CN106758247A - 一种棉织物整理剂及其应用 - Google Patents
一种棉织物整理剂及其应用 Download PDFInfo
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Abstract
本发明公开了一种棉织物整理剂，该整理剂按质量份数计包括以下组分：烷基醇酰胺聚氧乙烷醚：4‑9份，聚芳醚砜酮改性树脂：40‑60份，月桂酸：4‑7份，氧化锌：8‑10份，苯乙烯系弹性体：15‑18份，复合阻燃剂：5‑9份异丙醇：20‑30份，增稠剂邻苯二甲酸二辛酯：3‑5份；本发明还涉及一种棉织物整理剂的应用，该织物具有良好的阻燃性，提高了安全性，使织物柔软舒服。
Description
技术领域
本发明涉及一种整理剂具体涉及一种棉织物整理剂及其应用。
背景技术
随着生活水平的提高，人们越来越重视生活的质量，希望能获得有舒适感的衣着，以及卫生健康的居住环境，对于各种各样的纺织品要求越来越高，特别是安全、安心、舒适、健康、卫生、清洁等"绿色"观念的形成，使纺织品的抗菌、防霉、防臭后整理加工更加受到人们的重视。
发明内容
本发明所要解决的技术问题是，针对以上现有技术存在的缺点，提出一种棉织物整理剂及其应用，该织物具有良好的阻燃性，提高了安全性，使织物柔软舒服。
本发明解决以上技术问题的技术方案是：
一种棉织物整理剂，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：4-9份，聚芳醚砜酮改性树脂：40-60份，月桂酸：4-7份，氧化锌：8-10份，苯乙烯系弹性体：15-18份，复合阻燃剂：5-9份异丙醇：20-30份，增稠剂邻苯二甲酸二辛酯：3-5份，其中，
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐；
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：40-70份，聚芳醚砜酮：20-35份；
聚芳醚砜酮改性树脂制备方法具体操作如下：将聚芳醚砜酮与环氧树脂按1:2的比例混合，将混合物熔融制得预聚体PEK/EP, 熔融温度为280-300℃，然后将预聚体用粉末机打成粉末即得到聚芳醚砜酮改性树脂。
本发明进一步限定的技术方案为：
前述棉织物整理剂中，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：4份，聚芳醚砜酮改性树脂：40份，月桂酸：4份，氧化锌：8份，苯乙烯系弹性体：15份，复合阻燃剂：5份异丙醇：20份，增稠剂邻苯二甲酸二辛酯：3份，其中，
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：40份，聚芳醚砜酮：20份；
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
前述棉织物整理剂中，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：9份，聚芳醚砜酮改性树脂：60份，月桂酸：7份，氧化锌：10份，苯乙烯系弹性体：18份，复合阻燃剂：9份异丙醇：30份，增稠剂邻苯二甲酸二辛酯：5份，其中，
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：70份，聚芳醚砜酮：35份；
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
前述棉织物整理剂中，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：7份，聚芳醚砜酮改性树脂：50份，月桂酸：5份，氧化锌：9份，苯乙烯系弹性体：16份，复合阻燃剂：7份异丙醇：25份，增稠剂邻苯二甲酸二辛酯：4份，其中，
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：60份，聚芳醚砜酮：25份；
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
前述棉织物整理剂中，磷氮硅三元阻燃剂的制备：
（1）向装有冷凝管、滴液漏斗的三口烧瓶中通入氮气5-8min，依次加入磷酸和乙醇，将γ-（2,3-环氧丙氧基）丙基三甲氧硅烷逐滴加入，滴加速度控制在3-5g/min，在室温下反应3-4h；反应结束后，将三口烧瓶置于恒温水浴锅内，用旋转蒸发器减压蒸馏除去溶剂和低沸物，即得到磷硅二元阻燃剂。其中整个反应过程保持连续机械搅拌，搅拌速度为300-400r/min；
（2）在容器中加入磷硅二元阻燃剂和脲，室温下连续机械搅拌5-10min，得到磷氮硅三元阻燃剂。
本发明还涉及了一种棉织物整理剂的应用，具体包括以下步骤：将准备好的棉织物放在100℃的热水中预煮，然后捞出浸入整理剂中，浴比1:20，整理温度为70-80℃，整理时间20-30min，取出在70-80℃下哄10-12min，调节温度至100-130℃哄5-8min，在20-30℃的温水中皂洗，用0-5℃的水冲洗，最后在80-90℃下烘干即可处理。
本发明的有益效果是：
本发明中加入苯乙烯系弹性体，用弹性体包覆复合阻燃剂形成微囊结构，均匀分散与使聚苯醚树脂中，改善了两相的亲和力，减少了界面的应力集中，从而改善了体系的综合性能（如机械性能和阻燃性能等），同时，用弹性体包覆复合阻燃剂形成微囊结构，使得复合阻燃剂在阻燃方面达到最有效的结合，相比于以往阻燃剂的加入大大降低了体系的绝缘电阻和断裂伸长率，本发明中加入了弹性体，阻燃剂的拉伸强度变化不大，且生产的制品韧性高、耐低温性能好、耐环境应力开裂性能也得到提高。
本发明中使用的复合阻燃剂，具有无毒、阻燃效率高等优点，可以通过升华及分解释放出的惰性气体以达到阻燃的目的，磷氮在一定情况下有协同阻燃的效果，采用复配的阻燃剂，使阻燃基材阻燃效果更好的发挥，且极限氧指数也能得到提高，同时，添加的复合阻燃剂具有耐高温耐水抗迁移的性能改善了一般阻燃剂不耐水易析出并且耐温低的缺点，能在200℃-280℃加工温度下顺利挤出不发生分解，在98%湿度+85℃高温高湿环境下7天样片表面无裂纹、表面无析出物。
具体实施方式
实施例1
本实施例提供一种棉织物整理剂，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：4份，聚芳醚砜酮改性树脂：40份，月桂酸：4份，氧化锌：8份，苯乙烯系弹性体：15份，复合阻燃剂：5份异丙醇：20份，增稠剂邻苯二甲酸二辛酯：3份，其中，
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：40份，聚芳醚砜酮：20份；
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
聚芳醚砜酮改性树脂制备方法具体操作如下：将聚芳醚砜酮与环氧树脂按1:2的比例混合，将混合物熔融制得预聚体PEK/EP, 熔融温度为280℃，然后将预聚体用粉末机打成粉末即得到聚芳醚砜酮改性树脂。
前述棉织物整理剂中，磷氮硅三元阻燃剂的制备：
（1）向装有冷凝管、滴液漏斗的三口烧瓶中通入氮气5min，依次加入磷酸和乙醇，将γ-（2,3-环氧丙氧基）丙基三甲氧硅烷逐滴加入，滴加速度控制在3g/min，在室温下反应3h；反应结束后，将三口烧瓶置于恒温水浴锅内，用旋转蒸发器减压蒸馏除去溶剂和低沸物，即得到磷硅二元阻燃剂。其中整个反应过程保持连续机械搅拌，搅拌速度为300r/min；
（2）在容器中加入磷硅二元阻燃剂和脲，室温下连续机械搅拌5min，得到磷氮硅三元阻燃剂。
本发明还涉及了一种棉织物整理剂的应用，具体包括以下步骤：将准备好的棉织物放在100℃的热水中预煮，然后捞出浸入整理剂中，浴比1:20，整理温度为70℃，整理时间20min，取出在70℃下哄10min，调节温度至100℃哄5min，在20℃的温水中皂洗，用0℃的水冲洗，最后在80℃下烘干即可处理。
实施例2
本实施例提供一种棉织物整理剂，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：9份，聚芳醚砜酮改性树脂：60份，月桂酸：7份，氧化锌：10份，苯乙烯系弹性体：18份，复合阻燃剂：9份异丙醇：30份，增稠剂邻苯二甲酸二辛酯：5份，其中，
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：70份，聚芳醚砜酮：35份；
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
聚芳醚砜酮改性树脂制备方法具体操作如下：将聚芳醚砜酮与环氧树脂按1:2的比例混合，将混合物熔融制得预聚体PEK/EP, 熔融温度为300℃，然后将预聚体用粉末机打成粉末即得到聚芳醚砜酮改性树脂。
前述棉织物整理剂中，磷氮硅三元阻燃剂的制备：
（1）向装有冷凝管、滴液漏斗的三口烧瓶中通入氮气8min，依次加入磷酸和乙醇，将γ-（2,3-环氧丙氧基）丙基三甲氧硅烷逐滴加入，滴加速度控制在5g/min，在室温下反应4h；反应结束后，将三口烧瓶置于恒温水浴锅内，用旋转蒸发器减压蒸馏除去溶剂和低沸物，即得到磷硅二元阻燃剂。其中整个反应过程保持连续机械搅拌，搅拌速度为400r/min；
（2）在容器中加入磷硅二元阻燃剂和脲，室温下连续机械搅拌10min，得到磷氮硅三元阻燃剂。
本发明还涉及了一种棉织物整理剂的应用，具体包括以下步骤：将准备好的棉织物放在100℃的热水中预煮，然后捞出浸入整理剂中，浴比1:20，整理温度为80℃，整理时间30min，取出在80℃下哄12min，调节温度至130℃哄8min，在30℃的温水中皂洗，用5℃的水冲洗，最后在90℃下烘干即可处理。
实施例3
本实施例提供一种棉织物整理剂，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：7份，聚芳醚砜酮改性树脂：50份，月桂酸：5份，氧化锌：9份，苯乙烯系弹性体：16份，复合阻燃剂：7份异丙醇：25份，增稠剂邻苯二甲酸二辛酯：4份，其中，
聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：60份，聚芳醚砜酮：25份；
复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
聚芳醚砜酮改性树脂制备方法具体操作如下：将聚芳醚砜酮与环氧树脂按1:2的比例混合，将混合物熔融制得预聚体PEK/EP, 熔融温度为290℃，然后将预聚体用粉末机打成粉末即得到聚芳醚砜酮改性树脂。
前述棉织物整理剂中，磷氮硅三元阻燃剂的制备：
（1）向装有冷凝管、滴液漏斗的三口烧瓶中通入氮气7min，依次加入磷酸和乙醇，将γ-（2,3-环氧丙氧基）丙基三甲氧硅烷逐滴加入，滴加速度控制在4g/min，在室温下反应4h；反应结束后，将三口烧瓶置于恒温水浴锅内，用旋转蒸发器减压蒸馏除去溶剂和低沸物，即得到磷硅二元阻燃剂。其中整个反应过程保持连续机械搅拌，搅拌速度为350r/min；
（2）在容器中加入磷硅二元阻燃剂和脲，室温下连续机械搅拌8min，得到磷氮硅三元阻燃剂。
本发明还涉及了一种棉织物整理剂的应用，具体包括以下步骤：将准备好的棉织物放在100℃的热水中预煮，然后捞出浸入整理剂中，浴比1:20，整理温度为75℃，整理时间25min，取出在75℃下哄11min，调节温度至120℃哄6min，在25℃的温水中皂洗，用3℃的水冲洗，最后在85℃下烘干即可处理。
除上述实施例外，本发明还可以有其他实施方式。凡采用等同替换或等效变换形成的技术方案，均落在本发明要求的保护范围。
Claims (6)
1.一种棉织物整理剂，其特征在于，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：4-9份，聚芳醚砜酮改性树脂：40-60份，月桂酸：4-7份，氧化锌：8-10份，苯乙烯系弹性体：15-18份，复合阻燃剂：5-9份异丙醇：20-30份，增稠剂邻苯二甲酸二辛酯：3-5份，其中，
所述的复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐；
所述聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：40-70份，聚芳醚砜酮：20-35份；
所述的聚芳醚砜酮改性树脂制备方法具体操作如下：将聚芳醚砜酮与环氧树脂按1:2的比例混合，将混合物熔融制得预聚体PEK/EP, 熔融温度为280-300℃，然后将预聚体用粉末机打成粉末即得到聚芳醚砜酮改性树脂。
2.根据权利要求1所述的棉织物整理剂，其特征在于，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：4份，聚芳醚砜酮改性树脂：40份，月桂酸：4份，氧化锌：8份，苯乙烯系弹性体：15份，复合阻燃剂：5份异丙醇：20份，增稠剂邻苯二甲酸二辛酯：3份，其中，
所述聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：40份，聚芳醚砜酮：20份；
所述的复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
3.根据权利要求1所述的棉织物整理剂，其特征在于，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：9份，聚芳醚砜酮改性树脂：60份，月桂酸：7份，氧化锌：10份，苯乙烯系弹性体：18份，复合阻燃剂：9份异丙醇：30份，增稠剂邻苯二甲酸二辛酯：5份，其中，
所述聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：70份，聚芳醚砜酮：35份；
所述的复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
4.根据权利要求1所述的棉织物整理剂，其特征在于，该整理剂按质量份数计包括以下组分：
烷基醇酰胺聚氧乙烷醚：7份，聚芳醚砜酮改性树脂：50份，月桂酸：5份，氧化锌：9份，苯乙烯系弹性体：16份，复合阻燃剂：7份异丙醇：25份，增稠剂邻苯二甲酸二辛酯：4份，其中，
所述聚芳醚砜酮改性树脂按质量份数计包括以下成分：环氧树脂：60份，聚芳醚砜酮：25份；
所述的复合阻燃剂为等比例混合的磷氮硅三元阻燃剂和三聚氰胺尿酸盐。
5.根据权利要求1所述的棉织物整理剂，其特征在于，所述磷氮硅三元阻燃剂的制备：
（1）向装有冷凝管、滴液漏斗的三口烧瓶中通入氮气5-8min，依次加入磷酸和乙醇，将γ-（2,3-环氧丙氧基）丙基三甲氧硅烷逐滴加入，滴加速度控制在3-5g/min，在室温下反应3-4h；反应结束后，将三口烧瓶置于恒温水浴锅内，用旋转蒸发器减压蒸馏除去溶剂和低沸物，即得到磷硅二元阻燃剂，
其中整个反应过程保持连续机械搅拌，搅拌速度为300-400r/min；
（2）在容器中加入磷硅二元阻燃剂和脲，室温下连续机械搅拌5-10min，得到磷氮硅三元阻燃剂。
6.如权利要求1所述的棉织物整理剂的应用，其特征在于，具体包括以下步骤：将准备好的棉织物放在100℃的热水中预煮，然后捞出浸入整理剂中，浴比1:20，整理温度为70-80℃，整理时间20-30min，取出在70-80℃下哄10-12min，调节温度至100-130℃哄5-8min，在20-30℃的温水中皂洗，用0-5℃的水冲洗，最后在80-90℃下烘干即可处理。
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Application publication date: 20170531 |