CN108531004A - A kind of ship Corrosion resisting paint without need of cleaning rust and preparation method thereof - Google Patents
A kind of ship Corrosion resisting paint without need of cleaning rust and preparation method thereof Download PDFInfo
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- CN108531004A CN108531004A CN201810204404.0A CN201810204404A CN108531004A CN 108531004 A CN108531004 A CN 108531004A CN 201810204404 A CN201810204404 A CN 201810204404A CN 108531004 A CN108531004 A CN 108531004A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of ship Corrosion resisting paint without need of cleaning rust, are used for the surface of direct brushing ship corrosion steel, and ship Corrosion resisting paint without need of cleaning rust is formulated composed of the following components by mass percentage：Styrene-acrylic emulsion 20 25%, epoxy resin 15 20%, acrylic resin modified 5 20%, stable rust 3 5%, filler 10 50%, dispersant 0.1 0.3%, antifoaming agent 0.1 0.4% and coupling agent 1 3%.The invention also discloses a kind of preparation methods of ship Corrosion resisting paint without need of cleaning rust.Ship of the present invention can be brushed directly with Corrosion resisting paint without need of cleaning rust on the surface of ship corrosion steel, suitable for there is the antirust of the ship steel surface of corrosion, hard oxide scale layer or old paint film, it can be penetrated into rusty scale when application and close entire rusty scale, permeability is strong, coating adhesion is high, favorable rust preventing effect, and can use under severe conditions, there is preferable durability and weatherability.
Description
Technical field
The present invention relates on rust paint technical field more particularly to a kind of ship Corrosion resisting paint without need of cleaning rust and its preparation sides
Method.
Background technology
Ship corrodes very serious under briny environment, it is desirable that the excellent coating of performance carries out anti-corrosion.Ship is used anti-
Shield coating has certain service life, such as：3 years or 5 years.When being repaired more than validity period, often can be appreciated that certain structures due to
Has there is heavy corrosion in face coat destruction.These rusty scales are removed in maintenance process, could be painted again.Ship is come
It says, due to bulky, the limitation of maintenance time in the process of running, it is difficult to remove the rusty scale on steel substrate surface.If rusty scale
It does not remove thoroughly, the binding force of coating and steel substrate will be influenced, the reduced service life of coating can be caused, accelerate Ship Structure
Corrosion.
This practical problem can be quickly solved using on rust paint, traditional painting work includes polishing, sandblasting, bottom
The five steps work such as paint, middle paint and finishing coat, Corrosion resisting paint without need of cleaning rust only need polishing and the work of two step of application, have broken previous tradition,
Face is brushed together in bottom, exempts from sandblasting, saves material cost, and construction is simple reduces field operation difficulty and manual work cost.But
The requirement for anticorrosion of ship's repairs ＆ maintenance facilities is also not achieved on rust paint performance at present.Common on rust paint mainly has osmosis type, transformant, steady
Three kinds of sizing.For rust-converter coating, since paint ingredient is based on phosphoric acid, extra phosphoric acid can influence the attachment of finishing coat
Power causes coating premature failure.For osmosis type, when rusty scale is more than 0.5mm or more, coating is difficult penetrate into coating interior
Portion.For stable type coating, directly in application, the adhesive force on rusty scale is obviously not as good as the steel substrate of no rusty scale, so coating
Easily peel off.
The etch-proof requirement of ship equipment is cannot be satisfied on rust paint in the prior art, therefore, it is necessary to design
It is a kind of directly to brush on the surface of ship corrosion steel, favorable rust preventing effect, it is environmentally friendly, pollution-free, suitable for there is rust
Erosion, hard oxide scale layer or old paint film ship steel surface antirust, and ship Corrosion resisting paint without need of cleaning rust easy for construction and
Preparation method.
Invention content
In view of this, the main purpose of the present invention is to provide a kind of tables that can directly brush in ship corrosion steel
Face, favorable rust preventing effect is environmentally friendly, pollution-free, suitable for there is the ship steel table of corrosion, hard oxide scale layer or old paint film
Face antirust, and ship Corrosion resisting paint without need of cleaning rust and preparation method thereof easy for construction.
In order to solve the above-mentioned technical problem, the invention discloses a kind of ship Corrosion resisting paint without need of cleaning rust, for directly brushing
The surface of ship corrosion steel, ship Corrosion resisting paint without need of cleaning rust are formulated composed of the following components by mass percentage：Benzene
Acrylic emulsion 20-25%, epoxy resin 15-20%, acrylic resin modified 5-20%, stable rust 3-5%, filler 10-50%, point
Powder 0.1-0.3%, antifoaming agent 0.1-0.4% and coupling agent 1-3%.
Further, the stable rust is zinc oxide and phosphoric acid diphenylguanidine, the zinc oxide and the phosphoric acid diphenylguanidine
Mass ratio is 1：1.
Further, the filler is one or more in iron oxide red, graphene or barium sulfate.
Preferably, the dispersant is in polyacrylamide, fatty acid polyethylene glycol ester, calgon or methyl anyl alcohol
It is one or more.
Further, the antifoaming agent is polysiloxane-based antifoaming agent, and the coupling agent is silane coupling agent.
Preferably, ship Corrosion resisting paint without need of cleaning rust is formulated composed of the following components by mass percentage：Phenylpropyl alcohol breast
Liquid 20%, epoxy resin 20%, acrylic resin modified 10%, stable rust 4%, filler 43.8%, dispersant 0.1%, defoaming
Agent 0.1% and coupling agent 2%.
Correspondingly, the invention also discloses a kind of preparation method of ship Corrosion resisting paint without need of cleaning rust, include the following steps：
S1, stock, by styrene-acrylic emulsion, epoxy resin, acrylic resin modified, stable rust, filler, dispersant, antifoaming agent
It stocks up according to the ratio with coupling agent；
S2, batch mixing：Epoxy resin and acrylic resin modified is sequentially added in styrene-acrylic emulsion, after stirring and dissolving successively plus
Enter stable rust, dispersant, antifoaming agent and coupling agent, be stirring evenly and then adding into filler disease fineness of grind to 5-10 μm, detect viscosity,
It filters, discharge after qualification, packaging obtains.
Implement the present invention, has the advantages that：
(1) ship Corrosion resisting paint without need of cleaning rust of the invention can be brushed directly in the surface of ship corrosion steel, antirust effect
Fruit is good, environmentally friendly, pollution-free, suitable for there is the antirust of the ship steel surface of corrosion, hard oxide scale layer or old paint film.
(2) ship Corrosion resisting paint without need of cleaning rust of the invention, permeability is strong, and when application can penetrate into steel surface rust layer simultaneously
Entire rusty scale is closed, coating adhesion is high, and coating quality is good, and can use under severe conditions, has preferable resistance to
Long property and weatherability.
(3) preparation method of ship Corrosion resisting paint without need of cleaning rust of the invention, the preparation method is simple for process, suitable for industrialization
Production can be applied to each industry such as petrochemical industry, wind-powered electricity generation, mechanical equipment, vehicle, road and bridge, food processing and civilian neck
Domain.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiment of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment one
The invention discloses a kind of ship Corrosion resisting paint without need of cleaning rust, are used for the surface of direct brushing ship corrosion steel, institute
It is composed of the following components by mass percentage to state ship Corrosion resisting paint without need of cleaning rust formula：Styrene-acrylic emulsion 20%, epoxy resin
15%, acrylic resin modified 10%, stable rust 3%, filler 50%, dispersant 0.3%, antifoaming agent 0.2% and coupling agent
1.5%.The stable rust is zinc oxide and phosphoric acid diphenylguanidine, and the mass ratio of the zinc oxide and the phosphoric acid diphenylguanidine is 1：1.
The filler is iron oxide red.The dispersant is polyacrylamide.The antifoaming agent is polysiloxane-based antifoaming agent, the idol
Connection agent is silane coupling agent.
Performance test：
(1) adhesive force：It is 0 grade that cross-cut methods, which test adhesive force,；
(2) salt fog resistance：Destructive neutral salt spray test 300h, unilateral corrosion are less than 2mm；
(3) corrosion-resistant medium：3.5% sodium chloride solution generates after impregnating 200 hours without blistering and point rust；Finished product packet
Dress carries out finished product packing.
Embodiment two
Present embodiment discloses a kind of preparation method of ship Corrosion resisting paint without need of cleaning rust, the ship band in the present embodiment
The anticorrosive paint that becomes rusty uses the proportioning of embodiment one, the preparation method of the ship Corrosion resisting paint without need of cleaning rust in embodiment one, including
Following steps：
S1, stock, by styrene-acrylic emulsion, epoxy resin, acrylic resin modified, zinc oxide, phosphoric acid diphenylguanidine, iron oxide
Red, polyacrylamide, polysiloxane-based antifoaming agent and silane coupling agent are stocked up by the proportioning in embodiment one；
S2, batch mixing：Epoxy resin and acrylic resin modified is sequentially added in styrene-acrylic emulsion, after stirring and dissolving successively plus
Enter zinc oxide, phosphoric acid diphenylguanidine, iron oxide red, polyacrylamide, polysiloxane-based antifoaming agent and silane coupling agent, stirs evenly
Filler disease fineness of grind is added afterwards to 5 μm, detects viscosity, filters, discharge after qualified, packaging obtains.
Experiment：On the shipbuilding steel plate surface that corrosion class is D grades, after the floating rust surface treatment degree of removing reaches DSt ranks
Direct spraying ship Corrosion resisting paint without need of cleaning rust of the present invention after placing 3-4 hours at room temperature, is placed in 60 DEG C of oven dryings 8 hours, film
60 microns thick, observation discovery surface of steel plate is without rusty scale after standing 48 hours, and coating surface is uniform, and covering is high, and adhesive force is good.
Embodiment three
The invention discloses a kind of ship Corrosion resisting paint without need of cleaning rust, are used for the surface of direct brushing ship corrosion steel, institute
It is composed of the following components by mass percentage to state ship Corrosion resisting paint without need of cleaning rust formula：Styrene-acrylic emulsion 20%, epoxy resin
20%, acrylic resin modified 10%, stable rust 4%, filler 43.8%, dispersant 0.1%, antifoaming agent 0.1% and coupling agent
2%.
Performance test：
(1) adhesive force：It is 0 grade that cross-cut methods, which test adhesive force,；
(2) salt fog resistance：Destructive neutral salt spray test 300h, unilateral corrosion are less than 1mm；
(3) corrosion-resistant medium：3.5% sodium chloride solution generates after impregnating 200 hours without blistering and point rust, carry out at
Product are packed.
Example IV
Present embodiment discloses a kind of preparation method of ship Corrosion resisting paint without need of cleaning rust, the ship band in the present embodiment
The anticorrosive paint that becomes rusty uses the proportioning of embodiment three, the preparation method of the ship Corrosion resisting paint without need of cleaning rust in embodiment three, including
Following steps：
S1, stock, by styrene-acrylic emulsion, epoxy resin, acrylic resin modified, stable rust, filler, dispersant, antifoaming agent
It stocks up by the proportioning in embodiment three with coupling agent；
S2, batch mixing：Epoxy resin and acrylic resin modified is sequentially added in styrene-acrylic emulsion, after stirring and dissolving successively plus
Enter stable rust, filler, dispersant, antifoaming agent and coupling agent, is stirring evenly and then adding into filler disease fineness of grind to 8 μm, detection is viscous
Degree is filtered after qualified, is discharged, packaging obtains.
Experiment：On the shipbuilding steel plate surface that corrosion class is D grades, after the floating rust surface treatment degree of removing reaches DSt ranks
Direct spraying ship Corrosion resisting paint without need of cleaning rust of the present invention after placing 4 hours at room temperature, is placed in 60 DEG C of oven dryings 6 hours, film thickness
55 microns, observation discovery surface of steel plate is without rusty scale after standing 48 hours, and coating surface is uniform, and covering is high, and adhesive force is good.
Embodiment five
The invention discloses a kind of ship Corrosion resisting paint without need of cleaning rust, are used for the surface of direct brushing ship corrosion steel, institute
It is composed of the following components by mass percentage to state ship Corrosion resisting paint without need of cleaning rust formula：Styrene-acrylic emulsion 25%, epoxy resin
18%, acrylic resin modified 10%, stable rust 4%, filler 41.6%, dispersant 0.2%, antifoaming agent 0.2% and coupling agent
1%.The stable rust is zinc oxide and phosphoric acid diphenylguanidine, and the mass ratio of the zinc oxide and the phosphoric acid diphenylguanidine is 1：1.Institute
It is barium sulfate to state filler.The dispersant is fatty acid polyethylene glycol ester.The antifoaming agent is polysiloxane-based antifoaming agent, described
Coupling agent is silane coupling agent.
Performance test：
(1) adhesive force：It is 0 grade that cross-cut methods, which test adhesive force,；
(2) salt fog resistance：Destructive neutral salt spray test 300h, unilateral corrosion are less than 2mm；
(3) corrosion-resistant medium：3.5% sodium chloride solution generates after impregnating 200 hours without blistering and point rust；Finished product packet
Dress carries out finished product packing.
Embodiment six
Present embodiment discloses a kind of preparation method of ship Corrosion resisting paint without need of cleaning rust, the ship band in embodiment five
The preparation method of rust anticorrosive paint, includes the following steps：
S1, stock, by styrene-acrylic emulsion 25%, epoxy resin 18%, acrylic resin modified 10%, zinc oxide 2%, phosphoric acid
Diphenylguanidine 2%, barium sulfate 41.6%, fatty acid polyethylene glycol ester 0.2%, polysiloxane-based antifoaming agent 0.2% and silane coupled
Agent 1% is stocked up by the proportioning in embodiment five；
S2, batch mixing：Epoxy resin and acrylic resin modified is sequentially added in styrene-acrylic emulsion, after stirring and dissolving successively plus
Enter zinc oxide, phosphoric acid diphenylguanidine, barium sulfate, fatty acid polyethylene glycol ester, polysiloxane-based antifoaming agent and silane coupling agent, stirs
The uniform rear filler disease fineness of grind that is added detects viscosity to 10 μm, filters, discharges after qualified, packaging obtains.
Experiment：On the shipbuilding steel plate surface that corrosion class is D grades, after the floating rust surface treatment degree of removing reaches DSt ranks
Direct spraying ship Corrosion resisting paint without need of cleaning rust of the present invention after placing 3-4 hours at room temperature, is placed in 60 DEG C of oven dryings 6 hours, film
50-60 microns thick, observation discovery surface of steel plate is without rusty scale after standing 48 hours, and coating surface is uniform, and covering is high, adhesive force
It is good.
Embodiment seven
The invention discloses a kind of ship Corrosion resisting paint without need of cleaning rust, are used for the surface of direct brushing ship corrosion steel, institute
It is composed of the following components by mass percentage to state ship Corrosion resisting paint without need of cleaning rust formula：Styrene-acrylic emulsion 23%, epoxy resin
16%, acrylic resin modified 14%, stable rust 3%, filler 40.5%, dispersant 0.3%, antifoaming agent 0.2% and coupling agent
3%.The stable rust is zinc oxide and phosphoric acid diphenylguanidine, and the mass ratio of the zinc oxide and the phosphoric acid diphenylguanidine is 1：1.Institute
It is iron oxide red, graphene and barium sulfate to state filler, and the mass ratio of the iron oxide red, graphene and barium sulfate is 1:1:1.Institute
Dispersant is stated as calgon and methyl anyl alcohol, the mass ratio of the calgon and the methyl anyl alcohol is 2:1.It is described
Antifoaming agent is polysiloxane-based antifoaming agent, and the coupling agent is silane coupling agent.
Performance test：
(1) adhesive force：It is 0 grade that cross-cut methods, which test adhesive force,；
(2) salt fog resistance：Destructive neutral salt spray test 300h, unilateral corrosion are less than 2mm；
(3) corrosion-resistant medium：3.5% sodium chloride solution generates after impregnating 200 hours without blistering and point rust；Finished product packet
Dress carries out finished product packing.
Embodiment eight
Present embodiment discloses a kind of preparation method of ship Corrosion resisting paint without need of cleaning rust, the ship band in embodiment seven
The preparation method of rust anticorrosive paint, includes the following steps：
S1, stock, by styrene-acrylic emulsion 23%, epoxy resin 16%, acrylic resin modified 14%, zinc oxide 1.5%, phosphorus
Sour diphenylguanidine 1.5%, iron oxide red 13.5%, graphene 13.5%, barium sulfate 13.5%, calgon 0.2%, methylpent
Alcohol 0.1%, polysiloxane-based antifoaming agent 0.2% and silane coupling agent 3% are stocked up by the proportioning in embodiment seven；
S2, batch mixing：Epoxy resin and acrylic resin modified is sequentially added in styrene-acrylic emulsion, after stirring and dissolving successively plus
Enter zinc oxide, phosphoric acid diphenylguanidine, iron oxide red, graphene, barium sulfate, calgon, methyl anyl alcohol, polysiloxane-based defoaming
Agent and silane coupling agent are stirring evenly and then adding into filler disease fineness of grind to 9 μm, detect viscosity, filter, discharging, wrap after qualified
Dress obtains.
Experiment：On the shipbuilding steel plate surface that corrosion class is D grades, after the floating rust surface treatment degree of removing reaches DSt ranks
Direct spraying ship Corrosion resisting paint without need of cleaning rust of the present invention after placing 3-4 hours at room temperature, is placed in 60 DEG C of oven dryings 6 hours, film
50-60 microns thick, observation discovery surface of steel plate is without rusty scale after standing 48 hours, and coating surface is uniform, and covering is high, adhesive force
It is good.
Implement the present invention, has the advantages that：
(1) ship Corrosion resisting paint without need of cleaning rust of the invention can be brushed directly in the surface of ship corrosion steel, antirust effect
Fruit is good, environmentally friendly, pollution-free, suitable for there is the antirust of the ship steel surface of corrosion, hard oxide scale layer or old paint film.
(2) ship Corrosion resisting paint without need of cleaning rust of the invention, permeability is strong, and when application can penetrate into steel surface rust layer simultaneously
Entire rusty scale is closed, coating adhesion is high, and coating quality is good, and can use under severe conditions, has preferable resistance to
Long property and weatherability.
(3) preparation method of ship Corrosion resisting paint without need of cleaning rust of the invention, the preparation method is simple for process, suitable for industrialization
Production can be applied to each industry such as petrochemical industry, wind-powered electricity generation, mechanical equipment, vehicle, road and bridge, food processing and civilian neck
Domain.
Above disclosed is only several preferred embodiments of the present invention, cannot limit the present invention's with this certainly
Interest field, therefore equivalent changes made in accordance with the claims of the present invention, are still within the scope of the present invention.
Claims (7)
1. a kind of ship Corrosion resisting paint without need of cleaning rust is used for the surface of direct brushing ship corrosion steel, which is characterized in that the ship
Oceangoing ship Corrosion resisting paint without need of cleaning rust is formulated composed of the following components by mass percentage：Styrene-acrylic emulsion 20-25%, epoxy resin 15-
20%, acrylic resin modified 5-20%, stable rust 3-5%, filler 10-50%, dispersant 0.1-0.3%, antifoaming agent 0.1-
0.4% and coupling agent 1-3%.
2. ship Corrosion resisting paint without need of cleaning rust according to claim 1, which is characterized in that the stable rust is zinc oxide and phosphorus
The mass ratio of sour diphenylguanidine, the zinc oxide and the phosphoric acid diphenylguanidine is 1：1.
3. ship Corrosion resisting paint without need of cleaning rust according to claim 2, which is characterized in that the filler is iron oxide red, stone
It is one or more in black alkene or barium sulfate.
4. ship Corrosion resisting paint without need of cleaning rust according to claim 1 or 3, which is characterized in that the dispersant is polypropylene
It is one or more in amide, fatty acid polyethylene glycol ester, calgon or methyl anyl alcohol.
5. ship Corrosion resisting paint without need of cleaning rust according to claim 4, which is characterized in that the antifoaming agent is polysiloxane-based
Antifoaming agent, the coupling agent are silane coupling agent.
6. ship Corrosion resisting paint without need of cleaning rust according to claim 1, which is characterized in that the ship Corrosion resisting paint without need of cleaning rust
Formula is composed of the following components by mass percentage：Styrene-acrylic emulsion 20%, epoxy resin 20% are acrylic resin modified
10%, stable rust 4%, filler 43.8%, dispersant 0.1%, antifoaming agent 0.1% and coupling agent 2%.
7. a kind of preparation method of ship Corrosion resisting paint without need of cleaning rust, which is characterized in that include the following steps：S1, stock, by benzene
Acrylic emulsion, epoxy resin, acrylic resin modified, stable rust, filler, dispersant, antifoaming agent and coupling agent carry out standby according to the ratio
Material；
S2, batch mixing：Epoxy resin and acrylic resin modified is sequentially added in styrene-acrylic emulsion, is sequentially added after stirring and dissolving steady
Become rusty agent, dispersant, antifoaming agent and coupling agent, is stirring evenly and then adding into filler disease fineness of grind to 5-10 μm, detects viscosity, qualified
It filters, discharge afterwards, packaging obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810204404.0A CN108531004A (en) | 2018-03-13 | 2018-03-13 | A kind of ship Corrosion resisting paint without need of cleaning rust and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810204404.0A CN108531004A (en) | 2018-03-13 | 2018-03-13 | A kind of ship Corrosion resisting paint without need of cleaning rust and preparation method thereof |
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| CN108531004A true CN108531004A (en) | 2018-09-14 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109501995A (en) * | 2018-12-25 | 2019-03-22 | 南通理工学院 | A kind of new energy hybrid power ship battery system |
| CN113004759A (en) * | 2020-12-30 | 2021-06-22 | 昆明狴犴人力资源服务有限公司 | Organic coating material on surface of neodymium iron boron permanent magnet and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101775108A (en) * | 2010-03-26 | 2010-07-14 | 哈尔滨工业大学 | Synthesis of modified aqueous epoxy resin and method for preparing antiseptic rusty paint |
| CN102206446A (en) * | 2010-03-31 | 2011-10-05 | 王胜美 | Preparation method for water-based anti-rust paint for rusty surfaces |
| CN106243862A (en) * | 2016-08-23 | 2016-12-21 | 中国科学院宁波材料技术与工程研究所 | Electric power pylon anti-corrosion primer, its preparation method and application |
-
2018
- 2018-03-13 CN CN201810204404.0A patent/CN108531004A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101775108A (en) * | 2010-03-26 | 2010-07-14 | 哈尔滨工业大学 | Synthesis of modified aqueous epoxy resin and method for preparing antiseptic rusty paint |
| CN102206446A (en) * | 2010-03-31 | 2011-10-05 | 王胜美 | Preparation method for water-based anti-rust paint for rusty surfaces |
| CN106243862A (en) * | 2016-08-23 | 2016-12-21 | 中国科学院宁波材料技术与工程研究所 | Electric power pylon anti-corrosion primer, its preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 北京市职工技术协会，北京市技术交流中心: "《涂装技师手册》", 30 April 2005 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109501995A (en) * | 2018-12-25 | 2019-03-22 | 南通理工学院 | A kind of new energy hybrid power ship battery system |
| CN113004759A (en) * | 2020-12-30 | 2021-06-22 | 昆明狴犴人力资源服务有限公司 | Organic coating material on surface of neodymium iron boron permanent magnet and preparation method thereof |
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Application publication date: 20180914 |