CN106751700A - A kind of high abrasion high tenacity rubber seal - Google Patents

A kind of high abrasion high tenacity rubber seal Download PDF

Info

Publication number
CN106751700A
CN106751700A CN201611225556.6A CN201611225556A CN106751700A CN 106751700 A CN106751700 A CN 106751700A CN 201611225556 A CN201611225556 A CN 201611225556A CN 106751700 A CN106751700 A CN 106751700A
Authority
CN
China
Prior art keywords
parts
abaca fibre
modified
concentration
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611225556.6A
Other languages
Chinese (zh)
Inventor
黄炳喜
杨浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI ARAM SEALS Co Ltd
Original Assignee
ANHUI ARAM SEALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI ARAM SEALS Co Ltd filed Critical ANHUI ARAM SEALS Co Ltd
Priority to CN201611225556.6A priority Critical patent/CN106751700A/en
Publication of CN106751700A publication Critical patent/CN106751700A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • C08L71/03Polyepihalohydrins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of high abrasion high tenacity rubber seal, its raw material includes by weight:30 50 parts of epichlorohydrin rubber, 12 20 parts of methyl vinyl silicone rubber, 20 30 parts of nitrile rubber, 6 12 parts of diatomite, 48 parts of calcium carbonate, 24 parts of magnesia, 12 16 parts of bismuth oxide, 10 20 parts of barium metaborate, 8 16 parts of glass microballoon, be modified 48 parts of abaca fibre, 24 parts of dimethyl silicone polymer, 36 parts of aminomethyl phenyl diethoxy silane, 48 parts of epoxy aliphatic acid methyl ester, 13 parts of magnesium stearate, 24 parts of diisononyl phthalate, 0.4 1 parts of Triallyl isocyanurate, 24 parts of dizinc acrylate resin, 1.5 3 parts of cumyl peroxide.The present invention has excellent wear-resisting and toughness, and with good resistance to elevated temperatures, while seal is non-aging, long service life.

Description

A kind of high abrasion high tenacity rubber seal
Technical field
The present invention relates to technical field of sealing technology, more particularly to a kind of high abrasion high tenacity rubber seal.
Background technology
Vehicle fuel pump seal is not only related to the normal use of fuel pump while being also related to the safety of vehicle, existing In technology caused by the normal sealing property problem having because of seal the problems such as oil leak, so that cause certain safety hidden to vehicle Suffer from.Vehicle fuel pump seal of the prior art generally uses nitrile rubber material, but nitrile rubber exist it is wear-resisting, The defect of toughness and resistance to elevated temperatures difference, long-term use cannot ensure the sealing effectiveness of seal, it would be highly desirable to solve.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of high abrasion high tenacity rubber seal, has There is excellent wear-resisting and toughness, though long-term use is also not in phenomenon of osmosis, and with good resistance to elevated temperatures, Long-term use will not also deform under high temperature, while seal is non-aging, long service life.
A kind of high abrasion high tenacity rubber seal proposed by the present invention, its raw material includes by weight:Epichlorohydrin rubber 30- 50 parts, methyl vinyl silicone rubber 12-20 parts, nitrile rubber 20-30 parts, diatomite 6-12 parts, calcium carbonate 4-8 parts, magnesia 2-4 parts, bismuth oxide 12-16 parts, barium metaborate 10-20 parts, glass microballoon 8-16 parts, be modified 4-8 parts of abaca fibre, poly dimethyl Siloxanes 2-4 parts, 3-6 parts of aminomethyl phenyl diethoxy silane, epoxy aliphatic acid methyl ester 4-8 parts, magnesium stearate 1-3 parts, adjacent benzene 2-4 parts of dioctyl phthalate dinonyl, Triallyl isocyanurate 0.4-1 parts, dizinc acrylate resin 2-4 parts, cumyl peroxide 1.5-3 parts.
Preferably, diatomite, calcium carbonate, magnesia, bismuth oxide, barium metaborate, glass microballoon, modified abaca fibre, poly- Dimethyl siloxane, the weight ratio of aminomethyl phenyl diethoxy silane are 8-10:5-7:2.5-3.5:13-15:13-17:10- 14:5-7:2.5-3.5:4-5.
Preferably, epoxy aliphatic acid methyl ester, magnesium stearate, the weight ratio of diisononyl phthalate are 5-7:1.5- 2.5:2.5-3.5.
Preferably, its raw material includes by weight:Epichlorohydrin rubber 35-45 parts, methyl vinyl silicone rubber 14-18 parts, fourth Nitrile rubber 22-28 parts, diatomite 8-10 parts, calcium carbonate 5-7 parts, magnesia 2.5-3.5 parts, bismuth oxide 13-15 parts, barium metaborate 13-17 parts, glass microballoon 10-14 parts, be modified 5-7 parts of abaca fibre, dimethyl silicone polymer 2.5-3.5 parts, aminomethyl phenyl two Ethoxysilane 4-5 parts, epoxy aliphatic acid methyl ester 5-7 parts, magnesium stearate 1.5-2.5 parts, diisononyl phthalate 2.5- 3.5 parts, Triallyl isocyanurate 0.6-0.8 parts, dizinc acrylate resin 2.5-3.5 parts, cumyl peroxide 2-2.5 parts.
Preferably, the abaca fibre that is modified is prepared using following technique:By bamboo powder feeding sodium hydroxide solution immersion, filter, Dry, heated up in feeding vacuum tank, insulation, intensification, insulation, cooling, washing adds sodium hydroxide solution stirring equal to being in neutrality It is even, add solution of zinc sulfate to stir, vacuum filtration, to ammoniacal liquor is added dropwise in filter cake, add cetyl trimethylammonium bromide, Abaca fibre, tributyl phosphate microwave treatment, filtering, washing dry, pulverize and obtains modified abaca fibre.
Preferably, the abaca fibre that is modified is prepared using following technique:30-50 parts of bamboo powder is sent into concentration by weight is The sodium hydroxide solution immersion of 1.5-2.5mol/L, filtering is dried, and is heated up in feeding vacuum tank, and insulation heats up, insulation, drop Temperature, washing adds 80-120 parts of concentration to be stirred for the sodium hydroxide solution of 1-3wt% extremely in neutrality, and 10-30 parts of addition is dense Spend for the solution of zinc sulfate of 1.5-2.5wt% stirs, vacuum filtration, be 10-20% to 15-25 parts of concentration is added dropwise in filter cake Ammoniacal liquor, add 1-3 parts of cetyl trimethylammonium bromide, 25-45 parts of abaca fibre, at 50-70 parts of tributyl phosphate microwave Reason, filtering, washing dry, pulverize and obtain modified abaca fibre.
Preferably, the abaca fibre that is modified is prepared using following technique:30-50 parts of bamboo powder is sent into concentration by weight is The sodium hydroxide solution immersion 15-35h of 1.5-2.5mol/L, filtering is dried, and 900-1100 DEG C is warming up in feeding vacuum tank, Insulation 10-20min, is warming up to 1400-1800 DEG C, is incubated 20-40min, lowers the temperature, and washing is in neutrality, and 80-120 parts of addition is dense Spend for the sodium hydroxide solution of 1-3wt% stirs, add 10-30 parts of concentration to be stirred for the solution of zinc sulfate of 1.5-2.5wt% Mix uniform, vacuum filtration is the ammoniacal liquor of 10-20% to 15-25 parts of concentration is added dropwise in filter cake, adds 1-3 parts of cetyl front three Base ammonium bromide, 25-45 part abaca fibre, 50-70 parts of tributyl phosphate microwave treatment 10-20min, microwave power is 350- 450W, filtering, washing dry, pulverize and obtain modified abaca fibre.
The present invention is obtained using conventional fabrication process.
The present invention has excellent wear-resisting and toughness, though long-term use is also not in phenomenon of osmosis, and with very Good resistance to elevated temperatures, long-term use will not also deform at high temperature, while seal is non-aging, long service life.
The present invention with modified butadiene acrylonitrile rubber, epichlorohydrin rubber, methyl vinyl silicone rubber as major ingredient, using peroxidating diisopropyl Benzene, Triallyl isocyanurate, dizinc acrylate resin collaboration make crosslinking degree of the present invention good as vulcanizing system, and elasticity is good, high The lower compression resistant permanent deformation performance of temperature is extremely excellent;In modified abaca fibre of the invention, bamboo powder is by NaOH and vacuum After calcining charing process, greatly, pore structure is flourishing for specific surface area, and surface-active is high, with NaOH, zinc sulfate and ammoniacal liquor Cooperation generates zinc oxide particles and can be grown in pretreatment bamboo powder surface, and in cetyl trimethylammonium bromide, tricresyl phosphate fourth Intert with the fiber of abaca fibre and formed network structure in the presence of ester, improve antibacterial, the uvioresistant of modified abaca fibre Performance, mechanical property is good;Modified abaca fibre cooperates with barium metaborate, bismuth oxide, calcium carbonate, diatomite, glass microballoon, More preferably, under aminomethyl phenyl diethoxy silane, the cooperation of dimethyl silicone polymer, mutual adhesion is strong, makes this for adsorptivity Invention anti-wear performance is excellent, and good toughness, resistance to elevated temperatures is excellent;Epoxy aliphatic acid methyl ester, magnesium stearate, phthalic acid two are different Nonyl ester can effectively strengthen the mobility of sizing material, further enhance of the invention elastic and resistance to permanent compression set, though compared with It is elastic also fabulous with resistance to permanent compression set performance under the big temperature difference.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high abrasion high tenacity rubber seal proposed by the present invention, its raw material includes by weight:Epichlorohydrin rubber 30 Part, 20 parts of methyl vinyl silicone rubber, 20 parts of nitrile rubber, 12 parts of diatomite, 4 parts of calcium carbonate, 4 parts of magnesia, bismuth oxide 12 Part, 20 parts of barium metaborate, 8 parts of glass microballoon, be modified 8 parts of abaca fibre, 2 parts of dimethyl silicone polymer, aminomethyl phenyl diethoxy 6 parts of base silane, 4 parts of epoxy aliphatic acid methyl ester, 3 parts of magnesium stearate, 2 parts of diisononyl phthalate, triallyl isocyanide urea 1 part of acid esters, 2 parts of dizinc acrylate resin, 3 parts of cumyl peroxide.
Embodiment 2
A kind of high abrasion high tenacity rubber seal proposed by the present invention, its raw material includes by weight:Epichlorohydrin rubber 50 Part, 12 parts of methyl vinyl silicone rubber, 30 parts of nitrile rubber, 6 parts of diatomite, 8 parts of calcium carbonate, 2 parts of magnesia, bismuth oxide 16 Part, 10 parts of barium metaborate, 16 parts of glass microballoon, be modified 4 parts of abaca fibre, 4 parts of dimethyl silicone polymer, aminomethyl phenyl diethoxy 3 parts of base silane, 8 parts of epoxy aliphatic acid methyl ester, 1 part of magnesium stearate, 4 parts of diisononyl phthalate, triallyl isocyanide urea 0.4 part of acid esters, 4 parts of dizinc acrylate resin, 1.5 parts of cumyl peroxide.
Modified abaca fibre is prepared using following technique:Bamboo powder feeding sodium hydroxide solution immersion, filtering are dried, sent Enter intensification in vacuum tank, insulation is heated up, and insulation is lowered the temperature, wash in neutrality, addition sodium hydroxide solution stirs, addition Solution of zinc sulfate stirs, vacuum filtration, to ammoniacal liquor is added dropwise in filter cake, adds cetyl trimethylammonium bromide, abaca fine Dimension, tributyl phosphate microwave treatment, filtering, washing dry, pulverize and obtains modified abaca fibre.
Embodiment 3
A kind of high abrasion high tenacity rubber seal proposed by the present invention, its raw material includes by weight:Epichlorohydrin rubber 35 Part, 18 parts of methyl vinyl silicone rubber, 22 parts of nitrile rubber, 10 parts of diatomite, 5 parts of calcium carbonate, 3.5 parts of magnesia, bismuth oxide 13 parts, 17 parts of barium metaborate, 10 parts of glass microballoon, be modified 7 parts of abaca fibre, 2.5 parts of dimethyl silicone polymer, aminomethyl phenyl two 5 parts of Ethoxysilane, 5 parts of epoxy aliphatic acid methyl ester, 2.5 parts of magnesium stearate, 2.5 parts of diisononyl phthalate, three allyls 0.8 part of base isocyanuric acid ester, 2.5 parts of dizinc acrylate resin, 2.5 parts of cumyl peroxide.
Modified abaca fibre is prepared using following technique:It is the hydrogen-oxygen of 2mol/L that 40 parts of bamboo powders are sent into concentration by weight Change sodium solution immersion, filtering is dried, and is heated up in feeding vacuum tank, and insulation heats up, insulation, cooling, and washing is added in neutrality 100 parts of concentration stir for the sodium hydroxide solution of 2wt%, add 20 parts of concentration equal for the solution of zinc sulfate stirring of 2wt% It is even, vacuum filtration, to the ammoniacal liquor that 20 parts of concentration are 15% is added dropwise in filter cake, add 2 parts of cetyl trimethylammonium bromides, 35 parts Abaca fibre, 60 parts of tributyl phosphate microwave treatments, filtering, washing dry, pulverize and obtains modified abaca fibre.
Embodiment 4
A kind of high abrasion high tenacity rubber seal proposed by the present invention, its raw material includes by weight:Epichlorohydrin rubber 45 Part, 14 parts of methyl vinyl silicone rubber, 28 parts of nitrile rubber, 8 parts of diatomite, 7 parts of calcium carbonate, 2.5 parts of magnesia, bismuth oxide 15 Part, 13 parts of barium metaborate, 14 parts of glass microballoon, be modified 5 parts of abaca fibre, 3.5 parts of dimethyl silicone polymer, aminomethyl phenyl diethyl 4 parts of TMOS, 7 parts of epoxy aliphatic acid methyl ester, 1.5 parts of magnesium stearate, 3.5 parts of diisononyl phthalate, triallyl 0.6 part of isocyanuric acid ester, 3.5 parts of dizinc acrylate resin, 2 parts of cumyl peroxide.
Modified abaca fibre is prepared using following technique:It is the hydrogen of 2.5mol/L that 30 parts of bamboo powders are sent into concentration by weight Sodium hydroxide solution soaks 15h, and filtering is dried, and 1100 DEG C are warming up in feeding vacuum tank, is incubated 10min, is warming up to 1800 DEG C, Insulation 20min, cooling, washing adds 120 parts of concentration to be stirred for the sodium hydroxide solution of 1-3wt% in neutrality, adds 10-30 parts of concentration stirs for the solution of zinc sulfate of 1.5-2.5wt%, vacuum filtration, is to 15 parts of concentration are added dropwise in filter cake 20% ammoniacal liquor, adds 1 part of cetyl trimethylammonium bromide, 45 parts of abaca fibres, 50 parts of tributyl phosphate microwave treatments 20min, microwave power is 350W, filtering, washing, dry, pulverize and obtains modified abaca fibre.
Embodiment 5
A kind of high abrasion high tenacity rubber seal proposed by the present invention, its raw material includes by weight:Epichlorohydrin rubber 40 Part, 16 parts of methyl vinyl silicone rubber, 26 parts of nitrile rubber, 9 parts of diatomite, 6 parts of calcium carbonate, 3 parts of magnesia, bismuth oxide 14 Part, 15 parts of barium metaborate, 12 parts of glass microballoon, be modified 6 parts of abaca fibre, 3 parts of dimethyl silicone polymer, aminomethyl phenyl diethoxy 4.5 parts of base silane, 6 parts of epoxy aliphatic acid methyl ester, 2 parts of magnesium stearate, 3 parts of diisononyl phthalate, triallyl isocyanide 0.7 part of urea acid esters, 3 parts of dizinc acrylate resin, 2.2 parts of cumyl peroxide.
Modified abaca fibre is prepared using following technique:It is the hydrogen of 1.5mol/L that 50 parts of bamboo powders are sent into concentration by weight Sodium hydroxide solution soaks 35h, and filtering is dried, and 900 DEG C are warming up in feeding vacuum tank, is incubated 20min, is warming up to 1400 DEG C, is protected Warm 40min, cooling, washing adds 80 parts of concentration to be stirred for the sodium hydroxide solution of 3wt% in neutrality, adds 10 parts Concentration stirs for the solution of zinc sulfate of 2.5wt%, vacuum filtration, to the ammoniacal liquor that 15 parts of concentration of dropwise addition in filter cake are 20%, Add 1 part of cetyl trimethylammonium bromide, 45 parts of abaca fibres, 50 parts of tributyl phosphate microwave treatment 20min, microwave power It is 350W, filtering, washing dry, pulverize and obtain modified abaca fibre.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of high abrasion high tenacity rubber seal, it is characterised in that its raw material includes by weight:Epichlorohydrin rubber 30-50 Part, methyl vinyl silicone rubber 12-20 parts, nitrile rubber 20-30 parts, diatomite 6-12 parts, calcium carbonate 4-8 parts, magnesia 2-4 Part, bismuth oxide 12-16 parts, barium metaborate 10-20 parts, glass microballoon 8-16 parts, be modified 4-8 parts of abaca fibre, poly dimethyl silicon 2-4 parts of oxygen alkane, 3-6 parts of aminomethyl phenyl diethoxy silane, epoxy aliphatic acid methyl ester 4-8 parts, magnesium stearate 1-3 parts, adjacent benzene two 2-4 parts of formic acid dinonyl, Triallyl isocyanurate 0.4-1 parts, dizinc acrylate resin 2-4 parts, cumyl peroxide 1.5-3 parts.
2. high abrasion high tenacity rubber seal according to claim 1, it is characterised in that diatomite, calcium carbonate, oxidation Magnesium, bismuth oxide, barium metaborate, glass microballoon, modified abaca fibre, dimethyl silicone polymer, aminomethyl phenyl diethoxy silane Weight ratio be 8-10:5-7:2.5-3.5:13-15:13-17:10-14:5-7:2.5-3.5:4-5.
3. high abrasion high tenacity rubber seal according to claim 1 or claim 2, it is characterised in that epoxy aliphatic acid methyl ester, hard Fatty acid magnesium, the weight ratio of diisononyl phthalate are 5-7:1.5-2.5:2.5-3.5.
4. the high abrasion high tenacity rubber seal according to claim any one of 1-3, it is characterised in that its raw material is by weight Part includes:Epichlorohydrin rubber 35-45 parts, methyl vinyl silicone rubber 14-18 parts, nitrile rubber 22-28 parts, diatomite 8-10 parts, Calcium carbonate 5-7 parts, magnesia 2.5-3.5 parts, bismuth oxide 13-15 parts, barium metaborate 13-17 parts, glass microballoon 10-14 parts, change Property 5-7 parts of abaca fibre, dimethyl silicone polymer 2.5-3.5 parts, 4-5 parts of aminomethyl phenyl diethoxy silane, epoxyfatty acid Methyl esters 5-7 parts, magnesium stearate 1.5-2.5 parts, diisononyl phthalate 2.5-3.5 parts, Triallyl isocyanurate 0.6-0.8 parts, dizinc acrylate resin 2.5-3.5 parts, cumyl peroxide 2-2.5 parts.
5. the high abrasion high tenacity rubber seal according to claim any one of 1-4, it is characterised in that modified abaca fibre Prepared using following technique:Bamboo powder feeding sodium hydroxide solution immersion, filtering are dried, heated up in feeding vacuum tank, insulation, Heat up, insulation, cooling, washing adds solution of zinc sulfate to stir in neutrality, adding sodium hydroxide solution to stir, Vacuum filtration, to ammoniacal liquor is added dropwise in filter cake, adds at cetyl trimethylammonium bromide, abaca fibre, tributyl phosphate microwave Reason, filtering, washing dry, pulverize and obtain modified abaca fibre.
6. the high abrasion high tenacity rubber seal according to claim any one of 1-5, it is characterised in that modified abaca fibre Prepared using following technique:30-50 parts of bamboo powder is sent into concentration for the sodium hydroxide solution of 1.5-2.5mol/L soaks by weight Bubble, filtering is dried, and sends into intensification in vacuum tank, and insulation is heated up, and insulation is lowered the temperature, and is washed in neutrality, and 80-120 parts of addition is dense Spend for the sodium hydroxide solution of 1-3wt% stirs, add 10-30 parts of concentration to be stirred for the solution of zinc sulfate of 1.5-2.5wt% Mix uniform, vacuum filtration is the ammoniacal liquor of 10-20% to 15-25 parts of concentration is added dropwise in filter cake, adds 1-3 parts of cetyl front three Base ammonium bromide, 25-45 part abaca fibre, 50-70 parts of tributyl phosphate microwave treatment, filtering, washing dry, pulverize and changed Property abaca fibre.
7. the high abrasion high tenacity rubber seal according to claim any one of 1-6, it is characterised in that modified abaca fibre Prepared using following technique:30-50 parts of bamboo powder is sent into concentration for the sodium hydroxide solution of 1.5-2.5mol/L soaks by weight Bubble 15-35h, filtering is dried, and 900-1100 DEG C is warming up in feeding vacuum tank, is incubated 10-20min, is warming up to 1400-1800 DEG C, 20-40min is incubated, cooling, washing adds 80-120 parts of concentration to be stirred for the sodium hydroxide solution of 1-3wt% in neutrality Uniformly, 10-30 parts of concentration is added to be stirred for the solution of zinc sulfate of 1.5-2.5wt%, vacuum filtration is added dropwise in filter cake 15-25 parts of concentration is the ammoniacal liquor of 10-20%, adds 1-3 parts of cetyl trimethylammonium bromide, 25-45 parts of abaca fibre, 50- 70 parts of tributyl phosphate microwave treatment 10-20min, microwave power is 350-450W, filtering, and washing dry, pulverize and is modified Abaca fibre.
CN201611225556.6A 2016-12-27 2016-12-27 A kind of high abrasion high tenacity rubber seal Pending CN106751700A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611225556.6A CN106751700A (en) 2016-12-27 2016-12-27 A kind of high abrasion high tenacity rubber seal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611225556.6A CN106751700A (en) 2016-12-27 2016-12-27 A kind of high abrasion high tenacity rubber seal

Publications (1)

Publication Number Publication Date
CN106751700A true CN106751700A (en) 2017-05-31

Family

ID=58921931

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611225556.6A Pending CN106751700A (en) 2016-12-27 2016-12-27 A kind of high abrasion high tenacity rubber seal

Country Status (1)

Country Link
CN (1) CN106751700A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107245206A (en) * 2017-07-26 2017-10-13 安徽蓝通科技股份有限公司 A kind of polychloroethylene pipes of good airproof performance
CN109535510A (en) * 2018-11-21 2019-03-29 宁波旭泰橡胶工业有限公司 A kind of sealing ring
CN109749445A (en) * 2017-11-02 2019-05-14 丹阳市贝尔特橡塑制品有限公司 A kind of high-strength rubber product
CN110982243A (en) * 2019-12-23 2020-04-10 安徽微威环保科技有限公司 Wear-resistant rubber sealing strip material and preparation method thereof
CN112266511A (en) * 2020-10-30 2021-01-26 安徽中联汽车零部件有限公司 Preparation method of wear-resistant automobile Y-shaped rubber ring

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509297A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 Anti-aging transformer sealing gasket and preparation method thereof
CN104163994A (en) * 2014-07-09 2014-11-26 安徽京鸿密封件技术有限公司 Acid-resistant sealing member used for automobile radiator

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509297A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 Anti-aging transformer sealing gasket and preparation method thereof
CN104163994A (en) * 2014-07-09 2014-11-26 安徽京鸿密封件技术有限公司 Acid-resistant sealing member used for automobile radiator

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
周惠久: "《新材料辞典》", 31 December 1996 *
沈新元: "《高分子材料加工原理》", 31 December 2014, 中国纺织出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107245206A (en) * 2017-07-26 2017-10-13 安徽蓝通科技股份有限公司 A kind of polychloroethylene pipes of good airproof performance
CN109749445A (en) * 2017-11-02 2019-05-14 丹阳市贝尔特橡塑制品有限公司 A kind of high-strength rubber product
CN109535510A (en) * 2018-11-21 2019-03-29 宁波旭泰橡胶工业有限公司 A kind of sealing ring
CN110982243A (en) * 2019-12-23 2020-04-10 安徽微威环保科技有限公司 Wear-resistant rubber sealing strip material and preparation method thereof
CN112266511A (en) * 2020-10-30 2021-01-26 安徽中联汽车零部件有限公司 Preparation method of wear-resistant automobile Y-shaped rubber ring

Similar Documents

Publication Publication Date Title
CN106751700A (en) A kind of high abrasion high tenacity rubber seal
CN103360680B (en) Polypropylene and polyethylene Calcium carbonate filler master batch and preparation technology thereof
WO2018036431A1 (en) Modified nanocomposite silicone rubber seal ring and preparation thereof
CN104910447B (en) A kind of flame retardant rubber
CN104895297A (en) Anti-bacterial, anti-static and anti-corrosive rubber floor
US11067145B2 (en) Method for producing latex composition
CN107857897A (en) A kind of hindered phenol functionalization graphene and its preparation method and application
CN104293065A (en) Nano self-cleaning coating and preparation method thereof
CN105153497A (en) High-property modified nitrile butadiene rubber cable material used for ships
CN110964307A (en) Flame-retardant wear-resistant thermoplastic polyurethane composite material and preparation method thereof
CN106566239A (en) Carbon fibre reinforced PA66/PP electric power fitting material containing organic acid lanthanum salt, and preparation method thereof
CN106566241A (en) Insulation flame-retardant glass fiber reinforced PA66/PPS/PES power fitting material and preparation method thereof
CN106543713A (en) A kind of polytetrafluoroethylmodified modified wear-resisting type glass fiber reinforced PA66 electric armour clamp material and preparation method thereof
DE19629063A1 (en) Liquid silicone rubber with low compression set
CN108314989A (en) A kind of purification air-conditioning air hose fluid sealant and preparation method thereof
CN106243421A (en) A kind of preparation method of oil resistant modification composite environmental-friendly rubber substrate
CN106543718B (en) A kind of high flame retardant high temperature resistant nylon composite material and preparation method thereof
CN105949542A (en) High-temperature-resisting composite rubber damping material
CN115595686A (en) Warm-keeping functional polyester fiber and preparation method thereof
CN104497584A (en) Silicone rubber and preparation method thereof
CN106243420A (en) A kind of Antioxidant rubber material
CN111801379B (en) Latex and composite
CN106589738A (en) Fast-self-repairing shape memory polymer material
CN106543714A (en) A kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant and preparation method thereof
CN110776749A (en) Heat-conducting anti-static silica gel product and micro injection molding process thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170531

WD01 Invention patent application deemed withdrawn after publication