CN106752467A - A kind of stainless steel anticorrosive coating and preparation method thereof - Google Patents

A kind of stainless steel anticorrosive coating and preparation method thereof Download PDF

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Publication number
CN106752467A
CN106752467A CN201610381862.2A CN201610381862A CN106752467A CN 106752467 A CN106752467 A CN 106752467A CN 201610381862 A CN201610381862 A CN 201610381862A CN 106752467 A CN106752467 A CN 106752467A
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parts
methacrylic acid
methyl acrylate
stainless steel
powder
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徐挺
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of stainless steel anticorrosive coating and preparation method thereof, it is prepared from by the raw material of following weight portion:Alkyd resin, 40~50 parts;Polyvinyl acetate resin, 55~65 parts;SiO 2 powder, 25~35 parts;Isobutanol, 10~20 parts;Dimethylethanolamine, 10~20 parts;Phenyltrimethoxysila,e, 5~15 parts;Acetone, 5~15 parts;Talcum powder, 10~14 parts;Water, 85~95 parts;Totally 7~9 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 6~8:1.The stainless steel anticorrosive coating that the present invention is provided can significantly improve the Corrosion Protection of stainless steel, and this may be relevant with methyl acrylate in raw material and methacrylic acid weight ratio, and methyl acrylate and methacrylic acid weight ratio are 6~8:When 1, the Corrosion Protection to stainless steel is best.

Description

A kind of stainless steel anticorrosive coating and preparation method thereof
Technical field
The invention belongs to chemistry painting industry field, and in particular to a kind of stainless steel anticorrosive coating and preparation method thereof.
Background technology
The economic loss that the annual metal erosion of China is caused accounts for the 3~5% of gross national product, loss exceed fire, disaster caused by a windstorm and The damnous summation of earthquake.For a long time, in order to reduce the loss of corrosion, people take many measures, such as electricity of metal Chemoproection method, corrosive medium facture, coating Protection Code etc..But it is most universal, most economical so far, most practical Safeguard measure or coating protection, anticorrosion with coat with its easy construction, it is economic and practical, by device area, shape constraint with And the features such as with certain decorative effect and be widely used.
The content of the invention
It is an object of the invention to provide a kind of stainless steel anticorrosive coating and preparation method thereof.
Above-mentioned purpose of the invention is achieved by following technical scheme:
A kind of stainless steel anticorrosive coating, is prepared from by the raw material of following weight portion:Alkyd resin, 40~50 parts;It is poly- Vinyl acetate resin, 55~65 parts;SiO 2 powder, 25~35 parts;Isobutanol, 10~20 parts;Dimethylethanolamine, 10~20 Part;Phenyltrimethoxysila,e, 5~15 parts;Acetone, 5~15 parts;Talcum powder, 10~14 parts;Water, 85~95 parts;Propylene Totally 7~9 parts of sour methyl esters and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 6~8:1.
Further, described stainless steel anticorrosive coating is prepared from by the raw material of following weight portion:Alkyd resin, 45 Part;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts;Dimethylethanolamine, 15 parts; Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts;Methyl acrylate and methyl-prop Totally 8 parts of olefin(e) acid, methyl acrylate and methacrylic acid weight ratio are 7:1.
Further, described stainless steel anticorrosive coating is prepared from by the raw material of following weight portion:Alkyd resin, 40 Part;Polyvinyl acetate resin, 55 parts;SiO 2 powder, 25 parts;Isobutanol, 10 parts;Dimethylethanolamine, 10 parts; Phenyltrimethoxysila,e, 5 parts;Acetone, 5 parts;Talcum powder, 10 parts;Water, 85 parts;Methyl acrylate and metering system Totally 7 parts of acid, methyl acrylate and methacrylic acid weight ratio are 6:1.
Further, described stainless steel anticorrosive coating is prepared from by the raw material of following weight portion:Alkyd resin, 50 Part;Polyvinyl acetate resin, 65 parts;SiO 2 powder, 35 parts;Isobutanol, 20 parts;Dimethylethanolamine, 20 parts; Phenyltrimethoxysila,e, 15 parts;Acetone, 15 parts;Talcum powder, 14 parts;Water, 95 parts;Methyl acrylate and methyl-prop Totally 9 parts of olefin(e) acid, methyl acrylate and methacrylic acid weight ratio are 8:1.
The preparation method of above-mentioned stainless steel anticorrosive coating, step is as follows:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Advantages of the present invention:
The stainless steel anticorrosive coating that the present invention is provided can significantly improve the Corrosion Protection of stainless steel, this may with raw material in Methyl acrylate is relevant with methacrylic acid weight ratio, and methyl acrylate and methacrylic acid weight ratio are 6~8:When 1, Corrosion Protection to stainless steel is best.
Specific embodiment
Essentiality content of the invention is further illustrated with reference to embodiment, but the scope of the present invention do not limited with this.To the greatest extent Pipe is explained in detail with reference to preferred embodiment to the present invention, it will be understood by those within the art that, can be to the present invention Technical scheme modify or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1:The preparation of stainless steel anticorrosive coating
Parts by weight of raw materials ratio:
Alkyd resin, 45 parts;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts;Two Methylethanolamine, 15 parts;Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts; Totally 8 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 7:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 2:The preparation of stainless steel anticorrosive coating
Parts by weight of raw materials ratio:
Alkyd resin, 40 parts;Polyvinyl acetate resin, 55 parts;SiO 2 powder, 25 parts;Isobutanol, 10 parts;Two Methylethanolamine, 10 parts;Phenyltrimethoxysila,e, 5 parts;Acetone, 5 parts;Talcum powder, 10 parts;Water, 85 parts;Third Totally 7 parts of e pioic acid methyl ester and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 6:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 3:The preparation of stainless steel anticorrosive coating
Parts by weight of raw materials ratio:
Alkyd resin, 50 parts;Polyvinyl acetate resin, 65 parts;SiO 2 powder, 35 parts;Isobutanol, 20 parts;Two Methylethanolamine, 20 parts;Phenyltrimethoxysila,e, 15 parts;Acetone, 15 parts;Talcum powder, 14 parts;Water, 95 parts; Totally 9 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 8:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 4:The preparation of stainless steel anticorrosive coating
Parts by weight of raw materials ratio:
Alkyd resin, 45 parts;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts;Two Methylethanolamine, 15 parts;Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts; Totally 8 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 6:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 5:The preparation of stainless steel anticorrosive coating
Parts by weight of raw materials ratio:
Alkyd resin, 45 parts;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts;Two Methylethanolamine, 15 parts;Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts; Totally 8 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 8:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 6:Comparative example, methyl acrylate and methacrylic acid weight ratio are 5:1
Parts by weight of raw materials ratio:
Alkyd resin, 45 parts;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts;Two Methylethanolamine, 15 parts;Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts; Totally 8 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 5:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 7:Comparative example, methyl acrylate and methacrylic acid weight ratio are 9:1
Parts by weight of raw materials ratio:
Alkyd resin, 45 parts;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts;Two Methylethanolamine, 15 parts;Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts; Totally 8 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 9:1.
Preparation method:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
Embodiment 8:Effect example
The salt spray resistance of the difference coating of testing example 1~7, salt-fog resistant test result is as follows:
Salt-fog resistant test
Embodiment 1 5000h comes off without foaming, nothing, non-corroding
Embodiment 4 5000h comes off without foaming, nothing, non-corroding
Embodiment 5 5000h comes off without foaming, nothing, non-corroding
Embodiment 6 , there is corrosion phenomena in 1500h local sheddings
Embodiment 7 , there is corrosion phenomena in 1500h local sheddings
The effect and embodiment 4,5 of embodiment 2,3 are basically identical.
Above-mentioned result of the test shows that the stainless steel anticorrosive coating that the present invention is provided can significantly improve the anticorrosive property of stainless steel Can, this may be relevant with methyl acrylate in raw material and methacrylic acid weight ratio, methyl acrylate and methacrylic acid weight The ratio between amount part is 6~8:When 1, the Corrosion Protection to stainless steel is best.
The effect of above-described embodiment indicates that essentiality content of the invention, but with this does not limit protection scope of the present invention. It will be understood by those within the art that, technical scheme can be modified or equivalent, without de- From the essence and protection domain of technical solution of the present invention.

Claims (5)

1. a kind of stainless steel anticorrosive coating, it is characterised in that be prepared from by the raw material of following weight portion:Alkyd resin, 40~50 parts;Polyvinyl acetate resin, 55~65 parts;SiO 2 powder, 25~35 parts;Isobutanol, 10~20 parts;Diformazan Ethylethanolamine, 10~20 parts;Phenyltrimethoxysila,e, 5~15 parts;Acetone, 5~15 parts;Talcum powder, 10~14 parts;Water, 85~95 parts;Totally 7~9 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 6~8:1.
2. stainless steel anticorrosive coating according to claim 1, it is characterised in that by the raw material system of following weight portion It is standby to form:Alkyd resin, 45 parts;Polyvinyl acetate resin, 60 parts;SiO 2 powder, 30 parts;Isobutanol, 15 parts; Dimethylethanolamine, 15 parts;Phenyltrimethoxysila,e, 10 parts;Acetone, 10 parts;Talcum powder, 12 parts;Water, 90 parts; Totally 8 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 7:1.
3. stainless steel anticorrosive coating according to claim 1, it is characterised in that by the raw material system of following weight portion It is standby to form:Alkyd resin, 40 parts;Polyvinyl acetate resin, 55 parts;SiO 2 powder, 25 parts;Isobutanol, 10 parts; Dimethylethanolamine, 10 parts;Phenyltrimethoxysila,e, 5 parts;Acetone, 5 parts;Talcum powder, 10 parts;Water, 85 parts; Totally 7 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 6:1.
4. stainless steel anticorrosive coating according to claim 1, it is characterised in that by the raw material system of following weight portion It is standby to form:Alkyd resin, 50 parts;Polyvinyl acetate resin, 65 parts;SiO 2 powder, 35 parts;Isobutanol, 20 parts; Dimethylethanolamine, 20 parts;Phenyltrimethoxysila,e, 15 parts;Acetone, 15 parts;Talcum powder, 14 parts;Water, 95 parts; Totally 9 parts of methyl acrylate and methacrylic acid, methyl acrylate and methacrylic acid weight ratio are 8:1.
5. the preparation method of any stainless steel anticorrosive coating of Claims 1 to 4, it is characterised in that step is as follows:
Step S1, by isobutanol, dimethylethanolamine, phenyl three after alkyd resin and polyvinyl acetate resin melting with liquid Methoxy silane, acetone, methyl acrylate and methacrylic acid mixing and stirring, obtain liquid hybrid resin;
Step S2, SiO 2 powder and talcum powder are dispersed in water, obtain aqueous suspensions;
Step S3, liquid hybrid resin and aqueous suspensions are mixed, and are stirred.
CN201610381862.2A 2016-05-31 2016-05-31 A kind of stainless steel anticorrosive coating and preparation method thereof Pending CN106752467A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828317A (en) * 2017-12-01 2018-03-23 李晓强 Good corrosion resistant bridge framework of steel reinforcement coating of freeze-thaw resistance and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1472263A (en) * 2003-05-08 2004-02-04 同济大学 Steel-structure anti-corrosion coating and preparing mehtod thereof
CN103173110A (en) * 2011-12-26 2013-06-26 西安长庆图博可特石油管道涂层有限公司 Oil pipe external anticorrosive coating and preparation method thereof
CN103483949A (en) * 2013-08-23 2014-01-01 苏州长盛机电有限公司 Anticorrosive paint for stainless steel
CN105086791A (en) * 2015-08-05 2015-11-25 天长市开林化工有限公司 High-performance water-based alkyd resin coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1472263A (en) * 2003-05-08 2004-02-04 同济大学 Steel-structure anti-corrosion coating and preparing mehtod thereof
CN103173110A (en) * 2011-12-26 2013-06-26 西安长庆图博可特石油管道涂层有限公司 Oil pipe external anticorrosive coating and preparation method thereof
CN103483949A (en) * 2013-08-23 2014-01-01 苏州长盛机电有限公司 Anticorrosive paint for stainless steel
CN105086791A (en) * 2015-08-05 2015-11-25 天长市开林化工有限公司 High-performance water-based alkyd resin coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828317A (en) * 2017-12-01 2018-03-23 李晓强 Good corrosion resistant bridge framework of steel reinforcement coating of freeze-thaw resistance and preparation method thereof

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Application publication date: 20170531