CN106752014A - Stalk/weaving dead meal/plastic waste composite coining product and its manufacture method - Google Patents

Stalk/weaving dead meal/plastic waste composite coining product and its manufacture method Download PDF

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Publication number
CN106752014A
CN106752014A CN201710022260.2A CN201710022260A CN106752014A CN 106752014 A CN106752014 A CN 106752014A CN 201710022260 A CN201710022260 A CN 201710022260A CN 106752014 A CN106752014 A CN 106752014A
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China
Prior art keywords
plastic waste
stalk
dead meal
weaving
weaving dead
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CN201710022260.2A
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Chinese (zh)
Inventor
张长武
黄海兵
张佳彬
潘立其
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Ningbo Pan Environmental Protection Technology Co Ltd
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Ningbo Pan Environmental Protection Technology Co Ltd
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Priority to CN201710022260.2A priority Critical patent/CN106752014A/en
Publication of CN106752014A publication Critical patent/CN106752014A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/007Manufacture of substantially flat articles, e.g. boards, from particles or fibres and at least partly composed of recycled material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/02Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/10Esters of organic acids, i.e. acylates
    • C08L1/12Cellulose acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/22Cellulose xanthate
    • C08L1/24Viscose
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18Homopolymers or copolymers of nitriles
    • C08L33/20Homopolymers or copolymers of acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

Abstract

The invention discloses a kind of stalk/weaving dead meal/plastic waste composite coining product and its manufacture method, the composite coining product is fabricated by by stalk, weaving dead meal, plastic waste, isocyanate adhesive molding, and specific manufacture method is as follows:First, the form according to stalk is processed to stalk, obtains irregular crushed straw aggregate, dries to moisture content and is down to less than 15%;2nd, weaving dead meal is processed into irregular fragment, dries to moisture content and be down to less than 15%;3rd, plastic waste is processed into irregular fragment, dries to moisture content and be down to less than 15%;4th, enter glue mixer after mixing dried crushed straw aggregate, weaving dead meal and plastic waste in proportion, apply isocyanate adhesive, mat formation in a mold, send into hot press hot pressing compression molding.Raw materials for production of the present invention belong to twice laid, have greatly saved cost of goods manufactured, improve added value of product, while it also avoid the stacking and burning of discarded object, protect environment.

Description

Stalk/weaving dead meal/plastic waste composite coining product and its manufacture method
Technical field
The present invention relates to a kind of composite coining product and its manufacture method.
Background technology
Stalk is the general name of ripe crops cauline leaf (fringe) part, belongs to string class.China as large agricultural country, often Year can generate more than 700,000,000 tons of stalk.The utilization technology of current stalk mainly includes:Mechanized Straw also field, excessively abdomen also field, cultivation food With bacterium, Biogas, as the raw material of industry, for modes such as biomass power generations.Stalk contains substantial amounts of cellulose, is alternative The valuable renewable resource of timber.It is difficult gluing technique, adhesive price currently with the difficult point of stalk manufacture wood-based plate Height, early investment is big etc..
Weaving dead meal is from the leftover bits of garment enterprise, and the species included in this kind of discarded object is more, such as acrylic fibers, Terylene, linen-cotton etc., the mixture of often several fibers, ratio do not know, random composition.The recovery profit of current waste textile With physiochemical mutagens, chemical recovery and energy regenerating can be divided into.Physiochemical mutagens refer to using mechanical means decomposition or crush textile, lead to Classification, purification, drying, reprocessing treatment are crossed, the production of fabric is reused for;But classification is difficult, technical requirements are high, and pre-treatment should It is many with equipment, high cost.Chemical recovery is to allow high molecular polymer depolymerization to decompose by chemical method to regroup, but technique is multiple It is miscellaneous, and to add chemical solvent.Energy regenerating is, by burning generation heat, for thermal power generation, but environment to be produced dirty Dye.
Plastic waste could be rotted for 500~1000 years, and landfill is easily polluted to soil and water quality, and burning can have been produced Evil gas, pollutes to air.The purposes of current recycled plastic is used to produce regenerated plastics, but product quality is poor, property It is unstable, easily become fragile, it is only used for the production of low grade products.
Above-mentioned three kinds of raw materials belong to mutually immiscible material in chemistry, and surface nature has obvious difference, therefore There is larger difficulty in compound aspect, relevant report is had no at present.
The content of the invention
It is an object of the invention to provide a kind of stalk/weaving dead meal/plastic waste composite coining product and its manufacturer Method, makes full use of weaving leftover bits, plastic waste that stalk and garment enterprise are produced as primary raw material, imposes isocyanates Adhesive, forms the stalk with characteristic of environmental protection/weaving discarded object/plastic waste composite coining product, has both reduced to wood Material demand, prevents pollution problem of these raw materials to environment again.
The purpose of the present invention is achieved through the following technical solutions:
A kind of stalk/weaving dead meal/plastic waste composite coining product, by stalk, weaving dead meal, plastic waste, Isocyanate adhesive molding is fabricated by, wherein:The mass ratio of stalk, weaving dead meal and plastic waste is 20~90:10 ~40:10~40, the applied amount of isocyanate adhesive for over dry material (stalk+weaving dead meal+plastic waste) quality 1~ 6%.
A kind of manufacture method of above-mentioned wood particulate/weaving dead meal/plastic waste composite coining product, including following step Suddenly:
First, the form according to stalk is processed to stalk, obtains irregular crushed straw aggregate, dries to moisture content drop To less than 15%;
2nd, weaving dead meal is processed into irregular fragment, dries to moisture content and be down to less than 15%;
3rd, plastic waste is processed into irregular fragment, dries to moisture content and be down to less than 15%;
4th, enter glue mixer after mixing dried crushed straw aggregate, weaving dead meal and plastic waste in proportion, apply Isocyanate adhesive, mats formation in a mold, sends into hot press hot pressing compression molding, controls hot pressing temperature for 160~200 DEG C, Unit pressure is 4.0~7.0MPa, and the dwell time is 15~30 seconds/mm.
In the present invention, the weaving dead meal can be discarded weaving face fabric cotton, fiber crops, polyamide fibre, acrylic fibers, spandex, terylene, glutinous The mixture of one or more compositions in glue fiber, acetate fiber, but it is not limited to these compositions.
In the present invention, the plastic waste is the mixture of one or more compositions in PE, PP, PET.
In the present invention, the adhesive be isocyanate adhesive or Urea-formaldehyde resin adhesive, wherein:Isocyanates is gluing The applied amount of agent is the 1~6% of over dry material (wood particulate+weaving dead meal+plastic waste) quality, Urea-formaldehyde resin adhesive Applied amount is the 8~15% of over dry material (wood particulate+weaving dead meal+plastic waste) quality.
In the present invention, the size of the composite coining product is:Length × width x thickness=(500~2440) mm × (500~ 1220) mm × (8~180) mm.
In the present invention, the length of the irregular crushed straw aggregate is 1~20mm, width be 0.5~7mm, thickness be 0.2~ 2mm。
In the present invention, the area of the weaving irregular fragment of dead meal is 100~400mm2
In the present invention, the area of the irregular fragment of plastic waste is 100~400mm2
The invention has the advantages that:
(1) raw materials for production belong to twice laid, and the purchase cost of stalk, weaving discarded object and plastic waste is extremely low, not even Purchase cost is needed, cost of goods manufactured has greatly been saved, added value of product is improved, while it also avoid the stacking of discarded object And burning, protect environment.
(2) stalk fibre is instead of to a certain extent using textile fabric, save the raw material output-input ratio of stalk, and Increased the toughness of composite coining product.
(3) addition of plastic waste can a certain degree of consumption for reducing adhesive.
(4) the characteristics of composite coining product produced by the present invention has light weight, intensity high, low cost, without formaldehyde, ring Protect and have concurrently certain water resistance and anti-flammability.
(5) the composite coining product properties is excellent, and without formaldehyde, MOR and elastic modelling quantity can meet use requirement, Water resistance is good, dimensionally stable, and production cost is relatively low, widely used.Different according to material rate, finished product can be widely used for building Build, interior decoration, the field such as transport.
Brief description of the drawings
Fig. 1 is the manufacturing process flow diagram of wood particulate/weaving dead meal/plastic waste composite coining product.
Specific embodiment
Technical scheme is further described with reference to embodiment, but is not limited thereto, it is every right Technical solution of the present invention is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention, all should be contained Cover in protection scope of the present invention.
Embodiment 1:
In the present embodiment, stalk/weaving dead meal/plastic waste composite coining product is by stalk, weaving dead meal, plastics Waste material, isocyanate adhesive molding are fabricated by, wherein:The mass ratio of stalk, weaving dead meal and plastic waste is 80: 10:10, the applied amount of isocyanate adhesive is the 1~6% of over dry material (stalk+weaving dead meal+plastic waste) quality.Such as Shown in Fig. 1, specific manufacture method is as follows:
First, the form according to stalk is processed to raw material, forms length for 2~5mm, width are that 1~3mm, thickness are The irregular particle of 0.5~1mm;Into wet feed feed bin, treatment is dried, dries to moisture content and be down to less than 15%;
2nd, weaving dead meal is carried out into machinery to smash, is processed into area for 100~200mm2Irregular fragment;Into Wet feed feed bin, is dried treatment, dries to moisture content and is down to less than 15%;
3rd, it is 100~200mm the method that plastic waste uses chopping or smashes to be processed into area2Irregular fragment; Into wet feed feed bin, treatment is dried, dries to moisture content and be down to less than 15%;
4th, siccative feed bin is entered after mixing dried crushed straw aggregate, weaving dead meal and plastic waste in proportion;
5th, according to product needed, discharging in proportion enters glue mixer, applies adhesive, mats formation in a mold, sends into hot pressing Machine hot pressing compression molding, it is 180 DEG C to control hot pressing temperature, and unit pressure is 5.5MPa, and the dwell time is 18 seconds/mm, forms tool There is the composite coining product of certain geometrical shape.
In the present embodiment, composite coining product properties is excellent, and MOR 25MPa, elastic modelling quantity is 4500MPa, interior knot It is that 4.5%, 24h thickness swelling rates are 14.5% to close intensity 0.84MPa, 2h thickness swelling rate.
In the present embodiment, the size of the composite coining product is:Length × width x thickness=1200mm × 1000mm × 15mm.
In the present embodiment, the weaving dead meal is discarded weaving face fabric cotton, fiber crops, polyamide fibre, acrylic fibers, spandex, terylene, viscose The mixture of one or more compositions in fiber, acetate fiber, accounting 10%, you can obtain good toughening effect.
In the present embodiment, the plastic waste is the mixture of one or more compositions in PE, PP, PET, and accounting does not surpass Cross 10%, you can in the consumption of reduction adhesive to a certain degree, and increase the intensity of pressing.
In the present embodiment, the isocyanate adhesive is purchased from Wanhua Chemical Group Co., Ltd..Add in applying glue Enter a certain amount of solvent (not higher than 10%), on the one hand reduce the cost of adhesive, on the other hand improve dividing for isocyanates Property is dissipated, is more uniformly distributed glue spraying, improve product quality.
Embodiment 2:
The present embodiment is with the difference of embodiment 1 yes:The mass ratio of stalk, weaving dead meal and plastic waste is 50:20: 30, the applied amount of isocyanate adhesive is the 4% of over dry material (stalk+weaving dead meal+plastic waste) quality.Properties of product It is as follows:MOR is 17MPa, and elastic modelling quantity is 3200MPa, and internal bond strength is 0.58MPa, and 2h thickness swelling rates are 4.0%, 24h thickness swelling rate are 9.8%.
Embodiment 3:
The present embodiment is with the difference of embodiment 1 yes:The mass ratio of stalk, weaving dead meal and plastic waste is 50:30: 20, the applied amount of isocyanate adhesive is the 4% of over dry material (stalk+weaving dead meal+plastic waste) quality.MOR 18MPa, elastic modelling quantity is 2200MPa, and internal bond strength 0.58MPa, 2h thickness swelling rate are 1.9%, 24h water sucting thickness Expansion rate is 6.2%.
Embodiment 4:
The present embodiment is with the difference of embodiment 1 yes:The mass ratio of stalk, weaving dead meal and plastic waste is 20:40: 40, the applied amount of isocyanate adhesive is the 3% of over dry material (stalk+weaving dead meal+plastic waste) quality.Properties of product It is as follows:MOR is 15MPa, and elastic modelling quantity is 1800MPa, and internal bond strength is 0.54MPa, and 2h thickness swelling rates are 3.6%, 24h thickness swelling rate are 8.3%.
Embodiment 5:
The present embodiment is with the difference of embodiment 1~4 yes:The adhesive is Urea-formaldehyde resin adhesive, and its applied amount is exhausted The 10% of siccative quality.

Claims (8)

1. a kind of stalk/weaving dead meal/plastic waste composite coining product, it is characterised in that the composite coining product is by straw Stalk, weaving dead meal, plastic waste, isocyanate adhesive molding are fabricated by, wherein:Stalk, weaving dead meal and plastics The mass ratio of waste material is 20~90:10~40:10~:40, the applied amount of isocyanate adhesive is stalk, weaving dead meal and The 1~6% of plastic waste absolute dry mass.
2. stalk according to claim 1/weaving dead meal/plastic waste composite coining product, it is characterised in that described The size of composite coining product is:Length × width x thickness=(500~2440) mm × (500~1220) mm × (8~180) mm.
3. stalk according to claim 1/weaving dead meal/plastic waste composite coining product, it is characterised in that described Weaving dead meal be one kind in discarded weaving face fabric cotton, fiber crops, polyamide fibre, acrylic fibers, spandex, terylene, viscose fiber, acetate fiber or The mixture of several compositions.
4. stalk according to claim 1/weaving dead meal/plastic waste composite coining product, it is characterised in that described Plastic waste is the mixture of one or more compositions in PE, PP, PET.
5. the wood particulate described in a kind of claim 1-4 any claims/weaving dead meal/plastic waste compound die compacting The manufacture method of product, it is characterised in that methods described step is as follows:
First, the form according to stalk is processed to stalk, obtains irregular crushed straw aggregate, dries to moisture content and is down to Less than 15%;
2nd, weaving dead meal is processed into irregular fragment, dries to moisture content and be down to less than 15%;
3rd, plastic waste is processed into irregular fragment, dries to moisture content and be down to less than 15%;
4th, enter glue mixer after mixing dried crushed straw aggregate, weaving dead meal and plastic waste in proportion, apply isocyanide Acid esters adhesive, mats formation in a mold, sends into hot press hot pressing compression molding, and it is 160~200 DEG C, unit to control hot pressing temperature Pressure is 4.0~7.0MPa, and the dwell time is 15~30 seconds/mm.
6. the manufacture method of stalk according to claim 5/weaving dead meal/plastic waste composite coining product, it is special Levy in being the step one, the length of irregular crushed straw aggregate is 1~20mm, width be 0.5~7mm, thickness be 0.2~ 2mm。
7. the manufacture method of stalk according to claim 5/weaving dead meal/plastic waste composite coining product, it is special Levy in being the step 2, the area of irregular fragment is 100~400mm2
8. the manufacture method of stalk according to claim 5/weaving dead meal/plastic waste composite coining product, it is special Levy in being the step 3, the area of irregular fragment is 100~400mm2
CN201710022260.2A 2017-01-12 2017-01-12 Stalk/weaving dead meal/plastic waste composite coining product and its manufacture method Pending CN106752014A (en)

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CN201710022260.2A CN106752014A (en) 2017-01-12 2017-01-12 Stalk/weaving dead meal/plastic waste composite coining product and its manufacture method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113736278A (en) * 2021-08-30 2021-12-03 上海纤苏新材料科技有限公司 Fiber-plastic section floor tile and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101058210A (en) * 2007-06-05 2007-10-24 李茂林 Regenerating fabric fiber plywood and its manufacturing method
CN101879740A (en) * 2010-06-22 2010-11-10 上海理工大学 Method for preparing vegetable fiber-plastic composite density board
CN102205765A (en) * 2011-04-02 2011-10-05 匡赞辉 Method for producing agricultural residue wheat straw/waste plastic pencil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101058210A (en) * 2007-06-05 2007-10-24 李茂林 Regenerating fabric fiber plywood and its manufacturing method
CN101879740A (en) * 2010-06-22 2010-11-10 上海理工大学 Method for preparing vegetable fiber-plastic composite density board
CN102205765A (en) * 2011-04-02 2011-10-05 匡赞辉 Method for producing agricultural residue wheat straw/waste plastic pencil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113736278A (en) * 2021-08-30 2021-12-03 上海纤苏新材料科技有限公司 Fiber-plastic section floor tile and preparation method thereof

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Application publication date: 20170531