CN106758306A - A kind of acid amides based polyurethanes suede-like artificial leather manufacture method for being easy to dye - Google Patents

A kind of acid amides based polyurethanes suede-like artificial leather manufacture method for being easy to dye Download PDF

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Publication number
CN106758306A
CN106758306A CN201610132486.3A CN201610132486A CN106758306A CN 106758306 A CN106758306 A CN 106758306A CN 201610132486 A CN201610132486 A CN 201610132486A CN 106758306 A CN106758306 A CN 106758306A
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CN
China
Prior art keywords
suede
artificial leather
paint
lacquer
dyeing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610132486.3A
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Chinese (zh)
Inventor
朱广和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangyin Huadong Plastic Products Co Ltd
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Jiangyin Huadong Plastic Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangyin Huadong Plastic Products Co Ltd filed Critical Jiangyin Huadong Plastic Products Co Ltd
Publication of CN106758306A publication Critical patent/CN106758306A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Textile Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The present invention relates to a kind of acid amides based polyurethanes suede-like artificial leather manufacture method be easy to and dye, it is to use Amide based solvents type polyurethane resin to configure to cover with paint, lacquer, colour wash, etc. slurry, then slurry will be covered with paint, lacquer, colour wash, etc. to cover with paint, lacquer, colour wash, etc. in suede-like artificial leather scrim surfaces, the polyurethane suede-like artificial leather for being dyeed by dyeing treatment again, covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:100 parts of Amide based solvents type polyurethane resin, 20~120 parts of dimethylformamide, 20~120 parts of acetone.Amide based solvents type polyurethane resin is used as artificial leather top finishing material, dyeing process can be carried out with dyestuff, color effects by that can obtain dyestuff coloring after dyeing treatment, make product have the characteristics of bright-colored, coating permeability is good, surface color fastness is high, color animal migration is small.

Description

A kind of acid amides based polyurethanes suede-like artificial leather manufacture method for being easy to dye
Technical field
The invention belongs to polyurethane suede-like artificial leather preparation method technical field, and in particular to a kind of acid amides for being easy to dye The manufacture method of based polyurethanes suede-like artificial leather.
Background technology
Surface has the artificial leather of dyestuff coloring effect, and its bright in luster, transparency is high, is applied to the fashion such as case and bag women's shoes It is loved by people on product, but conventional synthesis leather generally uses pigment coloring mode, it is impossible to and reaching dyestuff coloring is had Effect, although dyestuff coloring effect can be obtained using the manufacture method that the coloring of dyestuff water colouring agent is added in coating material, But this manufacture method can bring serious colour migration to move, poor color fastness, the problems such as cost price is high, making for product is constrained With.
In traditional synthetic leather manufacturing process, mill base, toner and organic dyestuff, metal network need to be added in coating paste
The coloring materials such as dyestuff are closed, so that assign finished leather different colors, but coat colorization feel is partially hard, and coloring formula is once It is determined that after, coating is presented solid color, and gloss and color and luster are dull, without the stereovision such as the depth, light and shade, new and old.Exploitation is just In dyeing artificial leather be those skilled in the art need thinking problem.
The content of the invention
The technical problems to be solved by the invention are directed to above-mentioned prior art and provide a kind of polyurethane suede be easy to and dye Dough figurine fabricate-leather, can be dyeed with dyestuff, and product has the characteristics of bright-colored, coating permeability is good, surface color fastness is high.
The present invention the used technical scheme that solves the above problems is:A kind of acid amides based polyurethanes matte people for being easy to dye Fabricate-leather manufacture method, is to use Amide based solvents type polyurethane resin to configure to cover with paint, lacquer, colour wash, etc. slurry, then will cover with paint, lacquer, colour wash, etc. slurry and covers with paint, lacquer, colour wash, etc. in suede Dough figurine fabricate-leather scrim surfaces, then the polyurethane suede-like artificial leather dyeed by dyeing treatment;
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of Amide based solvents type polyurethane resin
20~120 parts of dimethylformamide
20~120 parts of acetone.
Preferably, described covering with paint is to make surface technology by release liners dry method to fit to Amide based solvents type polyurethane surface layer In artificial leather wet half-finished product.
Preferably described covering with paint is that Amide based solvents type polyurethane is covered with paint, lacquer, colour wash, etc. into slurry with surface printing method to cover with paint, lacquer, colour wash, etc. in artificial leather Dry method surface of semi-finished.
Preferably, the covering with paint is that Amide based solvents type polyurethane is applied into finish coat with rolling method to be coated with to artificial leather base fabric Surface of semi-finished.
Described dyeing
Polyurethane resin artificial leather in the present invention is easy to dyeing, and dyeing processing mode includes pad dyeing, dye gigging, overflow dyeing or gas Stream dyeing.
Compared with prior art, the advantage of the invention is that:Using Amide based solvents type polyurethane resin as matte people Fabricate-leather top finishing material, can carry out dyeing process with dyestuff, the color effect by that can obtain dyestuff coloring after dyeing treatment Really, making product has the characteristics of bright-colored, coating permeability is good, surface color fastness is high, color animal migration is small, with common matte people Fabricate-leather dyeing is few compared to dyestuff usage amount, and dyeing time is very short, and dyeing can be completed compared with low temperature, and dyeing is simpler Single, cost is relatively low, energy saving.
Specific embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1
Be easy to the acid amides based polyurethanes suede-like artificial leather manufacture method of dyeing, configured using Amide based solvents type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and is covered with paint, lacquer, colour wash, etc. in suede-like artificial leather scrim surfaces, foregoing covering with paint is to make face by release liners dry method Technology fits in suede-like artificial leather wet half-finished product Amide based solvents type polyurethane surface layer, then is obtained by pad dyeing treatment The polyurethane suede-like artificial leather of dyeing.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of Amide based solvents type polyurethane resin
100 parts of dimethylformamide
80 parts of acetone.
Embodiment 2
Be easy to the acid amides based polyurethanes suede-like artificial leather manufacture method of dyeing, configured using Amide based solvents type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and be covered with paint, lacquer, colour wash, etc. in suede-like artificial leather scrim surfaces, foregoing covering with paint is to use surface printing method by acid amides Based solvent type polyurethane is covered with paint, lacquer, colour wash, etc. slurry and is covered with paint, lacquer, colour wash, etc. in suede-like artificial leather dry method surface of semi-finished, then is dyeed by dye gigging treatment Polyurethane suede-like artificial leather.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of Amide based solvents type polyurethane resin
80 parts of dimethylformamide
60 parts of acetone.
Embodiment 3
Be easy to the acid amides based polyurethanes suede-like artificial leather manufacture method of dyeing, configured using Amide based solvents type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and be covered with paint, lacquer, colour wash, etc. in suede-like artificial leather scrim surfaces, foregoing covering with paint is to use rolling method by amide groups Solvent borne polyurethane applies finish coat coating to suede-like artificial leather base fabric surface of semi-finished, then it is to be contaminated to be processed by airflow dyeing The polyurethane suede-like artificial leather of color.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of Amide based solvents type polyurethane resin
80 parts of dimethylformamide
100 parts of acetone.
Embodiment 4
Be easy to the acid amides based polyurethanes suede-like artificial leather manufacture method of dyeing, configured using Amide based solvents type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and be covered with paint, lacquer, colour wash, etc. in suede-like artificial leather scrim surfaces, foregoing covering with paint is to use surface printing method by acid amides Based solvent type polyurethane is covered with paint, lacquer, colour wash, etc. slurry and is covered with paint, lacquer, colour wash, etc. in suede-like artificial leather dry method surface of semi-finished, then it is to obtain to be processed by overflow dyeing The polyurethane suede-like artificial leather of dyeing.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of Amide based solvents type polyurethane resin
80 parts of dimethylformamide
60 parts of acetone.

Claims (5)

1. it is a kind of be easy to dyeing acid amides based polyurethanes suede-like artificial leather manufacture method, it is characterised in that:It is to use amide groups molten Slurry is covered with paint, lacquer, colour wash, etc. in the configuration of formulation polyurethane resin, then will be covered with paint, lacquer, colour wash, etc. slurry and is covered with paint, lacquer, colour wash, etc. in suede-like artificial leather scrim surfaces, then by dyeing The polyurethane suede-like artificial leather that treatment is dyeed,
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of Amide based solvents type polyurethane resin
20~120 parts of dimethylformamide
20~120 parts of acetone.
2. it is according to claim 1 be easy to dyeing acid amides based polyurethanes suede-like artificial leather manufacture method, it is characterised in that: The covering with paint is to make surface technology by release liners dry method Amide based solvents type polyurethane surface layer is fitted into suede-like artificial leather wet method On semi-finished product.
3. it is according to claim 1 be easy to dyeing acid amides based polyurethanes suede-like artificial leather manufacture method, it is characterised in that: The covering with paint is that Amide based solvents type polyurethane is covered with paint, lacquer, colour wash, etc. into slurry with surface printing method to cover with paint, lacquer, colour wash, etc. in suede-like artificial leather dry method semi-finished product Surface.
4. it is according to claim 1 be easy to dyeing acid amides based polyurethanes suede-like artificial leather manufacture method, it is characterised in that: The covering with paint is that Amide based solvents type polyurethane is applied into finish coat with rolling method to be coated with to suede-like artificial leather base fabric surface of semi-finished.
5. it is according to claim 1 be easy to dyeing acid amides based polyurethanes suede-like artificial leather manufacture method, it is characterised in that: The dyeing treatment is pad dyeing, dye gigging, overflow dyeing or airflow dyeing.
CN201610132486.3A 2015-11-21 2016-03-10 A kind of acid amides based polyurethanes suede-like artificial leather manufacture method for being easy to dye Pending CN106758306A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2015108064716 2015-11-21
CN201510806471 2015-11-21

Publications (1)

Publication Number Publication Date
CN106758306A true CN106758306A (en) 2017-05-31

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113954487A (en) * 2021-11-16 2022-01-21 山东同大海岛新材料股份有限公司 Pigskin-imitated moisture-absorbing superfine fiber leather and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113954487A (en) * 2021-11-16 2022-01-21 山东同大海岛新材料股份有限公司 Pigskin-imitated moisture-absorbing superfine fiber leather and preparation method thereof

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Application publication date: 20170531