CN106757127A - For electrolysis water without spacing diaphragm cell - Google Patents
For electrolysis water without spacing diaphragm cell Download PDFInfo
- Publication number
- CN106757127A CN106757127A CN201510817643.XA CN201510817643A CN106757127A CN 106757127 A CN106757127 A CN 106757127A CN 201510817643 A CN201510817643 A CN 201510817643A CN 106757127 A CN106757127 A CN 106757127A
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- China
- Prior art keywords
- water
- anode
- negative electrode
- electrolysis
- diaphragm cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
- C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
It is a kind of for electrolysis water without spacing diaphragm cell, including at least one electrolyzer unit, each electrolyzer unit is separated into anode chamber and cathode chamber by cation-exchange membrane, anode conducting net is provided with anode chamber, negative electrode conductive mesh is provided with cathode chamber, anode conducting net is identical with the structure and composition of negative electrode conductive mesh, and the polyelectrolyte rolled into a ball by macromolecular material grafting sulfonic groups is made.The present invention due between electrolytic tank electrode without spacing, without spacing i.e. between electrode pad and amberplex, the conductive mesh for employing and can helping Ion transfer is added, water energy is enough flowed freely, being fully contacted between electrode, amberplex is ensure that again, substantially increases electrolytic efficiency.Can be with Direct Electrolysis pure water, it is possible to subnormal voltage operation.
Description
Technical field
The present invention relates to electrolysis tech, it is more particularly to a kind of for electrolysis water without spacing diaphragm cell.
Background technology
Hydrogen is prepared by electrolysis water and oxygen is widely known in this area, and what existing electrolytic cell was generally used
It is the electrolytic cell of barrier film style, has certain spacing between the electrode and barrier film of electrolytic cell, causes electrolytic bath voltage
Raise, electrolytic efficiency is low, the problems such as electrolyzer temperature is high.
How electrolytic efficiency that electrolysis water prepare hydrogen and oxygen is improved, and reducing energy consumption reduces electrolytic cell caloric value,
It is that electrolysis water prepares hydrogen and oxygen problem in the urgent need to address.
The content of the invention
The purpose of the present invention, exactly in order to solve the above problems, there is provided a kind of electric without spacing barrier film for electrolysis water
Solution groove.
In order to achieve the above object, present invention employs following technical scheme：It is a kind of for electrolysis water without spacing every
Membrane electrolysis cells, including at least one electrolyzer unit, each electrolyzer unit are separated into anode by cation-exchange membrane
Room and cathode chamber, are provided with anode conducting net in anode chamber, and negative electrode conductive mesh, anode conducting are provided with cathode chamber
Net is identical with the structure and composition of negative electrode conductive mesh, by the polyelectrolyte that macromolecular material grafting sulfonic groups are rolled into a ball
It is made.
The anode chamber includes closely coupled anode frame and anode water guide frame, and positive plate is embedded with anode frame,
Anode conducting net is embedded with anode water guide inframe, with a chromatography oxygen coating on the positive plate.
Inlet opening and the apopore of anode chamber are correspondingly provided with the anode frame and anode water guide frame.
The cathode chamber includes closely coupled negative electrode frame and negative electrode water guide frame, and minus plate is embedded with negative electrode inframe,
Negative electrode conductive mesh is embedded with negative electrode water guide inframe, with a chromatography hydrogen coating on the minus plate.
Inlet opening and the apopore of cathode chamber are correspondingly provided with the negative electrode frame and negative electrode water guide frame.
Described cation-exchange membrane is the cation-exchange membrane of macromolecular material grafting sulfonic groups group.
The macromolecular material includes fluoro-containing macromolecule material.
The thickness of described cation-exchange membrane is 0.15-0.25 millimeters, and resistance is 5 ohm-sqs centimetre, explosion
Intensity is more than 5 kg/cms.
Also include upper head plate and bottom plate, at least one electrolyzer unit is clamped and is connected to form by upper head plate and bottom plate
Electrolytic cell.
Two water inlets, acid water/oxygen outlet, alkaline water/hydrogen outlet, anode connection are provided with bottom plate
Post and cathode terminal；Two water inlets distinguish the inlet opening of jointed anode room and the inlet opening of cathode chamber, acid water
/ oxygen outlet jointed anode room apopore, alkaline water/hydrogen outlet connection cathode chamber apopore；Anode terminal connects
Connect positive plate, cathode terminal connection minus plate.
The present invention makes it compared with prior art as a result of above technical scheme, has the following advantages that and special
Point：
1st, due between electrolytic tank electrode without between spacing, i.e. electrode pad and amberplex without spacing.Add
The conductive mesh that can help Ion transfer is employed, water energy is enough flowed freely, electrode, ion exchange are ensure that again
Being fully contacted between film, substantially increases electrolytic efficiency.
2nd, pure water Direct Electrolysis into high-purity can be made with Direct Electrolysis pure water, more than pure water conductance 20uS/cm
Hydrogen and oxygen, because the electrical conductivity of pure water is very low, resistance is big, and pure water cannot be entered using traditional electrolysis tech
Row Direct Electrolysis produce hydrogen or oxygen gas, it is necessary to add electrolyte, the decomposition voltage of water only has 1.23V in theory, but
It is to realize in actual application.
3rd, can be with subnormal voltage operation：Working voltage can be reduced using without spacing cell technologies, due to pure water electricity
Resistance it is very big, it is necessary to applied voltage it is just high, using traditional electrolyte groove technique, even if decomposition voltage 24V-36V
It is difficult to pure water is electrolyzed to produce oxyhydrogen, because applied voltage is high, the temperature of electrolytic cell is raised very greatly, and energy consumption is very big,
Cannot be economical produce hydrogen or oxygen gas, after without spacing cell technologies, decomposition voltage can be in 6V or so
Electrolytic tank electrolysis can just be started, decomposition voltage can be as needed adjusted, it is ensured that the gas output of stabilization.
It is of the invention to can be applied to following field without spacing diaphragm cell：
1：Aerospace field
We are it is equally known that be non-existent in space oxygen, our space station, spacefarer needs in space
Live, it is necessary to oxygen sustains life, but from earth upper band oxygen cylinder to space, its cost is very high, and
Limited amount, it is many that relatively electric acquisition is easy for, it is possible to use solar energy a, kg of water can be electrolysed out 670
The oxygen for rising or so, it is ensured that people demand more than a day.
2：High altitude anoxia
There is wide highlands in China, people live in highlands, work, tourism, due to highlands
The reason for height above sea level, rarefaction of air influences the normal work life of people, but there is water highlands, there is electricity,
The oxygen deficiency problem of local space can be solved, improves local environment.
3：Personal oxygen uptake
Requirement with people to quality of life is improved constantly, aging population, tourist industry, the hair of mountaineering
Exhibition, the increase in demand of personal oxygen uptake problem.Using traditional oxygen bag due to being limited by dress amount of oxygen, it is impossible to
Supply for a long time, air segregative line can only be used as Emergency use, personal oxygen breathing device currently on the market
System, physical separation concentration is carried out using the requirement in air, and volume is big, and purity is low, using without spacing diaphragm electrolysis
Purewater Technique, can solve the problems, such as personal oxygen uptake with very comfortable, can be continuous without too big equipment and weight
Oxygen uptake needs, and by our experiment, including battery or power supply, integral device can be at 3-4 kilograms.
4：The energy-saving and emission-reduction in automobile burning field
According to Peking University, the systems theory research of Beijing University of Technology, hydrogen or oxygen gas in the work of internal combustion engine,
The efficiency of combustion of internal combustion engine can be provided after a small amount of hydrogen or oxygen gas of addition, discharge is reduced, fuel is saved, this is
China is currently in order to improve air quality, the major policy of reduction pollutant emission is electric without spacing barrier film by using
Solution technology, can produce pure water electrolysis the principle of hydrogen or oxygen gas, and traditional addition electrolyte phase to compare, to vapour
The operation of car engine is more safe and reliable, can be that the energy-saving and emission-reduction of China are contributed.
5：Daily life field
A；Electrolysis alkaline water
Electrolysis alkaline water is drunk in last century this proposition of doomsday has very big benefit to the health of the mankind, our countries in
The item industry standard of correlation is proposed within 2007, but our national existing electrolysis water manufacturing enterprises are all extremely difficult to
A grades of product standard of the item industry standard of wetting system is electrolysed, only Japanese original product can reach, and price is for we
Several trainings of home brands, its reason is exactly cell technologies, by the experiment of our a period of times, using continuously
Away from electrolysis tech, pure water (RO technologies, pure water of the electrical conductivity below 50) easily very can be electrolyzed to produce pH10
Alkaline water above, the negative potential of alkaline water can reach more than 500mV.And all using domestic oneself product
The amberplex and conductive mesh of board, it is not necessary to using the expensive amberplex from the U.S., Japanese import
Material.Created conditions to create domestic independent brand.
Because using without spacing Diaphragm Electrolysis Technology, the electrolytic cell that the tank voltage of operation is relatively Japanese is lower, reduces
The caloric value of electrolytic cell, saving energy consumption improves operational efficiency, increases service life, meets China's electrolysis water
The PH indexs and current potential index of industry standard, decomposition voltage only need to 6-12V or so.
B：Produce industrial strong alkaline water
Our human survivals advocate low-carbon (LC), environmentally friendly, the developing policy of energy-conservation, and we are in industrial production, people at present
Daily life be unable to do without cleaning agent, be commonly called as surfactant, its pollution to environment be very it is serious it is annual I
The consumption of state-owned millions of tons of Betengent product, using without spacing Diaphragm Electrolysis Technology, in addition and its a small amount of
In the case of inorganic salts, can be with the strong electrolysis water for reaching more than pH12.5 of very comfortable.And decomposition voltage can
To be reduced to 6V or so.Energy consumption is greatly reduced, electrolytic efficiency is improved, reduces volume.Negative electricity can be produced
The strong basicity electrolysis water with very strong dirt-removing power of position more than 300mv, is that the enhancement of environment of China contributes.
Brief description of the drawings
Fig. 1 is general structure schematic diagram without spacing diaphragm cell of the present invention for electrolysis water.
Fig. 2 is the cross section structure diagram of Fig. 1.
Fig. 3 is the decomposition texture schematic diagram of Fig. 1.
Fig. 4 is use state schematic diagram of the invention.
Specific embodiment
Referring to Fig. 1, Fig. 2, Fig. 3, the present invention for electrolysis water without spacing diaphragm cell, by upper head plate 1
At least one electrolyzer unit is clamped with bottom plate 2 is connected to form.The electrolyzer unit passes through cation-exchange membrane
7 are separated into anode chamber and cathode chamber, and anode conducting net is provided with anode chamber, negative electrode are provided with cathode chamber conductive
Net, anode conducting net is identical with the structure and composition of negative electrode conductive mesh, is rolled into a ball by macromolecular material grafting sulfonic groups
Polyelectrolyte is made.
Referring to Fig. 2, Fig. 3, the anode chamber in the present invention includes closely coupled anode frame 4 and anode water guide frame 5,
Positive plate 3 is embedded with anode frame 4, anode conducting net 6 is embedded with anode water guide frame 5, in positive plate
It is upper to chromatograph oxygen coating with one.Inlet opening and the water outlet of anode chamber are correspondingly provided with anode frame and anode water guide frame
Hole.
Referring to Fig. 2, Fig. 3, the cathode chamber in the present invention includes closely coupled negative electrode frame 9 and negative electrode water guide frame 8,
Minus plate 11 is embedded with negative electrode frame 9, negative electrode conductive mesh 10 is embedded with negative electrode water guide frame 8, in negative electrode
With a chromatography hydrogen coating on plate.Inlet opening and the water outlet of cathode chamber are correspondingly provided with negative electrode frame and negative electrode water guide frame
Hole.
Cation-exchange membrane in the present invention is the cation-exchange membrane of macromolecular material grafting sulfonic groups group, macromolecule
Material includes fluoro-containing macromolecule material.The thickness of cation-exchange membrane be 0.15-0.25 millimeter, resistance for 5 ohm/
Square centimeter, burst strength is more than 5 kg/cms.
Coordinate referring to Fig. 1, Fig. 4, two water inlets 21,22, acid water/oxygen outlet are provided with bottom plate 2
23rd, alkaline water/hydrogen outlet 24, anode terminal 25 and cathode terminal 26；Two water inlets are connected respectively
The inlet opening of anode chamber and the inlet opening of cathode chamber, acid water/oxygen outlet jointed anode room apopore, alkaline water/
Hydrogen outlet connects cathode chamber apopore；Anode terminal jointed anode plate, cathode terminal connection minus plate.
Positive plate, minus plate in the present invention are the middle metal coating plates with location hole, surrounding or are carried up and down
Locating slot, it is ensured that the position of electrode assembling is correctly, in place.
Anode frame, negative electrode frame in the present invention are with the electrode frame of macromolecular material compression molding, if around having solid
Fixed fixing hole, and have paddle hole.
Water guide frame in the present invention is the water guide frame for using macromolecular material compression molding, around there is some fixations
Fixing hole and paddle hole.
Conductive mesh in the present invention is the macromolecule conducting material rolled into a ball by grafting sulfonic groups by macromolecular material, in net
Shape structure, conductive mesh constitutes the water guide layer of cathode chamber or anode chamber simultaneously, is conducive to the flowing of water to radiate.
Cation-exchange membrane in the present invention is handed over from the sulfonic group cation of fluorine-based material or organic polymer base material
Change film, thickness 0.15-0.25 millimeters, ion film resistance：5 ohm-sqs centimetre.Burst strength is more than 5 kilograms
/ square centimeter.
Bottom plate in the present invention around has the insulated column of some stationary electrolysis grooves by high molecule plastic compression molding
Son, for stationary electrolysis groove, it is ensured that the uniformity of electrolytic cell, standard, bottom plate also has four paddle holes,
For the circulation of cell bath, bottom plate also has two electrode interfaces, for the electrode connection of electrolytic cell.
Upper head plate in the present invention has the fixing hole of stationary electrolysis groove above by high molecule plastic compression molding, is used for
Stationary electrolysis groove.
The following is two Application Examples, its installation diagram is as shown in Figure 4.
Embodiment 1：
Assembling one by three positive plates, three anode frames, six weather boards, two minus plates, two negative electrode frames,
Six conductive mesh, four cation-exchange membranes, the electrolytic cell of upper and lower end plate assembling, every piece of area of electrode 25 is flat
Square centimetre, the pure water that water inlet is processed using counter-infiltration (RO water), conductive 20Us/cm. is in applied voltage 8V
Under conditions of, 1 liter per minute of alkaline water, the electrolysis water of generation, alkaline water pH reaches 9.5-10, acid water pH5
Hereinafter, this fully proves efficiency of the electrolytic efficiency without spacing electrolytic cell far above plain electrolysers,
Embodiment 2
Assembling one by five positive plates, five anode frames, ten weather boards, four minus plates, four negative electrode frames,
Eight cation-exchange membranes, ten conductive mesh, the electrolytic cell of upper and lower end plate assembling, every piece of area of electrode 35 is flat
Square centimetre, the pure water that water inlet is processed using counter-infiltration (RO water), conductive 20Us/cm. is in applied voltage 10-20V
Under conditions of, electric current 20-22 amperes.Using water circulating pump, intake from the water inlet of bottom plate, anode chamber's water outlet
Mouth enters oxygen steam-water separator, and cathode chamber delivery port enters hydrogen steam-water separator, can produce 30 liters of oxygen
Gas and 60 liters of hydrogen.
Claims (10)
1. it is a kind of for electrolysis water without spacing diaphragm cell, it is characterised in that：Including at least one electrolytic cell
Unit, each electrolyzer unit is separated into anode chamber and cathode chamber by cation-exchange membrane, and sun is provided with anode chamber
Pole conductive mesh, is provided with the structure and composition phase of negative electrode conductive mesh, anode conducting net and negative electrode conductive mesh in cathode chamber
Together, the polyelectrolyte rolled into a ball by macromolecular material grafting sulfonic groups is made.
2. as claimed in claim 1 for electrolysis water without spacing diaphragm cell, it is characterised in that：It is described
Anode chamber includes closely coupled anode frame and anode water guide frame, and positive plate is embedded with anode frame, is led in anode
Water inframe is embedded with anode conducting net, with a chromatography oxygen coating on the positive plate.
3. as claimed in claim 2 for electrolysis water without spacing diaphragm cell, it is characterised in that：It is described
Inlet opening and the apopore of anode chamber are correspondingly provided with anode frame and anode water guide frame.
4. as claimed in claim 1 for electrolysis water without spacing diaphragm cell, it is characterised in that：It is described
Cathode chamber includes closely coupled negative electrode frame and negative electrode water guide frame, and minus plate is embedded with negative electrode inframe, is led in negative electrode
Water inframe is embedded with negative electrode conductive mesh, with a chromatography hydrogen coating on the minus plate.
5. as claimed in claim 4 for electrolysis water without spacing diaphragm cell, it is characterised in that：It is described
Inlet opening and the apopore of cathode chamber are correspondingly provided with negative electrode frame and negative electrode water guide frame.
6. as claimed in claim 1 for electrolysis water without spacing diaphragm cell, it is characterised in that：It is described
Cation-exchange membrane be macromolecular material grafting sulfonic groups group cation-exchange membrane.
7. as claimed in claim 6 for electrolysis water without spacing diaphragm cell, it is characterised in that：It is described
Macromolecular material includes fluoro-containing macromolecule material.
8. as claimed in claims 6 or 7 for electrolysis water without spacing diaphragm cell, it is characterised in that：
The thickness of described cation-exchange membrane is 0.15-0.25 millimeters, and resistance is 5 ohm-sqs centimetre, burst strength
More than 5 kg/cms.
9. as claimed in claim 1 for electrolysis water without spacing diaphragm cell, it is characterised in that：Also wrap
Upper head plate and bottom plate are included, at least one electrolyzer unit is clamped and is connected to form electrolytic cell by upper head plate and bottom plate.
10. as claimed in claim 9 for electrolysis water without spacing diaphragm cell, it is characterised in that：Under
End plate is provided with two water inlets, acid water/oxygen outlet, alkaline water/hydrogen outlet, anode terminal and negative electrode
Binding post；Two water inlets distinguish the inlet opening of jointed anode room and the inlet opening of cathode chamber, and acid water/oxygen goes out
Mouth jointed anode room apopore, alkaline water/hydrogen outlet connection cathode chamber apopore；Anode terminal jointed anode
Plate, cathode terminal connection minus plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510817643.XA CN106757127A (en) | 2015-11-23 | 2015-11-23 | For electrolysis water without spacing diaphragm cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510817643.XA CN106757127A (en) | 2015-11-23 | 2015-11-23 | For electrolysis water without spacing diaphragm cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106757127A true CN106757127A (en) | 2017-05-31 |
Family
ID=58962971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510817643.XA Pending CN106757127A (en) | 2015-11-23 | 2015-11-23 | For electrolysis water without spacing diaphragm cell |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106757127A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109354132A (en) * | 2018-12-03 | 2019-02-19 | 刘新志 | Pure apparatus for electrolyzing and electrolysis barrel water drinking machine |
| CN110279923A (en) * | 2019-07-15 | 2019-09-27 | 许昌百昌纳米科技有限公司 | A kind of overturning-preventing intelligence hydrogen ventilator |
| CN110862125A (en) * | 2019-11-01 | 2020-03-06 | 杨国锋 | Small-sized water electrolysis device and system thereof |
| WO2024067611A1 (en) * | 2022-09-30 | 2024-04-04 | 青岛海尔电冰箱有限公司 | Cathode for oxygen treatment apparatus and refrigerator |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4605482A (en) * | 1981-04-28 | 1986-08-12 | Asahi Glass Company, Ltd. | Filter press type electrolytic cell |
| US4666574A (en) * | 1979-11-27 | 1987-05-19 | Asahi Glass Company, Ltd. | Ion exchange membrane cell and electrolytic process using thereof |
| JPH02259090A (en) * | 1989-03-31 | 1990-10-19 | Sasakura Eng Co Ltd | Production of ozone by electrolysis |
| CN205295488U (en) * | 2015-11-23 | 2016-06-08 | 上海好旭新能源科技发展有限公司 | A continuously apart from diaphragm electrolysis groove for brineelectrolysis |
-
2015
- 2015-11-23 CN CN201510817643.XA patent/CN106757127A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4666574A (en) * | 1979-11-27 | 1987-05-19 | Asahi Glass Company, Ltd. | Ion exchange membrane cell and electrolytic process using thereof |
| US4605482A (en) * | 1981-04-28 | 1986-08-12 | Asahi Glass Company, Ltd. | Filter press type electrolytic cell |
| JPH02259090A (en) * | 1989-03-31 | 1990-10-19 | Sasakura Eng Co Ltd | Production of ozone by electrolysis |
| CN205295488U (en) * | 2015-11-23 | 2016-06-08 | 上海好旭新能源科技发展有限公司 | A continuously apart from diaphragm electrolysis groove for brineelectrolysis |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109354132A (en) * | 2018-12-03 | 2019-02-19 | 刘新志 | Pure apparatus for electrolyzing and electrolysis barrel water drinking machine |
| CN110279923A (en) * | 2019-07-15 | 2019-09-27 | 许昌百昌纳米科技有限公司 | A kind of overturning-preventing intelligence hydrogen ventilator |
| CN110862125A (en) * | 2019-11-01 | 2020-03-06 | 杨国锋 | Small-sized water electrolysis device and system thereof |
| WO2024067611A1 (en) * | 2022-09-30 | 2024-04-04 | 青岛海尔电冰箱有限公司 | Cathode for oxygen treatment apparatus and refrigerator |
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