CN106758301A - A kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method - Google Patents

A kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method Download PDF

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Publication number
CN106758301A
CN106758301A CN201610123079.6A CN201610123079A CN106758301A CN 106758301 A CN106758301 A CN 106758301A CN 201610123079 A CN201610123079 A CN 201610123079A CN 106758301 A CN106758301 A CN 106758301A
Authority
CN
China
Prior art keywords
acid amides
artificial leather
paint
base class
polyurethane resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610123079.6A
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Chinese (zh)
Inventor
季建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Hualian Plastic Products Co Ltd
Original Assignee
Wuxi Hualian Plastic Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Hualian Plastic Products Co Ltd filed Critical Wuxi Hualian Plastic Products Co Ltd
Publication of CN106758301A publication Critical patent/CN106758301A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/08Properties of the materials having optical properties
    • D06N2209/0807Coloured
    • D06N2209/083Multi-coloured
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The present invention relates to a kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method, it is to use acid amides base class solvent type polyurethane resin to configure to cover with paint, lacquer, colour wash, etc. slurry, then slurry will be covered with paint, lacquer, colour wash, etc. to cover with paint, lacquer, colour wash, etc. in artificial leather base fabric surface, the polyurethane artificial leather for being dyeed by dyeing treatment again, covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:100 parts of acid amides base class solvent type polyurethane resin, 20~120 parts of dimethylformamide, 20~120 parts of acetone.Acid amides base class solvent type polyurethane resin is used as artificial leather top finishing material, dyeing process can be carried out with dyestuff, color effects by that can obtain dyestuff coloring after dyeing treatment, make product have the characteristics of bright-colored, coating permeability is good, surface color fastness is high, color animal migration is small.

Description

A kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method
Technical field
The invention belongs to polyurethane resin artificial leather preparation method technical field, and in particular to a kind of acid amides for being easy to dye The manufacture method of base class solvent type polyurethane resin artificial leather.
Background technology
Surface has the artificial leather of dyestuff coloring effect, and its bright in luster, transparency is high, is applied to the fashion such as case and bag women's shoes It is loved by people on product, but conventional synthesis leather generally uses pigment coloring mode, it is impossible to and reaching dyestuff coloring is had Effect, although dyestuff coloring effect can be obtained using the manufacture method that the coloring of dyestuff water colouring agent is added in coating material, But this manufacture method can bring serious colour migration to move, poor color fastness, the problems such as cost price is high, making for product is constrained With.
In traditional synthetic leather manufacturing process, mill base, toner and organic dyestuff, metal network need to be added in coating paste
The coloring materials such as dyestuff are closed, so that assign finished leather different colors, but coat colorization feel is partially hard, and coloring formula is once It is determined that after, coating is presented solid color, and gloss and color and luster are dull, without the stereovision such as the depth, light and shade, new and old.Exploitation is just In dyeing artificial leather be those skilled in the art need thinking problem.
The content of the invention
The technical problems to be solved by the invention are directed to above-mentioned prior art and provide a kind of polyurethane people be easy to and dye Fabricate-leather, can be dyeed with dyestuff, and product has the characteristics of bright-colored, coating permeability is good, surface color fastness is high.
The present invention the used technical scheme that solves the above problems is:A kind of acid amides base class solvent type polyurethane resin is artificial Leather manufacture method, is to use acid amides base class solvent type polyurethane resin to configure to cover with paint, lacquer, colour wash, etc. slurry, then will cover with paint, lacquer, colour wash, etc. slurry and covers with paint, lacquer, colour wash, etc. in people Fabricate-leather scrim surfaces, then the polyurethane artificial leather dyeed by dyeing treatment;
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of acid amides base class solvent type polyurethane resin
20~120 parts of dimethylformamide
20~120 parts of acetone.
Preferably, the covering with paint is to make surface technology by release liners dry method acid amides base class solvent borne polyurethane surface layer is fitted Onto artificial leather wet half-finished product.
Preferably described covering with paint is that acid amides base class solvent borne polyurethane is covered with paint, lacquer, colour wash, etc. into slurry with surface printing method to cover with paint, lacquer, colour wash, etc. in artificial Revolutionary cadre's method surface of semi-finished.
Preferably, the covering with paint is that acid amides base class solvent borne polyurethane is applied into finish coat with rolling method to be coated with to artificial leather base Cloth surface of semi-finished.
Described dyeing
Polyurethane resin artificial leather in the present invention is easy to dyeing, and dyeing processing mode includes pad dyeing, dye gigging, overflow dyeing or gas Stream dyeing.
Compared with prior art, the advantage of the invention is that:Using acid amides base class solvent type polyurethane resin as artificial Leather top finishing material, can carry out dyeing process with dyestuff, the color effects by that can obtain dyestuff coloring after dyeing treatment, Make product that there is the characteristics of bright-colored, coating permeability is good, surface color fastness is high, color animal migration is small, contaminated with common artificial leather Form and aspect are fewer than dyestuff usage amount, and dyeing time is very short, and dyeing can be completed compared with low temperature, dyeing relatively simple, cost Relatively low, energy saving.
Specific embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1
Acid amides base class solvent type polyurethane resin artificial leather manufacture method, is configured using acid amides base class solvent type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and is covered with paint, lacquer, colour wash, etc. in artificial leather base fabric surface, foregoing covering with paint is to make surface technology by release liners dry method Acid amides base class solvent borne polyurethane surface layer is fitted in artificial leather wet half-finished product, then dyeed by pad dyeing treatment Polyurethane artificial leather.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of acid amides base class solvent type polyurethane resin
100 parts of dimethylformamide
80 parts of acetone.
Embodiment 2
Acid amides base class solvent type polyurethane resin artificial leather manufacture method, is configured using acid amides base class solvent type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and be covered with paint, lacquer, colour wash, etc. in artificial leather base fabric surface, foregoing covering with paint is to use surface printing method by acid amides base class Solvent borne polyurethane is covered with paint, lacquer, colour wash, etc. slurry and is covered with paint, lacquer, colour wash, etc. in artificial leather dry method surface of semi-finished, then the poly- ammonia dyeed by dye gigging treatment Ester artificial leather.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of acid amides base class solvent type polyurethane resin
80 parts of dimethylformamide
60 parts of acetone.
Embodiment 3
Acid amides base class solvent type polyurethane resin artificial leather manufacture method, is configured using acid amides base class solvent type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and is covered with paint, lacquer, colour wash, etc. in artificial leather base fabric surface, foregoing covering with paint is using rolling method that acid amides base class is molten Formulation polyurethane painting finish coat coating arrives artificial leather base fabric's surface of semi-finished, then by gathering that airflow dyeing treatment is dyeed Urethane artificial leather.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of acid amides base class solvent type polyurethane resin
80 parts of dimethylformamide
100 parts of acetone.
Embodiment 4
Acid amides base class solvent type polyurethane resin artificial leather manufacture method, is configured using acid amides base class solvent type polyurethane resin Slurry is covered with paint, lacquer, colour wash, etc., slurry then will be covered with paint, lacquer, colour wash, etc. and be covered with paint, lacquer, colour wash, etc. in artificial leather base fabric surface, foregoing covering with paint is to use surface printing method by acid amides base class Solvent borne polyurethane is covered with paint, lacquer, colour wash, etc. slurry and is covered with paint, lacquer, colour wash, etc. in artificial leather dry method surface of semi-finished, then processes what is dyeed by overflow dyeing Polyurethane artificial leather.
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of acid amides base class solvent type polyurethane resin
80 parts of dimethylformamide
60 parts of acetone.

Claims (5)

1. a kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method, it is characterised in that:It is to use acid amides base class molten Slurry is covered with paint, lacquer, colour wash, etc. in the configuration of formulation polyurethane resin, then will be covered with paint, lacquer, colour wash, etc. slurry and is covered with paint, lacquer, colour wash, etc. in artificial leather base fabric surface, then is processed by dyeing The polyurethane artificial leather for being dyeed,
Covering with paint, lacquer, colour wash, etc. slurry includes the component of following mass parts:
100 parts of acid amides base class solvent type polyurethane resin
20~120 parts of dimethylformamide
20~120 parts of acetone.
2. acid amides base class solvent type polyurethane resin artificial leather manufacture method according to claim 1, it is characterised in that:Institute State covering with paint be by release liners dry method make surface technology by acid amides base class solvent borne polyurethane surface layer fit to artificial leather wet method half into On product.
3. acid amides base class solvent type polyurethane resin artificial leather manufacture method according to claim 1, it is characterised in that:Institute It is that acid amides base class solvent borne polyurethane is covered with paint, lacquer, colour wash, etc. into slurry with surface printing method to cover with paint, lacquer, colour wash, etc. in artificial leather dry method surface of semi-finished to state covering with paint.
4. acid amides base class solvent type polyurethane resin artificial leather manufacture method according to claim 1, it is characterised in that:Institute It is that acid amides base class solvent borne polyurethane is applied into finish coat with rolling method to be coated with to artificial leather base fabric's surface of semi-finished to state covering with paint.
5. acid amides base class solvent type polyurethane resin artificial leather manufacture method according to claim 1, it is characterised in that:Institute It is pad dyeing, dye gigging, overflow dyeing or airflow dyeing to state dyeing treatment.
CN201610123079.6A 2015-11-19 2016-03-05 A kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method Pending CN106758301A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2015107987023 2015-11-19
CN201510798702 2015-11-19

Publications (1)

Publication Number Publication Date
CN106758301A true CN106758301A (en) 2017-05-31

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610123079.6A Pending CN106758301A (en) 2015-11-19 2016-03-05 A kind of acid amides base class solvent type polyurethane resin artificial leather manufacture method

Country Status (1)

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CN (1) CN106758301A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113136136A (en) * 2021-05-13 2021-07-20 苏州贝斯特装饰新材料有限公司 Surface finishing agent for PVC synthetic leather, preparation method thereof and PVC synthetic leather

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113136136A (en) * 2021-05-13 2021-07-20 苏州贝斯特装饰新材料有限公司 Surface finishing agent for PVC synthetic leather, preparation method thereof and PVC synthetic leather

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Application publication date: 20170531