CN106752770A - A kind of indoor decorative metal powdery paints - Google Patents
A kind of indoor decorative metal powdery paints Download PDFInfo
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- CN106752770A CN106752770A CN201611187695.4A CN201611187695A CN106752770A CN 106752770 A CN106752770 A CN 106752770A CN 201611187695 A CN201611187695 A CN 201611187695A CN 106752770 A CN106752770 A CN 106752770A
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- powdery paints
- decorative metal
- indoor decorative
- indoor
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
- C09D5/035—Coloring agents, e.g. pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The present invention relates to powder coating technology field, and in particular to a kind of indoor decorative metal powdery paints, the indoor decorative metal powdery paints are made up of the raw material of following weight portion：40 60 parts of modifying epoxy resin by organosilicon, 35 45 parts of indoor polyester resin, 34 parts of curing agent, 14 parts of metallic pigments, 36 parts of modified porous konilite, 25 parts of lightweight barium sulfate, 0.5 1.5 parts of titanate coupling agent, 0.5 1 parts of styrax, 1.5 3 parts of levelling agent, 5 10 parts of color stuffing, 0.2 0.5 parts of gas phase of white carbon black；The color stuffing is composed of the following raw materials by weight：15 25 parts of nano imvite, 10 20 parts of mica powder, 8 12 parts of wollastonite, 10 15 parts of glass dust, black 10 16 parts of ferrochrome, 10 20 parts of titanium dioxide, red 8 12 parts of high-temperature resisting pigment, indoor decorative metal powdery paints of the present invention are nontoxic, it is pollution-free, environmental protection, can be with primary coating film forming, construction cost is low, good decorating effect, and film has good humidity resistance, toughness, impact resistance and tensile strength.
Description
Technical field
The present invention relates to powder coating technology field, and in particular to a kind of indoor decorative metal powdery paints.
Background technology
Metal powder coating refer to containing metallic pigments (such as：Cu-Zn alloy powder, silver-colored aluminium powder etc.) various powdery paints.Metal powder
Last coating can show a kind of bright, luxurious decorative effect, be especially suitable for furniture, ornaments and automobile etc. indoor, outer object
Spraying.In manufacturing process, domestic market mainly uses dry pigmentation, in the world also using method is adhesively fixed.With economy
Development and people's living standard increasingly raising, requirement of the people to itself sphere of life comfort level and aesthetics is also increasingly
It is high so that application of the metal powder coating in whole decorative painting is more and more wider, is current fine arts type decoration powder
Main product.
Metal dust end coating does not use the volatile solvents such as organic solvent, water, therefore powdery paints is inorganic solvent type
Coating, greatly reduces the potential safety hazard produced by solvent, such as because the operating personnel caused containing organic solvent are organic molten
Agent poisoning or because fire for bringing of organic solvent etc..Metal powder coating film metal luster, with splendid many
The defencive function of chromatic effect and protrusion, for the top grade industrial goods such as automobile, household electrical appliances, instrument and meter provide bright and colourful outward appearance
Decoration.As long as toasted to can obtain performance directly by powder paint in iron material or aluminium by suitable pre-treatment etc.
The persistence of excellent film coated surface, such as film, including：Rub, impact, adherence, toughness, corrosion resistance and resistance to
Chemicals performance etc., but its humidity resistance and impact resistance still need to do further raising.
The content of the invention
The invention provides a kind of indoor decorative metal powdery paints, the indoor decorative metal powdery paints without
Poison, it is pollution-free, environmental protection, can be low with primary coating film forming, construction cost, good decorating effect, film have good humidity resistance,
Toughness, impact resistance and tensile strength.
To realize above technical scheme, the present invention is achieved by the following technical programs：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
40-60 parts, indoor polyester resin 35-45 parts, curing agent 3-4 parts, metallic pigments 1-4 parts, modified porous konilite 3-6 parts, it is light
2-5 parts of matter barium sulfate, titanate coupling agent 0.5-1.5 parts, styrax 0.5-1 parts, levelling agent 1.5-3 parts, color stuffing 5-10 parts,
Gas phase of white carbon black 0.2-0.5 parts；
The color stuffing is composed of the following raw materials by weight：Nano imvite 15-25 parts, mica powder 10-20 parts, wollastonite
8-12 parts, glass dust 10-15 parts, ferrochrome it is black 10-16 parts, titanium dioxide 10-20 parts, high-temperature resisting pigment it is red 8-12 parts.
Preferably, the indoor decorative metal powdery paints are made up of the raw material of following weight portion：Organic silicon modified epoxy
50 parts of oxygen tree fat, 40 parts of indoor polyester resin, 4 parts of curing agent, 2 parts of metallic pigments, 5 parts of modified porous konilite, lightweight sulfuric acid
3 parts of barium, 1 part of titanate coupling agent, 0.8 part of styrax, 2.5 parts of levelling agent, 8 parts of color stuffing, 0.3 part of gas phase of white carbon black.
Preferably, the color stuffing is composed of the following raw materials by weight：20 parts of nano imvite, 15 parts of mica powder, silicon ash
10 parts of stone, 12 parts of glass dust, black 12 parts of ferrochrome, 15 parts of titanium dioxide, red 10 parts of high-temperature resisting pigment.
Preferably, the metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder.
Preferably, the preparation method of the modified porous konilite is：Its quality 0.5-2% will be added in porous konilite
Silane coupler, mixed at high speed 20-40min obtains final product.
Preferably, the levelling agent is organosilicon-modified acrylate.
Preferably, the particle diameter of the Cu-Zn alloy powder be 30-70 μm, the particle diameter of silver-colored aluminium powder be 30-70 μm.
Beneficial effects of the present invention are：
1. the present invention prepares metal powder coating and can improve the low-temperature flexibility of coating using organic-silicon-modified epoxy resin
And humidity resistance.
2. adding porous konilite is used in metal powder coating be favorably improved the adhesive force and caking property of product.Together
When, due to the presence of hydroxyl, using coupling agent treatment after, can strengthen its crosslinking, the effect of reinforcement, improve the drawing of coating film
Stretch intensity and shock resistance.
3. in the present invention add the color stuffing for being high temperature resistant type, make metal powder coating with well it is thermally-stabilised
Property, the addition of wherein nano imvite can strengthen antikathode stripping and the water boiling resistance performance of powdery paints.
4. indoor decorative metal powdery paints of the present invention are nontoxic, pollution-free, environmental protection, can be constructed with primary coating film forming
Low cost, good decorating effect.
Specific embodiment
Technical solution of the invention is further illustrated with reference to specific embodiment, embodiment is not to be construed as right
The limitation of technical solution.
Embodiment 1：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
50 parts, 40 parts of indoor polyester resin, 4 parts of curing agent, 2 parts of metallic pigments, 5 parts of modified porous konilite, 3 parts of lightweight barium sulfate,
1 part of titanate coupling agent, 0.8 part of styrax, 2.5 parts of organosilicon-modified acrylate, 8 parts of color stuffing, gas phase of white carbon black 0.3
Part.
The color stuffing is composed of the following raw materials by weight：20 parts of nano imvite, 15 parts of mica powder, 10 parts of wollastonite,
Black 12 parts of 12 parts of glass dust, ferrochrome, 15 parts of titanium dioxide, red 10 parts of high-temperature resisting pigment.
The metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder that particle diameter be 30-70 μm of the particle diameter for 30-70 μm；It is described modified
The preparation method of porous konilite is：To add the silane coupler of its quality 2% in porous konilite, mixed at high speed 20min,
Obtain final product.
Embodiment 2：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
60 parts, 35 parts of indoor polyester resin, 4 parts of curing agent, 1 part of metallic pigments, 6 parts of modified porous konilite, 2 parts of lightweight barium sulfate,
1.5 parts of titanate coupling agent, 0.5 part of styrax, 3 parts of organosilicon-modified acrylate, 5 parts of color stuffing, gas phase of white carbon black 0.5
Part；
The color stuffing is composed of the following raw materials by weight：25 parts of nano imvite, 10 parts of mica powder, 12 parts of wollastonite,
Black 16 parts of 10 parts of glass dust, ferrochrome, 10 parts of titanium dioxide, red 12 parts of high-temperature resisting pigment.
The metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder that particle diameter be 30-70 μm of the particle diameter for 30-70 μm；It is described modified
The preparation method of porous konilite is：The silane coupler of its quality 0.5%, mixed at high speed will be added in porous konilite
40min, obtains final product.
Embodiment 3：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
40 parts, 45 parts of indoor polyester resin, 3 parts of curing agent, 4 parts of metallic pigments, 3 parts of modified porous konilite, 5 parts of lightweight barium sulfate,
0.5 part of titanate coupling agent, 1 part of styrax, 1.5 parts of organosilicon-modified acrylate, 10 parts of color stuffing, gas phase of white carbon black 0.2
Part；
The color stuffing is composed of the following raw materials by weight：15 parts of nano imvite, 20 parts of mica powder, 8 parts of wollastonite, glass
Black 10 parts of 15 parts of glass powder, ferrochrome, 20 parts of titanium dioxide, red 8 parts of high-temperature resisting pigment.
The metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder that particle diameter be 30-70 μm of the particle diameter for 30-70 μm；It is described modified
The preparation method of porous konilite is：The silane coupler of its quality 1.5%, mixed at high speed will be added in porous konilite
60min, obtains final product.
Embodiment 4：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
60 parts, 45 parts of indoor polyester resin, 3 parts of curing agent, 2 parts of metallic pigments, 6 parts of modified porous konilite, 5 parts of lightweight barium sulfate,
0.5 part of titanate coupling agent, 0.5 part of styrax, 3 parts of organosilicon-modified acrylate, 10 parts of color stuffing, gas phase of white carbon black 0.2
Part；
The color stuffing is composed of the following raw materials by weight：18 parts of nano imvite, 18 parts of mica powder, 10 parts of wollastonite,
Black 16 parts of 12 parts of glass dust, ferrochrome, 15 parts of titanium dioxide, red 10 parts of high-temperature resisting pigment.
The metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder that particle diameter be 30-70 μm of the particle diameter for 30-70 μm；It is described modified
The preparation method of porous konilite is：To add the silane coupler of its quality 1% in porous konilite, mixed at high speed 35min,
Obtain final product.
Embodiment 5：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
50 parts, 40 parts of indoor polyester resin, 3 parts of curing agent, 3 parts of metallic pigments, 5 parts of modified porous konilite, 3 parts of lightweight barium sulfate,
1.5 parts of titanate coupling agent, 1 part of styrax, 2.5 parts of organosilicon-modified acrylate, 6 parts of color stuffing, gas phase of white carbon black 0.4
Part；
The color stuffing is composed of the following raw materials by weight：22 parts of nano imvite, 12 parts of mica powder, 12 parts of wollastonite,
Black 10 parts of 10 parts of glass dust, ferrochrome, 20 parts of titanium dioxide, red 12 parts of high-temperature resisting pigment.
The metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder that particle diameter be 30-70 μm of the particle diameter for 30-70 μm；It is described modified
The preparation method of porous konilite is：The silane coupler of its quality 1.2%, mixed at high speed will be added in porous konilite
30min, obtains final product.
Embodiment 6：
A kind of indoor decorative metal powdery paints, are made up of the raw material of following weight portion：Modifying epoxy resin by organosilicon
40 parts, 35 parts of indoor polyester resin, 4 parts of curing agent, 4 parts of metallic pigments, 3 parts of modified porous konilite, 2 parts of lightweight barium sulfate,
1.5 parts of titanate coupling agent, 1 part of styrax, 1.5 parts of organosilicon-modified acrylate, 5 parts of color stuffing, gas phase of white carbon black 0.5
Part；
The color stuffing is composed of the following raw materials by weight：25 parts of nano imvite, 20 parts of mica powder, 8 parts of wollastonite, glass
Black 16 parts of 10 parts of glass powder, ferrochrome, 20 parts of titanium dioxide, red 8 parts of high-temperature resisting pigment.
The metallic pigments include Cu-Zn alloy powder, silver-colored aluminium powder that particle diameter be 30-70 μm of the particle diameter for 30-70 μm；It is described modified
The preparation method of porous konilite is：The silane coupler of its quality 1.8%, mixed at high speed will be added in porous konilite
20min, obtains final product.
Performance test：
Embodiment 1-6 is prepared into indoor decorative metal powdery paints according to a conventional method, then carries out performance test, surveyed
Test result is as in the table below：
The performance test results of table 1
It is more than the description to the embodiment of the present invention, by the foregoing description of the disclosed embodiments, makes this area special
Industry technical staff can realize or use the present invention.Various modifications to these embodiments come to those skilled in the art
Say and will be apparent, generic principles defined herein can not depart from the situation of the spirit or scope of the present invention
Under, realize in other embodiments.Therefore, the present invention is not intended to be limited to the embodiments shown herein, but to accord with
Close the most wide scope consistent with principles disclosed herein and features of novelty.
Claims (7)
1. a kind of indoor decorative metal powdery paints, it is characterised in that be made up of the raw material of following weight portion：It is organic-silicon-modified
Epoxy resin 40-60 parts, indoor polyester resin 35-45 parts, curing agent 3-4 parts, metallic pigments 1-4 parts, modified porous konilite
3-6 parts, 2-5 parts of lightweight barium sulfate, titanate coupling agent 0.5-1.5 parts, styrax 0.5-1 parts, levelling agent 1.5-3 parts, face fills out
5-10 parts, gas phase of white carbon black 0.2-0.5 parts of material；
The color stuffing is composed of the following raw materials by weight：Nano imvite 15-25 parts, mica powder 10-20 parts, wollastonite 8-12
Part, glass dust 10-15 parts, ferrochrome it is black 10-16 parts, titanium dioxide 10-20 parts, high-temperature resisting pigment it is red 8-12 parts.
2. indoor decorative metal powdery paints according to claim 1, it is characterised in that by the raw material of following weight portion
It is made：50 parts of modifying epoxy resin by organosilicon, 40 parts of indoor polyester resin, 4 parts of curing agent, 2 parts of metallic pigments, modified porous powder
5 parts of quartz, 3 parts of lightweight barium sulfate, 1 part of titanate coupling agent, 0.8 part of styrax, 2.5 parts of levelling agent, 8 parts of color stuffing, gas phase
0.3 part of White Carbon black.
3. indoor decorative metal powdery paints according to claim 2, it is characterised in that the color stuffing is by following heavy
Amount part raw material composition：20 parts of nano imvite, 15 parts of mica powder, 10 parts of wollastonite, 12 parts of glass dust, black 12 parts of ferrochrome, titanium white
Red 10 parts of 15 parts of powder, high-temperature resisting pigment.
4. indoor decorative metal powdery paints according to claim 2, it is characterised in that the metallic pigments include copper
Bronze, silver-colored aluminium powder.
5. indoor decorative metal powdery paints according to claim 2, it is characterised in that the modified porous konilite
Preparation method be：To add the silane coupler of its quality 0.5-2% in porous konilite, mixed at high speed 20-40min, i.e.,
.
6. indoor decorative metal powdery paints according to claim 2, it is characterised in that the levelling agent is organosilicon
Modification acrylate.
7. indoor decorative metal powdery paints according to claim 2, it is characterised in that the particle diameter of the Cu-Zn alloy powder is
30-70 μm, the particle diameter of silver-colored aluminium powder be 30-70 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611187695.4A CN106752770A (en) | 2016-12-20 | 2016-12-20 | A kind of indoor decorative metal powdery paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611187695.4A CN106752770A (en) | 2016-12-20 | 2016-12-20 | A kind of indoor decorative metal powdery paints |
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| CN106752770A true CN106752770A (en) | 2017-05-31 |
Family
ID=58896319
Family Applications (1)
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| CN201611187695.4A Pending CN106752770A (en) | 2016-12-20 | 2016-12-20 | A kind of indoor decorative metal powdery paints |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110218506A (en) * | 2019-07-01 | 2019-09-10 | 中山市绿浪助剂有限公司 | High-temperature-resistant multicolor metal powder coating and preparation method thereof |
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Cited By (1)
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| CN110218506A (en) * | 2019-07-01 | 2019-09-10 | 中山市绿浪助剂有限公司 | High-temperature-resistant multicolor metal powder coating and preparation method thereof |
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