CN106753077B - The preparation method of painting canvas patch - Google Patents
The preparation method of painting canvas patch Download PDFInfo
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- CN106753077B CN106753077B CN201611078357.7A CN201611078357A CN106753077B CN 106753077 B CN106753077 B CN 106753077B CN 201611078357 A CN201611078357 A CN 201611078357A CN 106753077 B CN106753077 B CN 106753077B
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- Prior art keywords
- painting canvas
- adhesive sticker
- preparation
- back side
- backing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D3/00—Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
- B44D3/18—Boards or sheets with surfaces prepared for painting or drawing pictures; Stretching frames for canvases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
A kind of painting canvas patch, it is characterised in that the adhesive sticker including painting canvas and coated on the painting canvas back side, the thickening of addition thickener is made the adhesive sticker by obtaining suspension after filtering, then in suspension by microballoon lotion.The invention also discloses the preparation methods of painting canvas patch.Compared with prior art, the present invention has the advantages that the adhesive sticker that microballoon lotion is made into, due to containing microspheroidal structure, so that the binding force that the spherical surface of each pressure sensitive adhesive microballoon is centripetal by one, simultaneously because of the fixed function of bottom surface adherend, keep each microballoon immovable in a certain range deformation, therefore, even under long-term pressure effect, both it had been able to achieve and had suitably been bonded with adherend, will not occur may be implemented to paste repeatedly with adherend intimate surface contact and the case where be detached from substrate.
Description
Technical field
The present invention relates to the painting canvas that one kind can paste, the present invention also relates to the preparation method of this kind of painting canvas.
Background technique
Polyacrylate pressure sensitive adhesive is typically all acrylic acid (ester) copolymer, this kind of pressure sensitive adhesive usually have it is following these
Feature: 1. formula is simple, does not add the auxiliary agents such as anti-aging agent, tackifying resin, softening agent generally；2. it is wider to be bonded range, to big portion
Polarity material surface or porous material surface all have good adhesive property, such as metal, cement, paper, timber, ceramics
Deng.Also have to the plastics such as polyvinyl chloride, polyester, polystyrene and polyolefin through sided corona treatment and fiber simultaneously good viscous
Connect performance.3. good weatherability, no matter indoors or outdoor long-term since acrylate copolymer does not contain carbon-carbon double bond
Using good adhesive property can be kept；4. low toxicity is nontoxic, medical and hygiene article can be used for directly as package packing supplies
And the outer packing of food.
Traditional glue product is that glue is completely covered on to substrate surface, the side that glue product and adherend are bonded with face
Formula bonding.Therefore, with when being stripped object removing two kinds of situations often occur for glue product: first is that glue remains in adherend table
Face, second is that part adherend is transferred to glue surface.Both of these case declines glue product adhesive property after pasting repeatedly.
In addition, not developing a kind of glue for being specifically adapted to painting canvas stickup, in other words existing market in the prior art yet
The painting canvas that can have paste functionality was not seen also.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of painting canvas of suitable stickup for the above-mentioned state of the art
Patch.
Another technical problem to be solved by this invention is to provide a kind of preparation side of painting canvas patch that can be pasted repeatedly
Method.
The technical scheme of the invention to solve the technical problem is: a kind of painting canvas patch, it is characterised in that including drawing
Cloth and adhesive sticker coated on the painting canvas back side, the adhesive sticker by microballoon lotion by obtaining suspension after filtering, then in suspension
The thickening of middle addition thickener is made, also, aforementioned microsphere lotion includes that component and its weight proportion are as follows:
Isooctyl acrylate monomer 2-EHA 65~90%
Methyl methacrylate MMA 4~25%
Acrylic acid AA 4~20%
- 1788 PVA-1788 2~6% of polyvinyl alcohol
Benzoyl peroxide BPO 0.5~2%
Acetoacetoxyethyl methacrylate AAEM 3~10%
Glycidyl methacrylate GMA 0.1~2%
Hydroxy-ethyl acrylate 2-HEA 1~6%.
As best, the component and its weight proportion of the microballoon lotion are as follows:
Isooctyl acrylate monomer 78%
Methyl methacrylate 5%
Acrylic acid 4%
Polyvinyl alcohol -1,788 3.8%
Benzoyl peroxide 0.7%
Acetoacetoxyethyl methacrylate 5.2%
Glycidyl methacrylate 0.1%
Hydroxy-ethyl acrylate 3.2%.
Preferably, the thickener additive amount is the 0.5~10% of microballoon lotion weight, also, after thickener addition
Measuring viscosity with NDJ type viscosimeter is 5000~8500mPa.s.
Preferably, the thickener be Zhejiang Province Chuanhua Co., Ltd production model TF312, TF312A,
TF312B or TF312C, or be cellulose thickener.
Further, the back side of the adhesive sticker is also covered with backing.
A kind of preparation method of painting canvas patch, includes the following steps:
1. the preparation of microballoon lotion:
By Isooctyl acrylate monomer, methyl methacrylate, hydroxy-ethyl acrylate, acrylic acid and methacrylic acid acetoacetyl
Oxygroup ethyl ester is mixed and stirred for, and forms dispersed phase；
Deionized water and polyvinyl alcohol -1788 are mixed, water temperature rises to 30-95 DEG C, 5~25min is dissolved, to sufficiently dissolve
After be cooled to 25~65 DEG C after above-mentioned dispersed phase is added, at a temperature of 25-65 DEG C disperse 20min-60min after be warming up to 70-90
DEG C, mixing speed 300-500rpm leads to nitrogen and reacts 5-10h, is then cooled to 30-60 DEG C of discharging, polyvinyl alcohol 1788 and
The mass ratio of deionized water is 1.:2~1:6；
2. obtaining suspension after thickening above-mentioned microballoon lotion filtering, adhesive sticker is obtained；
3. adhesive sticker is coated on the painting canvas back side.
It further, further include 4. step covers backing at the back side of adhesive sticker.
Step 3. described in coating operation it is as follows: adhesive sticker is uniformly applied to bar spreader coated processed
The painting canvas back side；Step 4. described in adhesive sticker the back side covering backing operation it is as follows: backing is laid on adhesive sticker,
It is bonded uniformly with hand, is placed on 2~20min in 50~90 DEG C of baking ovens and takes out.This is by having been manually done.
Step 3. described in coating operation and step 4. adhesive sticker the back side covering backing operation it is as follows:
It is coated using coating machine, the mode of blade coating is selected to produce, blade coating knife and coating wheel angle are 45-60 °, are led to
It crosses scraper angle, adhesive sticker and is uniformly coated on the painting canvas back side through scraper, open gap between pressure roll and rubber rollers, use double-sided adhesive
Band cements backing with the painting canvas for being painted with adhesive sticker, and backing and the painting canvas for being painted with adhesive sticker pass through pressure roll and three groups of extraction wheels,
Pressure roll leads to 30~80 DEG C of warm water, and pressure is 2~15kgf, and matched rubber rollers lead to 16~25 DEG C of cold water, and drawing is temperature after taking turns
It is set as the drying tunnel of 50~90 DEG C of 15~30m long, coating machine speed is set as 3~10m/min, then cold by 2~10 groups
But take turns, cooling wheel leads to 16~25 DEG C of cold water, finally use surface winder or central coiling machine, winding drawing tension be 15~
30N。
Compared with the prior art, the advantages of the present invention are as follows: the adhesive sticker that microballoon lotion is made into, due to containing microspheroidal knot
Structure, so that the binding force that the spherical surface of each pressure sensitive adhesive microballoon is centripetal by one, while because of the fixed function of bottom surface adherend,
Keep each microballoon immovable in a certain range deformation, therefore, even being both able to achieve under long-term pressure effect
It is suitably bonded with adherend, will not occur may be implemented repeatedly with adherend intimate surface contact and the case where be detached from substrate
It pastes, particularly suitable in the stickup of painting canvas.
Detailed description of the invention
Fig. 1 is to make schematic diagram in embodiment 2.
Specific embodiment
Below in conjunction with drawings and examples, present invention is further described in detail.
Embodiment 1, the preparation method of painting canvas patch includes the following steps: in the present embodiment
1. the preparation of microballoon lotion:
By Isooctyl acrylate monomer, methyl methacrylate, hydroxy-ethyl acrylate, acrylic acid and methacrylic acid acetoacetyl
Oxygroup ethyl ester is mixed and stirred for, and forms dispersed phase；
Deionized water and polyvinyl alcohol -1788 are mixed, water temperature rises to 30-95 DEG C, 5~25min is dissolved, to sufficiently dissolve
After be cooled to 25~65 DEG C after above-mentioned dispersed phase is added, at a temperature of 25-65 DEG C disperse 20min-60min after be warming up to 70-90
DEG C mixing speed is that 300-500rpm leads to nitrogen and reacts 5~10h, is then cooled to 30-60 DEG C of discharging, polyvinyl alcohol 1788 with go
The mass ratio of ionized water is 1.:2~1:6；
2. obtaining suspension after thickening above-mentioned microballoon lotion filtering, adhesive sticker is obtained；
3. adhesive sticker is coated on the painting canvas back side；Using craft, adhesive sticker is uniformly applied to using bar spreader through
The painting canvas back side that coating process is crossed；
4. covering backing at the back side of adhesive sticker, backing is laid on adhesive sticker, is bonded uniformly with hand, is placed on 83
5min takes out in DEG C baking oven.
Microballoon lotion includes that component and its weight proportion are as follows:
Isooctyl acrylate monomer 78%
Methyl methacrylate 5%
Acrylic acid 4%
Polyvinyl alcohol -1,788 3.8%
Benzoyl peroxide 0.7%
Acetoacetoxyethyl methacrylate 5.2%
Glycidyl methacrylate 0.1%
Hydroxy-ethyl acrylate 3.2%.
Thickener additive amount is the 0.5~10% of microballoon lotion weight, also, uses NDJ type viscosimeter after thickener addition
Measuring viscosity is 5000~8500mPa.s.Thickener is the model TF312 of Zhejiang Province Chuanhua Co., Ltd's production.
It can be release paper, PVC film, PET film etc. if backing, as the beautiful polyester film Co., Ltd of Yangzhou Yi Huadong
PET film thickness it is most thin can accomplish 0.011mm, the PVC film of Suzhou Hua Su plastics Co., Ltd can accomplish 0.05mm-
Between 0.5mm, pass through ROHS, REACH, the multinomial detection such as EN 71-3.
It is 4.5~7.2N/25MM that gained painting canvas, which pastes 180 ° of peel strengths, and repeating fissility is 4~6.8N/25MM.
Embodiment 2, coating operation in the present embodiment and as follows in the back side of adhesive sticker covering backing operation
The step of the present embodiment production of machinery, embodiment 1 describes, is directed to paste backing by hand, and bar spreader is manual
Coating adhesive sticker is limited in scope, and the effect of coating machine is not good yet the effect of coating, can be used for hand-made, is not suitable for big
Batch production.
In the present embodiment, the coverage mode of backing is: being coated with coating machine, selects the mode of blade coating to produce, scrape
It applies knife and coating wheel angle is 45-60 °, the painting canvas back side is uniformly coated on through scraper by scraper angle, adhesive sticker.Open pressure
Gap between roller and rubber rollers is cemented backing with the painting canvas for being painted with adhesive sticker with double faced adhesive tape, and double faced adhesive tape width 5cm is put down
Row is pasted in door width direction, and double-sided adhesive takes up fixed function, is facilitated backing and is painted with the painting canvas of adhesive sticker at pressure roll preferably
Compound, the tractive force of machine can be moved forward with composite material, so that the continuity of production is realized, by double-sided adhesive at winding
Bearing dismisses, and backing is generally 1-2cm longer than painting canvas door width, paste in this way flatness is preferable.
As shown in Figure 1, rubber rollers 1 are located above applicator roll 2, painting canvas is by their gaps, in 5 back side shape adhesive sticker of painting canvas
Layer 6, pressure roll 3 is located above rubber rollers 4, and composite material moves forward, and 7 materials of back are preferably compound in 6 back side of non-drying glue layer.
Backing in the present embodiment and the painting canvas of adhesive sticker is painted with by pressure roll and three groups of extraction wheels, pressure roll is 60 DEG C logical
Warm water, pressure 7kgf, matched rubber rollers lead to 23 DEG C of cold water, are set as the drying tunnel of 83 DEG C of 21m long after extraction wheel for temperature,
Coating machine speed is set as 4.2m/min, then passes through 6 groups of cooling wheels, and cooling wheel leads to 23 DEG C of cold water, finally uses surface winder
Or central coiling machine can be wound, winding drawing tension is 21N, and both economical finished door width is 1.5-2.05m.It is used
Painting canvas be also possible to print the painting canvas after pattern.Finished product: painting canvas+adhesive sticker+backing combination product can be cut out as needed
It cuts, pack.
Other step reference implementation examples 1.
It is 8.5N/25MM that gained painting canvas, which pastes 180 ° of peel strengths, and repeating fissility is 7.8N/25MM.
Embodiment 3, the microballoon lotion in the present embodiment includes that component and its weight proportion are as follows:
Isooctyl acrylate monomer 70%
Methyl methacrylate 15%
Acrylic acid 4%
Polyvinyl alcohol -1,788 3%
Benzoyl peroxide 1.1%
Acetoacetoxyethyl methacrylate 3.5%
Glycidyl methacrylate 0.6%
Hydroxy-ethyl acrylate 2.8%.
Other step reference implementation examples 2.
Claims (8)
1. a kind of preparation method of painting canvas patch, it is characterised in that painting canvas patch includes painting canvas and not doing coated on the painting canvas back side
Glue, by microballoon lotion, by obtaining suspension after filtering, then in suspension, the thickening of addition thickener is made the adhesive sticker, and
And aforementioned microsphere lotion includes that component and its weight proportion are as follows:
Isooctyl acrylate monomer 65~90%
Methyl methacrylate 4~25%
Acrylic acid 4~20%
Polyvinyl alcohol -1,788 2~6%
Benzoyl peroxide 0.5~2%
Acetoacetoxyethyl methacrylate 3~10%
Glycidyl methacrylate 0.1~2%
Hydroxy-ethyl acrylate 1~6%；
The sum of said combination is 100%；
Include the following steps:
1. the preparation of microballoon lotion:
By Isooctyl acrylate monomer, methyl methacrylate, glycidyl methacrylate, hydroxy-ethyl acrylate, acrylic acid and
Acetoacetoxyethyl methacrylate is mixed and stirred for, and forms dispersed phase；
Deionized water and polyvinyl alcohol -1788 are mixed, water temperature rises to 30-95 DEG C, 5~25min is dissolved, to drop after completely dissolution
Temperature is dispersed after 20min-60min to be warming up to 70-90 DEG C at a temperature of 25-65 DEG C and be stirred to above-mentioned dispersed phase is added after 25~65 DEG C
Mixing speed is that 300-500rpm leads to nitrogen reaction 5-10h, is then cooled to 30-60 DEG C of discharging, polyvinyl alcohol 1788 and deionization
The mass ratio of water is 1:2~1:6；
2. thickening the above-mentioned filtered suspension of microballoon lotion, adhesive sticker is obtained；
3. adhesive sticker is coated on the painting canvas back side.
2. preparation method according to claim 1, it is characterised in that the component and its weight proportion of the microballoon lotion are such as
Under:
Isooctyl acrylate monomer 78%
Methyl methacrylate 5%
Acrylic acid 4%
Polyvinyl alcohol -1,788 3.8%
Benzoyl peroxide 0.7%
Acetoacetoxyethyl methacrylate 5.2%
Glycidyl methacrylate 0.1%
Hydroxy-ethyl acrylate 3.2%.
3. preparation method according to claim 1, it is characterised in that the thickener additive amount is microballoon lotion weight
0.5~10%, also, measuring viscosity with NDJ type viscosimeter after thickener addition is 5000~8500mPa.s.
4. preparation method according to claim 3, it is characterised in that the thickener is Zhejiang Province Chuanhua Co., Ltd
Model TF312, TF312A, TF312B or TF312C of production, or be cellulose thickener.
5. preparation method according to claim 1, it is characterised in that the back side of the adhesive sticker is also covered with backing.
6. preparation method according to claim 1, it is characterised in that further include step 4. in the back side of adhesive sticker covering back
Material.
7. preparation method according to claim 6, it is characterised in that step 3. described in coating operation it is as follows: use bar
Adhesive sticker is uniformly applied to the coated processed painting canvas back side by spreader；
Step 4. described in adhesive sticker the back side covering backing operation it is as follows: backing is laid on adhesive sticker, with hand general
It is bonded uniformly, is placed on 2~20min in 50~90 DEG C of baking ovens and takes out.
8. preparation method according to claim 5 or 6, it is characterised in that step 3. described in coating operation and step 4.
It is as follows in the back side of adhesive sticker covering backing operation:
It is coated using coating machine, the mode of blade coating is selected to produce, blade coating knife and coating wheel angle are 45-60 °, by scraping
Nose angle degree, adhesive sticker are uniformly coated on the painting canvas back side through scraper, open gap between pressure roll and rubber rollers, will with double faced adhesive tape
Backing and the painting canvas for being painted with adhesive sticker cement, and backing and the painting canvas for being painted with adhesive sticker pass through pressure roll and three groups of extraction wheels, pressure
Roller leads to 30~80 DEG C of warm water, and pressure is 2~15kgf, and matched rubber rollers lead to 16~25 DEG C of cold water, sets after drawing wheel for temperature
For the drying tunnel of 50~90 DEG C of 15~30m long, coating machine speed is set as 3~10m/min, then passes through 2~10 groups of cooling wheels,
Cooling wheel leads to 16~25 DEG C of cold water, finally uses surface winder or central coiling machine, and winding drawing tension is 15~30N.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611078357.7A CN106753077B (en) | 2016-11-30 | 2016-11-30 | The preparation method of painting canvas patch |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611078357.7A CN106753077B (en) | 2016-11-30 | 2016-11-30 | The preparation method of painting canvas patch |
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| Publication Number | Publication Date |
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| CN106753077A CN106753077A (en) | 2017-05-31 |
| CN106753077B true CN106753077B (en) | 2019-11-26 |
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| CN201611078357.7A Active CN106753077B (en) | 2016-11-30 | 2016-11-30 | The preparation method of painting canvas patch |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111234726A (en) * | 2020-03-18 | 2020-06-05 | 安徽富印新材料有限公司 | Pressure-sensitive adhesive tape capable of being repeatedly pasted and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087658A (en) * | 2013-02-23 | 2013-05-08 | 福州福维胶粘剂有限公司 | Waterborne copolymer emulsion for canvas coatings and preparation method thereof |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
| CN105602487A (en) * | 2015-12-21 | 2016-05-25 | 福清宏宝化工有限公司 | Water-based adhesive and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN204432217U (en) * | 2015-01-12 | 2015-07-01 | 广东高璐美数码科技有限公司 | Structure is drawn in a kind of environmental protection repeatedly replaceable canvas frame |
-
2016
- 2016-11-30 CN CN201611078357.7A patent/CN106753077B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087658A (en) * | 2013-02-23 | 2013-05-08 | 福州福维胶粘剂有限公司 | Waterborne copolymer emulsion for canvas coatings and preparation method thereof |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
| CN105602487A (en) * | 2015-12-21 | 2016-05-25 | 福清宏宝化工有限公司 | Water-based adhesive and preparation method thereof |
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| CN106753077A (en) | 2017-05-31 |
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