 武汉纺织大学 Low-temperature dyeing method capable of improving strength of wool textile
CN103774460A (en) * 2013-12-23 2014-05-07 武汉纺织大学 Method for improving dyeing depth of cotton fiber aggregate pigment
US20140335751A1 (en) * 2013-05-08 2014-11-13 Shan James LEE Dyed textiles and method of producing the same
CN105239296A (en) * 2015-11-09 2016-01-13 武汉纺织大学 Method for improving softness performance of pigment dyed fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101195963A (en) * 2007-12-28 2008-06-11 武汉科技学院 Method for dyeing production of textile pigment
CN101994249A (en) * 2010-10-18 2011-03-30 武汉纺织大学 Pigment dyeing method for loose cotton fiber
US20140335751A1 (en) * 2013-05-08 2014-11-13 Shan James LEE Dyed textiles and method of producing the same
CN103469627A (en) * 2013-09-25 2013-12-25 武汉纺织大学 Low-temperature dyeing method capable of improving strength of wool textile
CN103774460A (en) * 2013-12-23 2014-05-07 武汉纺织大学 Method for improving dyeing depth of cotton fiber aggregate pigment
CN105239296A (en) * 2015-11-09 2016-01-13 武汉纺织大学 Method for improving softness performance of pigment dyed fabric

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385961A (en) * 2017-06-23 2017-11-24 安庆市枞江汽车部件制造有限公司 A kind of high-quality ribbon reproducibility colouring method
CN107938391A (en) * 2017-12-01 2018-04-20 山东黄河三角洲纺织科技研究院有限公司 A kind of flax fiber colouring method
CN107938391B (en) * 2017-12-01 2020-10-30 山东黄河三角洲纺织科技研究院有限公司 Flax fiber dyeing method
CN110106719A (en) * 2019-04-12 2019-08-09 武汉纺织大学 A kind of method that high-performance textile is dyed from pressurised carrier

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