CN105602487A - Water-based adhesive and preparation method thereof - Google Patents
Water-based adhesive and preparation method thereof Download PDFInfo
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- CN105602487A CN105602487A CN201510967006.0A CN201510967006A CN105602487A CN 105602487 A CN105602487 A CN 105602487A CN 201510967006 A CN201510967006 A CN 201510967006A CN 105602487 A CN105602487 A CN 105602487A
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- based adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention proposes a water-based adhesive and a preparation method thereof. The water-based adhesive is prepared from raw materials including acrylate monomers, acrylic acid and/or ester monomers. The preparation method comprises the steps of preparing pre-emulsion; preparing a seed; and performing a semi-continuous operation, wherein the pre-emulsion is prepared by preparing a backing material through an emulsifier, then adding the acrylate monomers, acrylic acid and/or the ester monomers, and stirring; seed emulsion is prepared by adding the part of pre-emulsion and a first catalyst for reaction based on another backing material; and in the semi-continuous operation, a second catalyst is completely dropwise added within 3-5 hours and a step-reaction is performed to prepare the water-based adhesive. The water-based adhesive prepared with the method not only has large viscous force, achieves a marking effect of a product in normal use and is unlikely to be peeled off, but also can be easily washed away only with water when needing to be washed.
Description
Technical field
The present invention relates to adhesive material field, be specifically related to a kind of water-based adhesive sticker and preparation method thereof.
Background technology
The adhesive sticker using on market now, easily sticks to body surface and incrust afterwards in use, causes the later stageCleaning difficulty.
Summary of the invention
For solving the problems of the technologies described above, the object of the invention is to propose a kind of water-based adhesive sticker and preparation method thereof, thisWater-based adhesive sticker not only has the good viscous force of holding, and meets mark action that product during normal use has and incrust,And in the time that cleaning, needs only need water cleaning just can wash away easily.
The technical scheme that water-based adhesive sticker of the present invention adopts is:
A kind of water-based adhesive sticker, it is by the raw material including acrylate monomer, acrylic acid and/or its ester monomerBe prepared from, its preparation method comprises the following steps:
S1. prepare pre-emulsion
In reaction vessel, the first emulsifying agent, with adding after the first hot water dissolving in the first deionized water, is dissolved completelyAfter make the first bed material, in the first bed material, first add acrylate monomer to dissolving completely, then add and described acrylateThe acrylic acid that monomer is different and/or its ester monomer, obtain pre-emulsion through stirring;
S2. prepare seed emulsion
1. the second emulsifying agent is made to the second bed material with adding after the second hot water dissolving in the second deionized water, stir and riseTemperature, to 75-80 DEG C, is added the pre-emulsion that quality percentage composition is 3%-8%;
2. in temperature is the scope of 70-75 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 15-35 minute, between the stage of reaction, heat up more than 5-10 DEG C;
S3. semicontinuous operation
4. in 2-3 hour, splash into residue pre-emulsion, temperature control is at 78-83 DEG C;
5. drip the second catalyst simultaneously, in 3-5 hour, drip off; After dropwising, enter insulation maturation stage, until burnIn bottle, backflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
It should be noted that, add the pre-emulsion that quality percentage composition is 3%-8% and refer to that interpolation accounts for the total matter of pre-emulsionThe pre-emulsion of amount percentage 3%-8%. Remaining pre-emulsion is the pre-emulsion of remaining 92%-97%.
Acrylic acid and/or its ester monomer refer to one or more that comprise acrylic monomers and acrylate monomer;Now the acrylate monomer in acrylic acid and/or its ester monomer is to be not identical list with the acrylate monomer first addingBody. The acrylate monomer for example first adding is methacrylate monomer, in the acrylic acid adding below and/or its ester monomerIf there is the acrylate monomer of adding, be that another or more than one are not all the monomers of methyl acrylate. Preferably, thirdOlefin(e) acid and/or its ester monomer comprise soft monomer, hard monomer and function monomer, and add according to this order. Described soft monomer is as thirdThe positive butyl ester of olefin(e) acid, isodecyl acrylate; Described hard monomer is as methyl methacrylate; Described function monomer is as acrylic acid, methylAcrylic acid.
Preferably, described acrylate monomer is methyl acrylate or ethyl acrylate; Described acrylic acid and/or itsEster monomer is n-butyl acrylate, Isooctyl acrylate monomer, isodecyl acrylate, methyl methacrylate, acrylic acid, metering systemTwo or more of acid.
Preferably, the first described emulsifying agent and the second described emulsifying agent are all anion emulsifiers.
Preferably, described anion emulsifier is lauryl sodium sulfate, special fatty alcohol ether sulphate or alkyl sulphurAcid sodium.
Preferably, the quality summation of the first emulsifying agent and the second emulsifying agent is acrylate monomer and acrylic acid and/or itsThe 2%-2.5% of ester monomer mass summation.
Preferably, the first described catalyst and the second described catalyst are mixing of initator and the 3rd deionized waterLiquid.
Preferably, the initator quality summation of the initator of the first catalyst and the second catalyst is acrylate monomer and propyleneThe 0.4%-0.5% of acid and/or its ester monomer mass summation; The quality summation of first, second, and third deionized water is propyleneThe 1.55-1.65 of acid ester monomer and acrylic acid and/or its ester monomer mass summation doubly.
Preferably, the mass ratio of the initator of the first catalyst and its 3rd deionized water is 1:10-1:15, the second catalystThe mass ratio of initator and its 3rd deionized water is 1:40-1:45.
Preferably, described initator is sodium peroxydisulfate, ammonium persulfate or potassium peroxydisulfate. Further initiator system of ammonium persulfate.Under test of many times, inventor find due to potassium peroxydisulfate water-soluble poor, initiating activity is higher, causes emulsion particle diameterGreatly, wider distribution. The emulsion system that sodium peroxydisulfate causes is more responsive to polymerizing condition, and its particle diameter and distribution fluctuates thereof are larger.And the particle size distribution of ammonium persulfate institute initiated polymerization is more stable and comparatively desirable.
The preparation method of water-based adhesive sticker of the present invention is to adopt the preparation method who relates in such scheme.
Also need again to illustrate, " first " of the present invention, " second ", " the 3rd " are only used to distinguish sameThe raw material of character, it is point raw materials of using several times same nature that those skilled in the art can be well understood to, its consumption canIdentical also can be different.
Compared with prior art, beneficial effect of the present invention is:
The prepared adhesive sticker of the present invention has water miscible feature, can repeatedly peel off and paste, initial bonding strength withHold viscous force and can reach the requirement as label; Product only needs water to clean in needing to clean after use just can be easilyWash away, very convenient;
The adhesive sticker that the present invention obtains has water-soluble preferably, can be used for cosmetics of everyday use, curable product, packaging for foodstuffLabel, has actual application and promotional value.
Detailed description of the invention
Further set forth the present invention below in conjunction with specific embodiment. These embodiment are only not used in for the present invention is describedLimit the scope of the invention. The experimental technique of unreceipted actual conditions in the following example, conventionally according to normal condition or according toThe condition of manufacturer's suggestion. Unless otherwise defined, all specialties that use in literary composition and scientific words and art technology peopleThe familiar meaning of member is identical.
Embodiment 1
Table 1
Containing scale (formula) as shown in Table 1, the preparation of water-based adhesive sticker comprises the following steps batching:
S1. prepare pre-emulsion
In reaction vessel, special fatty alcohol ether sulphate, with adding in deionized water after a small amount of hot water dissolving, is treatedAfter CL, first add methyl acrylate to dissolving completely, then add successively n-butyl acrylate, methyl methacrylate, thirdOlefin(e) acid, obtains pre-emulsion through stirring.
S2. prepare seed emulsion
1. by special fatty alcohol ether sulphate with adding after hot water dissolving in deionized water, stir and be warming up to 75 DEG C, addAdd quality percentage composition and be 4% pre-emulsion;
2. in the time that temperature is 70 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 20 minutes, heat up during this time 5 DEG C.
S3. semicontinuous operation
1. in 2 hours, splash into residue pre-emulsion, temperature control is at 78 DEG C;
2. drip the second catalyst, time for adding is 4 hours simultaneously. After dropwising, enter insulation maturation stage, until burnIn bottle, backflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
Embodiment 2
Table 2
Batching is containing scale (formula) as above shown in table 2, and the preparation of water-based adhesive sticker comprises the following steps:
S1. prepare pre-emulsion
In reaction vessel, lauryl sodium sulfate, with adding in deionized water after a small amount of hot water dissolving, is treated completely moltenXie Hou, first adds methyl acrylate to dissolving completely, then adds successively n-butyl acrylate, acrylic acid isooctyl, acrylic acid, warpCross to stir and obtain pre-emulsion.
S2. prepare seed emulsion
1. by lauryl sodium sulfate with adding after hot water dissolving in deionized water, stir and be warming up to 75 DEG C, add matterThe pre-emulsion that amount percentage composition is 5%;
2. in the time that temperature is 70 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 20 minutes, heat up during this time 7 DEG C.
S3. semicontinuous operation
1. in 2 hours, splash into residue pre-emulsion, temperature control is at 80 DEG C;
2. drip the second catalyst, time for adding is 4 hours simultaneously. After dropwising, enter insulation maturation stage, until burnIn bottle, backflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
Embodiment 3
Table 3
Batching is containing scale (formula) as above shown in table 3, and the preparation of water-based adhesive sticker comprises the following steps:
S1. prepare pre-emulsion
In reaction vessel, lauryl sodium sulfate, with adding in deionized water after a small amount of hot water dissolving, is treated completely moltenXie Hou, first adds ethyl acrylate to dissolving completely, then adds successively isodecyl acrylate, methyl methacrylate, acrylic acid,Obtain pre-emulsion through stirring.
S2. prepare seed emulsion
1. by lauryl sodium sulfate with adding after hot water dissolving in deionized water, stir and be warming up to 75 DEG C, add matterThe pre-emulsion that amount percentage composition is 6%;
2. in the time that temperature is 70 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 25 minutes, heat up during this time 8 DEG C.
S3. semicontinuous operation
1. in 2 hours, splash into residue pre-emulsion, temperature control is at 80 DEG C;
2. drip the second catalyst, time for adding is 5 hours simultaneously. After dropwising, enter insulation maturation stage, until burnIn bottle, backflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
Embodiment 4
Table 4
Batching is containing scale (formula) as above shown in table 4, and the preparation of water-based adhesive sticker comprises the following steps:
S1. prepare pre-emulsion
In reaction vessel, by sodium alkyl sulfonate with adding in deionized water after a small amount of hot water dissolving, until completely dissolved,First add ethyl acrylate to dissolving completely, then add successively acrylic acid isooctyl, methyl methacrylate, the positive fourth of acrylic acidEster, acrylic acid, obtain pre-emulsion through stirring.
S2. prepare seed emulsion
1. by sodium alkyl sulfonate with adding after hot water dissolving in deionized water, stir and be warming up to 75 DEG C, add quality hundredDivide the pre-emulsion that content is 7%;
2. in the time that temperature is 70 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 30 minutes, heat up during this time 8 DEG C.
S3. semicontinuous operation
1. in 3 hours, splash into residue pre-emulsion, temperature control is at 83 DEG C;
2. drip the second catalyst simultaneously, in 3 hours, drip off. After dropwising, enter insulation maturation stage, until flaskInterior backflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
Embodiment 5
Table 5
Batching is containing scale (formula) as above shown in table 5, and the preparation of water-based adhesive sticker comprises the following steps:
S1. prepare pre-emulsion
In reaction vessel, lauryl sodium sulfate, with adding in deionized water after a small amount of hot water dissolving, is treated completely moltenXie Hou, first adds methyl acrylate to dissolving completely, then adds successively acrylic acid isooctyl, methyl methacrylate, acrylic acidPositive butyl ester, acrylic acid, obtain pre-emulsion through stirring.
S2. prepare seed emulsion
1. by lauryl sodium sulfate with adding after hot water dissolving in deionized water, stir and be warming up to 75 DEG C, add matterThe pre-emulsion that amount percentage composition is 8%;
2. in the time that temperature is 70 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 35 minutes, heat up during this time 10 DEG C.
S3. semicontinuous operation
1. in 3 hours, splash into residue pre-emulsion, temperature control is at 83 DEG C;
2. drip the second catalyst simultaneously, in 3 hours, drip off. After dropwising, enter insulation maturation stage, until flaskInterior backflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
The adhesive sticker that embodiment 1-embodiment 5 is made is made adhesive label, tests the first sticky of adhesive labelPower with hold viscous force,
Adhesive label initial bonding strength is tested according to GB4852, JISZ0237 standard (pressure sensitive adhesive tape tack test sideMethod--rolling ball method) test;
Adhesive label is held viscous force test and is tested according to GB4851 (pressure-sensitive tape is held viscosity test method), surveysTest result sees the following form 6:
Table 6
| Tack/steel ball number | Hold viscosity/come off the time | |
| Embodiment 1 | 1 foot of steel ball | 10h |
| Embodiment 2 | 1 foot of steel ball | 10.2h |
| Embodiment 3 | 1 foot of steel ball | 10.3h |
| Embodiment 4 | 1 foot of steel ball | 10.5h |
| Embodiment 5 | 1 foot of steel ball | 10.2h |
As can be seen from Table 6, the prepared adhesive sticker of the present invention has water miscible feature, initial bonding strength with hold viscous force canReach the requirement as label, and its effect is very good, can repeatedly peels off and paste.
The adhesive sticker that embodiment 1-embodiment 5 is made is made adhesive label, uses after a period of time, clear with clear waterWash, test result is in table 7:
Table 7
As can be seen from Table 7, adhesive label water cleans and just can wash away rapidly easily, very convenient.
Listed a series of detailed description is above only for the illustrating of feasibility embodiment of the present invention,They are not in order to limit the scope of the invention, and allly do not depart from equivalent embodiment or the change that skill spirit of the present invention is doneWithin all should being included in protection scope of the present invention.
Claims (10)
1. a water-based adhesive sticker, is characterized in that, it is by comprising acrylate monomer, acrylic acid and/or its ester monomerBe prepared from interior raw material, its preparation method comprises the following steps:
S1. prepare pre-emulsion
In reaction vessel, the first emulsifying agent, with adding after the first hot water dissolving in the first deionized water, is made after dissolving completelyBecome the first bed material, in the first bed material, first add acrylate monomer to dissolving completely, then add and described acrylate monomerDifferent acrylic acid and/or its ester monomer, obtain pre-emulsion through stirring;
S2. prepare seed emulsion
1. the second emulsifying agent is made to the second bed material with adding after the second hot water dissolving in the second deionized water, stir and be warming up to75-80 DEG C, adds the pre-emulsion that quality percentage composition is 3%-8%;
2. in temperature is the scope of 70-75 DEG C, add the first catalyst, then carry out initial action by washed with de-ionized water;
3. react 15-35 minute, between the stage of reaction, heat up more than 5-10 DEG C;
S3. semicontinuous operation
4. in 2-3 hour, splash into residue pre-emulsion, temperature control is at 78-83 DEG C;
5. drip the second catalyst simultaneously, in 3-5 hour, drip off; After dropwising, enter insulation maturation stage, until in flaskBackflow phenomenon disappears substantially, and in flask, liquid level generates a soft film, stops reaction, cooling discharge.
2. water-based adhesive sticker according to claim 1, is characterized in that, described acrylate monomer is methyl acrylateOr ethyl acrylate; Described acrylic acid and/or its ester monomer are n-butyl acrylate, Isooctyl acrylate monomer, acrylic acid isodecylTwo or more of ester, methyl methacrylate, acrylic acid, methacrylic acid.
3. water-based adhesive sticker according to claim 2, is characterized in that, the first described emulsifying agent and the second described breastAgent is all anion emulsifiers.
4. water-based adhesive sticker according to claim 3, is characterized in that, described anion emulsifier is dodecyl sulphurAcid sodium, special fatty alcohol ether sulphate or sodium alkyl sulfonate.
5. water-based adhesive sticker according to claim 4, is characterized in that, the quality of the first emulsifying agent and the second emulsifying agent is totalWith the 2%-2.5% that is acrylate monomer and acrylic acid and/or its ester monomer mass summation.
6. water-based adhesive sticker according to claim 5, is characterized in that, the first described catalyst and the second described catalystBe the mixed liquor of initator and the 3rd deionized water.
7. water-based adhesive sticker according to claim 6, is characterized in that, the drawing of the initator of the first catalyst and the second catalystSending out agent quality summation is the 0.4%-0.5% of acrylate monomer and acrylic acid and/or its ester monomer mass summation; The first,The quality summation of the two and the 3rd deionized water is the 1.55-of acrylate monomer and acrylic acid and/or its ester monomer mass summation1.65 doubly.
8. water-based adhesive sticker according to claim 7, is characterized in that, the initator of the first catalyst and its 3rd deionizationThe mass ratio of water is 1:10-1:15, and the mass ratio of the initator of the second catalyst and its 3rd deionized water is 1:40-1:45.
9. water-based adhesive sticker according to claim 8, is characterized in that, described initator is sodium peroxydisulfate, persulfuric acidAmmonium or potassium peroxydisulfate.
10. a method of preparing the arbitrary described water-based adhesive sticker of claim 1-9, is characterized in that, it adopts describedPreparation method.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753077A (en) * | 2016-11-30 | 2017-05-31 | 宁波康大美术用品集团有限公司 | Painting canvas patch and preparation method thereof |
| CN107488423A (en) * | 2017-05-09 | 2017-12-19 | 温州市威利达皮革原料有限公司 | Paper adhesive sticker formula |
| CN108192534A (en) * | 2017-12-29 | 2018-06-22 | 上海金大塑胶有限公司 | A kind of novel Self-leveling adhesive material |
| CN108203572A (en) * | 2017-12-29 | 2018-06-26 | 上海金大塑胶有限公司 | A kind of preparation method of the aqueous adhesive sticker of Self-leveling |
| CN112442319A (en) * | 2019-08-27 | 2021-03-05 | 佛山胶力王科技有限公司 | Medical non-setting adhesive heat-sensitive production line |
| CN115819663A (en) * | 2022-11-28 | 2023-03-21 | 天津安达君胜科技有限公司 | Fixing agent for vacuum brazing and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1352223A (en) * | 2000-11-02 | 2002-06-05 | 福州大学 | New aqueous emulsion type paper-plastic composite adhesive and its preparing method |
| CN102533174A (en) * | 2011-12-07 | 2012-07-04 | 新丰杰力电工材料有限公司 | Emulsion type acrylate pressure sensitive adhesive and preparation method thereof |
| CN105037615A (en) * | 2015-09-10 | 2015-11-11 | 江苏国胶化学科技有限公司 | Production process of PSA adhesive sticker used for BOPP |
-
2015
- 2015-12-21 CN CN201510967006.0A patent/CN105602487B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1352223A (en) * | 2000-11-02 | 2002-06-05 | 福州大学 | New aqueous emulsion type paper-plastic composite adhesive and its preparing method |
| CN102533174A (en) * | 2011-12-07 | 2012-07-04 | 新丰杰力电工材料有限公司 | Emulsion type acrylate pressure sensitive adhesive and preparation method thereof |
| CN105037615A (en) * | 2015-09-10 | 2015-11-11 | 江苏国胶化学科技有限公司 | Production process of PSA adhesive sticker used for BOPP |
Non-Patent Citations (2)
| Title |
|---|
| 徐学峰 等: "水性丙烯酸酯纸塑复膜胶的制备及性能", 《塑料工业》 * |
| 王海霞: "碱溶性丙烯酸酯乳液啤酒贴标胶的合成及性能研究", 《中国胶粘剂》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753077A (en) * | 2016-11-30 | 2017-05-31 | 宁波康大美术用品集团有限公司 | Painting canvas patch and preparation method thereof |
| CN106753077B (en) * | 2016-11-30 | 2019-11-26 | 宁波康大美术用品集团有限公司 | The preparation method of painting canvas patch |
| CN107488423A (en) * | 2017-05-09 | 2017-12-19 | 温州市威利达皮革原料有限公司 | Paper adhesive sticker formula |
| CN108192534A (en) * | 2017-12-29 | 2018-06-22 | 上海金大塑胶有限公司 | A kind of novel Self-leveling adhesive material |
| CN108203572A (en) * | 2017-12-29 | 2018-06-26 | 上海金大塑胶有限公司 | A kind of preparation method of the aqueous adhesive sticker of Self-leveling |
| CN112442319A (en) * | 2019-08-27 | 2021-03-05 | 佛山胶力王科技有限公司 | Medical non-setting adhesive heat-sensitive production line |
| CN115819663A (en) * | 2022-11-28 | 2023-03-21 | 天津安达君胜科技有限公司 | Fixing agent for vacuum brazing and preparation method thereof |
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| CN105602487B (en) | 2018-05-22 |
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